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Rumah Jurnal UIN Sunan Gunung Djati Bandung Jl. AH Nasution No.105 Cibiru, Bandung 40614
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Gunung Djati Conference Series
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ISSN : 27746585     EISSN : -     DOI : -
Core Subject : Religion, Economy, Science, Education, Agriculture, Social, Engineering,
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Gunung Djati Conference Series merupakan penyedia layanan publikasi dan konferensi berbagai bidang keilmuan yang diterbitkan oleh UIN Sunan Gunung Djati Bandung dan sebagai sarana publikasi hasil penelitian. Penerbit ini memuat artikel yang belum pernah dipublikasikan sebelumnya yang berupa artikel hasil penelitian ataupun penelitian terapan. Informasi mengenai pedoman penulisan artikel dan prosedur pengiriman artikel terdapat pada setiap penerbitan. Semua artikel yang masuk akan melalui ‘peer-review process’ setelah memenuhi persyaratan sesuai pedoman penulisan artikel, kemudian penerbit menyerahkan semua template ke pelaksana konferensi keilmuan. Penerbitan artikel ini dilakukan sesuai kegiatan yang dilaksanakan oleh penyelenggara konferensi.
Arjuna Subject : Umum - Umum
Articles 1,955 Documents
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Kestabilan Propoxur dalam Berbagai Solven Sebagai Upaya Pengurangan Resiko Keselamatan dan Lingkungan dengan Pendekatan Komputasi BADRA SANDITYA RATTYANANDA; CAHYONO DANANG PRASETYO; HASAN HARIRI
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Propoxur was an active ingredient of pesticide that was commonly used as an insecticide. In Indonesia, Propoxur was produced by PT. Inti Everspring Indonesia by reacting MIC with ortho-Isopropoxy phenol with xylene solvent. The use of xylene as a solvent can lead to bad consequences if not handled properly, ranging from harm to the body, flammable and can poison the environment. Therefore, it was necessary to conduct a study to replace xylene with other solvents that were less harmful and environmentally friendly. The research was conducted by simulating propoxur with ORCA software using the PBE method and the basis set 6-31G. After optimum structure obtained, the electronic energy in various solvents using implicite approach with the SMD method compared. The electronic energy obtained in the gas phase was -707.60003 eh. In polar solvents, the energy obtained were -707.61585 eh in water and -707.61548 eh in DMSO. In non-polar solvents, the energy obtained were -707.61512 eh for xylene, -707.61563 eh in Toluene, -707.61756 eh in Iodobenzen, and -707.61970 eh in Ortho-Dichlorobenzene (ODCB). For the solvent in the form of ionic liquid, it was found that -707.61602 eh for [EMIM][TfO] and -707.61392 eh for [BMIM][BF4]. From the simulation, it was found that xylene as propoxur solvent is possible to be replaced with benzene-derived solvents, namely Iodobenzene and ODCB. The ionic liquids usage for solvent was very possible to be developed in the future because it was more environmentally friendly even though the price is still very high. In the future, it was necessary to carry out further energetic studies to determine whether the change in solvency affects the activation energy and laboratory tests to follow up on these computational result
Studi Komputasi Energetika dan Mekanisme Reaksi Degradasi Pestisida Oxamyl di Lingkungan BADRA SANDITYA RATTYANANDA
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

The one of main problems in the agriculture field was the presence of pests that can cause crop failure. Pesticide was a chemical substance to accomplish the problem of attack from pests, one type that good enough was the pesticide formulation from oxamyl. Behind its efficacy to eradicate pests, oxamyl was banned in several countries due to environmental pollution issues. Therefore, it was necessary to do research that oxamyl can be degraded spontaneously in the environment. The research was conducted using ORCA 5.0.3 software to calculate the optimal structure using the PBE DFT functional and the 6-31G basis set. The structure that has been optimized with the implicit solvent water SMD method was continued with numerical frequency calculations because the inclusion of the SMD method can only be calculated numerically. Oxamyl degradation reaction occurs simultaneously by hydrolysis and reduction. Degradation with hydrolysis mechanism was endothermic and non-spontaneous at low temperatures, this degradation can be spontaneous when the temperature was increased to 94.4 °C or assisted by the presence of biocatalysts in the form of bacteria from the genus Pseudomonas to reduce activation energy. Degradation by reduction mechanism resulted in the values of G < 0, H < 0 and S > 0 which from these values can be predicted that the reaction will be exothermic and spontaneous at all temperatures. Furthermore, it was necessary to search for the transition state to determine the amount of activation energy of the degradation process. For research in the field, it was necessary to directly add a biocatalyst to optimize the degradation process because the reaction is not spontaneous and requires heat.
