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Pengaktifan Kapas Sebagai Resin Penukar Kation Asam Lemah Arnelli, Arnelli; S., M. S.H. Yoga; Astuti, Yayuk
JURNAL SAINS DAN MATEMATIKA Volume 14 issue 4 Year 2006
Publisher : JURNAL SAINS DAN MATEMATIKA

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Abstract

ABSTRAK---Dengan menggunakan beberapa reaksi kimia, gugus hidroksi dalam struktur selulosa mampu diubah menjadi senyawa eter (R-O-R). Senyawa eter yang disintesis tersebut mengandung gugus karboksilat yang mempunyai kation aktif yang dapat dipertukarkan dengan kation lain. Sebagai sumber selulosa adalah kapas alam. Pada penelitian ini, kapas alam diaktifkan dengan NaOH dan asam trikloroasetat sehingga menghasilkan senyawa eter selulosa. Pemanfatannya sebagai penukar kation dilakukan terhadap kation Cu. Hasil penelitian menunjukkan bahwa kondisi pengaktifan yang memberikan kapasitas adsorbsi optimum adalah pada suhu alkalisasi 60 0C, lama reaksi 120 menit dan konsentrasi asam trikloroasetat sebesar 0.06 M. pada kondisi pengaktifan ini kapas aktif mampu mengadsorbsi kation tembaga 44.10-2 mg/g kapas aktif.   Kata kunci: kapas aktif, trikloroasetat, penukar kation
Pengaruh Konsentrasi Ca2+ dan (PO4)3- pada Pembentukan Hidroksiapatit di dalam Matriks Selulosa Bakterial Windarti, Tri; Astuti, Yayuk
Jurnal Kimia Sains dan Aplikasi Vol 9, No 3 (2006): Volume 9 Issue 3 Year 2006
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (286.55 KB) | DOI: 10.14710/jksa.9.3.60-64

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Pembentukan hidroksiapatit Ca10(PO4)6(OH)2 dalam matriks selulosa bakterial dilakukan dengan cara merendam selulosa bakterial dalam larutan CaCl2 selama 18 jam, dilanjutkan dengan merendam dalam larutan KH2PO4 selama 18 jam pada pH 9. Perendaman tersebut dilakukan dengan berbagai variasi konsentrasi Ca2+ dan PO42-. Kadar kalsium yang terdeposit dalam selulosa bakterial dianalisis dengan AAS. Kadar fosfat dianalisis dengan Stannous Chloride methode dan untuk mengetahui apakah kalsium fosfat yang terdeposit membentuk struktur hidroksiapatit, dilakukan analisis dengan difraksi sinar X. Difraktogram sinar X menunjukkan telah terbentuk struktur hidroksiapatit dalam matriks selulosa bakterial dan rasio ideal C/P hidroksiapatit sebesar 1,676 terjadi pada perbandingan Ca2+: PO43- = 125 : 25.
Al Ions Doping Effect on The Diffusion Coefficient and Capacity of Li4Ti5O12 (Lithium Titanate, LTO) in Lithium-Ion Battery Anode Priyono, Slamet; Daniswara, Lufthansyah; Khoiri, Rahma; Astuti, Yayuk
http://dx.doi.org/10.31427/IJSTT.2020.3.2.3
Publisher : Unijourn Publisher

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Abstract

Li4Ti5O12 (LTO) anode doped with Al ions with varying concentrations (Al = 0; 0.005; 0.015; 0.03; 0.045) was successfully synthesized using the sol-gel method. Al-doped LTO samples were obtained through the sintering of gel at 850oC for 4 hours under a normal atmosphere. Electrochemical performance such as charge-discharge capacity and diffusion coefficient were characterized using an automatic battery cycler. The cells consist of electrode sheets (LTO doping Al) as a working electrode, lithium metal as the counter electrode, Celgard film as the separator, and LiPF6 as an electrolyte. Cyclic voltammetry test results show that a greater scan rate results in decreased capacity and greater polarization voltage. In addition, an increase in concentrations used in Al doping on LTO causes capacity, and the diffusion coefficient tends to decrease.
Pemanfaatan Fly Ash Limbah Pembakaran Batubara sebagai Zat Mineral Tambahan (Additive) terhadap Perbaikan Kualitas dan Kuat Tekan Semen Wijaya, Roni Adi; Astuti, Yayuk; Wijayanti, Septi
MEDIA KOMUNIKASI TEKNIK SIPIL Volume 27, Nomor 1, JULI 2021
Publisher : Department of Civil Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (410.244 KB) | DOI: 10.14710/mkts.v27i1.31558

