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PENGARUH PENAMBAHAN MAPE PADA PROSES PEMBUATAN KOMPOSIT BERBASIS SEKAM PADI DAN BENTONIT ALAM (The Effect of MAPE Addition on Formation Process of Rice Husk and Natural Bentonite Based Composite) Mulana, Farid; Fathanah, Umi; Syarifuddin, Syarifuddin
Jurnal Hasil Penelitian Industri Vol 27, No 1 (2014)
Publisher : Baristand Industri Banda Aceh

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Rice husk and natural bentonite as well as virgin HDPE were used as rawmaterials to form composite. The aim of study is to know the effect of rice husk and naturalbentonite ratio as filler and the percentage of polyethylene-graft-maleic anhydride(MAPE) as coupling agent on quality of formed composites. The composite formationprocess was done by application of hot press method at 170 oC for 30 minutes. Afterheated and pressed then composites was cooled to room temperature and finallycomposites were tested its mechanical properties of tensile strength and bending strength.The results showed that addition of natural bentonite into matrix of rice husk can increasemechanical properties of composite compared to composites prepared by using only ricehusk and virgin HDPE. The amount of added MAPE affect values of tensile and bendingstrength of composites. The addition of MAPE and natural bentonite on formation ofcomposites caused the increasing adhesion bond between matrix and filler and as a resultalso increased the mechanical properties of composites. On ratio ofrice husk and naturalbentonite of 70:30 with addition of 5 wt% MAPE was obtained the highest tensile strengthvalue of 18.2 MPa and the highest bending strength value of 9.2 MPa.

Biopolymer From Starch And Chitosan As Bioplastic Material For Food Packaging Umi Fathanah; Mirna Rahman Lubis; Ryan Moulana
Proceedings of The Annual International Conference, Syiah Kuala University - Life Sciences & Engineering Chapter Vol 5, No 1 (2015): Engineering
Publisher : Syiah Kuala University

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This research aims to improve economic value of cassava peel waste as raw material of bioplastic making, whose existence is still very abundant and has not been benefitted optimally. Bioplastic making is conducted by mixing starch and chitosan with gliserol as plasticizer. Bioplastic making is carried out at gelatinization temperature of 80oC. Chitosan addition is carried out at variatios of 0; 10; 20; 30; and 40 (% w). Research result indicates that mechanical property i.e. optimum value of tensile strength is obtained at value of 38.25 MPa with chitosan addition as much of 30%. The highest elongation percentage is obtained as much of 41.25% with addition of 10% chitosan. Physical property of resulted bioplastic is obtained from the best swelling test at addition of 40% chitosan i.e. 0.38%, and bioplastic density obtained is ranged from 2 – 3.33 g/ml. Analysis of functional group by using FTIR exhibits the existence of ester and carbonyl groups that indicates that resulted bioplastic could be degraded. Whereas biodegradability test on environment exhibits that bioplastic could be completely degraded in soil for 24 days.

Sintesis, Karakterisasi dan Kinerja Membran Hidrofobik Menggunakan Polyvinyl Pyrrolidone (PVP) sebagai Aditif Umi Fathanah; Mirna Rahmah Lubis; Zuhra Mahyuddin; Syawaliah Muchtar; Mukramah Yusuf; Cut Meurah Rosnelly; Sri Mulyati; Rina Hazliani; Devi Rahmanda; Suraiya Kamaruzzaman; Meuthia Busthan
ALCHEMY Jurnal Penelitian Kimia Vol 17, No 2 (2021): September
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.17.2.48435.140-150