Adsorpsi Ion Logam Cd(II) oleh Selulosa Limbah Sabut Kelapa sebagai Adsorben Berbiaya Murah SHOFIA KHOERUNNISA SAEF; VINA AMALIA; ADI MULYANA SUPRIATNA
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Water will become polluted if the metal content of Cd(II) exceeds the threshold. Cd(II) levels can be reduced by adsorption in water using cellulose as an adsorbent and the adsorbent used is cellulose from coconut fiber. In this study, the synthesis of cellulose from coconut fiber was carried out, then characterized by FTIR and SEM to identify the functional groups and the structure of the coir adsorbent fiber. Subsequently, an analysis was conducted on the effect of the adsorbent performance in absorbing metal ions Cd(II), and the adsorption isotherm model was determined. Cellulose from coconut fiber was synthesized by drying in direct sunlight for 3 days, then activated with NaOH activator for 24 hours, and delignification method was carried out with 8% NaOH. The synthesis results were characterized using FTIR and SEM. Cellulose was applied by batch method on Cd(II) metal with mass variation (0,01-0,05 g), contact time variation (15-60 minutes), pH variation (3-7), and initial concentration variation (0,6-1,4 ppm) and determining the optimum conditions using the AAS instrumentation. Cellulose characterization was identified using FTIR indicating that there are functional groups in the form of C-O and C-O-C bonds, while from the results of SEM analysis, it is known that coconut coir cellulose has fiber for adsorption. Based on the results of the adsorption analysis of cellulose on metal Cd(II) showed the optimum results at an adsorbent mass of 0,05 g for 45 minutes at pH 7 and the initial concentration of Cd(II) used was 0,6 ppm. The isotherm-adsorption of Cd(II) metal on coconut coir cellulose followed the Langmuir isotherm model with R2 of 0,9524
Interaksi Asam Galat dan Metil Galat dari Tumbuhan Kasturi (Mangifera casturi) sebagai Inhibitor Protein Human Epidermal Growth Factor 2 (HER2): Evaluasi Molekular Docking NOER KOMARI; ROBIATUL ADAWIYAH; SAMSUL HADI; EKO SUHARTONO
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Kasturi (Mangifera casturi) is a endemic plant of Borneo. The polyphenol content of M. casturi leaves has antioxidant properties, including gallic acid and methyl gallic. The antioxidant potential of gallic acid and methyl gallate of M. casturi leaves is thought to inhibit the growth of breast cancer cells. Human Epidermal Growth Factor 2 (HER-2) protein is an important factor in the epidermal growth of breast cells and is also a target for breast cancer treatment. This study aims to investigate the potential of gallic acid and methyl gallic compounds from M. casturi as inhibitors of HER-2 protein. Molecular docking parameters in Gibbs free energy, interaction of gallic acid and methyl gallic ligands with HER-2 protein residues Kasturi (Mangifera casturi) is a endemic plant of Borneo. The polyphenol content of M. casturi leaves has antioxidant properties, including gallic acid and methyl gallic. The antioxidant potential of gallic acid and methyl gallate of M. casturi leaves is thought to inhibit the growth of breast cancer cells. Human Epidermal Growth Factor 2 (HER-2) protein is an important factor in the epidermal growth of breast cells and is also a target for breast cancer treatment. This study aims to investigate the potential of gallic acid and methyl gallic compounds from M. casturi as inhibitors of HER-2 protein. Molecular docking parameters in Gibbs free energy, interaction of gallic acid and methyl gallic ligands with HER-2 protein residues
Perbedaan Jumlah Sel Sertoli Pasca Pemberian Ekstrak Etanol Akar Purwoceng (Pimpinella alpina) ANNISA FARAH FADHILAH; FITRANTO ARJADI; NUR SIGNA AINI GUMILAS
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Paradoxical Sleep Deprivation (PSD) is one form of stress models in laboratory animals resulting in oxidative stress. Oxidative stress can decrease the number of Sertoli cells. Ethanol extract of purwoceng roots containing active substances for proliferation of Sertoli cells is expected to increase the number of Sertoli cells. Objective: To determine differences in the number of Sertoli cells after administration of ethanol extract of purwoceng roots in male rats after stress model of PSD induction. Method: This was an experimental research with posttest only with control group design. Thirty rats were divided into six groups: group A (negative control), group B (PSD with 7 days sleep recovery), group C (PSD), group D (PSD with 16.75 mg/ml/200grBB of ethanol extract of purwoceng roots), group E (PSD with 33.50 mg/ml/200grBB of ethanol extract of purwoceng roots), and group F (PSD with 50.25 mg/ml/200grBB of ethanol extract of purwoceng roots). Induction of PSD conducted for 96 hours and followed by administration of ethanol extract of purwoceng roots for 7 days. Result: The number of Sertoli cells in group A had the highest rates (29,17±3,58), followed by group D (28,77±3,16), group E (27,66±2,51), group B (27,45±1,45), group F (27,44±1,71), and group C (27,29±1,54). Kruskal-Wallis test showed the value of p=0,858. Conclusion: There was no significant difference in the mean number of Sertoli cells of male white rats after administration of various doses of ethanol extract of purwoceng roots.