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Serangkaian pengujian dilakukan untuk menentukan pengaruh penambahan fly ash limbah pembakaran batubara sebagai zat mineral tambahan (additive) terhadap perbaikan kualitas dan kuat tekan semen sesuai Standar Nasional Indonesia (SNI 15-2049-2004). Metode penelitian meliputi preparasi sampel, pembuatan semen dengan variasi fly ash 0%, 5%, 8%, 12%, dan 15%, uji sifat kimia dan fisika semen. Parameter yang diukur yaitu kadar komposisi kimia (%) menggunakan X-Ray Fluorescence Spectroscopy (XRF) ARL 9800 OASIS, kadar freelime (%) secara volumetri, kadar Insoluble Residue (%) secara gravimetri, kuat tekan (kg/cm2), dan kehalusan semen (cm2/g). Hasil penelitian menunjukkan bahwa penambahan fly ash meningkatkan kandungan SiO2 semen, sehingga memperbanyak senyawa C3S dan C2S yang merupakan komponen kuat tekan semen. Selain itu, penambahan fly ash berbanding lurus dengan kadar IR, kuat tekan, kehalusan, dan berbanding terbalik dengan kadar freelime. Sehingga penambahan fly ash dapat memperbaiki kualitas semen dengan menaikan komponen kimia, menaikan kuat tekan, dan mengurangi keretakan atau ekspansi semen.
Preparasi sel mamalia CHO-DG44 dan isolasi plasmid dari bakteri Eschericia coli DH5-alfa sebagai tahap dalam produksi protein terapeutik erythropoetin sebagai obat anemia Alfi Saadah; Adi Santoso; Popi Hadi Wisnu Wardhani; Yayuk Astuti
Jurnal Biologi Udayana Vol 24 No 2 (2020): JURNAL BIOLOGI UDAYANA
Publisher : Program Studi Biologi, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Udayana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24843/JBIOUNUD.2020.v24.i02.p04

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Erythropoietin (Miranda dkk.) merupakan suatu hormon yang menstimulasi sumsum tulang untuk memproduksi sel-sel darah merah yang dibutuhkan oleh tubuh untuk membawa oksigen ke organ-organ vital. Sel CHO-DG44 merupakan salah satu sel mamalia yang dapat digunakan untuk produksi erythropoietin. Penelitian ini bertujuan menentukan pertumbuhan optimum sel CHO-DG44 selama 12 hari, dengan menggunakan parameter densitas dan viabilitas serta menentukan karakteristik DNA bakteri E. Coli DH5 alfa hasil isolasi menggunakan metode elektroforesis yang telah sesuai untuk transfeksi ke dalam sel CHO-DG44. Hasil penelitian menunjukkan Sel CHO-DG44 memiliki viabilitas rata-rata 69,82% untuk media 1 dan 75,99% untuk media 2 dengan densitas rata-rata berturut-turut yaitu 3.130.000 sel/mL dan 4.106.000 sel/mL. Sedangkan media kultur yang menghasilkan sel dengan viabilitas (kemampuan hidup) yang tinggi yaitu pada hari ke 4 untuk erlenmeyer 1 dan hari ke 6 untuk erlenmeyer 2. Dari hasil elektroforesis, DNA plasmid memiliki ukuran 5954 bp dengan konsentrasi DNA sebesar 117 ng/µl, yang sesuai dengan ukuran dan konsentrasi plasmid DNA agar dapat ditransfeksikan ke dalam sel CHO-DG44.
Production and Characterization of Adsorbent from Oyster Shell (Crassostrea gigas) Using Physics and Chemical Activation with ZnCl2 and Its Application for Removal of Hexavalent Chromium Lia Handayani; Azwar Thaib; Nurhayati Nurhayati; Yayuk Astuti; Adi Darmawan
Elkawnie: Journal of Islamic Science and Technology Vol 6, No 2 (2020)
Publisher : Universitas Islam Negeri Ar-Raniry Banda Aceh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22373/ekw.v6i2.7333

