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Synthesis and Characterization of Diesel Lubricity Enhancer through Transesterification Reaction of Palm Oil with 1,2-Ethanediol Yulfi Zetra; Sovia Masfuri Walidatus Sholihah; R. Y. Perry Burhan; R. Arizal Firmansyah
Automotive Experiences Vol 4 No 2 (2021)
Publisher : Automotive Laboratory of Universitas Muhammadiyah Magelang in collaboration with Association of Indonesian Vocational Educators (AIVE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (693.084 KB) | DOI: 10.31603/ae.4664

Abstract

Desulphurization of diesel fuel is necessary to be done to reduce sulphur content in the air. However, the desulphurization process will reduce the lubrication properties of diesel fuel. In order to overcome the problem, it needs bioadditive to improve the lubricity. Lubricity of diesel fuel can be improved by the subsistence of chemical compound that is hydroxyethyl esther (HEE). HEE is synthesized through the transesterification reaction of palm oil (triglycerides) and 1,2 ethanediol at 150 °C for 5 hours and K2CO3 catalyst as well. The conversion of TG into the products is 72.90%. The characterization using Gas Chromatography-Mass Spectrometry (GC-MS) indicates that the chemical compound in synthesis products comprise free fatty acids, hydroxyethyl esters and by-products. The obtained products can be used as bioadditives to improve the lubricity of diesel fuel.
Synthesis of Bio-additive for Low Sulphur Diesel: Transesterification of Soybean Oil and Ethylene Glycol using K2CO3 Catalyst Rhiby Ainur Basit Hariyanto; R. Arizal Firmansyah; R. Y. Perry Burhan; Yulfi Zetra
Automotive Experiences Vol 4 No 1 (2021)
Publisher : Automotive Laboratory of Universitas Muhammadiyah Magelang in collaboration with Association of Indonesian Vocational Educators (AIVE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (546.03 KB) | DOI: 10.31603/ae.4694

Abstract

The desulphurization process of diesel fuel is carried out to reduce the amount of SO2 emissions that can cause acid rain. However, the desulphurization process in diesel fuel not only removes the sulfur compounds but polyaromatic and polar compounds are also eliminated during this process. The loss of these two compounds can reduce the lubricity properties of diesel fuel. Therefore, it is necessary to add an additive compound that can increase the lubricity properties. In this research, 2-hydroxyethyl ester (HEE) was synthesized as an additive to increase the lubricity of diesel fuel. This compound was synthesized through the transesterification reaction of soybean oil and ethylene glycol with K2CO3 as the base catalyst. The composition of the synthesized additives was analyzed using the Gas Chromatography-Mass Spectrometry (GC-MS). Based on the results of GC-MS spectrum analysis, it is known that the 2-hydroxyethyl ester compound has been formed with a yield of 66.5% (relative to the area of the chromatogram peak). The HEE compound obtained is a mixture of 2 hydroxyethyl palmitate, 2 hydroxyethyl linoleate, 2 hydroxyethyl stearate, 2 hydroxyethyl arachidonate, 2 hydroxyethyl nervate, and 2 hydroxyethyl behenate.
Karakteristik Geokimia Organik Fraksi Keton Batubara Sawahlunto, Sumatera Barat Yulfi Zetra; Amirotul Ula; Zjahra Vianita Nugraheni; R.Y Perry Burhan
Akta Kimia Indonesia Vol 2, No 1 (2017)
Publisher : LPPM, Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (653.736 KB) | DOI: 10.12962/j25493736.v2i1.2289

