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Prarancangan Pabrik Dimetil Eter Dari Tandan Kosong Sawit (TKS) Menggunakan Proses Indirect Synthesis Dengan Disain Alat Utama Reaktor DME Ruth E. M. Sinaga; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 8 (2021): Edisi 2 Juli s/d Desember 2021
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

The need for renewable energy increases with the number of business and process that require biogas and dimethyl ether as the raw material in the manufacturing process. Dimethyl ether is widely used as refregerant, propellant in aerosol products, solvent, and extraction agent. The main raw materials used in manufacture of dimethyl ether by indirect synthesis process is palm empty fruit bunch. This plant is planned to operate for 330 days per year and work continuously for 24 hours/day with capacity of 50,000 ton/year which will be established in Dumai, Riau. The remaining time for 1 year of the operation process is used for shutdown, plant maintenance, maintenance and repair of equipment. The design of the main equipment in this plant is Dimethyl Ether fixed bed reactor which functions to generate dimethyl ether by methanol dehydration process. Reactor is operated at a pressure of 5 Bar and a temperature of 250 °C. The economic analysis on the design of this plant shows that the dimethyl ether plant from palm empty fruit bunch is feasible to be established with the profits that the plant gets after tax is Rp. 1,807,080,722/year and the plant's Payback Period (PBP) is 2.29 years. Keywords: Dimethyl Ether, Economic Analysis, Empty Fruit Bunch, Plant Design
Degradasi Zat Warna Methylene Blue Dengan Metode Fotofenton Menggunakan Katalis nano-Fe0@CS Rahman Fikri; Panca Setia Utama; Edy Saputra
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 8 (2021): Edisi 1 Januari s/d Juni 2021
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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In this study, nano-Fe0@CS were synthesized by hydrothermal method. Studied Methylene Blue (MB) degradation process and find the best composition of the degradation process. Catalytic performance of nano-Fe0@CS was tested in Phenton process for MB degradation in aqueous solution with H2O2 3%, and MB concentration variant. The best process conditions was observed by 99.99% removal of 30 ppm MB within 90 min with added 0.3 g/l nano-Fe0@CS and 2 ml H2O2 3% in 250 ml solution.Keywords: Degradation, Methylene Blue, nano-Fe0@CS, Phenton Process
Prarancangan Pabrik Dimetil Eter Dari TKS Dengan Proses Indirect Synthesis Dengan Disain Alat Utama Destilasi Metanol Muthia Anugerah Fitri; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 8 (2021): Edisi 1 Januari s/d Juni 2021
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Abstract

The use of LPG as a gas fuel is still needed by the community in various sectors, where in the future the needs of the community will increase as the industry progresses. One of the alternative fuels that can be developed as LPG substitution is Dimethyl Ether. Dimethyl Ether is produced through the process of synthesis and dehydration of methanol from natural gas. Natural gas is a natural resource that can not be renewed, so there are alternative raw materials that are renewable, one of which is empty palm bunches. The plant is planned to operate for 330 days per year and work continuously for 24 hours / day with a capacity of 50,000 tons / year to be established in Dumai, Riau. The main equipment design at the plant is methanol distillation operated at a pressure of 1 atm and feed temperature of 72,580C. Economic analysis of the plant's design shows that the ether dimethyl of empty palm bunches is feasible to be established with the profit the factory gets after tax is Rp. 90.354.036.131/year and payback period of 2,29 years Keywords : Dimethyl Ether, Economic Analysis, LPG, Natural Gas, Plant Design
Aktivitas Fotodegradasi Fenol Dengan Variasi Suhu Degradasi Menggunakan Komposit Tio2-Cnt(Cocopas) Nadhia Gasani Putri; Desi Heltina; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 7 (2020): Edisi 1 Januari s/d Juni 2020
