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PENGARUH PELAPISAN PERMUKAAN PARTIKEL SiC DENGAN OKSIDA METAL TERHADAP MODULUS ELASTISITAS KOMPOSIT Al/SiC Zainuri, M; Siradj, Eddy S; Priadi, Dedi; Zulfia, Anne; Darminto, Darminto
Makara Journal of Science Vol. 12, No. 2
Publisher : UI Scholars Hub

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Abstract

The Influence of Coating Oxide Metal on Surface of SiC Particles to Elastic Modulus of Al/SiC Composites. The isotropic composites of Al/SiC is made by powder metallurgy method, the quality of mechanical materials depend on interfacial bonding between matrix (Al) and reinforcement (SiC). The quality of interfacial bonding can influence to elastic modulus of composites which is made by solid process. SiC particles were coated by metal oxide aim to enhance quality interfacial bonding between matrix and reinforcement. These research using three kinds of coating materials, which are Mg oxide, Cu oxide and Al oxide, and these materials were deposited on surface of SiC particles. From three kinds of materials coating Al2O3 is the best to enhance quality interfacial bonding between matrix and reinforce than the others as CuO or MgO. There is Intermetalic phase formatted on CuO coating, and MgO coating have many porous where they can make decrease quality of Al-SiC composites. All of volume fraction of SiC on the Al/SiC composites, which oxide aluminum coating on SiC surface have highest value of elastic modulus than the others metal oxides.
Synthesis Optimization of Cathode Precursor Ni0,5 Mn0,4 Co0.1 (OH)2 with Coprecipitation Method Razak, Muhammad Abdul; Zulfia, Anne
Jurnal Pendidikan Teknologi Kejuruan Vol 6 No 1 (2023): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/jptk.v6i1.30523

Abstract

The use of conventional fuels such from fossils sourced is non-renewable energy, which makes this energy source less environmentally friendly. The battery that is nowadays used widely is the Lithium-Ion type with variations in the type of electrode. Electrodes have an important role in battery performance, especially at the cathode. Predecessor cathode types such as LiCoO2, LiMnO, and LiNiCo have various disadvantages due to their dangerous nature, insufficient capacity, and poor stability. NMC cathode (NiMnCo), in this case, NMC541 is presented to overcome these deficiencies. The process of making NMC541 cathode can be done by various synthesis methods, one of which is Co-precipitation. The synthesis parameter directly influences the performance of the cathode precursor produced, especially on its microstructure. For that, we try to optimize the synthesis parameters, such as Stirring Speed, and Aging time. The result said that samples with 900 Rpm stirring speed give the best product precursor along to their small size particle and good conductivity. Meanwhile, Aging co-precipitation doesn’t significantly affect coprecipitation precursor products.
Influence of Electrolyte Molarity and Applied Voltage on the Purification of Ferronickel by Electrolysis Method Astini, Vita; Meirawati, Selvia; Nengsih, Sulistia; -, Arif; -, Hasriyanti; Soedarsono, Johny Wahyuadi Mudaryoto; Zulfia, Anne
Metalurgi Vol 39, No 1 (2024): Metalurgi Vol. 39 No. 1 2024
Publisher : National Research and Innovation Agency (BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55981/metalurgi.2024.742

Abstract

The current advancements in the automotive industry highlight the critical need for electric vehicles, which require a reliable supply of nickel for battery production. A potential nickel source is Ferronickel's local content, which can be used as a secondary resource. However, research on converting smelted Ferronickel into electrolytic nickel is still limited. This study aims to examine the effects of electrolyte molarity and applied voltage during the electrolysis process for refining Ferronickel. The molarities of HCl employed in this research are 0.1, 0.25, 0.5, 0.75, and 1 M for 2 hours. Additionally, the molarities of HCl are set at 2, 3, and 4 M for 6 hours. Further experiments were performed using varying voltages of 1, 2, 4, 6, and 8 V while keeping the solution concentration constant at 1 M and maintaining an electrolysis duration of 2 hours. The electrolysis solution was subsequently analyzed using the AAS (atomic absorption spectrophotometry) test. The results indicated that higher molarity levels were associated with increased current, resulting in faster reaction rates and greater solubilization of nickel metal. The Ni concentration rose with higher molarity, increasing from 76.50 mg/L in .25 M HCl to 91.88 mg/L in 1 M HCl. In contrast, the Fe concentration remained nearly constant across various molarity levels, ranging from 11.81 mg/L in .25 M HCl to 11.95 mg/L in 1 M HCl, suggesting a minimal influence of molarity below 1 M. Fe exhibited a strong positive correlation with increasing electrolyte molarity, showing a significant rise in concentration from 49.06 g/L at 2 M to 90.17 g/L at 4 M. Ni showed a more modest response to elevated molarity, with concentrations increasing from 11.95 g/L at 2 M to 22.70 g/L at 4 M. The Ni concentration increased with the applied voltage up to 6 V, reaching 95.57 mg/L, but then decreased to 77.67 mg/L at 8 V, indicating that the optimum voltage is 6 V. The Fe concentration displayed slight fluctuations but remained relatively stable across different voltage levels, measuring 11.81 mg/L at 1 V and 12.28 mg/L at 8 V, indicating that the applied voltage does not significantly influence Fe concentration in the solution.
Enhancing laminate composites: Investigating the impact of kevlar layering and titanium carbide nanoparticles Oktaviani, Adinda; Zulfia, Anne; Rahmadiawan, Dieter
Teknomekanik Vol. 6 No. 2 (2023): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/teknomekanik.v6i2.26572