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Abstract: Oyster shell waste has been investigated as a raw material for making adsorbents that will be activated. Physical activation uses temperatures of 500 ºC, 600 ºC, 700 ºC, 800 ºC, 900 ºC and chemical activation uses ZnCl2 with a concentration of 1 %, 5 %, 10 % and 15 %. Based on the analysis of the characteristics that have been carried out for physically activated adsorbents, the oyster shell calcined at 800 ºC produces the best characteristics, it is a radius of 35.11 Å with a percentage of removal of 38.04 %, as well as the results of the FTIR, XRF and SEM analysis gives the best results among others. Whereas for chemically activated adsorbents, the use of activator ZnCl2 10% produces adsorbents with the best characteristics among others with a radius of 84.14 Å and removal percentage of 65.68 %, the best results for adsorbents activated using 10% ZnCl2 are also supported by analysis results given by FTIR, XRF, and SEM.Keywords: Adsorbent; BET; Cr6+; Oyster Shell Waste; XRF Abstrak: Cangkang tiram (Crassostrea gigas) telah diteliti sebagai bahan baku pembuatan adsorben yang akan diaktivasi secara fisika dan kimia. Pembuatan adsorben dengan aktivasi secara fisika menggunakan variasi suhu 500 ºC, 600 ºC, 700 ºC, 800 ºC dan 900 ºC. sedangkan aktivasi kimia yaitu menggunakan aktivator ZnCl2 menggunakan variasi konsentrasi 1 %, 5 %, 10% dan 15 %. Berdasarkan analisa karakteristik yang telah dilakukan untuk adsorben-adsorben yang telah diaktivasi secara fisika, cangkang tiram yang di kalsinasi pada suhu 800ºC menghasilkan karakteristik yang paling baik, yaitu radius pori-pori 35,11 Å dengan persentase penyisihan sebesar 38,04 %, begitu pula dengan hasil analisa FTIR, XRF dan SEM memberikan hasil terbaik diantara yang lain. sedangkan untuk adsorben-adsorben yang diaktivasi secara kimia, penggunaan aktivator ZnCl2 10% menghasilkan adsorben dengan karakteristik yang paling baik diantara lainnya dengan radius pori-pori 84,14 Å dan persentase penyisihan sebesar 65,68%, hasil terbaik untuk adsorben yang diaktivasi menggunakan ZnCl2 10 % juga didukung oleh hasil analisa dari FTIR, XRF dan SEM.
The Characterization of Oyster Shell (Crassostrea gigas) as Adsorbent in The Removal of Cr(VI) Ions. A Study of NaOH and H2SO4 Activation Effect Lia Handayani; Cut Rahmawati; Nurhayati Nurhayati; Yayuk Astuti; Adi Darmawan
Elkawnie: Journal of Islamic Science and Technology Vol 6, No 1 (2020)
Publisher : Universitas Islam Negeri Ar-Raniry Banda Aceh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22373/ekw.v6i1.5543

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Abstract : Oyster shell as one of the highest bio-waste in Alue Naga Aceh Besar District, Indonesia, was used as an adsorbent to remove a heavy metal Cr (VI) ion. The study was started by calcinating oyster shells at a high temperature of 800 ºC for 3 hours. The effect of various acid (H2SO4) and base (NaOH) activator was studied using characterization and adsorption experiments. The characterization obtained the sample activated by 10% NaOH (Na10-ACT) and 10% H2SO4 (H10-ACT) had the highest surface area which had 14.23 m2/g, 10.77 m2/g, respectively. Furthermore, the adsorption experiments confirmed the highest surface area by showing the highest Cr (IV) ion removal of 57.66%, 70.7%, respectively. The further investigation using X-ray fluorescence (XRF) determined that the Na10-ACT adsorbent has a better composition compared to the H10-ACT due to its high purities.Abstrak : Cangkang tiram sebagai salah satu bio-limbah padat di Desa Alue Naga Kabupaten Aceh Besar, digunakan sebagai adsorben untuk menghilangkan ion logam berat Cr (IV). Penelitian ini diawali dengan mengkalsinasi cangkang tiram pada temperatur tinggi 800ºC selama tiga jam. Pengaruh penambahan aktivator asam (H2SO4) dan basa (NaOH) juga dipelajari melalui karakterisasi dan pengujian adsorpsi. Hasil karakterisasi menunjukkan sampel yang diaktivasi dengan 10% NaOH (Na10-ACT) dan 10% H2SO4 (H10-ACT) memiliki luas permukaan tertinggi yaitu 14,23 m2/g, 10,77 m2/g, masing-masing. Lebih lanjut, pengujian adsorpsi juga mendukung luas permukaan yang tinggi dengan menghilangkan ion Cr (IV) sebesar 57,66%, 70,7%, masing-masing. Investigasi melalui analisa XRF menyimpulkan bahwa Na10-ACT memiliki komposisi yang lebih baik dibanding H10-ACT karena memiliki kemurnian yang tinggi.
The Effect of White Turmeric Extract (Curcuma Zedoaria) and Lactobacillus sp Herbal Mixture as Feed Additive on Animal Productivity Yayuk Astuti; Mega Bara Cahyantari
Journal of Science & Science Education Vol 4 No 1 (2020): JoSSE Vol. 4 No. 1 (May 2020)
Publisher : Faculty of Science and Mathematics, Universitas Kristen Satya Wacana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24246/josse.v4i1p1-9

