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All Journal Jurnal Rekayasa Proses Reaktor International Journal of Renewable Energy Development Journal of Engineering and Technological Sciences Jurnal Chemurgy Chemistry Indonesian Journal of Chemical Research Jurnal Rekayasa Proses FLUIDA Jurnal Teknik ASEAN Journal of Chemical Engineering Equilibrium Journal of Chemical Engineering Jurnal Teknik Kimia Indonesia Jurnal Teknik Kimia dan Lingkungan International Journal of Renewable Energy Development Jurnal Rekayasa Proses Journal of Engineering and Technological Sciences Scientific Contributions Oil and Gas
Tirto Prakoso
Chemical Engineering Department, Faculty Of Industrial Technology, Institut Teknologi Bandung
Aerospace Engineering Automotive Engineering Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Control & Systems Engineering Earth & Planetary Sciences Education Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mechanical Engineering Social Sciences

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Synthesis and Characterization of Hydrochar and Bio-oil from Hydrothermal Carbonization of Sargassum sp. using Choline Chloride (ChCl) Catalyst Heri Rustamaji; Tirto Prakoso; Jenny Rizkiana; Hary Devianto; Pramujo Widiatmoko; Guoqing Guan
International Journal of Renewable Energy Development Vol 11, No 2 (2022): May 2022
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2022.42595

Abstract

The purpose of this study is to alter the biomass of Sargassum sp. into elective fills and high valuable biomaterials in a hydrothermal process at 200oC for 90 minutes, using ZnCl2 and CaCl2 activating agents, withChClas a catalyst. This method generatedthree primaryoutputs: hydrochar, bio-oil, and gasproducts. ChCl to water ratio varies from 1:3, 1:1, and 3:1. The hydrochar yield improved when the catalyst ratio was increased, but the bio-oil and gas yield declined. The highest hydrochar yields were 76.95, 63.25, and 44.16 percent in ZnCl2, CaCl2, and no activating agent samples, respectively.The porosity analysis observed mesopore structures with the most pore diameters between 3.9-5.2 nm with a surface area between 44.71-55.2. The attribute of interaction between activator and catalyst plays a role in pore formation. The hydrochar products with CaCl2 showed the best thermal stability. From the whole experiment, the optimum hydrochar yield (76.95%), optimum surface area (55.42 m2 g-1), and the increase in carbon content from 21.11 to 37.8% were achieved at the ratio of ChCl to water was three, and the activating agent of ZnCl2. The predominant bio-oil components were hexadecane, hexadecanoic, and 9-octadecenoic acids, with a composition of 51.65, 21.44, and 9.87%, respectively the remaining contained aromatic alkanes and other fatty acids. The findings of this study reported that adding activating agents and catalysts improve hydrochar yield and characteristics of hydrochar and bio-oil products, suggesting the potential of hydrochar as a solid fuel or biomaterial and bio-oil as liquid biofuel
Exploration of Novel Lipase from Plant Seeds and Plant Latexes Istyami, Astri Nur; Sari, Myra Wardati; Gultom, Cristy Hagi; Prakoso, Tirto; Soerawidjaja, Tatang Hernas
Indonesian Journal of Chemical Research Vol 12 No 1 (2024): Edition for May 2024
Publisher : Jurusan Kimia, Fakultas Sains dan Teknologi, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2024.12-ist

Abstract

As the demand for fatty acids increases, the enzymatic process of triglyceride hydrolysis emerges as a promising technology. Compared to microbial lipase, utilization of plant lipase is more practical due to its ease of preparation and cost-efficiency. This work aimed to verify the degree of lipolysis of several novel lipase sources from plants. Novel lipase sources investigated were seeds of kapok (Ceiba pentandra), java almond (Sterculia foetida), pongam (Milletia pinnata), sea mango (Cerbera manghas), tamanu (Calophyllum inophyllum), latex of sea mango, aveloz (Euphorbia tirucalli), and jackfruit (Artocarpus heterophyllus). Several acknowledged plant lipase sources were also compared, i.e. seeds of castor bean (Ricinus communis), physic nut (Jatropha curcas), rice bran (Oryza sativa), latex of frangipani (Plumeria rubra) and papaya (Carica papaya). Plant lipase was utilized in the hydrolysis of olive oil at room temperature. Results for seed and latex lipase were compared and technical issues were reported. Several plant lipases are remarkably active and potential to compete with microorganism lipases in industrial applications.
Comparative study of nyamplung (Callophylum inophyllum) kernel oil obtained from mechanical and chemical extraction for biofuel production Hanifah Widiastuti; Meiti Pratiwi; Godlief F. Neonufa; Tatang H. Soerawidjaja; Tirto Prakoso
Jurnal Rekayasa Proses Vol 13 No 2 (2019): Volume 13, Number 2, 2019
Publisher : Jurnal Rekayasa Proses