Sintesis dan Karakterisasi Komposit Hidroksiapatit/Kitosan/Alginat sebagai Injectable Bone Substitute (IBS) RASMIYANTI; VINA AMALIA; SONI SETIADJI
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Cases of osteoporosis to cause bone damage such as fractures require bone surgery through autograft, allograft and xenograft methods. Injectable Bone Substitute (IBS) is a bone filling material in the form of a suspension or paste. In the case of osteoporosis, the IBS method can be overcome because it can adjust to the bone cavity to be filled. One of the materials that can be made in the form of IBS is hydroxyapatite (HAp). HAp has similar properties to bone, but HAp is easily brittle, so it needs to be modified in the form of a composite by adding alginate and chitosan to increase its hardness. This study aims to investigate the properties of HAp/chitosan/alginate composites in the form of IBS through viscosity test, injectability test, setting time test, and pore size test. The method used to synthesize HAp was a sol-gel and HAp/chitosan/alginate composite using the ex-situ method with a mass ratio of HAp:chitosan:alginate (60:10:30), (60:20:20), and (60:30:10) through the process of mixing alginate solution and chitosan solution for 120 minutes. The viscosity value is related to the percentage of injectability, which is 35 dPa.s to 41 dPa.s at room temperature and the percentage of injectability is 91.05% to 97.57%. The setting time test in the HAp substrate was able to experience setting within 3 hours 11 minutes to 3 hours 58 minutes and experienced weight gain. The IBS suspension composition (60:20:20) was able to reduce the pore size as indicated by the SEM results from 5.76 m to 4.28 m.The viscosity value is related to the percentage of injectability, which is 35 dPa.s to 41 dPa.s at room temperature and the percentage of injectability is 91.05% to 97.57%. The setting time test in the HAp substrate was able to experience setting within 3 hours 11 minutes to 3 hours 58 minutes and experienced weight gain. The IBS suspension composition (60:20:20) was able to reduce the pore size as indicated by the SEM results from 5.76 m to 4.28 m.
Analisis Pengaruh Konsentrasi Ragi dan Waktu Fermentasi Terhadap Nilai Gizi dan Aktivitas Antioksidan Tempe Kedelai Kombinasi Kacang Roay (Phaseolus lunatus L) AI PADHILAH FAUZIAH; ASEP SUPRIADIN; ASSYIFA JUNITASARI
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Tempeh is a fermented food product that has the potential as a source of antioxidants and contains several nutrients needed by the body. The existence of innovation in terms of raw materials, namely the addition of other types of beans such as lima beans (Phaseolus lunatus L) has the potential to minimize soybean imports from outside. There are two factors that can affect the quality of tempeh during the fermentation process, namely the concentration of added yeast and also the length of fermentation time, so it is necessary to do research on the effect of these two factors. The method used in this study was a Randomized Block Design (RBD) with 2 factors and 2 repetitions. The first factor is yeast concentration with 3 variations (1.5%, 2% and 2.5%) and the second factor is fermentation time with 3 variations (42 hours, 48 hours and 54 hours). Furthermore, the analysis of the influence of these two factors on nutritional value using the proximate method (including water content, ash content, fat content, protein content and carbohydrate content), antioxidant activity using the DPPH method and organoleptic tests. The results showed that the addition of yeast concentration and fermentation time had a significant effect on the nutritional value, antioxidant activity and organoleptic. The best treatment was obtained in soybean tempeh combination of lima beans with the addition of 2.5% yeast concentration and 42 hours fermentation time, namely water content 60.92%, ash content 0.76%, fat content 1.33%, protein content 31.45%. and carbohydrate content of 5.54%, antioxidant activity of 34.23% and based on organoleptic tests are preferred and acceptable among the public.