Abstract

Batubara Sawahlunto, Sumatera Barat dianalisis untuk menentukan karakter geokimia organiknya. Batubara diekstraksi soxhlet dengan pelarut diklorometana:metanol (93:7). Hasil ekstrak organik difraksinasi menggunakan kromatografi kolom. Fraksi keton kemudian dianalisis menggunakan Kromatografi Gas-Spektrometri Massa (KG-SM). Analisis fraksi keton batubara Sawahlunto menunjukkan keberadaan senyawa iso dan anteiso-alkan-2-on, dan isoprenoid keton. Senyawa ini diasumsikan berasal dari rantai klorofil-α pada bakteri. Senyawa hopanon dan sikloheksil keton menunjukkan asal usul batubara dari bakteri. Peringkat kematangan batubara Sawahlunto adalah rendah dikarenakan terdapat senyawa hopanon pada batubara Sawahlunto. Proses kematangan batubara juga dapat terhambat jika komponen yang ada pada batubara berikatan dengan oksigen
UPAYA re-PRODUKSI SUMUR TUA CEKUNGAN WONOCOLO MELALUI KARAKTERISASI GEOKIMIA ORGANIK R. Y Perry Burhan; Yulfi Zetra; Pusparatu Pusparatu; Zjahra Vianita Nugraheni
Akta Kimia Indonesia Vol 4, No 1 (2019)
Publisher : LPPM, Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (662.754 KB) | DOI: 10.12962/j25493736.v4i1.4729

Abstract

Penelitian yang dilakukan terhadap biomarka fraksi hidrokarbon alifatik menunjukkan adanya senyawa n-alkana (n-C13 - n-C27); isoprenoid pristana (Pr) dan fitana (Ph); 4,4,8,9,9-pentametildekalina; 4-b-(H)-eudesmana; 8-b-(H)-drimana; 2,3,6,9,9-pentametildekalina dan 8-b-(H)-homodrimana. Pola distribusi kelompok biomarka n-alkana ditunjukkan oleh persebaran unimodal n-C13 - n-C27, yang menunjukkan asal usul senyawa organik sedimen terdistribusi merata berasal dari fitoplankton dan zooplankton, bakteri dan tumbuhan tingkat tinggi. Rasio Pr > Ph merupakan indikator lingkungan pengendapan oksik dengan kadar garam yang rendah. Adanya senyawa 4-b-(H)-eudesmana mengindikasikan senyawa organik berasal dari tumbuhan darat tingkat tinggi konifer yang tumbuh pada zaman Devonian Akhir. Keberadaan senyawa 8-b-(H)-drimana mengindikasikan adanya masukan alga hijau, plankton dan bakteri Botryococcus braunii. Namun tingginya kelimpahan senyawa 8-b-(H)-homodrimana dibandingkan kelompok senyawa sesquiterpena lainnya merupakan indikator senyawa organik yang berasal dari tumbuhan darat tingkat tinggi. Kontribusi biomarka yang berhasil diungkapkan pada penelitian ini menunjukkan bahwa sedimen sumur tua Wonocolo ini adalah unik dan menarik untuk dipelajari lebih lanjut karena senyawa organiknya variatif, berasal dari bakteri, plankton dan tumbuhan darat tingkat tinggi.
PENINGKATAN KETERAMPILAN PEMBUATAN DAN PEMASARAN KECAP BIJI NANGKA: ALTERNATIF BAHAN PENDAMPING MAKANAN DI KEPUTIH SURABAYA Endah Mutiara Marhaeni Putri; Wahyu Prasetyo Utomo; Zein Firdaus Ramadhan; R.Y. Perry Burhan; M. Rachimoellah; Fahimah Martak; Agus Wahyudi; Yulfi Zetra; M. Nadjib Mujahid; Zjahra Vianita Nugraheni
ABDIMAS ALTRUIS: Jurnal Pengabdian Kepada Masyarakat Vol 2, No 1 (2019): April 2019
Publisher : Universitas Sanata Dharma

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (713.134 KB) | DOI: 10.24071/aa.v2i1.2128

Abstract

Synthesis of 2-Hydroxyethyl Esters from Castor Oil as Lubrication Bio-Additive Candidates for Low-Sulfur Fossil Diesel Arizal Firmansyah; Yulfi Zetra; Rafwan Year Perry Burhan; Didik Prasetyoko; Novesar Jamarun
Indonesian Journal of Chemistry Vol 22, No 3 (2022)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.73038

