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Journal : International Journal of Renewable Energy Development

Effect of Temperature on Plasma-Assisted Catalytic Cracking of Palm Oil into Biofuels Istadi, I.; Riyanto, Teguh; Buchori, Luqman; Anggoro, Didi Dwi; Saputra, Roni Ade; Muhamad, Theobroma Guntur
International Journal of Renewable Energy Development Vol 9, No 1 (2020): February 2020
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.9.1.107-112

Abstract

Plasma-assisted catalytic cracking is an attractive method for producing biofuels from vegetable oil. This paper studied the effect of reactor temperature on the performance of plasma-assisted catalytic cracking of palm oil into biofuels. The cracking process was conducted in a Dielectric Barrier Discharge (DBD)-type plasma reactor with the presence of spent RFCC catalyst. The reactor temperature was varied at 400, 450, and 500 ºC. The liquid fuel product was analyzed using a gas chromatography-mass spectrometry (GC-MS) to determine the compositions. Result showed that the presenceof plasma and catalytic role can enhance the reactor performance so that the selectivity of the short-chain hydrocarbon produced increases. The selectivity of gasoline, kerosene, and diesel range fuels over the plasma-catalytic reactor were 16.43%, 52.74% and 21.25%, respectively, while the selectivity of gasoline, kerosene and diesel range fuels over a conventional fixed bed reactor was 12.07%, 39.07%, and 45.11%, respectively. The increasing reactor temperature led to enhanced catalytic role of cracking reaction,particularly directing the reaction to the shorter hydrocarbon range. The reactor temperature dependence on the liquid product components distribution over the plasma-catalytic reactor was also studied. The aromatic and oxygenated compounds increased with the reactor temperature.©2020. CBIORE-IJRED. All rights reserved
Biofuels Production from Catalytic Cracking of Palm Oil Using Modified HY Zeolite Catalysts over A Continuous Fixed Bed Catalytic Reactor Istadi, I.; Riyanto, Teguh; Buchori, Luqman; Anggoro, Didi D.; Pakpahan, Andre W. S.; Pakpahan, Agnes J.
International Journal of Renewable Energy Development Vol 10, No 1 (2021): February 2021
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2021.33281

Abstract

The increase in energy demand led to the challenging of alternative fuel development. Biofuels from palm oil through catalytic cracking appear as a promising alternative fuel. In this study, biofuel was produced from palm oil through catalytic cracking using the modified HY zeolite catalysts. The Ni and Co metals were impregnated on the HY catalyst through the wet-impregnation method. The catalysts were characterized using X-ray fluorescence, X-ray diffraction, Brunauer–Emmett–Teller (BET), Pyridine-probed Fourier-transform infrared (FTIR) spectroscopy, and Scanning Electron Microscopy (SEM) methods. The biofuels product obtained was analyzed using a gas chromatography-mass spectrometry (GC-MS) method to determine its composition. The metal impregnation on the HY catalyst could modify the acid site composition (Lewis and Brønsted acid sites), which had significant roles in the palm oil cracking to biofuels. Ni impregnation on HY zeolite led to the high cracking activity, while the Co impregnation led to the high deoxygenation activity. Interestingly, the co-impregnation of Ni and Co on HY catalyst could increase the catalyst activity in cracking and deoxygenation reactions. The yield of biofuels could be increased from 37.32% to 40.00% by using the modified HY catalyst. Furthermore, the selectivity of gasoline could be achieved up to 11.79%. The Ni and Co metals impregnation on HY zeolite has a promising result on both the cracking and deoxygenation process of palm oil to biofuels due to the role of each metal. This finding is valuable for further catalyst development, especially on bifunctional catalyst development for palm oil conversion to biofuels.
A Review on the Recent Breakthrough Methods and Influential Parameters in the Biodiesel Synthesis and Purification S. Silviana; Didi Dwi Anggoro; H. Hadiyanto; Cantika Aulia Salsabila; Kevin Aprilio; Anisa Widia Utami; Afriza Ni'matus Sa'adah; Febio Dalanta
International Journal of Renewable Energy Development Vol 11, No 4 (2022): November 2022
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2022.43147

