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Journal : Journal of Green Science and Technology

The Effect of Variations in Sulfuric Acid - Oxalic Acid Electrolyte Concentration and Additional Aeration on 1100 Series Aluminum Anodization Results Leoanggraini, Unung; Irianto, Indra; Aji, Restu; Paramitha, Tifa; Sihombing, Rony
Journal of Green Science and Technology Vol 8 No 2 (2024): Journal of Green Science and Technology Vol.8 No.2 September 2024
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v8i2.9425

Abstract

Aluminum is one of the materials used in making various types of goods because it has good properties such as being light, ductile and has good corrosion resistance. One of the disadvantages of aluminum is its low level of hardness. This can be overcome by treating aluminum, one of which is the anodization process. In this research, variations in the type of electrolyte used were sulfuric acid-oxalic acid, the electrolyte concentration was 16% with an interval of 0.5, the temperature used was room temperature with a current density of 3/dm2 and a coating time of 30 minutes. The aim of this research is to determine the acid concentration and the effect of the aeration system on mechanical properties. From the data obtained, it was found that the difference in weight of the best metal with the addition of aeration at a concentration of 13.5+2.5 was 0.0411 gr. This shows that as the concentration of oxalic acid increases it can accelerate the process of aluminum oxide formation, then for electrolyte concentrations of 16+0, 15.5+0.5, 15+1, 14.5+1.5 and 14+2 the difference in mass weight metals increased respectively by 0.0337 gr, 0.0335 gr, 0.0366 gr, 0.0390 and 0.0411 gr. In the anodization process without   additional aeration, the best metal weight difference is found at an electrolyte concentration of 13.5+2.5 of 0.0401 gr. This shows that increasing the concentration of oxalic acid can accelerate the process of aluminum oxide formation. Then at electrolyte concentrations of 16+0, 15.5+0.5, 15+1, 14.5+1.5 and 14+2 the difference in metal mass weight gradually increases by 0.0182 gr, 0.0293 gr, 0.0318 gr, 0.0322 and 0.0362 gr. Keywords: Aluminum, Anodization, Oxide Coating, Electrolyte Solution, Sulfuric Acid, Oxalic acid
Anodizing Characteristics of AA1100 in 20% Sulfuric–Phosphoric Acid Electrolytes under Aerated and Non-Aerated Conditions at Various Times Tri Hariyadi; Tita Rosita; Aniqa Arjumand Bano Harvani; Silvia Fatimatur Rahmawati; Tifa Paramitha; Adhitasari, Alfiana; Sihombing, Rony
Journal of Green Science and Technology Vol 10 No 1 (2026): Journal of Green Science and Technology Vol. 10 No.1 March 2026
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v10i1.11796

Abstract

Aluminum alloy AA1100 exhibits good corrosion resistance but suffers from low surface hardness and wear resistance, which can be improved through anodizing. However, limited studies have examined the combined influence of sulfuric–phosphoric acid electrolyte composition and aeration. This study investigates the effect of sulfuric–phosphoric acid electrolyte composition and aeration on oxide layer mass, thickness, and hardness during anodizing. Anodization was conducted using a total electrolyte concentration of 20% with varying sulfuric acid (15–20%) and phosphoric acid (5–0%) ratios at a current density of 3 A/dm², operating times of 15 and 30 minutes, and room temperature under aerated and non-aerated conditions. The results show that aeration significantly increased oxide layer formation, yielding an average oxide mass of 0.0173 g compared to 0.0106 g in non-aerated systems. The maximum oxide mass (0.0375 g) was obtained at 20% sulfuric acid with aeration for 30 minutes. The highest oxide layer thickness of 47.94 µm was achieved using a 19% sulfuric acid–1% phosphoric acid electrolyte under aerated conditions at 30 minutes. Meanwhile, the maximum surface hardness of 352.60 HVN was obtained at 15% sulfuric acid–5% phosphoric acid with aeration for 15 minutes. These findings demonstrate that electrolyte composition and aeration play a critical role in optimizing anodic oxide growth and mechanical properties of AA1100.
Utilization Of Sengon Wood Sawdust Waste as Esterified Cellulose-Based Bioadsorbent for CD(II) Wastewater Purification Fauzan, Rizky; Mujahidah, Nisa Rahmah; Nugraha, Teguh Aditya; Azzahra, Nasya; Paramitha, Tifa; Soeswanto, Bambang; Sihombing, Rony Pasonang
Journal of Green Science and Technology Vol 9 No 3 (2025): Journal of Green Science and Technology Vol. 9 No. 3 December 2025 Special Editio
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v9i3.10650