Abstract

The present work aims to study the synthesis of 2-hydroxyethyl esters from castor oil and its lubrication properties, promising as a lubrication bio-additive in low sulfur diesel fuel. This compound has been successfully synthesized from castor oil and ethylene glycol. The oil to ethylene glycol molar ratio was adjusted to 1:10, and the catalyst loading was used at 9% mole oil. Then, the mixture was refluxed for 5 h. The product components were characterized using GC-MS. The standard ASTM method was used to study the kinematic viscosity and lubrication. The product was dominated by 2-hydroxyethyl esters (94.16%), di-ester (1.12%), and cyclic ester (1.92%). The analysis of friction coefficient and wear scar diameter (WSD) using High-Frequency Reciprocating Rig (HFRR) shows the coefficient of friction and WSD of the product better than reference diesel fuel. From the results of this study, the 2-hydroxyethyl ester of castor oil, especially 2-hydroxyethyl ricinoleate, is the main responsible for the lubricating properties. Thus, 2-hydroxyethyl esters of castor oil can be proposed as an alternative bio-additive to improve the lubrication of low-sulfur fossil diesel fuels.
Low-Calorie Coal Liquefaction Products as an Alternative Fuel Oil Yulfi Zetra; Anis Febriati; Dyah Nirmala; Rafwan Year Perry Burhan; Arizal Firmansyah; Zjahra Vianita Nugraheni
Indonesian Journal of Chemistry Vol 22, No 6 (2022)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.74584

Abstract

Liquefaction of low-rank coal has been done to optimize the utilization of low-rank coal, which is less economical for obtaining alternative fuel oil. Coal samples were taken from the Bukit Pinang coal mine, Samarinda Ulu, East Kalimantan. Coal was liquefied using the NEDOL procedure at PUSPITEK, Serpong, South Tangerang, Indonesia. This Bukit Pinang coal liquefaction produces five fractions consisting of Naphta, Light Oil (LO), Middle Oil (MO), Heavy Oil (HO), and Coal Liquid Bottom (CLB) fractions. The liquefaction yield was dominated by the HO and CLB fractions (> 50% by weight). The naphtha, MO and LO fractions were fractionated using SiO2 GF254 Thin Layer Chromatography (TLC) plate. It produced aliphatic and aromatic hydrocarbon fractions. Aliphatic hydrocarbon fractions were analyzed using a Gas Chromatography-Mass Spectrometer (GC-MS), while the aromatic hydrocarbon fractions were not analyzed. Mass spectrum studies showed that the components consisted of n-alkanes, isoalkanes (branched alkanes), cycloalkanes and alkyl cycloalkanes. The aliphatic hydrocarbon components resulting from the liquefaction of low-rank coal showed its equivalence with the components that make up fuel oil. Therefore, this coal liquefaction can be suggested as an optimization for low-rank coal, which is less economical.
Analisis Aspek Molekuler Biomarka Alkana Bercabang Core Badak 1/208 Muara Badak, Kutai Kartanegara, Kalimantan Timur R. Arizal Firmansyah; R. Y. Perry Burhan
Journal of Natural Sciences and Mathematics Research Vol 1, No 1 (2015): June
Publisher : Faculty of Science and Technology, Universitas Islam Negeri Walisongo Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (72.184 KB) | DOI: 10.21580/jnsmr.2015.1.1.481

Abstract

Study compound biomarka branched alkanes on core 1/208 Rhinos have done to contribute to the activities of oil exploration wells 1/208 Muara Badak Badak, East Kalimantan's Kutai Kartanegara-through core biomarka profile branched alkanes. Core samples extracted by alternately with solvent mixture of toluene-methanol (3: 1) and chloroform-methanol (3: 1). Then fractionated by Column Chromatography and Thin Layer Chromatography to obtain aliphatic hydrocarbon fraction. Fractions obtained were identified using Gas Chromatography-Mass Spectrometry.The content biomarka aliphatichydrocarbon fraction were identified, among others, iso and anteiso alkanes, mono and trimethyl alkanes. Compounds iso and anteiso alkanes, and alkyl alkane other, providing information that the source of organic material core samples I and II is derived from microorganisms prokaryotic or biogenic precursor derived from cyanobacteria (marine microorganisms) and homologous monomethyl alkanes found in core samples II closer homologous series monomethyl alkanes found in sediments and oil and Precambrian Proterozoic era, so it can be said that the core sample II core samples older than I.
GEOKIMIA ORGANIK FRAKSI AROMATIK LIGHT OIL PRODUK PENCAIRAN BATUBARA AREA (PIT) BINTANG SANGATTA KALIMANTAN TIMUR Lukman Sugiharto Wijaya; R. Y. Perry Burhan
Journal of Research and Technology Vol. 2 No. 1 (2016): JRT Volume 1 No 1 Jun 2016
Publisher : 2477 - 6165