Pengaruh Konsentrasi Sorbitol terhadap Karakteristik Edible Film Pati Kentang (Solanum tuberosum L.) dan Pengaplikasiannya pada Dodol Nanas RIZKY RAMDHANI; VINA AMALIA; ASSYIFA JUNITASARI
Gunung Djati Conference Series Vol. 15 (2022): Prosiding Seminar Nasional Kimia Tahun 2022
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Plastic packaging on food has a negative impact on the environment because it is non-biodegradable. One way that can be done to overcome this problem is to replace plastic packaging on non-biodegradable food with biodegradable plastic, so that edible films are developed. An example of a material that can be used in the manufacture of edible films is potato starch. Edible films made of polysaccharides have low mechanical properties, so it is necessary to add a material that can improve the mechanical properties, namely plasticizer. The addition of sorbitol as a plasticizer is expected to improve the mechanical properties caused. In this study, the manufacture of edible films began with the extraction of potato starch, then added with sorbitol plasticizer with a concentration variation of 0.6; 0.9; and 1.2% (v/v). The edible film formed was then characterized by testing its physical and mechanical properties. Then applied as pineapple lunkhead packaging and hedonic organoleptic tests and descriptions were carried out. The addition of variations in the concentration of sorbitol affects the physical and mechanical properties caused. The morphology of the edible film was shown by SEM to determine the homogeneity of the mixture between starch and plasticizer. The best treatment in this study was edible film with the addition of 0.9% (v/v) sorbitol variation with a thickness of 0.0922 mm, tensile strength 9.84 MPa, elongation 16%, Young's modulus 0.615 MPa, and water uptake 111.39 %. The resulting edible film has a good level of homogeneity and a smooth surface. Application of edible film from potato starch as packaging on pineapple lunkhead can be accepted as an alternative packaging material for food based on organoleptic tests
Relevansi Aktivitas Bermain Kartu Huruf Terhadap Minat Baca Anak Usia Dini Hilman Mangkuwibawa; Yuyun Yulianingsih; Ade Rila Juliani
Gunung Djati Conference Series Vol. 13 (2022): The Conference on Islamic Early Childhood Education (CIECE)
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Landasan teori pada penelitian ini berdasarkan hasil yang didapat dari lapangan yang mana dalam pembelajaran aktivitas bermain kartu huruf sudah sangat efektif untuk digunakan, sejalan dengan peran siswa dalam pelaksanaannya, dimana permainan kartu huruf dapat menarik minat membaca anak. Tetapi dalam realitanya keinginan membaca pada anak dapat dikatakan masih lah rendah di tandai oleh kompetensi anak masih pada kisaran 20%. Karena ketertarikan yang belum terbagi secara merata. Penelitian ini menggunakan metode kuantitatif korelasional dengan observasi dan dokumentasi sebagai Teknik pengumpulan data. Selanjutnya hasil penelitian berada pada kategori sangat baik dalam interval 70-79, dan kategori sangat baik pun mewakili minat membaca pada anak dengan nilai 87,6 dalam interval 80-100. Hubungan antara aktivitas bermain kartu huruf dengan minat membaca pada anak usia dini di kelompok B RA Al-Falah Kecamatan Pangalengan Kabupaten Bandung dikategorikan sangat kuat atau sangat tinggi dengan harga korelasi 0,869 dan interval korelasi 0,800 – 1,000. Ativitas bermain kartu huruf pada anak usian dini memiliki peran sebesar 56% dengan 44% lainnya dikarenakan faktor lain
Pengaruh Metode Terapi ABA Dalam Meningkatkan Kemampuan Komunikasi Non Verbal Anak Autis Fadilla Ayuningtyas; Aam Kurnia; Ajeng Qisthy Islamadina
Gunung Djati Conference Series Vol. 13 (2022): The Conference on Islamic Early Childhood Education (CIECE)
Publisher : UIN Sunan Gunung Djati Bandung

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Abstract

Penelitian ini bertujuan mengetahui kemampuan awal komunikasi anak autis di Yayasan Pusppa Nadine Garut. Dasar pemikiran penelitian, melatih dan mengembangkan kemampuan komunikasi anak autis yang akan berpengaruh pada kemampuan komunikasi non verbal nya. Aspek perkembangan komunikasi non verbal yang akan dikembangkan yaitu kontak mata, mengangguk jika iya, menggeleng jika tidak, menunjuk benda sesuai perintah, melambaikan tangan, kiss bye, tos, ekspresi senyum, ekspresi menangis, ekspresi marah. Hipotesis penelitian adalah Ha: “Terdapat pengaruh penerapan metode terapi ABA dalam meningkatkan kemampuan komunikasi non verbal anak autis”. Ho: “Tidak terdapat pengaruh penerapan metode terapi ABA dalam meningkatkan kemampuan komunikasi non verbal anak autis”. Metode penelitian menggunakan pre-experimental dengan desain one group pretest-posttest. Subjek penelitian adalah siswa yayasan Pusppa Nadine Garut sebanyak 7 orang. Teknik pengumpulan data menggunakan penilaian unjuk kerja, observasi, dan studi literatur. Hasil penelitian yang diperoleh sebelum diterapkan terapi ABA (pretess) diperoleh nilai rata-rata sebesar 15,86 dan setelah diterapkan terapi ABA (posttest) sebesar 24,57 menunjukkan perubahan signifikan mengenai kemampuan komunikasi non verbal anak autis antara sebelum (pretest) dan sesudah (posttest) setelah diterapkan metode terapi ABA. Artinya terbukti bahwa metode terapi ABA berpengaruh dalam meningkatan kemampuan komunikasi non verbal anak autis di Yayasan Pusppa Nadine Garut

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