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Optimum Temperature and Time for Acid Hydrolysis in Reducing Sugar Manufacturing from Arabica Coffee Cascara with Response Surface Methodology (RSM) Suryati, S; Meriatna, M; Masrullita, M; Safriwardy, Ferri; Ardiansyah, Ardiansyah
International Journal for Educational and Vocational Studies Vol 3, No 2 (2021)
Publisher : Universitas Malikussaleh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29103/ijevs.v3i2.4666

Abstract

This research aims to utilize the Arabica coffee cascara waste as a resource for reducing sugar production, including the investigation on the temperature and time required of the acid hydrolysis. The samples were initially pretreated (drying and milling), followed by delignification with the organosolv technique using alcohol. Then, the hydrolysis was carried out using sulfuric acid (1%) at a particular temperature (95, 100, and 105 °C) and time (2, 4, and 6 h) variations. Yield percentage, density, and reducing concentration were analyzed in each trial to generate a response surface methodology model. Based on the results, the hydrolysis can be optimized at 96.46 °C for 2.59 h, yielding 16.7696% reducing sugar.
Pemanfaatan Jerami Padi (Oryza Sativa L.) Sebagai Bahan Baku Dalam Pembuatan CMC (Carboximetil Cellulose) Masrullita Masrullita; Meriatna Meriatna; Zulmiardi Zulmiardi; Ferri Safriwardy; Auliani Auliani; RIZKA NURLAILA
Jurnal Rekayasa Proses Vol 15, No 2 (2021)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.69569

Abstract

Rice straw is a waste from rice plants that contains 37.71% cellulose, 21.99% hemicellulose, and 16.62% lignin. High cellulose content in rice straw can be used as raw material for the manufacture of Carboxymethyl Cellulose (CMC). CMC is a cellulose derivative widely used in food, pharmaceutical, detergent, textile and cosmetic products industries as a thickener, stabilizer of emulsions, or suspensions and bonding. This study aims to process rice straw waste into CMC with variations in sodium monochloroacetate of 5,6,7,8 and 9 grams. The method used in this research is by synthesis using 15% NaOH solvent, with a reaction time of 3.5 hours and 5 grams of rice straw. The results showed that the best CMC was obtained at a concentration of 9 grams of sodium monochloroacete with a yield characterization of 94%, pH 6, water content of 13.39%, degree of substitution (Ds) of 0.80, and viscosity of 1.265 cP.
Pemanfaatan Jerami Padi (Oryza Sativa L.) Sebagai Bahan Baku Dalam Pembuatan CMC (Carboximetil Cellulose) Masrullita Masrullita; Meriatna Meriatna; Zulmiardi Zulmiardi; Ferri Safriwardy; Auliani Auliani; RIZKA NURLAILA
Jurnal Rekayasa Proses Vol 15, No 2 (2021)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.69569

Abstract

Rice straw is a waste from rice plants that contains 37.71% cellulose, 21.99% hemicellulose, and 16.62% lignin. High cellulose content in rice straw can be used as raw material for the manufacture of Carboxymethyl Cellulose (CMC). CMC is a cellulose derivative widely used in food, pharmaceutical, detergent, textile and cosmetic products industries as a thickener, stabilizer of emulsions, or suspensions and bonding. This study aims to process rice straw waste into CMC with variations in sodium monochloroacetate of 5,6,7,8 and 9 grams. The method used in this research is by synthesis using 15% NaOH solvent, with a reaction time of 3.5 hours and 5 grams of rice straw. The results showed that the best CMC was obtained at a concentration of 9 grams of sodium monochloroacete with a yield characterization of 94%, pH 6, water content of 13.39%, degree of substitution (Ds) of 0.80, and viscosity of 1.265 cP.
UJI MEKANIK KOMPOSIT SERAT DAUN NENAS BERMATRIK RESIN GETAH PINUS Zulmiardi Zulmiardi; Muhammad Sayuthi; Ferri Safriwardy; Meriatna Meriatna
Jurnal Teknologi Kimia Unimal Vol 10, No 1 (2021): Jurnal Teknologi Kimia Unimal - Mei 2021
Publisher : LPPM Universitas Malikussaleh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29103/jtku.v10i1.4160