Artikel ini melaporkan tentang sintesis, karakterisasi dan kinerja membran polyethersulfone (PES) yang dimodifikasi dengan aditif polyvinyl pyrrolidone (PVP) dengan tujuan untuk meningkatkan kinerja dan sifat antifouling membran. Membran PES modifikasi dibuat dengan penambahan 0,5% PVP sebagai aditif, menggunakan pelarut dimethyl sulfoxide (DMSO) dan n-methyl pyrrolidone (NMP). Pengaruh penambahan aditif dalam sistem membran dievaluasi dengan menganalisa perubahan struktur kimia menggunakan fourier transform infrared (FTIR), perubahan morfologi permukaan menggunakan scanning electron microscopy (SEM), uji kuat tarik menggunakan tensile strength meter, uji porositas membran dengan menggunakan metode gravimetri, serta pengujian kinerja filtrasi, dan sifat antifouling. Hasil analisa struktur membran dengan SEM menunjukkan adanya pengaruh jenis pelarut dan penambahan aditif terhadap perubahan morfologi membran. Selain itu modifikasi membran juga meningkatkan porositas, kinerja fluks permeasi serta sifat antifouling membran. Hasil uji filtrasi membran menunjukkan perolehan permeabilitas air pada membran D-0,5 dan N-0,5 masing masing sebesar 47,5 L/m2.jam.atm dan 41,5 L/m2.jam.atm dengan sifat antifouling membran modifikasi lebih besar dibandingkan dengan membran tanpa modifikasi. Synthesis, Characterization, and Performance of Hydrophobic Membranes Using Polyvinyl Pyrrolidone (PVP) as Additives. This paper discusses the synthesis, characterization and performance of polyethersulfone (PES) membranes modified with polyvinyl pyrrolidone (PVP) additives in order to improve the performance and antifouling properties of membranes. The modified PES membrane was prepared by adding 0.5% PVP as an additive, using dimethyl sulfoxide (DMSO) and n-methyl pyrrolidone (NMP) as solvents. The effect of adding additives to the membrane system was evaluated by analyzing changes in chemical structure using fourier transform infrared (FTIR), changes in surface morphology using scanning electron microscopy (SEM), tensile strength test using tensile strength meter, membrane porosity test using the gravimetric method, as well as testing the filtration performance and antifoulingproperties. The results of membrane structure analysis by SEM showed the influence of the type of solvent and additives on changes in membrane morphology. In addition, membrane modification also increases porosity, permeation flux performance, and membrane antifouling properties. The results of the membrane filtration test showed that the water permeability of D-0.5 and N-0.5 membranes was 47.5 L/m2.h.atm and 41.5 L/m2.h.atm, respectively, with modified membrane antifouling properties larger than the membrane without modification.

Produksi Material Enrico-Fermi (Memperkaya Kandungan Nitrogen Pada Pupuk Organik Dari Hasil Produk Samping Penyulingan Minyak Nilam) Novia Arisni; Riana Tania; Izarul Machdar; Umi Fathanah
Jurnal Serambi Engineering Vol 6, No 3 (2021): Juli 2021
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v6i3.3249

Utilization of distilled patchouli waste is still very limited, so to optimize it, research is carried out on the manufacture of granule compost from patchouli solid waste trough 3 stages of activity. First aerobic fermentation process of Aceh Jaya patchouli solid waste with variations in the ratio of patchouli solid waste and tofu industrial liquid waste used, namely 1:1; 1:3; and 1:5 then the ratio between waste and bioactivator EM4 is 1:3%; 1:5%; and 1:7%. The second process of Enrico-Fermi fertilizer granulation using granule adhesive, namely tapioca flour with the ratio between Enrico-Fermi fertilizer and adhesive material is 2:1. The three processes of testing the Enrico-Fermi material on patchouli plant growth. The results showed that the highest NPK content in the Enrico-Fermi fertilizer was obtained at the ratio between patchouli waste and tofu liquid waste, namely 1:3 and the addition of EM4 with 7% EM-4 concentrations, namely 5.83% nitrogen, 1.91% phosphorus. and 3.46% potassium. The yield of Enrico-Fermi granule fertilizer was 71.43%. The response of plants to Enrico-Fermi fertilizer resulted in an increase in plant stem height of 5.7 cm, 16 leaves and 3 branches.

Pemanfaatan Kulit Jagung sebagai Bioadsorben untuk Meregenerasi Minyak Goreng Bekas Umi Fathanah; Mirna Rahmah Lubis
Jurnal Serambi Engineering Vol 7, No 1 (2022): Januari 2022
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v7i1.3879

Cooking oil is a food processing medium that is often used by various levels of society for cooking needs. People’s habit of using cooking oil repeatedly at high temperatures will cause damage to the oil so that it greatly affects the nutrition and quality of processed foods. For this reason, it is very important to make efforts to regenerate cooking oil that has been used repeatedly with a safer process. Corn husks can be used as a bioadsorbent to regenerate used cooking oil. The purpose of this study was to investigate the effect of adding bioadsorbent from corn husks on the acquisition of moisture content, free fatty acids (FFA), and peroxide number. 200 ml of used cooking oil was contacted with corn husk bioadsorbent with the addition of 1, 5, and 10 grams of bioadsorbent and contact times of 30, 60, and 90 minutes. Furthermore, used cooking oil that has been regenerated was analyzed for moisture content, FFA, and peroxide number. The results showed that 10 grams of bioadsorbent with a contact time of 90 minutes had a moisture content of 0.15%, FFA 0.11%, and a peroxide number of 1.15 meq/kg, which met the cooking oil quality standard (SNI 3741-1995).