Abstract

Cadmium (Cd) is a heavy metal with high toxicity that can enter the body through contaminated food chains, so wastewater containing cadmium needs to be treated before being discharged into the environment. This study uses adsorption methods to reduce Cd(II) concentration in artificial wastewater by utilizing modified sengon wood sawdust cellulose as a bioadsorbent. Adsorption tests were conducted in batch mode at room temperature with constant stirring, and the results were analyzed using AAS. The objective of this study was to determine the optimum adsorption conditions using Response Surface Methodology (RSM) and to determine the adsorption capacity of the modified bioadsorbent based on the Freundlich or Langmuir adsorption isotherm models. The variations in bioadsorbent dose in this study were 2, 4, and 6 g/L; adsorption time variations were 30, 60, and 90 minutes; pH variations were 3, 4, and 5. Based on the design expert 13 RSM software, the optimum adsorption conditions for citric acid-modified bioadsorbent are a bioadsorbent dose of 3.957 g/L, time of 31.655 minutes, and pH of 4.968. For the EDTA-modified bioadsorbent, the optimum conditions were a bioadsorbent dose of 3.836 g/L, time of 30 minutes, and pH of 4.708. The results of the adsorption isotherm modeling indicate that the citric acid-modified and EDTA-modified bioadsorbents are more suitable for the Freundlich isotherm model due to their higher determination coefficient (R²). Thus, the adsorption capacities for the citric acid-modified and EDTA-modified bioadsorbents were determined to be 1.7828 mg/g and 1.5776 mg/g, respectively.
Anodizing Characterization of Aluminum 1100 Composition of Sulfuric Acid - Oxalic Acid 16% With Aeration and Nonaeration at Different Time Intervals Nurcahyo, Nurcahyo; Rizky, Rian Muhamad; Diningrat, Mangku Joyo; Adihartanto, Synbi Pasya Octaviarine; Khoirunisa, Tira Nur; Paramitha, Tifa
Journal of Green Science and Technology Vol 9 No 3 (2025): Journal of Green Science and Technology Vol. 9 No. 3 December 2025 Special Editio
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v9i3.10653

Abstract

Aluminum is a type of metal that is widely used in the industrial and household fields. This study aims to analyze the effect of variations in sulfuric acid and oxalic acid concentrations, as well as aeration systems, on the surface characteristics of aluminum 1100 through the anodizing process. The anodizing process is one of the surface treatment processes that is carried out with the aim of improving or improving the properties of a metal, including resistance to wear, increasing hardness, and aiming to beautify the appearance itself. This anodizing test is with sulfuric acid-oxalic acid electrolyte solution, electrolyte concentration 16%, at room temperature with a current density of 3/dm2 in time intervals of 20 minutes and 30 minutes. The data obtained from the test results showed that the oxide layer was formed maximally in the aeration system with a concentration of 13.5+2.5 and a time interval of 30 minutes of 0.0411 gr. This shows that the addition of oxalic acid and oxygen can accelerate the formation of the oxide layer. At electrolyte concentrations of 16+0, 15.5+0.5, 15+1, 14.5+1.5 and 14+2, there was an increase in the difference in oxide mass by 0.0337 gr, 0.0335 gr, 0.0366 gr, 0.0390 and 0.0411 gr.
Effectiveness Of Activated Carbon Of Reed (Imperata Cylindrica) As Methyl Orange Bioadsorbent with Batch Adsorption Method Suminar, Dian Ratna; Harianto, Dicky; Fauziah, Najmi; Febrian, Dea Tri; Kharisma, Luthfiana; Paramitha, Tifa
Journal of Green Science and Technology Vol 9 No 3 (2025): Journal of Green Science and Technology Vol. 9 No. 3 December 2025 Special Editio
Publisher : Faculty of Engineering, Universitas Swadaya Gunung Jati