Abstract

Penelitian ini bertujuan untuk menguji pemakaian serat daun nenas terhadap kekuatan tarik komposit berpenguat resin getah pinus pada kondisi beban tarik optimum untukmenghasilkan kekutan tarik pada masing-masing variasi arah serat acak dan ayaman. Penelitian dilakukan secara kontinyu dengan alat mesin uji tarik Multi Testing Machine (MTM). Variabel yang digunakan serat susunan acak dan anyaman dengan   ststandar specimen ASTMD 638-02 tipe 4 dengan dimensi specimen ( p= 110 cm, L = 19 cm, dan tebal t = 5 cm). Pengujian yang dilakukan pada penelitian ini antara lain pengujian tarik berdasarkan susunan laminat acak, anyaman dan photomakro. Hasil yang didapatkan dalam penilitian ini, susunan manufaktur yang tepat pada komposit serat nanas dengan susunan laminat acak dengan  nilai kekuatan tarik rata-rata  sebesar  148.14 MPa, sedangkan untuk susunan anyaman memiliki kekuatan tarik 112.26. Hasil penilitian ini kekuatan tarik optimasi fraksi volume 20%, 30% dan 40% bermatrik resin getah pinus dapat di ketahui bahwa susunan laminat acak lebih unggul dari susunan anyaman. Hasil photomakro pada penampang patahan komposit serat  nanas terdapat karakteristik patahan yang khas yaitu terdapat serabut serat yang tertarik keluar (Fiber Pull Out).
EFEKTIVITAS KARBON AKTIF KULIT SINGKONG (Manihot Esculenta Crantz) TERHADAP ADSORPSI ION LOGAM Fe2+ DENGAN AKTIVATOR NaOH Masrullita Masrullita; Yogi Ardhika Wijaya; Novi Sylvia; Ferri Safriwardy
Jurnal Teknologi Kimia Unimal Vol 10, No 2 (2021): Jurnal Teknologi Kimia Unimal - Nopember 2021
Publisher : LPPM Universitas Malikussaleh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29103/jtku.v10i2.5550

Abstract

Salah satu pencemar yang berbahaya dalam limbah buangan industri yaitu logam berat besi (Fe2+). Banyak teknik pengolahan yang dilakukan untuk mwnurunkan kadar logam berat besi. Salah satunya diantaranya adalah dengan teknik adsorbs.  Adsorpsi sering digunakan karena prosesnya yang sederhana dan efektif untuk mengurangi kadar logam berat. Penelitian ini bertujuan untuk menganalisis efektifitas karbon aktif kulit singkong sebagai adsorben pada penyerapan logam besi (Fe2+), mengkaji pengaruh waktu kontak dan variasi konsentrasi aktivator terhadap daya serap besi (Fe2+) serta mekanisme penyerapan melalui metode pendekatan isotherm adsorpsi Freundlich dan Langmuir. Penelitian ini dilakukan dengan suhu karbonasi 300 ºC selama 2 jam dengan variasi konsentrasi aktivator 10%, 20%, 25%, dan 30% serta memvariasikan waktu kontak selama 30, 60, 90, dan 120 menit. Hasil yang diperoleh adalah, % efisiensi adsorpsi maksimum yaitu 94,07% serta kapasitas adsorpsi maksimum yaitu 470,35 mg/g pada konsentrasi aktivator 30% dan waktu kontak 120 menit. Mekanisme adsorpsi yang terjadi mendekati persamaan isotherm Langmuir dengan nilai R2 = 0,9999, diduga proses penyerapan terjadi secara kimisorpsi monolayer. Dari hasil yang diperoleh dapat disimpulkan bahwa semakin lama waktu kontak dan semakin tinggi konsentrasi aktivator maka semakin tinggi kapasitas adsorpsi dan % efisiensi adsorpsi Fe2+ yang diperoleh.
Pemanfaatan Buah Pepaya Menjadi Abon Nabati di Desa Paloh Lada Kecamatan Dewantara Kabupaten Aceh Utara Rizka Nurlaila; Masrullita; Meriatna; Ferry Safriwardy
Jurnal Pengabdian Kepada Masyarakat Abdi Putra Vol 2 No 1 (2022): Januari 2022
Publisher : Universitas Nusa Putra & Persatuan Insinyur Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (477.466 KB) | DOI: 10.52005/abdiputra.v1i3.103