Karakterisasi dan Kinerja Membran Polyethersulfone Termodifikasi Aditif Anorganik secara Blending Polimer Umi Fathanah; Hesti Meilina
Jurnal Serambi Engineering Vol 6, No 4 (2021): Oktober 2021
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v6i4.3515

Recently, membrane technology has developed rapidly as a process for water treatment. The membrane process is in demand due to several advantages including being able to work at low temperatures, easier to operate and easy to scale up. Magnesium hydroxide (Mg(OH)2) is an inorganic compound that is inexpensive, non-toxic and hydrophilic, so it has the potential to be used as an additive in membrane fabrication. This study aims to determine the characteristics and performance (permeability and selectivity) of Polyethersulfone (PES) membrane modified with Mg(OH)2, using dimethyl Acetamide (DMAc) as solvent. The membrane was made by blending polymer with phase inversion technique and the characterization carried out included membrane morphological tests, functional group tests, water contact angle tests and evaluating membrane performance by measuring membrane selectivity and permeability. The results showed that the hydroxyl group contained in Mg(OH)2 was able to increase the hydrophilicity which was indicated by a decrease in the water contact angle on the modified membrane to 65o. The Mg(OH)2 additive acts as a pore-forming agent which can be seen in the changes in membrane morphology on the cross-section of the membrane surface. The performance of the membrane resulted in an increase in membrane permeability of 51 L/m2.hour.bar with humid acid rejection of 63%.

MODIFIKASI MEMBRAN POLYETHERSULFONE (PES) MENGGUNAKAN PELARUT NORMAL METHYL PYROLYDONE (NMP) SECARA NON-SOLVENT INDUCE PHASE SEPARATION (NIPS) Umi Fathanah; Izarul Machdar; Medyan Riza; Nasrul Arahman; Mirna Rahmah Lubis; Mukramah Mukramah
Prosiding Seminar Nasional USM Vol 2, No 1 (2019): Semnas Multidisiplin Ilmu
Publisher : Universitas Serambi Mekkah

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Clean water is a natural resource which is indispensable, due to the increase of population, water demand is also increasing. so that technology is needed in water treatment to satisfy the needs of clean water. Membrane separation technology is a technology that has grown rapidly in addressing the problems of water treatment. The purpose of this study was to determine the characteristics and performance of Polyethersulfone (PES) membranes modified with magnesium hydroxide or Mg(OH)2 and modification using chitosan. Membrane preparation was carried out by the phase inversion method, using an 18 wt% PES polymer modified with the addition of 0.2 wt% of Mg(OH)2, and modification using 0.2 wt% of chitosan. Furthermore, it was dissolved in N-Methyl pyrrolidone (NMP) as a solvent and the dope solution was stirred for 24 hours until it was homogeneous. Membrane characterization includes functional group analysis and measurement of the membrane water contact angle. Whereas membrane performance testing is done through permeability measurement and membrane rejection using a dead end ultrafiltration module. The results showed that the hydroxyl group (-OH) contained in Mg(OH)2 and chitosan were able to improve the hydrophilicity of the PES membrane. The membrane permeability coefficient modified with Mg(OH)2 gives a value of 8.236 L/m2.h.bar, while modifying the membrane using chitosan produces a value of 6.237 L/m2.h.bar. Both of them experience an increase compared to pure PES membrane without modification that has a permeability value of 4.123 L/m2.h.bar.