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33603/jgst.v9i3.10655

Abstract

The use of synthetic textile dyes causes environmental problems, namely the waste produced is still colored and difficult to degrade. Methyl orange is a synthetic dye in the textile industry which has low solubility in water, is difficult to degrade, has the potential to be carcinogenic and is toxic. To overcome this, adsorption can be carried out using activated carbon from reeds. This research aims to find out how active carbon of reeds is absorbed in methyl orange using the batch method with Langmuir isotherm analysis. Research methods include pretreatment of reeds, manufacture and activation of reeds carbon, testing the characteristics of activated carbon, adsorption process, and analysis of adsorption results using a UV-Vis spectrophotometer. The research was carried out by varying the concentration of methyl orange solution, adsorption time, and mass of activated carbon used. From the research, optimum conditions were obtained for the methyl orange adsorption process using reed activated carbon for 120 minutes with an activated carbon mass of 0.3 grams, a final concentration of 7.328 ppm was obtained with an initial concentration of 10 ppm, and a % adsorption of 26.72%.
Co-Authors -, Alfiana Adhitasari Adihartanto, Synbi Pasya Octaviarine Agustin, Delliana Aji, Restu Alatif, Ikhsan Akmal Alfiana Adhitasari Amelia Nur Aliah Andrijanto, Eko Anggraini, Yuki Martha Aniqa Arjumand Bano Harvani Arijan Vevayose Tarigan Aulia, Bunga Azzahra, Nasya Azzahra, Rafila Chika Azzahra, Tarisha Aulia Bambang Soeswanto binti Jamaluddin, Jamarosliza Dianty Rosirda Dewi Kurnia Diningrat, Mangku Joyo Dwi Irmawati, Dwi Elizabeth, Lidya Endang Kusumawati Endang Kusumawati Fauzan, Rizky Fauziah, Najmi Febrian, Dea Tri Gamaliel Tanaka Harianto, Dicky Hariyadi, Tri Herawati Budiastuti Heru Hermawan Hidayatulloh, Irwan Irianto, Indra Jayanti, Retno Dwi Kharisma, Luthfiana Khoirunisa, Tira Nur Lestari Herlianti Putri Luviana, Angely Malik, Dava Maulana Manfaati, Rintis Muhammad Misbahussalam Muhari, Emma Hermawati Mujahidah, Nisa Rahmah Mukhtar Ghozali Ngatin, Agustinus Nidaulhusna, Anisa Nirmala Utami Nugraha, Teguh Aditya Nurbaits, Alisya Nurcahyo, Nurcahyo Nurhasanah, Santy Nurul Annisa Nurulgina, Rahma Permatasari, Rahma Puspa Putri, Angelina Rachmawati, Anissa Nurul Rahma Ardelia Raissa Rahmawati, Sri Puji Ramadhan, Muhammad Zikri Ramadhani, Laily lsna Retno Indarti Reynaldi, Randi Rivaldo Rofie Fauzi Budiman Rizky Setianto Rizky, Rian Muhamad Robby Sudarman Rusdianasari Rusdianasari Sabinna Azahra Sulaeman Salsabila, Iva Najwa Salsabila, Salwa Ainaya Salsabila, Shafira Salsabilla, Iva Najwa Sari, Radianti Novita Setiawan, Kiranna Shalmadevy Setyaningrum, Sinta Shafira Yulianthina Sihombing, Rony Sihombing, Rony Pasonang Silvia Fatimatur Rahmawati Suminar, Dian Ratna Suryadi, Joko Teguh Aditya Nugraha Teguh Taufiqurohim Tika Paramitha Tika Paramitha Tita Rosita Tri Hariyadi Tri Reksa Saputra Trirahayu, Dhyna Analyes Unung Leoanggraini Utami, Khoirunnisa Wardana Putra, Adzikri Yusuf, Yusmardhany Zahwa, Keisya Adellia