Abstract

Abon adalah makanan yang dibuat dari suiran daging yang dimasak sampai kering dan awet disimpan selama berminggu-minggu hingga berbulan-bulan dalam kemasan kedap udara. Abon juga dapat dibuat dari sumber nabati seperti pepaya. Dalam jangka panjang diharapkan kelompok PKK dan masyarakat setempat termotivasi untuk menjadikan usaha produk abon pepaya menjadi industri rumah tangga (home industri). Tujuan dari pelaksanaan kegiatan ini adalah memberikan pengetahuan pengolahan hasil-hasil pertanian khususnya buah pepaya yang dapat dijadikan abon nabati dan meningkatkan pendapatan masyarakat. Target khusus yang ingin diharapkan dari kegiatan ini adalah timbulnya motivasi dan keinginan unutk berwirausaha mandiri pada masyarakat Desa Paloh Lada Kecamatan Dewantara Kabupaten Aceh Utara untuk memanfaatkan daging buah pepaya yang dijadikan abon. Hasil dari kegiatan ini adalah kelompok PKK dan masyarakat telah mampu unutk membuat abon nabati dari pepaya dan mengemasnya untuk meningkatkan nilai ekonomis.
Penyelenggaraan Pendidikan Berbasis Model Edutechnopreneur Islami Siraj Siraj; Taufiq Taufiq; Ferri Safriwardy
Journal on Education Vol 5 No 3 (2023): Journal on Education: Volume 5 Nomor 3 Tahun 2023
Publisher : Departement of Mathematics Education

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31004/joe.v5i3.1875

Abstract

Islamic character values should be the spirit that colors all aspects of education delivery, both in class-based learning, the climate of school life, and in the context of interaction with community life in general integrated into learning starting from planning, implementing, and evaluating in accordance with the characteristics of Basic Competencies (KD). Learning at SMK needs to be designed in accordance with the demands of the curriculum in an effort to instill islamic values through the practice of production-based training / production-based education and training learning and Islamic Edutechnopreneur. The purpose of this study is to describe the model of providing education based on the Islamic Edutechnopreneur model. This research uses a qualitative approach. The importance of this research is carried out because vocational and school teachers really need a model of providing education based on Islamic Edutechnopreneurs and their implementation in school life. The results showed that the success of the Edutechnopreneur production unit at SMK Negeri 7 Lhokseumawe really depends on the management implemented in the school. Therefore, it is important to strengthen the management of SMK so that the Islamic Edutechnopreneur production unit can be developed in an effort to strengthen the competitiveness of graduates. Teachers are an important resource, participating teachers in various trainings that allow them to develop in mastery of competencies and achieve increased insight and entrepreneurial skills.
Pengaruh Perbandingan Waktu Delignifikasi Dan Konsentrasi NaOH Dalam Pembuatan Gula Reduksi Dari Kulit Kopi Arabika (coffea Arabica) Masrullita Masrullita; Suryati Suryati; Tiara Rozah; Ferri Safriwardy
Jurnal Teknologi Kimia Unimal Vol 12, No 1 (2023): Jurnal Teknologi Kimia Unimal - Mei 2023
Publisher : Chemical Engineering Universitas Malikussaleh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29103/jtku.v12i1.11640

Abstract

Kopi  adalah  salah  satu  tanaman  yang  menghasilkan  produk  samping dalam  proses  pengolahannya yakni  kulit  kopi. Tujuan penelitian ini adalah untuk mengkaji pengaruh waktu delignifikasi dan konsentrasi NaOH pada hasil gula reduksi. Penelitian ini sudah banyak dilakukan sebelumnya menggunakan pelarut etanol dan asam kuat, yang belum dilakukan adalah menggunakan pelarut basa kuat. Penelitian ini menggunakan pelarut NaOH untuk mendegradasi lignin yang terdapat pada bahan baku. Pada proses pretreatment fisika kulit kopi dibersihkan lalu dimasukkan kedalam oven selama 24 jam, tujuannya untuk menghilangkan kadar air, kemudian dihaluskan menggunakan blender agar diperoleh hasil berbentuk serbuk. Proses delignifikasi menggunakan metode organosolv dengan variasi konsentrasi NaOH 1%, 3%, 5% dan 7% dengan variasi waktu delignifikasi 30 menit, 60 menit, 90 menit dan 120 menit. Proses hidrolisis menggunakan katalis H2SO4 1% pada suhu 100oC  selama 4 jam, kemudian diuji yield, densitas dan kadar gula reduksi menggunakan metode luff schrool untuk mengetahui berapa banyak kadar gula reduksi pada kulit kopi arabika. Kadar gula reduksi tertinggi terdapat pada konsentrasi NaOH 7% dan waktu delignifikasi 120 menit sebesar 68,28%. Yield tertinggi terdapat pada konsentrasi NaOH 7% dan waktu delignifikasi 120 menit sebesar 60,98%. Densitas tertinggi terdapat pada konsentrasi NaOH 7% dan waktu delignifikasi 120 menit sebesar 0,985 g/cm3. Hasil penelitian menunjukkan semakin besar konsentrasi NaOH dan lama waktu delignifikasi maka kadar gula reduksi yang dihasilkan akan semakin banyak.
Synthesis Carboxyl Methyl Cellulose (CMC) from Rice Straw (Oryza Sativa L.) Waste Masrullita, Masrullita; Nurlaila, Rizka; Zulmiardi, Zulmiardi; Safriwardy, Ferri; Auliani, Auliani; Meriatna, Meriatna
International Journal of Engineering, Science and Information Technology Vol 2, No 1 (2022)
Publisher : Department of Information Technology, Universitas Malikussaleh, Aceh Utara, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (553.889 KB) | DOI: 10.52088/ijesty.v2i1.200