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.42816

Abstract

Nyamplung (Callophylum inophyllum) contains oil around 40-73% in its seed. It has recently gained recognition as a potential source for biofuel production. The oil recovery process from renewable sources such as nyamplung is widely carried out by using chemical extraction with solvents. Nevertheless, this method is considered costly and there are safety issues as well as environmental concerns related to the solvents used. Therefore, mechanical extraction has emerged as an alternative method. In this study, the nyamplung oil recovered by mechanical extraction via hydraulic press and chemical extraction utilizing Soxhlet extraction was compared. Soxhlet extraction was carried out by using n-hexane as a solvent with a temperature of 70 oC for 5 hours. Before the extraction process, the kernel was initially pretreated to reduce the particle sizes and the water content. The results show that the oil yield recovered using the hydraulic press is 58%, which is comparable with the value obtained from Soxhlet extraction (65%). The oil characteristics were also compared, and the profiling shows no significant difference in the properties (saponification value, acid value, and iodine value) of oils recovered using both methods. The composition of fatty acids was also analyzed for utilization as a biofuel feedstock. Higher content of oleic acid was observed in oil resulted from chemical extraction while mechanical extraction yielded oil with higher palmitic acid content.
The Study of Hydrothermal Carbonization and Activation Factors' Effect on Mesoporous Activated Carbon Production From Sargassum sp. Using a Multilevel Factorial Design Prakoso, Tirto; Rustamaji, Heri; Yonathan, Daniel; Devianto, Hary; Widiatmoko, Pramujo; Rizkiana, Jenny; Guan, Guoqing
Reaktor Volume 22 No.2 August 2022
Publisher : Department of Chemical Engineering, Faculty of Engineering, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/reaktor.22.2.59-69

Abstract

Seaweeds are large-scale multicellular marine algae categorized based on color as Chlorophyceae, Rhodophyceae, and Phaeophyceae. No information has been provided on the conditions affecting the production of mesoporous activated carbon from one member of the described aquatic plants, namely Sargassum sp. Therefore, this study aimed to determine the impact of the main factors and their interactions on Sargassum sp.-derived activated carbon manufactured (SAC) by hydrothermal carbonization and CO2 activation methods. A mathematical approach was employed using a multilevel factorial design with the main factors being the activator type (ZnCl2, CaCl2, & KOH), hydrothermal temperature (200, 225, & 250oC), and activator ratios (2 & 4). Meanwhile, the response variables were yield and BET surface area (SBET) of SAC. Morphological, functional, crystallographic, and porosity characterization was carried out on the samples. The SAC-Ca-200-2 sample had the highest yield, with the value being 26.5 percent of weight. The activators having the highest specific surface area (SBET) were SAC-Zn-250-4, SAC-Ca-225-2, and SAC-K-250-2, with 1552, 1368, and 1799 m2/g, respectively. The pore size distribution in SAC products ranged from 2.16 to 10 nm in diameter. The analysis conducted indicated the activator type and interaction with its ratio substantially impacted the SAC yield value; besides, only the activator type affects the formation of high surface area pores.
Synthesis of rubber seed shell-derived porous activated carbons for promising supercapacitor application Rustamaji, Heri; Prakoso, Tirto; Devianto, Hary; Widiatmoko, Pramujo; Febriyanto, Pramahadi; Ginting, Simparmin br; Darmansyah, Darmansyah
International Journal of Renewable Energy Development Vol 14, No 2 (2025): March 2025
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2025.60869