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This study was conducted to determine the effect of herbal white turmeric extract (Curcuma zedoaria) with Lactobaccilus sp on the productivity of livestock. The test subjects within this study are 50 broiler chickens aged 0 days which were divided equally into two observation groups, namely the control group (A) and the treated group (B). The treatments are carried out as follows: A = no animal herbal mixture was added into the drinking water; B = drinking water was added with herbal mixture. Average body weight of the chickens were (A) 460 g and (B) 484 g, the feed conversion ratio values for chicken aged 6 and 13 days respectively are 0.696 (A); 0.644 (B) and 1.25 (A); 1.18 (B), while the performance index value (IP) of broiler chickens aged 6 and 13 days were 335 (A); 390 (B) and 272 (A); 315 (B), consecutively. In this study the addition of herb as feed additives into broiler chicken drinking water can increase the average body weight of the treatment group compared to the control group, the treatment group has a lower FCR value indicating good feed efficiency and IP values ​​above 300 implying good breeding process.
LiOH/Coconut Shell Activated Carbon Ratio Effect on the Electrical Conductivity of Lithium Ion Battery Anode Active Material Annisa Syifaurrahma; Arnelli Arnelli; Yayuk Astuti
Molekul Vol 16, No 3 (2021)
Publisher : Universitas Jenderal Soedirman

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (579.245 KB) | DOI: 10.20884/1.jm.2021.16.3.805

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A lithium ion battery anode active material comprised of LiOH (Li) and coconut shell activated carbon (AC) has been synthesized with Li/AC ratios of (w/w) 1/1, 2/1, 3/1, and 4/1 through the sol gel method. The present study aims to ascertain the best Li/AC ratio that produces an anode active material with the best electrical conductivity value and determine the characteristics of the anode active material in terms of functional groups, surface area, crystallinity, and capacity. Based on the electrical conductivity test using LCR, the active material Li/AC 2/1 had the highest electrical conductivity with a value of 2.064x10-3 Sm-1. The conductivity achieved was slightly smaller than that of the active material with no addition of LiOH on the activated carbon at an electrical conductivity of 5.434x10-3 Sm-1. The FTIR spectra of the activated carbon and Li/AC 2/1 showed differences with in the Li-O-C group absorption at 1075 cm-1 wavenumber and the wide absorption in the area of 547.5 cm-1 that represents Li-O vibration. Based on the results of SAA, the activated carbon had a larger surface area than Li/AC 2/1 at 17.057 m2g-1 and 5.615 m2g-1, respectively. The crystallinity of both active materials was low shown by the widening of the diffraction peaks. Tests with cyclic voltammetry (CV) proved that there was a reduction-oxidation reaction for the two samples in the first cycle with a large charge and discharge capacities of the activated carbon of 150.989 mAh and 92.040 mAh, while for Li/AC 2/1 they were 91.103 mAh and 47.580 mAh.
Bismuth Oxide Prepared by Sol-Gel Method: Variation of Physicochemical Characteristics and Photocatalytic Activity Due to Difference in Calcination Temperature Yayuk Astuti; Brigita Maria Listyani; Linda Suyati; Adi Darmawan
Indonesian Journal of Chemistry Vol 21, No 1 (2021)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.53144