Abstract

Rice straw is one of material containing cellulose to produce Carboxymethyl Cellulose (CMC). CMC is a non toxic polysaccharide that produces from cellulose that widely used in the pharmaceutical, food, textile, detergent, and cosmetic products industries. There are two stages usually use to produce CMC which are mercerization and esterification processes. Rice straw waste is one of the materials to produce CMC, it has a cellulose content of 37.7%, hemi-cellulose 21.99%, and lignin 16.62 %.  BPS Aceh shown that the total rice harvested area was 310.01 hectares, with a total production of 1.71 million tons, and rice produced at 982.57 thousand ton. This study aims to reduce waste and environmental pollution caused by rice straw and collects information of rice straw as a basic material to produce of carboxymethyl cellulose and to increase the economic value of rice straw.  The effects of various wieght parameters sodium monochloroacetate on chemical properties of CMC that produce from rice straw were investigated in this research. Rice straw was collected from a rice field in Nisam, North Aceh. The research conducted by synthesizing 5 grams rice straw for 5.5 hours using NaOH and Sodium Monochloroacetate solutions. With variations weight of sodium monochloroacetate are 5,6,7,8 and 9 grams. The characterization of CMC was carried out by Fourier Transform Infrared (FTIR), CMC yield, DS, Viscosity, water content, pH. The result shows that addition of sodium monochloroacetate was significant factors influence the chemical properties on CMC. The CMC that produced in this study achieved to National Indonesia Standard (SNI).
Analysis of tensile strength of composite fiber reinforced with areca Nut Skin Fiber using BQTN 157 EX Resin Safriwardy, Ferri; Rizki, Muhammad Nuzan; Masrullita, Masrullita; Simbolon, Muhammad Iqbal
International Journal of Trends in Mathematics Education Research Vol 6, No 4 (2023)
Publisher : SAINTIS Publishing

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33122/ijtmer.v6i4.284

Abstract

In the development of materials science, especially polymers, natural fibers such as areca nut shell fiber are increasingly attractive to use. The use of synthetic polymer materials made from fiber can replace conventional materials such as metal, wood and leather. They can replace conventional materials with the advantages of lower price, environmental friendliness, and recyclability. Areca nut shell fiber, as an example of a natural fiber, has great potential in the furniture industry, crafts, and as an ingredient in traditional medicine. This fiber is used as a reinforcing material in composites with an Unsaturated Polyester Yukalac resin matrix. Unsaturated Polyester Yukalac resin, with characteristics such as stiffness, flexibility, water resistance, chemical resistance and weather resistance, is used as a matrix in making composites. The aim of this research is to make a plastic composite prototype reinforced with areca palm fiber, varying the volume fraction of areca nut shell fiber by 30%:50%, 50%:60%, 70%:70%, 90%:80% and for the matrix using polyester resin. BQTN 157 EX. The fiber composition is arranged in a mold in the same direction using the hand lay up method. Composite testing is in the form of a tensile test referring to the ASTM 638-03 standard. The results of the largest tensile testing process were with a volume fraction of 50% with an average value of 7.11 MPa, and for tensile testing the lowest was a volume fraction of 70% with an average value of 6.17 MPa, it can be concluded for reinforced plastic composites Areca nut shell fiber has considerable ability to be applied as a structural material. This is a step towards the development of innovative and environmentally friendly composite materials for various industrial applications.