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Journal : Bulletin of Chemical Reaction Engineering

Synthesis of SnO2 Nanoparticles by High Potential Electrolysis Fredy Kurniawan; Rahmi Rahmi
Bulletin of Chemical Reaction Engineering & Catalysis 2017: BCREC Volume 12 Issue 2 Year 2017 (August 2017)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (107.684 KB) | DOI: 10.9767/bcrec.12.2.773.281-286

Abstract

SnO2 nanoparticles have been synthesized by high voltage electrolysis. Tin bare was used for anode and cathode. The effect of potentials and electrolyte were studied. The particles obtained after electrolysis was characterized using X-ray Diffraction (XRD). The diffractogram is in agreement with the standard diffraction pattern of SnO2 which is identified as tetragonal structure. The Fourier Transform Infrared (FTIR) spectrum indicates that there is a vibration of Sn–O asymmetric at 580 cm-1. The optimum potential for SnO2 nanoparticles synthesis is 60 V at 0.06 M HCl which shows the highest UV-Vis spectrum. The absorption peak of SnO2 nanoparticles by UV-Vis spectrophotometer appears at about 207 nm. The particle size analysis shows that the SnO2 nanoparticles obtained have the size distribution in a range of 25-150 nm with the highest volume at 83.11 nm. 
Production of Hydrocarbon (C7-C20) from Hydrocracking of Fatty Acid Methyl Esters on Pd/Al-MCM-41 Catalyst Hendro Juwono; Triyono Triyono; Sutarno Sutarno; Endang Tri Wahyuni; Harmami Harmami; Ita Ulfin; Fredy Kurniawan
Bulletin of Chemical Reaction Engineering & Catalysis 2017: BCREC Volume 12 Issue 3 Year 2017 (December 2017)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (107.684 KB) | DOI: 10.9767/bcrec.12.3.811.337-342

Abstract

The production of hydrocarbon (C7-C20) and alcohol (C11-C19)  from fatty acid methyl esters (FAMEs) compound are produced from the transesterification of the seed oil of the Nyamplung that has been conducted by the catalytic hydrocracking using Al-MCM-41 and Pd2+-impregnated-Al-MCM-41 catalysts. The performance of catalysts were compared by various analysis including the acidity that was determined by pyridine and FTIR, the crystal structure observed by XRD, the surface area and pore volume analyzed by BET/BJH, the surface morphology observed by TEM, the metal on the surface of catalyst observed by XPS and the product of the hydrocracking analyzed by GC-MS. Hexagonal structure of the MCM-41(100) was shown in the 2θ = 3o-5o of the diffractogram. The presence of impregnated Al and Pd observed at the 2θ = 20o and 34o, respectively. The Pd/Al-MCM-41 catalyst was more acidic than Al-MCM-41 catalyst. The surface area and pore volume of the catalyst decreased after the impregnation process. The tendency of catalytic hydrocracking of hydrocarbon produced was indicated that more amount of Palladium have more hydrocarbons aliphatic than alcohol. 
Co-Authors ., Syukrianto ., Umarudin Abdullah Aman Damai Adi Prawito Adi Soeprijanto Alvin Juniawan Anang Maryanto Anggriawan, Wahyu Ardhelia Maura Felisia Ari Nugroho Arif Rachmat, Arif Arynta Dharmayanti, Arynta Atik Rohmana Maftuhatul Fuad Baginda Zulkarnain Bagus, Muhammad Bahrul Ulum Dennis Farina Nury Diah Ayu Restuti Wulandari Diah Susanti Dipta Nusbangga, Dipta Djarot Sugiarso Endang Tri Wahyuni Endang Tri Wahyuni Erna Rochana Estu Yoga Elmi Gesa Febri Hadi Fitriyana Fitriyana Fransisca Bangun, Yulia Frizka Vietanti Fuji Ridha, Fuji Galuh Tiara Dewi HANGGARA, ANGGY YOGA Hariyati Purwaningsih Harmami Harmami Harmami Harmami Harus Laksana Guntur Hatta, Agus Muhamad Hendro Juwono Hendro Juwono Hendro Juwono Hendro Sutowijoyo Ika Puspita, Ika Ikhsan Setiawan Imam Abadi Isa, Illyas Md Ismail Azizi Ita Ulfin Ita Ulfin Julistyana Tistogondo Karlinda Karlinda Kartika A. Madurani Kaskoyo, Hari Koespiadi Kolo, Maria Magdalena Lia Marisca Permatasari Lourentia Candle Lutfi Andre Yahya Madurani, Kartika Anoraga Mahendra Wardhana, Mahendra Mega Vania Misbah Misbah Mochammad Zaki Nasrulloh Mohammad Teguh Hermanto Muhammad Alwi Syahara, Muhammad Alwi Muhammad Rivai Ni'mah, Yatim NUR EFENDI Nyoman Agus Sandika Purnaman Palupi Irene Desilvia Pemal Kabogi Praditya Bagaskara Qonitah Fardiyah R. Djarot Rahadian Zainul Rahmi Rahmi Rajwa Abidah Sudjarwo Ramadhana Sangyang Ady Regina Tutik Padmaningrum Rika Wijiyanti, Rika Romadhona, Syahrur Rooslan Edy Santosa Safira Aulia Sayyida Sayyida Sekartedjo Koentjoro, Sekartedjo Selvi Marcellia Setyadi Laksono Bahar Silvya Anggraini Sri Wiwoho Mudjanarko, Sri Wiwoho Suharmanto, Edi Sunarto Sunarto Suprapto Suprapto Suprapto Suprapto Suprapto, Suprapto Sutarno Sutarno Sutarno Sutarno Suyanta Suyanta Syahputra, Muhammad Yudha Syukrianto, Syukrianto Taslim Ersam Tri Paus Hasiholan Hutapea, Tri Paus Hasiholan Tri Widjaja Triyono Triyono Triyono Triyono Umarudin, Umarudin Vietanti, Frizka Wahyu Anggriawan Yunia Anisa Putri Yunita Triana Yunita Triana Zeni Rahmawati Zulkarnain Zulkarnain