Abstract

The quest for innovative and superior materials is a challenge in the realm of materials science and engineering. Traditional materials often fall short in meeting the demands of modern industries, especially in the military. Technological developments in the military domain are still progressing, one of which involves a new material for combat vehicle applications: a laminated composite. In this research, a composite consisting of AA7075 sheet metal and kevlar with epoxy resin and TiC nanopowder were prepared. A test was conducted to assess its performance in absorbing ballistic energy from projectiles. Solid Thickening Fluid (STF) was created by mixing TiC nanopowder with PEG-400 through 2 hours of stirring. The laminate composite structure was prepared using the hand layup method, followed by a drying process at room temperature. The addition of kevlar layers yielded promising results in the ballistic and impact tests, as the diameter of the perforation decreased progressively with each additional kevlar layer. The IK sample impact test value improved by 35.7% compared to the unimpregnated one. The production process of this material also consumes minimal energy, which suggest a potential for environmental sustainability.
A Comparative Study of LiNCA Cathode Recycled from Spent Lithium-Ion Batteries and Synthesized from Metal Precursor Jumari, Arif; Apriliani, Enni; Yudha, Cornelius Satria; Purwanto, Agus; Syahrial, Anne Zulfia; Pita Rengga, Wara Dyah
Indonesian Journal of Chemistry Vol 24, No 6 (2024)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.98276

Abstract

Spent lithium NCA (LiNCA) battery was recycled using organic and inorganic acids and the performances were compared against the cathode synthesized from precursor. The metals in the spent cathode were leached using sulfuric or citric acid and coprecipitated into ternary metal oxalate (TMO) after reduction and lithium separation. Subsequently, the coprecipitated solution was used for cathode synthesis. Leaching efficiencies for nickel, cobalt and aluminum using citric acid were 85.6, 94.1, and 99%, respectively, while the efficiencies using sulfuric acid were 96, 98, and 100%, respectively. TMO produced from coprecipitation had the same physical characteristics. It was important to acknowledge that all cathodes also had similar physical characteristics. The electrochemical tests showed that commercial cathodes had the highest capacity of 150 mAh/g. This was followed by those from precursors, sulfuric acid leaching, and citric acid leaching, which recorded 142, 135, and 130 mAh/g, respectively. Based on the cycle test at 1C, the sample from citric acid leaching was 86% after 20 cycles compared to others at 82–83%. The results suggested that spent LiNCA could be regenerated into new cathodes using acid with performance comparable to those synthesized from precursor. This presented a viable alternative for LiNCA cathode synthesis.
Optimization of NMC811 Synthesis via Oxalate Coprecipitation Method for Lithium-Ion Battery Cathode Angellinnov, Fiona; Subhan, Achmad; Priyono, Bambang; Syahrial, Anne Zulfia
Metalurgi Vol 39, No 2 (2024): Metalurgi Vol. 39 No. 2 2024
Publisher : National Research and Innovation Agency (BRIN)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55981/metalurgi.2024.759

Abstract

NMC811 was synthesized through the oxalate coprecipitation method, followed by the solid-state method of lithiation. Stirring speed (500, 750, 1000 rpm), aging time (0, 3, 5h), sintering atmosphere (with and without oxygen flow), sintering temperature (700, 750, 800 °C), and lithium concentration (0, 2, 5% excess) effect on the NMC811 were examined. Characterization results showed that the optimum stirring speed and aging time are 750 rpm and 3 hours. Based on structural analysis, the best condition for sintering is in oxygen atmospheres at 800 °C with a lithium concentration of 2% excess. NMC811, synthesized with these optimum parameters, provided a 212.93 mAh/g capacity. These findings deliver insight into NMC811 synthesis optimization.
DESIGN AND SELECTION OF PADDLE MATERIALS FOR HIGH-LEVEL ROWING COMPETITION APPLICATIONS USING MULTI-CRITERIA DECISION ANALYSIS Nurfitrah, Aditya Eka; Riva Nanda, Iksan; Syahrial, Anne Zulfia
Indonesian Physical Review Vol. 8 No. 1 (2025)
Publisher : Universitas Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/ipr.v8i1.355