Abstract

This work investigates synthesizing activated carbon obtained from rubber seed shells utilizing several activating agents (KOH, CaCl2, and ZnCl2) for supercapacitor applications. Activated carbon was produced from a rubber seed shell using hydrothermal carbonization at 275 °C for 60 minutes and a 120-minute activation treatment at 800 °C. Various activating agents pronounced impacted the pore architecture, surface area, crystallinity, and level of graphitization, which collectively determined the electrochemical characteristics of the resulting materials. Incorporating activation agents enhances the specific surface area and influences the extent of graphitization of activated carbon. The specific surface area of activated carbon products ranges from 367 to 735.2 m² g⁻¹. Further investigation through electrochemical analysis, conducted with a carefully engineered two-electrode system, demonstrated a peak electrode capacitance value of 246 F g-1 at 50 mA g-1 for an ACZn-based supercapacitor. Supercapacitor cells’ energy and power densities reached significant levels, measuring 5.47 Wh kg-1 and 246 W kg-1, respectively. The RSS-derived activated carbon-based supercapacitor exhibited remarkable longevity in a 5000-cycle test, with consistent capacitance retention and coulombic efficiency of 100.11% and 100%, respectively. This work presents a sustainable pathway for producing activated carbon electrodes, contributing to the global circular economy and demonstrating considerable industrial potential.
Morphological and thermal stability analysis of Sn/C electrodes synthesized through impregnation and precipitation methods for CO2 electroreduction Eviani, Mitra; Prakoso, Tirto; Kusdiana, Dadan; Widiatmoko, Pramujo; Devianto, Hary
International Journal of Renewable Energy Development Vol 14, No 5 (2025): September 2025
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2025.61280

Abstract

This study investigates tin (Sn) based electrodes supported by graphite for the electrochemical reduction of carbon dioxide (ECO2R) to formic acid, comparing precipitation and impregnation synthesis methods. Electrodes were characterized using Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Thermogravimetric Analysis (TGA), Cyclic Voltammetry (CV), Chronoamperometry, and Electrochemical Impedance Spectroscopy (EIS). The precipitation method yielded higher Sn content (91.22%) and superior thermal stability (3% mass loss at 1000°C vs. 45% for impregnation). Morphological analysis through SEM revealed precipitation-synthesized electrodes exhibited more uniform Sn particle distribution across the graphite surface, while impregnation resulted in larger Sn agglomerates with less homogeneous coverage, significantly influencing electroactive surface area and catalytic performance. The electrochemical performance of electrodes was tested using H-cell. CV showed decreased cathodic current for Sn/C electrodes compared to pure graphite in CO2-saturated electrolyte, while chronoamperometry indicated slightly better sustained performance for precipitation-synthesized electrodes with stabilized current densities after 3 hours of operation. EIS analysis suggested the precipitation method yields a marginally lower ohmic resistance (28.8 Ω vs. 29.8 Ω), resulting in a more favorable electrode structure for overall catalytic activity. Both methods showed lower ohmic resistance than that of pure graphite (38.1 Ω), the precipitation-synthesized Sn/C electrode emerged as the preferred selection for ECO2R to formic acid, balancing high Sn content, thermal stability, superior durability, and better Faradaic efficiency. The observed performance differences were attributed to distinct metal-support interactions formed during synthesis, with precipitation creating stronger metal-carbon bonds that enhance stability but potentially limit certain active sites necessary for optimal CO2 reduction kinetics. This comprehensive characterization revealed that the precipitation-synthesized electrode offers the most promising foundation for further development, potentially through process optimization, hybrid synthesis approaches, or targeted doping strategies to enhance catalytic activity while maintaining the advantageous stability characteristics.
Hidrogenasi Hidrotermal Katalitik Asam Oleat dengan Produksi Hidrogen secara in-situ Menggunakan Katalis NiO/y-Al2O3 Nainggolan, Federiko Markus Lasardo; Tirto Prakoso; Meiti Pratiwi
Jurnal Teknik: Media Pengembangan Ilmu dan Aplikasi Teknik Vol 22 No 2 (2023): Jurnal Teknik - Media Pengembangan Ilmu dan Aplikasi Teknik
Publisher : Fakultas Teknik - Universitas Jenderal Achmad Yani

