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Journal : VALENSI

Zeolit Sintetis Terfungsionalisasi 3-(Trimetoksisilil)-1-Propantiol sebagai Adsorben Kation Cu(II) dan Biru Metilena Sri Sugiarti; Charlena Charlena; Nurul Afiati Aflakhah
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 3, No. 1, Mei 2017
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v3i1.5144

Abstract

The more commonly used method for making synthetic zeolite from kaolin is hydrothermal method. This research tested a sol-gel method in processing synthetic zeolit  using kaolin as the basic ingrediant. The synthetic  zeolite  derived from the sol-gel method was then characterized using X-ray Difractometer and Scanning Electron Microscope, which found resulting products zeolite-A, zeolite Y and sodalite. The adsorption ability of the synthetic zeolites was tested using Cu(II) and methylene blue.  Functionalization of the synthetic zeolites by 3-(trimetoksisilil)-1-propantiol was  done to increase adsorption capacity. Zeolite A modified by 3-(trimetoksisilil)-1-propantiol  had the greater capacity to adsorb methylene blue at 30.11 mg/g. The adsorption isotherms of all the synthetic zeolites approached the Langmuir form. The adsorption energy off all synthetic zeolites approached the chemical adsorption.DOI: http://dx.doi.org/10.15408/jkv.v0i0.5144
Synthesis and Characterization of Hydroxyapatite from Green Mussel Shell with Sol-Gel Method Charlena Charlena; Akhiruddin Maddu; Tatang Hidayat
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 8, No. 2, November 2022
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v8i2.27494

Abstract

Hydroxyapatite (HAp) is a major component of bones and teeth. HAp is widely used to repair, fill, extend, and reconstruct damaged bone tissue. HAp is used for bone and dental implants, so it is necessary to synthesize HAp. HAp synthesis can utilize green mussel shell waste as a calcium precursor. This research synthesized HAp from a green mussel shell using the sol-gel method. The controlled synthesis parameter was pH, and the variable being compared was the heating temperature at 900 and 1100 °C. The HAp products were characterized by an X-ray diffractometer (XRD), Fourier-transform infrared spectrophotometer, and scanning electron microscope. The results showed that HAp was formed at alkaline pH, namely at pH 11. The XRD pattern showed that Hap was formed along with type A apatite carbonate, octacalcium phosphate, α- and β-tricalcium phosphate. The crystallinity was increased by raising the temperature and prolonging the heating time. The quality of HAp will improve with increasing crystallinity, and increasing the temperature will also raise the amount of HAp formed.