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Journal : Jurnal Spektra

Isothermal and non-isothermal crystallization Kinetic behavior of zinc-ferrite formation in theLow temperature flow injection co-precipitation synthesis reactor Sasito, Edie; Soegijono, Bambang; Manaf, Azwar
Jurnal Spektra Vol 14, No 2 (2013): Spektra: Jurnal Fisika dan Aplikasinya
Publisher : Jurnal Spektra

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Abstract

The kinetic behavior of zinc -ferrite crystallization process has been studied by co-precipitation of chlorine salt and alkaline solution. Either the parameter of temperature rate variation, pH previous of reactant and pH alkaline solution results non isothermal process was described by Ozawa equation,. There are significantly deferent in the taking both isothermal and non isothermal data. In the non- isothermal there are just oneexperiment can be sufficiency to reveal any crystal forming parameters but in the isothermal needs several different temperature experiments to reveals the parameter of crystal forming . In this research have be done one time non -isothermal experiment at means temperature 40 0C with temperature increase from 49 0C to 530C, and four time isothermal experiments at means temperature 60 0C,70 0C and 80 0C respectively. The sampling of experiment data have be done effectively using pH real- time video data logger. As a result the energy forming of the zinc ferrite both isothermal and non-isothermal are -4.27kcal/.mol,5.61kcal/mol respectively. The other kinetic parameter of crystallization and crystalline mechanism of both processes will be discussed.Keywords:co-precipitation, zinc-ferrite, non-isothermal process, crystallization, crystalline mechanism, data logger, kinetic behavior, flow injection co-precipitation synthesis.
Co-Authors Abdul Jami Adi Ganda Putra Agus Sukarto Agus Sukarto Ahmad Royani Akmal Johan Andreas Andreas Arbi Dimyati Arie Fiandimas Arieko Abdillah Asep Yudi Hercuadi Asep Yudi Hercuadi, Asep Yudi Bahfie, Fathan Bambang Soegijono Birawidha, David C Budhy Kurniawan Cahaya, Adam Badra Daulay, Amru Dedi Dedi Diah Susanti Djoko HP Doansi Tarihoran Dwita Suastiyanti Eddy Siradj Edie Sasito, Edie Eko Sulistiyono, Eko Elda Rayhana Elfrida Ratnawati Elisabeth A. S. Elsa Krisanti Erfan Handoko Erik Prasetyo Fajar Nurjaman Fajar Nurjaman Fathan Bahfie firdiyono, F Hafni Lissa Nuri Handoko, Djati Hasan Fahad Idris Novianto Iskandar Muda Iskandar Muda Iskandar Muda Lingga Hermanto Mabe Siahaan Manawan, Maykel Manawan, Maykel Marliyadi Pancoko Mas Ayu Elita Hafizah Maykel Manawan Mujamilah Mujamilah Mulyaningsih, Neng Nenden Musfirah Cahya Fajrah, Musfirah Cahya Nanang Sudrajat Nelson Saksono Nelson Saksono Novizal Novizal, Novizal Novrita Idayanti Nurul Taufiqu Rochman Nurul Taufiqu Rochman Pontas Sialagan Priyono K. Priyono P Priyono Priyono Rafael F Maniur Ridwan Ridwan Roekmijati Soemantojo Roekmijati Soemantojo, Roekmijati Roekmijati W. Roekmijati W. Soemantojo, Roekmijati W. Roekmijati Widaningroem Roekmijati Widaningroem, Roekmijati Roekmijati Widaningrum Roekmijati Widaningrum, Roekmijati Rudi Subagja Saptari, Sitti Ahmiatri Setijo Bismo Setijo Bismo Setyo Purwanto Setyo Purwanto Sialagan, Pontas Sipahutar, Wahyu Solafide Sri Mulyaningsih Sri Mulyaningsih Sukmara, Sony Suprihatin Suprihatin Taufik A. Bonaedy Tito Prastyo Rahman Tito Prastyo Rahman, Tito Prastyo Tri Haryono Ulin Herlina Valency, Tiara Wakid Ali Muntoha Widi Astuti Widi Astuti Wisnu A. Adi Wisnu Ari Adi Wisnu Ari Adi Wisnu Ari Adi Wisnu Ari Adi Yana Taryana Yuliana Sari Yuliusman Yuliusman Yuliusman Yuliusman Yuyu Wahyu