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Journal : Jurnal Riset Kimia

Optimization of P3HT:PCBM Bulk Heterojunction Polymer Solar Cells: Effects of Annealing Temperature and Active Layer Composition Hardeli, Hardeli; Sanjaya, Hary; Harahap, Riri Indah Nitami; Permatasari, Putri
Jurnal Riset Kimia Vol. 16 No. 2 (2025): September
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v16i2.817

Abstract

P3HT:PCBM-based polymer solar cells have demonstrated potential as an affordable substitute for conventional silicon-based photovoltaics. The performance of P3HT:PCBM bulk heterojunction solar cells is examined in this work in relation to the annealing temperature and the composition of the active layer. The morphology of the active layer was characterized using SEM, while the electrical properties were measured using current-voltage (I-V) characterization. Our findings show that 150°C is the ideal annealing temperature, resulting in the maximum power conversion efficiency (PCE) of 2.58%. SEM analysis revealed that this temperature produces the most homogeneous surface morphology. Additionally, a P3HT:PCBM ratio of 3:1 resulted in the best device performance, with a PCE of 4.36%. Short-circuit current and open-circuit voltage increase when the blend's P3HT level increases. These results offer important information for optimizing the production of P3HT:PCBM-based polymer solar cells, which could lead to increased organic photovoltaic device efficiency and possible commercial outcomes.
Optimization of Tannic Acid Polymerization to Improve the Efficiency of Dye-Sensitized Solar Cells: Effect of Temperature and Monomer Concentration Agustini, Dwi; Hardeli, Hardeli; Oktavia, Budhi; Permatasari, Putri
Jurnal Riset Kimia Vol. 16 No. 2 (2025): September
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v16i2.823

Abstract

This study investigates the effects of temperature and monomer concentration on tannic acid polymerization to enhance dye-sensitized solar cell (DSSC) efficiency. Tannic acid was polymerized using Trimethylolpropane Triglycidyl Ether (TMPGDE) as a crosslinker, with monomer concentrations of 2, 2.5, and 3 grams and temperatures ranging from 30°C to 110°C. UV-Vis analysis revealed a bathochromic shift in poly-tannic acid, indicating increased light absorption in the 200-800 nm range. FTIR confirmed the formation of new ether groups, signifying successful polymerization. The highest DSSC efficiency (8.984%) was achieved with 2.5 grams of monomer at 50°C, significantly outperforming unpolymerized tannic acid (1.35%). The optimal poly-tannic acid has an average molecular weight of 32,610.1568 and a polymerization degree of 19.182. This research demonstrates the potential of tannic acid polymerization for improving DSSC performance, paving the way for more efficient and cost-effective organic solar cells.