Abstract

Biodiesel has recently received much attention as an energy source with numerous benefits such as high degradability, negligible toxicity, and minimal emissions of carbon monoxide gases as well as particulates. Therefore, this research aims to compare, review, and summarize the conventional and advanced methods of biodiesel production. Currently, some emerging processes that were developed for advanced biodiesel production include microwave-assisted synthesis, ultrasonic-assisted synthesis, supercritical transesterification, and liquid phase plasma discharge technology. The types of feedstocks, catalysts, and operating conditions as the influential parameters in biodiesel synthesis are also discussed. Moreover, in the purification process, the effectiveness of purification depends on the type of catalyst applied in the synthesis process. This research also reviewed and compared several commonly used purification methods such as wet and dry washing, ion exchange and precipitation, complexation, and membrane-based separation that have shown significant results along with the impacts of biodiesel production on environmental and economic sectors
Co-Authors Afriza Ni'matus Sa'adah Aji Prasetyaningrum Andri Cahyo Kumoro Anindita Indriana Anisa Widia Utami Antonio Giovanno Aprilina Purbasari Arif Budiarto Asep Muhamad Samsudin, Asep Muhamad Asmadi, Mohd Bintang Ayu Kalimantini Bobby Rio Indriyantho Buchori , Luqman Cantika Aulia Salsabila Chusnul Khotimah Diah Anggraeni Jatraningrum Dian Cahyaningrum Didik Prasetyoko Dyah Hesti Wardhani Dyah Hesti Wardhani Fachmy Adji Pangestu Setiawan Fadhil Rifqi P Faleh Setia Budi Fathoni, Moch Zaenal FatmaTsaniya Chamdani Febio Dalanta Ganish Eko Mayndra Giveni Christina Silaen H Hadiyanto H. Hadiyanto Hacker, Viktor Hartati Hartati Hartuti Purnaweni Haryono Setiyo Huboyo Hassan, Abdull Hafidz Herawati Oktaviani Herawati Oktavianty Hermawan, Hermawan Herry Santosa I. Istadi Imtinan, Alifa Bakhitah Indro Sumantri Ismail, Siti Norazian Istadi Jamarudin, Aizah Kamsi Nur Oktavia Kevin Aprilio Le Monde, Brilliant Umara Luqman B Luqman Buchori Lutfi Af’idatul Kamilah Melissa Justine Renjaan Mhd. Shaumi Al Anshar Muhamad, Theobroma Guntur Nabilah, Farhanah Nasher, Kharissa Nerfiana Fradevi Nino Rinaldi Nita A Nita Aryanti Nor Aishah Saidina Amin Nor Basid Adiwibawa Prasetya Nugroho, Agung Nur Hidayati Nur Rokhati Nurani Ikhlas Nurcahyani, Septra Nurdiani, Maulida Nurushofa, Faustina Alda P Purwanto Pakpahan, Agnes J. Pakpahan, Andre W. S. Prihiyandhoko, Hageng Primasatya, Dimas Priyo Atmaji Putra, Muhammad Fadila Putri Anggraeni Resti Nur Utami Riko Rikardo Putra Riko Rikardo Putra Riskatama Atmaji Rispiandi Rispiandi Riyanto, Teguh Rohmadona H Rolita, Lisa Roschger, Michaela S Subandriyo Salsabila, Unik Hanifah Saputra, Roni Ade Sari Octavianingrum Setia Budi S Setia Budi Sasongko Setia Budi Sasongko Setiadi, Iqfan Dwi Sigit B Silviana , Silviana Silviana Silviana Slamet Supriyadi Sulardjaka Sulardjaka Teguh Riyanto Triani, Meiri Udin Mabruro Vitus Dwi Yunianto Budi Ismadi Wahyu Bahari Setianto Wahyu Bahari Setianto Wahyudi, Dhiky Wibawa, Muhammad Hanif Dzikri Wirda Udaibah Yayuk Astuti Yayuk Mundriyastutik Yusof, Nurul Asyikin Zainol, Muzakkir Mohamad Zainol, Muzakkir Mohammad Zainuddin, Kamarul Ridwan Zakaria, Zaki Yamani Zaqiyah Addarojah Zulfikar Muriadiputra