Modifikasi Membran Polyethersulfone dengan Penambahan Nanopartikel Mg(OH)2 dalam Pelarut Dimethyl Sulfoxide Umi Fathanah; Fachrul Razi; Mirna Rahmah Lubis; Mukramah Yusuf; Yanna Syamsuddin; Hesti Meilina; Syawaliah Muchtar; Suraiya Kamaruzzaman; Aula Khairunnisa
ALCHEMY Jurnal Penelitian Kimia Vol 18, No 2 (2022): September
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.18.2.58248.165-173

Membran Polyethersulfone (PES) bersifat hidrofobik yang memiliki ketahanan rendah terhadap sifat fouling. Fouling pada membran mengakibatkan penurunan kinerja membrane selama proses operasi. Oleh karena itu, modifikasi membran perlu dilakukan untuk meningkatkan sifat hidrofilik membrane. Pada penelitian ini modifikasi dilakukan dengan penambahan nanopartikel Mg(OH)2 yang bersifat tidak beracun, murah, dan mudah diperoleh. Penambahan aditif nanopartikel Mg(OH)2 pada membran PES dilakukan dengan cara pencampuran polimer dengan metode non solvent induced phase separation (NIPS) menggunakan pelarut dimethyl sulfoxide (DMSO). DMSO merupakan pelarut polar aprotik yang dapat melarutkan senyawa organik maupun anorganik dengan baik. DMSO juga merupakan pelarut yang tidak beracun, sehingga lebih aman dan ramah lingkungan. Penelitian ini bertujuan untuk menghasilkan membran PES hidrofilik dengan penambahan nanopartikel Mg(OH)2 dengan unjuk kerja terbaik. Pengaruh penambahan nanopartikel Mg(OH)2 dalam sistem membran dievaluasi dengan menganalisis perubahan struktur kimia PES menggunakan ATR-FTIR, perubahan morfologi menggunakan SEM, porositas menggunakan metoda gravimetri, serta pengujian kinerja (permeabilitas dan rejeksi) membran. Hasil penelitian menunjukkan bahwa penambahan nanopartikel Mg(OH)2, mengakibatkan perubahan pada struktur atau morfologi membrane PES, yang berpengaruh terhadap peningkatan permeabilitas membran. Penambahan nanopartikel Mg(OH)2 juga meningkatkan porositas membran dari 12% ‒ 40%. Kehadiran gugus hidroksil (-OH) dalam matriks membran dikonfirmasi dengan uji FTIR. Kinerja membran optimum diperoleh pada nilai permeabilitas air sebesar 56,4 L/m2.jam.bar, dengan rejeksi asam humus sebesar 61%.Modification of Polyethersulfone Membrane with the Addition of Mg(OH)2 Nanoparticles in Dimethyl Sulfoxide Solvent. Polyethersulfone (PES) membrane has hydrophobic characteristics and low resistance to fouling properties. The fouling on the membrane results in a decrease in the performance of the membrane during the operation process. Therefore, membrane modification needs to be done to increase the hydrophilic properties of the membrane. In this study, modifications were made by adding Mg(OH)2 nanoparticles which are non-toxic, inexpensive, and easy to obtain. The addition of Mg(OH)2 nanoparticle additives to PES membranes was carried out by blending polymers with the non-solvent induced phase separation (NIPS) method using dimethyl sulfoxide (DMSO) as solvent. DMSO is an aprotic polar solvent that can dissolve both organic and inorganic compounds well. DMSO is also a non-toxic solvent, making it safer and more environmentally friendly. This study aims to produce a hydrophilic PES membrane with the addition of Mg(OH)2 nanoparticles with the best performance. The effect of adding Mg(OH)2 nanoparticles in the membrane system was evaluated by analyzing changes in the chemical structure of PES using ATR-FTIR, morphological changes using SEM, porosity using the gravimetric method, and testing the performance (permeability and rejection) of the membrane. The results showed that the addition of Mg(OH)2 nanoparticles resulted in changes in the structure or morphology of the PES membrane, which affected the increase in membrane permeability. The addition of Mg(OH)2 nanoparticles also increased the porosity of the membrane from 12% to 40%. The presence of hydroxyl groups (-OH) in the membrane matrix was confirmed by FTIR analysis. The optimum membrane performance was obtained at the water permeability value of 56.4 L/m2.h.bar with 61% rejection of humic acid.