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55893/jt.vol22no2.580

Abstract

Hydrogenation reaction is one of the most important reactions for the oleochemical industry to convert unsaturated fatty acids into saturated fatty acids and their derivatives. The need for large amounts of hydrogen in hydrogenation reactions will be a problem in terms of hydrogen availability and economy. Catalytic hydrothermal technology offers several advantages including the ability to produce hydrogen in-situ. The focus of this research is to evaluate the effect of metal charge addition on the catalyst, the effect of tin addition on NiO/y-Al2O3 catalyst and the effect of glycerol addition as a source of H2 production in-situ on the hydrogenation conversion of oleic acid. The catalyst was prepared by dry impregnation method. XRD, XRF and BET characterization of the catalysts confirmed the presence of Ni and Sn metals on the catalysts. Hydrogenation conversion in the reaction without glycerol using NiO/y-Al2O3 catalyst at 300oC for 6 hours did not show significant changes with the addition of metal loading. However, the addition of Sn metal increased the selectivity of in-situ H2 production used to hydrogenate oleic acid with a hydrogenation conversion of 36%. The addition of glycerol to the reactants also increased the hydrogenation conversion compared to the reaction without glycerol.
Pemodelan Proses dan Evaluasi Ekonomi Produksi Bio-Oil dari Limbah Tandan Kosong Kelapa Sawit Fanany, Muhammad Rifki; Septhian Marno; Tirto Prakoso; Aqsha Aqsha; Astri Nur Istyami; Meiti Pratiwi; Indarto, Antonius
Jurnal Teknik: Media Pengembangan Ilmu dan Aplikasi Teknik Vol 22 No 2 (2023): Jurnal Teknik - Media Pengembangan Ilmu dan Aplikasi Teknik
Publisher : Fakultas Teknik - Universitas Jenderal Achmad Yani

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.55893/jt.vol22no2.587

Abstract

Oil palm empty fruit bunches (OPEFB) are solid waste which is the residue from processing palm oil into crude palm oil (CPO). The high number of OPEFB produced requires proper handling to minimize the negative impact on the surrounding environment. One of the solutions to deal with this is to process OPEFB into bio-oil using fast pyrolysis technology. Before applying the process in the real world, it is necessary to do an economic evaluation first to find out whether the process can be economically profitable. This study aims to carry out an economic evaluation of the bio-oil production process made from OPEFB using fast pyrolysis technology. Aspen Plus was used in this study to carry out process modeling, while the economic evaluation was based on several literatures such as previous books and journals. Based on the results of the economic evaluation, the total capital cost (TCC) required to build this facility is USD 1,152,686 with an operating expenditure (OpEx) of USD 168,107. Then, from the economic indicators in the form of payback period (PBP) and internal rate of return (IRR), this facility takes 4 years to reach PBP with an IRR of 22%.
Hematite-Gamma Alumina-based Solid Catalyst Development for Biodiesel Production from Palm Oil Rizkiana, Jenny; Bryan, Bryan; Gozali, Edbert; Bustomi, Agus Tendi Ahmad; Prakoso, Tirto
Journal of Engineering and Technological Sciences Vol. 56 No. 1 (2024)
Publisher : Directorate for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2024.56.1.4

Abstract

This research investigated the performance of hematite-gamma alumina (Fe2O3/γ-Al2O3) catalyst in biodiesel production from palm oil. A full factorial experimental design was utilized to analyze the effect of hematite content, catalyst loading, and methanol-to-oil ratio on catalyst performance. From the experiment, biodiesel in the range of 73.6 to 87.6% FAME content was obtained. It was concluded that the catalyst composition, the methanol-to-oil ratio, and the catalyst loading have a significant effect on the FAME content of the biodiesel. Hematite has strong affinity for fatty acids, so a larger hematite surface area will result in a higher fatty acid absorption capacity. The addition of excess methanol can reduce the contact inhibition between the reactants and the active site of the catalyst, thereby increasing the conversion rate of the reaction. Moreover, a higher amount of catalyst loading can result in an increase in the FAME content when accompanied by an increase in the hematite content of the catalyst.
Development and Fabrication of a Pressure Swing Adsorption System Using Molecular Sieve 13X for Integrated CO₂ Capture and Electrochemical Conversion Mitra Eviani; Tirto Prakoso; Dadan Kusdiana; Pramujo Widiatmoko; Ida Bagus Oka Lyong Budhatama; Setyo Yanus Sasongko; Aryan Fathoni Amri; Wibawa Hendra Saputera; Hary Devianto
Scientific Contributions Oil and Gas Vol 48 No 2 (2025)
Publisher : Testing Center for Oil and Gas LEMIGAS

