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Elvianto Dwi Daryono

Institut Teknologi Nasional Malang

Author-ID : 256277

Agriculture, Biological Sciences & Forestry Humanities Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Decision Sciences, Operations Research & Management Education Energy Engineering Environmental Science Industrial & Manufacturing Engineering Languange, Linguistic, Communication & Media Materials Science & Nanotechnology Mechanical Engineering Social Sciences Other

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IN SITU TRANSESTERIFIKASI MINYAK BIJI MAHONI MENJADI METIL ESTER DENGAN CO-SOLVENT THF (TETRAHYDROFURAN) Elvianto Dwi Daryono; Adrianus Chrisantus Rengga; Imaniar Safitri
Reaktor Volume 15, No.1, APRIL 2014
Publisher : Dept. of Chemical Engineering, Diponegoro University

Tujuan dari penelitian adalah untuk mengkaji efektifitas penggunaan co-solvent THF pada reaksi transesterifikasi in situ minyak biji mahoni sebagai solusi proses pembuatan biodiesel yang efektif dan efisien. Variabel dan kondisi operasi meliputi katalis NaOH, kecepatan pengadukan 450 rpm, suhu reaksi suhu kamar, rasio molar minyak:metanol = 1:101,39, rasio molar katalis:minyak = 0,5:1, % FFA minyak 1,42%, kadar air biji 0,8%, waktu reaksi 3, 8, 13, 18, dan 23 menit serta rasio molar minyak:THF 1:47,15, 1:57,85 dan 1:67,85. Biji mahoni yang telah dikeringkan dan dihaluskan ukuran +20/-30 mesh sebanyak 50 gram dimasukkan dalam labu leher tiga yang dilengkapi pendingin balik dan ditambahkan metanol, THF dan katalis NaOH serta dilakukan reaksi sesuai dengan variabel dan kondisi operasi penelitian. Setelah reaksi selesai dipisahkan antara ampas dan filtratnya. Filtrat didistilasi pada suhu ± 70oC dan residu hasil distilasi dimasukkan dalam corong pemisah dan didiamkan selama ± 12 jam agar terbentuk 2 lapisan. Lapisan atas sebagai metil ester kemudian dianalisis konsentrasi metil oleatnya dengan GC. Dari data hasil penelitian didapatkan hasil terbaik pada rasio molar minyak:THF = 1:67,85 dan waktu reaksi 23 menit dengan konsentrasi metil oleat 59,10% dan yield metil ester 79,69%. Densitas metil ester 0,8791 g/cm3 memenuhi SNI 04-7182-2006 yaitu 0,85 – 0,89 g/cm3. Kata kunci : biodiesel, co-solvent, minyak biji mahoni, transesterifikasi in situ Abstract The purpose of this research was to assess the effectiveness of the use of co-solvent THF for in situ transesterification reaction mahogany seed oil as a biodiesel manufacturing process solutions that effectively and efficiently. Variables and operating conditions include catalyst NaOH, stirring speed of 450 rpm, room temperature the reaction temperature, molar ratio of oil: methanol = 1: 101.39, the molar ratio of catalyst: oil = 0.5: 1, % FFA oil is 1,42%, moisture content seed of 0.8%, reaction time is 3, 8, 13, 18, and 23 minutes, and the molar ratio of oil: THF is 1: 47.15, 1: 57.85 and 1: 67.85. Mahogany seeds that have been dried and pulverized size +20/-30 mesh as much as 50 grams included in the three-neck flask equipped condenser and added methanol, THF and catalyst NaOH and the reaction carried out in accordance with the variables and operating conditions. After the reaction is complete, the filtrate and cake was separated. The filtrate is distilled at a temperature of ± 70°C and the residue distilled included in the separating funnel and allowed to stand for ± 12 hours in order to form two layers. The top layer as methyl esters were analyzed by GC to concentrations of methyl oleate. From the research data obtained the best results at a molar ratio of oil: THF = 1: 67.85 and reaction time 23 minutes with methyl oleate concentration of 59.10% and yield methyl ester of 79.69%. Methyl ester density 0.8791 g/cm3 meet SNI 04-7182-2006 from 0.85 to 0.89 g/cm3. Keywords : biodiesel, co-solvent, in situ transesterification, mahogany seed oil

One-phase Transesterification of Palm Oil in to Biodiesel with Co-solvent Methyl Esters: The Effect of Adding Co-solvent to Kinetic Energy and Dipole Moment Elvianto Daryono; Lalu Mustiadi
Reaktor Volume 22 No. 1 April 2022
Publisher : Dept. of Chemical Engineering, Diponegoro University

In the transesterification process, the problem is the low solubility of oil in methanol, so the reaction will run slowly. The solution to this problem is to add a co-solvent to increase the solubility so that a one-phase reaction will be formed. The co-solvent methyl ester is the right choice because it is a product of the reaction itself so that it does not require a separation process. The operating conditions of the study were mass of palm oil 250 g, mass of NaOH catalyst 0.8%wt, stirring speed 100 rpm, reaction temperature 60oC, the molar ratio of oil:methanol = 1:6, reaction time (5,10,15,20,25,30 minutes), and the mass of co-solvent (0,5,10,15%wt). The first stage of the research was to make co-solvent, then proceed with the transesterification reaction by adding co-solvent which was carried out according to the research operating conditions. The optimum condition of the study was obtained at reaction time 30 minutes and the addition of co-solvent 5%, with yield 97.4171%. The density of FAME 0.88 g/mL and the concentration of FAME 99.963% which complied with SNI 7185-2015. The simulation results of ChemDraw for components of triglyceride+methanol+NaOH+co-solvent obtained kinetic energy 3479.0264 kJ/mol and dipole moment 43279.8007 debyes.

Co-Authors Adam Yonanda Adi Sintoyo Adrianus Chrisantus Rengga Ahmad Faizal Alfiniam Ahmad Isnaini, Ahmad Dio Ajeng Oktavian Dwi Ana Anggorowati Dzaky Aqillah Fikriansyah Eka Maretyaningsih Agung Purwanti Endah Kusuma Rastini Erni Junita Sinaga Faidliyah Nilna Minah Febriara Fassa Aulia Rahman Firyaal Putri Verdina Fitri Icha Oryza Sativa Gunawan, Rendi Chandra Hudha, Mohammad Hutasoit, Gading F Imaniar Safitri Jimmy Lalu Mustiadi Maya Sista, Eliya Miftachul Arif Pratama Miraekel January Ekfar Princessa Mohammad Istnaeny Hudha Muyassaroh MUYASSAROH Muyassaroh Muyassaroh Nanik Astuti Rahman Puji Prasetyo, Angga Pursitta, Anggriarida Titta Qori Kurrota Aini Rendi Chandra Gunawan Rini Kartika Rini Kartika Dewi Rizky Nartika Nurfitri Sintoyo, Adi Siswi Astuti SYAIFUL BAHRI Theresia Sufin Tia Ardya Wahyu Cahyani Tri Poespowati Vina Nur Laily Zahra, Hadryza Anduanda Zukhriyah Zukhriyah

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