Pengaruh Penambahan Brij35 serta Methacryloyloxylethyl Phosphoryl Choline terhadap Karakteristik dan Kinerja Membran Mukramah Yusuf Wahab; Syawaliah Muchtar; Nasrul Arahman; Sri Mulyati; Medyan Riza; Umi Fathanah; Aula Chairunnisak; Fauzan Al Chalifa
Jurnal Serambi Engineering Vol 8, No 3 (2023): Juli 2023
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v8i3.6243

Artikel ini melaporkan tentang karakteristik dan kinerja dari membran polyvinylidene fluoride (PVDF) yang dimodifikasi dengan memadukan surfaktan nonionik dan aditif zwitterionik melalui metode nonsolvent-induced phased separation (NIPS). Modifikasi ini bertujuan untuk meningkatkan sifat hidrofilisitas dan kinerja membran. Membran PVDF modifikasi dibuat dengan penambahan 5 gram Brij-35 dan variasi Methacryloyloxylethyl phosphorylcholine (MPC) sebanyak 0,5 dan 1 gram sebagai aditif, menggunakan pelarut N, N-dimethylacetamide (DMAc) dan non-pelarut berupa akuades. Pengaruh penambahan aditif ke dalam sistem membran dianalisis dengan mengamati perubahan struktur morfologi membran menggunakan SEM, tingkat hidrofilisitas membran diuji dengan mengukur sudut kontak air pada permukaan membran. Selain itu membran juga diuji kinerja filtrasinya menggunakan modul cross-flow. Filtrasi dilakukan pada tekanan operasi 1 bar. Kemudian untuk pengujian rejeksi, digunakan larutan asam humus sebagai model kontaminannya. Kinerja filtrasi membran menggunakan sampel air murni menghasilkan nilai fluks maksimal pada membran yang dimodifikasi dengan penambahan Brij35-5. Namun, selektivitas yang dihasilkan menurun dari 96% (pure PVDF) menjadi 76%. Di sisi lain, membran yang dimodifikasi dengan penggabungan aditif mampu menghasilkan kinerja yang lebih baik yaitu dengan nilai fluks sebesar 126 L/m2h dan mampu merejeksi asam humus sebesar 90%.

Pengaruh Penambahan Brij35 serta Methacryloyloxylethyl Phosphoryl Choline terhadap Karakteristik dan Kinerja Membran Mukramah Yusuf Wahab; Syawaliah Muchtar; Nasrul Arahman; Sri Mulyati; Medyan Riza; Umi Fathanah; Aula Chairunnisak; Fauzan Al Chalifa
Jurnal Serambi Engineering Vol 8, No 3 (2023): Juli 2023
Publisher : Fakultas Teknik

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32672/jse.v8i3.6243

Artikel ini melaporkan tentang karakteristik dan kinerja dari membran polyvinylidene fluoride (PVDF) yang dimodifikasi dengan memadukan surfaktan nonionik dan aditif zwitterionik melalui metode nonsolvent-induced phased separation (NIPS). Modifikasi ini bertujuan untuk meningkatkan sifat hidrofilisitas dan kinerja membran. Membran PVDF modifikasi dibuat dengan penambahan 5 gram Brij-35 dan variasi Methacryloyloxylethyl phosphorylcholine (MPC) sebanyak 0,5 dan 1 gram sebagai aditif, menggunakan pelarut N, N-dimethylacetamide (DMAc) dan non-pelarut berupa akuades. Pengaruh penambahan aditif ke dalam sistem membran dianalisis dengan mengamati perubahan struktur morfologi membran menggunakan SEM, tingkat hidrofilisitas membran diuji dengan mengukur sudut kontak air pada permukaan membran. Selain itu membran juga diuji kinerja filtrasinya menggunakan modul cross-flow. Filtrasi dilakukan pada tekanan operasi 1 bar. Kemudian untuk pengujian rejeksi, digunakan larutan asam humus sebagai model kontaminannya. Kinerja filtrasi membran menggunakan sampel air murni menghasilkan nilai fluks maksimal pada membran yang dimodifikasi dengan penambahan Brij35-5. Namun, selektivitas yang dihasilkan menurun dari 96% (pure PVDF) menjadi 76%. Di sisi lain, membran yang dimodifikasi dengan penggabungan aditif mampu menghasilkan kinerja yang lebih baik yaitu dengan nilai fluks sebesar 126 L/m2h dan mampu merejeksi asam humus sebesar 90%.

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