Abstract

Research on synthesis of bismuth oxide (Bi2O3) using sol-gel method with varying calcination temperatures at 500, 600, and 700 °C has been done. This study aims to determine the effect of calcination temperature on the characteristics of the obtained products which encompasses crystal structure, surface morphology, band-gap energy, and photocatalytic activity for the decolorization of methyl orange dyes through its kinetic study. Bismuth oxide prepared by sol-gel method was undertaken by dissolving Bi(NO3)3·5H2O and citric acid in HNO3. The mixture was stirred then heated at 100 °C. The gel formed was dried in the oven and then calcined at 500, 600, and 700 °C for 5 h. The obtained products were a pale yellow powder, indicating the formation of bismuth oxide. This is confirmed by the existence of Bi–O and Bi–O–Bi functional groups through FTIR analysis. All three products possess the same mixed crystal structures of α-Bi2O3 (monoclinic) and γ-Bi2O3 (body center cubic), but their morphologies and band gap values are different. The higher the calcination temperature, the larger the particle size and the smaller the band gap value. The accumulative differences in characteristics appoint SG700 to have the highest photocatalytic activity compared to SG600 and SG500 as indicated by its percent degradation value and decolorization rate constant.
Co-Authors Abdul Jabbar Adi Darmawan ADI SANTOSO Agriccia Pangestica Saputry Ahmad Suseno Alfi Saadah Alfiansyah Alfiansyah Amilia Fauziyah Anisyah Anisyah Annisa Syifaurrahma Arnelli Arnelli Arum Dista Wulansari Aulia Zahra Ekaningsih Azwar Thaib Bara Yunianto Fathoni Brainy Happy Ana Tasiman Brainy Happy Ana Tasiman Brigita Maria Listyani Cut Rahmawati Daniswara, Lufthansyah Dayadi, Dayadi Didi Dwi Anggoro Didik Setyo Widodo Esti Ayu Faisal Syahputra Fandi Nasrun Cholis Faradina Azahra Zaqia Fauzan Musthafa Febrianti, Devi Fitriani Solichah Galih N. R. Pargiman Gaurav A. Bhaduri Gunawan Gunawan HARTATI Hartati Hartati Hasanuddin, Fenny Hasim Muzadi Hendri Widiyandari Hendri Widiyandari Hendri Widyandari Hermasnyah, Sam Husnayani, Husnayani Iis Nurhasanah Iis Nurhasanah Irman, Iriani Isumarni, Isumarni Jamaluddin Ahmad Jufri, Al Jafar Jumiati Jumiati Khalik, Suhartini Khalik, Suhartini Khoiri, Rahma Lia Handayani Lia Handayani Lia Handayani Linda Suyati Luqman Buchori M. S.H. Yoga S. Majid, Abdul Majid Zainuddin Mega Bara Cahyantari Muh. Fajar, Muh. Muh. Rohady Ramadhan Muhammad Hanafi Muhammad Rusdi Muslim, Agus Mustanir, Ahmad Nabila Amalia Izaaz Aanisa Narita Rizki Nayla Zahra Kamalia Nonci, Nurjannah Noor Afifah Nur Hidayati Nurhayati Nurhayati Nurhayati Nurhayati Nurlaelah Nurlaelah, Nurlaelah Nurul Latifah Nurwidah, Andi Pandji Triadiyaksa Pardoyo Pardoyo Pardoyo Pardoyo Popi Hadi Wisnu Wardhani Prasetya, Eko Fery Prisca Putri Elesta Pungki Hanipa R Kasau, Nurzin Rahayu, R.A. Yunita Suci Rahayu, Yunita Suci Rahmatul Fazira Rahmawati Rahmawati Ramdan, Ramdan Rasman Ratna Balgis Redi Joko Prasetyo Richard Leonardo Sianturi Rissa Kharismawati Rizka Andianingrum Roni Adi Wijaya Saade, Muhammad Faisal Samratusabri Subehan Siringoringo, Eliezer Patardo Siti Fatimah Siti Nurhayati Siti Susanti, Siti Slamet Priyono Subehan, Samratusabri Tamrin, Muh Tang, Jusman Taslimah Taslimah Teguh Iman Prastyo Titik Lestariningsih Titik Lestariningsih Tri Windarti Tri Windarti Triadiyaksa, Pandji Trie Nanda Mulyana Trisnasari, Damayanti Ulya Hanifah Henrika Putri Vega Norma Rafika Putri Wijayanti, Septi Yeni Aprilia Yusrianti Yusrianti, Yusrianti Zulfahmi Zulfahmi