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/scog.v48i2.1772

Abstract

This study focuses on the development and performance evaluation of a Pressure Swing Adsorption (PSA) system utilizing molecular sieve Zeolite 13X for CO2 capture. A fixed-bed reactor was designed and simulated with Aspen Adsorption to optimise adsorption conditions. The system, tested with a 24.75 L/min gas feed (10% CO2, 90% N2) at 30 °C and 6 bar, operated cyclically every 7 minutes. Simulation results recommended a reactor volume of 4.9 L (ID 102 mm × T/T 600 mm). Sensitivity analysis showed that adsorption capacity declined as CO2 concentration increased, with CO2 uptake decreasing from 24.75 L/min at 10%-mol to 8.44 L/min at 70%-mol. Key design parameters such as feed flow rate, intraparticle voids, bulk density, and particle size were also evaluated. A prototype was built based on simulation results and tested, achieving a 120 s breakthrough time and an optimal 60 s swing interval over 17 cycles. This work supports the future integration of PSA-based CO2 capture with electrochemical CO2 reduction (ECO2R).
Co-Authors Akiko Tanaka Akiko Tanaka Aqsha Aqsha Arry K. Rizky Aryan Fathoni Amri Astri Nur Istyami Astri Nur Istyami Azura, Nur Bryan Bryan Bustomi, Agus Tendi Ahmad Dadan Kusdiana Dadan Kusdiana Daniel Yonathan, Daniel Danu Wicaksana DARMANSYAH . Endar Puspawiningtiyas Eviani, Mitra Fanany, Muhammad Rifki Febriyanto, Pramahadi Godlief F. Neonufa Gozali, Edbert Guan, Guoqing Gultom, Cristy Hagi Guoqing Guan Hanifah Widiastuti Hary Devianto Heri Rustamaji Ida Bagus Oka Lyong Budhatama Indarto, Antonius Indra G. Pasaribu Isdiriayani Nurdin Istyami, Astri Nur Jenny Rizkiana Jenny Rizkiana Johnner P. Sitompul Kembara Alam, Alif Kurniawan, Indra B M.T.A.P. Kresnowati Makertihartha, I Gusti Bagus Ngurah Maria Mahardini Sakanti Mario C. Gultom Meiti Pratiwi Meiti Pratiwi Meiti Pratiwi Melyna, Ella Mitra Eviani Nainggolan, Federiko Markus Lasardo Nugroho, R Heru Parncheewa Udomsap Parncheewa Udomsap Pilanda Lembono Pradana, Yano Surya Pramujo Widiatmoko Pramujo Widiatmoko Pramujo Widiatmoko Pramujo Widiatmoko Pratiwi, Meiti Retno G. Dewi Rizkiana, Jenny Roy Winarso S Subagjo Saputera, Wibawa Hendra Sarastri Cintya Hapsari Sari, Myra Wardati Septhian Marno Setyo Yanus Sasongko Shinichi Goto Shinichi Goto Simparmin br Ginting Soerawidjaja, Tatang H. Subagjo Subagjo Tantra Diwa Larasati Tatang H Soerawidjaja Tatang H. Soerawidjaja Tatang H. Soerawidjaja Tatang H. Soerawidjaja Tatang H. Soerawidjaja Tatang Hernas Soerawidjaja Tatang Hernas Soerawidjaja Tatang Hernas Soerawidjaja Tatang Hernas Soerawidjaja Tatang Hernas Soerawidjaja Tatang Hernas Soerawidjaja Tatang Hernas Soerawidjaja Toshihiro Hirotsu Toshihiro Hirotsu Widdy Andya Fanny Widiatmoko, Pramujo Yoel Pasae