Abstract

The study evaluated a variety of material alternatives including wood, bamboo, carbon fiber reinforced polymer (CFRP), and ceramics for use in high-performance paddleboard. The selection process considers factors such as strength, density, cost, and durability with a focus on the most relevant material criteria for the product. The weighted addition method is used to evaluate and rank several alternative materials that have been selected based on these criteria. Wood and bamboo are chosen for their sustainability, CFRP for their superior strength-to-weight ratio, and ceramics for their resistance to extreme conditions. The study found that CFRP had the highest score of around 85.40 due to its superior strength and lightweight. The framework proposed in this study could provide tools for rowing teams to optimize paddle materials so that they offer the potential for increased speed and performance in the competition.  
Synthesis Optimization of Cathode Precursor Ni0,5 Mn0,4 Co0.1 (OH)2 with Coprecipitation Method Razak, Muhammad Abdul; Zulfia, Anne
Jurnal Pendidikan Teknologi Kejuruan Vol 6 No 1 (2023): Regular Issue
Publisher : Universitas Negeri Padang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24036/jptk.v6i1.30523

Abstract

The use of conventional fuels such from fossils sourced is non-renewable energy, which makes this energy source less environmentally friendly. The battery that is nowadays used widely is the Lithium-Ion type with variations in the type of electrode. Electrodes have an important role in battery performance, especially at the cathode. Predecessor cathode types such as LiCoO2, LiMnO, and LiNiCo have various disadvantages due to their dangerous nature, insufficient capacity, and poor stability. NMC cathode (NiMnCo), in this case, NMC541 is presented to overcome these deficiencies. The process of making NMC541 cathode can be done by various synthesis methods, one of which is Co-precipitation. The synthesis parameter directly influences the performance of the cathode precursor produced, especially on its microstructure. For that, we try to optimize the synthesis parameters, such as Stirring Speed, and Aging time. The result said that samples with 900 Rpm stirring speed give the best product precursor along to their small size particle and good conductivity. Meanwhile, Aging co-precipitation doesn’t significantly affect coprecipitation precursor products.
Co-Authors Abdul Aziz Ammar Achmad Subhan Achmad Subhan Agus Pramono AGUS PURWANTO Agus Sudjatno Agus Sukarto Agus Sukarto W Ahmad Taufik Akhmad Herman Yuwono Alexey Glushshenkov Alfaruq, Subkhan Alfirano Alfirano Ali Alhamidi Angellinnov, Fiona Anistasia Milandia Apriliani, Enni Ari Uliana Arif Arif Astini, Vita Bambang Prihandoko Bambang Priyono Bambang Priyono Bambang Suharno Bintang Adjiantoro D.N. Haerani Darminto . Darminto . Dedi Supriadi Dwi Marta Nurjaya, Dwi Marta Eddy S Siradj Eddy S. Siradj Efendi Mabruri Effendi Mabruri Ekavianti Prajatelistia Evvy Kartini Evvy Kartini Evvy Kartini Evvy Kartini Evvy Kartini Evvy Kartini Fadli Robby, Fadli G.N. Anastasia Sahari Ghiska Ramahdita Hanuna Haritsah Hasriyanti Hasriyanti Heri Jodi Heri Jodi Heri Jodi, Heri I Komang Astana Widi I Nyoman Jujur Indra Gunawan Ismojo Ismojo Jarot Raharjo johansyah johansyah Johny Wahyuadi Soedarsono Juliadi Juliadi Jumari, Arif Kirman Kirman, Kirman Kirman M. Lestari, Yulinda Lilis Mariani Lilis Mariani, Lilis Luh Putu Ratna Sundari M. Zainuri Mabruri, Effendi Mario Marfelly, Mario Meirawati, Selvia Melisa Melisa Moch Ardi Dimastiar Mochamad Chalid Muhammad Wira Akira Muhammad Yunan Hasbi Myrna Ariati, Myrna Nanik Indayaningsih Nasution, Annio Indah Lestari Nengsih, Sulistia Nofrijon Sofyan, Nofrijon Nurfitrah, Aditya Eka Nurul Huda Oktaviani, Adinda Priyo Sardjono Rahmadiawan, Dieter Ratna Juwita Razak, Muhammad Abdul Rd. Panji Maulana Riva Nanda, Iksan Sahari, G.N. Anastasia Salahuddin Junus Sibut Sotya Astutiningsih Subkhan Alfaruq Sudirman Sudirman Supardi Supardi Taufik Abimanyu Taufik Abimanyu, Taufik Verina Dalam Verina Dalam, Verina Wahid Muhamad Furkon Rahmatulloh, Wahid Muhamad Furkon Wahyudianingsih Wahyudianingsih Wara Dyah Pita Rengga Wayan Sujana Widyastuti . Widyastuti Widyastuti Yudha, Cornelius Satria Yudhistira Adityawardhana Yulinda Lestari Yustinus Purwamargapratala Zainuri, M