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Phenols found in the wastewater of some industries have acute toxicity. The photocatalysis process can be used to degrade organic compounds such as phenols. To increase the photocatalytic activity of TiO2, a composite formation was formed between TiO2 and carbon nanotubes (CNT). Before being composited, CNT dispersion was carried out using cocoPAS surfactant as dispersing agent. The purpose of this study is to determine the effect of degradation temperature on phenol degradation. The process of making TiO2-CNT(cocoPAS) composites begins by dispersing CNT with cocoPAS surfactants and then composite with TiO2. Photocatalytic activity of the TiO2-CNT(cocoPAS) composite was tested at an initial phenol concentration of 30 ppm with variation of degradation temperature of 30,40 and 50ºC for 4 hours under UV light. Morphology of TiO2-CNT(cocoPAS) composites were characterized using SEM and phenol concentrations were characterized using a UV-Vis spectrophotometer. The highest degradation of phenols by TiO2-CNT(cocoPAS) composites at the initial phenol concentration of 30 ppm was at the degradation temperature of 50ºC, which was 35.59%.Keywords : photocatalysis, composite, TiO2, CNT, cocoPAS, phenol, temperature
Kuat Tekan Beton Pofa (Palm Oil Fuel Ash) Dengan Bahan Tambah Silica Fume Wulan Ramanda Putri; Panca Setia Utama; Monita Olivia
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 8 (2021): Edisi 1 Januari s/d Juni 2021
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Waste from processed palm oil is increasing over time. Palm Oil Fuel Ash (POFA) from boilers can be used as a substitute for cement in concrete because it contains silica and alumina. This study examines the optimum mix of cement replacement by Palm Oil Fuel Ash (POFA) and silica fume addition to the concrete mixture. The variables used are the variation of silica fume addition (0-15%) with the control concrete is PCC concrete. The concrete will be tested for its compressive strength and porosity at the age of 7 and 28 days after curing in plain water. Based on the test result, the control concrete's compressive strength was 21,74 MPa. The highest compressive strength was the concrete mixture without POFA replacement with 15% silica fume addition, the compressive strength is 26,83 MPa. It proves the addition of silica fume in concrete increases the compressive strength. Keywords: Concrete, POFA, silica fume, compressive strength.
Pengaruh Waktu Dan Konsentrasi Polietilen Glikol Dalam Proses Presipitasi Silika Dari Palm Oil Mill Fly Ash (POMFA) Fitriani Fitriani; Edy Saputra; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 1 Januari s/d Juni 2019
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Silica precipitation synthesis has been carried out from palm oil mill fly ash waste by using polyethylene glycol as dispersant. This study aims to determine the effect of time and concentration of polyethylene glycol (PEG) on yield and primary particle size of silica. The silica from POMFA was extracted with NaOH. The precipitation process was sodium silicate (Na2SiO3) added with PEG-400 then heated at 70°C, precipitated using CO2 impregnation of 300 ml / minute and mechanical fragmentation of 1000 RPM. The time was variation : 90, 120, 150 and 180 minutes and PEG concentrations was variation : 5%, 10%, 15% and 20%. The silica obtained is separated by filter paper and washed with warm distilled water and dry at 105°C until the weight is constant. The resulting silica was characterization XRD and XRF test to determine the composition and purity of silica. The best time obtained from the precipitation process was at 180 minutes with silica yield of 84.27%, and for the smallest diameter silica primary particle size was obtained with the use of 5% PEG is 19.11 nm.Keywords: Precipitation, Polyethylene Glycol, Silica, yield
Prarancangan Pabrik Dimetil Eter Dari Tandan Kosong Sawit (TKS) Menggunakan Proses Indirect Synthesis Dengan Disain Alat Utama Destilasi Dimetil Eter Nurrahmiati Nurrahmiati; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 8 (2021): Edisi 1 Januari s/d Juni 2021
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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The level of LPG demand is increasing every year, even the import of LPG has been carried out for a long time, but the need for LPG has not been fulfilled, this has led to the establishment of a Dimethyl Ether (DME) factory to cover LPG needs in Indonesia. DME can also be used as a propellant in aerosol form such as hairspray, insecticide, and air freshener. The main raw material used in the manufacture of DME is Oil Palm Empty Bunches (TKS). This factory is built with a capacity of 50,000 tons / year which will be established in Pelintung, Medang Kampai District, Dumai. The DME production process is carried out by the Indirect Synthesis process where DME is made through 2 processes, namely methanol synthesis from EFB and DME synthesis from methanol. Methanol synthesis and DME synthesis occur in 2 different reactors where methanol is first synthesized then dehydrated to DME. The main equipment design in this plant is the DME Distillation which functions to separate DME as the top product from Methanol and water as the basic product. The feed, distillate and bottom temperatures in this distillation tower are 48,10C, 33,70C and 231.40C with a pressure of 9 atm. , 97 m. Economic analysis on the design of this factory shows that this factory is feasible to be established with a factory Payback Period (PBP) of 2.29 years and a BEP at a capacity of 38%.  Keywords: Dimethyl ether, economic Analysis, empty palm fruit bunches
Pengaruh Laju Alir CO2 Dan Suhu Pada Proses Presipitasi Silika Dengan Menggunakan Dispersan Polietilen Glikol Novi Purnama; Edy Saputra; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 2 Juli s/d Desember 2019
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Precipitated silica can be synthesised from Palm Mill Oil Fly Ash (POMFA) by alkali extraction combined with sol-gel precipitation. Sodium hydroxide were used to extract silica from POMFA to produce sodium silicate. Silica was precipitated using CO2, the effect of CO2 flow rate and temperature on the precipitation process were studied. The CO2 flow rate of 100, 200, 300 and 400 mL/min and temperature of 60.70, 80, 90oC were used at the precipitation process, to enhance the characteristic of precipitated silica obtained, dispersant PEG-400 5% (v/v) was added. The CO2 flow rate was stopped when the silica began to precipitate and the stirring speed increase up to 1000 RPM for 90 minutes. Silica obtained, was separated from the filtrate using filter paper, washed with hot distilled water and then dried. The maximum yield of 81.01% was obtained at temperature of 70oC and a flow rate of 200 mL/min. The precipitated silica was characterised using XRF to determine silica composition and XRD to determine wether the precipitated silica is in amorphous form. The Scherrer equation was applied to estimate the primary particle diameter.Keywords: CO2, Precipitated, Silica, Temperature, Yield
Aplikasi Rsm Untuk Optimasi Suhu Dan Waktu Pada Proses Pelarutan Silika Dari Pomfa Dengan Reaktor Hidrotermal Eri Kaiyul; Edy Saputra; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 6 (2019): Edisi 1 Januari s/d Juni 2019
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Response Surface Methodology (RSM) is a set of mathematical and statistical techniques that are useful for analyzing problems where several independent variables influence response. The ultimate goal of RSM is for optimizing response. The aim of this study to determine the optimal process conditions in the silica extraction process from POMFA by using Response Surface Methodology (RSM). Silica was extracted by reacting fly ash with NaOH and aquadest. The optimized variables were temperature of 120°C (low) and 150°C (high) and time of 4 hour (low) and 6 hour (high). The silica extract was precipitated using HCl 10% at temperature of 30°C; stirring speed of 500 rpm and pH 9. The silica gel was analyzed using XRF to determine chemical composition. The silica yield were calculated from the chemical composition obtained. RSM-CCD was applied to optimize the extraction process using software Minitab 16.1.1.Keywords: extraction, optimum, POMFA, RSM, silica
Advanced Oxidation Process (AOP): Degradasi Zat Warna Rhodamin B Dengan Metode Fotokatalitik Menggunakan Katalis Covalent Triazine Framework (CTF) Andes Sagita; Edy Saputra; Panca Setia Utama
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 7 (2020): Edisi 2 Juli s/d Desember 2020
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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BPS recorded the export value of national textile products reached US$ 13.22 billion in 2018 and increased to US$ 15.73 in 2019. The problem that later arises was the textile waste generated by those industries. One of the methods for treating textile dye waste is the photocatalytic. The catalyst used in this study is the Covalent Triazine Framework (CTF), while the radiation comes from a 250 watt mercury lamp. The dye waste used is rhodamine B. The CTF catalyst synthesis was carried out by the ionothermal method at a temperature of 450oC and argon atmosphere for 18 hours. 1,4-dicyanobenzene used as monomer and ZnCl2 as molten salt, the two ingredients are mixed in a furnace cup with a weight ratio of 1: 8 (monomer: molten salt). The best photocatalytic results were shown by variations in the concentration of 1 g/l catalyst and 10 ppm of rhodamine B with a degradation efficiency of 94.790%.   Keywords: covalent triazine framework, ionothermal, textile, photocatalytic