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Character geochemical of Coal in area (pit) Stars Sangatta, East Kalimantan shows that the coal is classified as steam coal with thermal maturity and have low calories (5768 kcal/kg). The coal is melted in the 1L autoclave for 60 minutes at a temperature of 450oC and a pressure of 12 MPa to obtain a product slurry. Fractionation of slurry product based on boiling point using a vacum distillation apparatus 10 mmHg. Fractions obtained include naphtha, light oil, middle oil, heavy oil and coal liquid bottom. Data show that the weight percentage of the product melting fraction is dominated by heavy oil and coal liquid bottom with percentage of total> 50%. Fraction of light oil in the fractionation further by TLC and the eluent n-hexane in order to obtain an aromatic fraction. The composition of the aromatic hydrocarbon fraction light oil products were characterized using gas chromatography mass spectrophotometer (GC-MS). The identification shows that derivative of kadalen compounds, that is compounds norkadalen (C14H16) which is the fraction of oil that can be potentially as diesel fuel.
Peningkatan Potensi Ekonomi Masyarakat Desa Pliwetan, Kecamatan Palang, Kabupaten Tuban Melalui Pembuatan dan Pemasaran Olahan Nugget Ikan Serta Pemanfaatan Limbah Olahan Ikan Sebagai Alternatif Pupuk Organik Cair Endah Mutiara Marhaeni Putri; R.Y. Perry Burhan; Yulfi Zetra; Muhammad Nadjib Mujahid; Triyanda Gunawan; Zjahra Vianita Nugraheni
Sewagati Vol 6 No 1 (2022)
Publisher : Pusat Publikasi ITS

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (198.061 KB) | DOI: 10.12962/j26139960.v6i1.8

Abstract

Potensi perikanan di Indonesia sangat besar. Pemanfaat total produk disektor perikanan di Indonesia sebagaian besar dikonsumsi dalam bentuk ikan. Untuk meningkatkan nilai ekonomi dari pengolahan ikan, olahan modern seperti Nugget ikan sangat potensial untuk diterapkan. Limbah cair industri pembuatan nugget ikan berpotensi mencemari lingkungan karena mengandung banyak bahan organik. Oleh karena itu, pada pengabdian kali ini, akan dilakukan pemanfaatan limbah ikan menjadi produk bernilai ekonomi yaitu pupuk organik cair. Dengan dilakukan pelatihan dan transfer ilmu dalam proses pembuatan dan pemasaran olahan nugget ikan serta pemanfaatan limbah olahan ikan sebagai alternatif POC. Adapun hasil yang didapatkan adalah Analisis pada nugget ikan tenggiri dan ikan tongkol masuk ke dalam persyaratan mutu SNI 7758:2013. Dan Analisis yang telah dilakukan pada pupuk organik cair memenuhi persyaratan standar kualitas kompos SNI 19-7030 2004. Diharapkan bahwa dari pengabdian ini masyarakat mendapat terobosan baru dalam hal olahan ikan modern dengan proses yang mudah dan sederhana.
Co-Authors Abduh Muharram Chairacita Adam Wiryawan Agus Wahyudi Agus Wahyudi Agus Wahyudi Agus Wahyudi Amirotul Ula Anis Febriati Arga Dias Pratama Arizal Firmansyah Arizal Firmansyah Aufa Fadhliah Aulia, Wulan Awalia Wardatil Firdaus Batari, Nirmala Puteri Christoffel S I Maweikere Didik Prasetyoko Dyah Nirmala Edi, Eduardus Endah Mutiara Endah Mutiara Marhaeni Putri Endah Mutiara Marhaeni Putri Fahimah Martak Fina Riandra Firdausa, Yunita Alfiyati Firdhausya, Talitha Fitra Gunawan, Triyanda Hamzah Fansuri Hariyanto, Rhiby Ainur Basit Hidayati, Ririn Eva Imam B. Sosrowidjojo Iqbal, Rendy Muhamad Jein Jelsi Lamia Kusuma, Hendra Siswanto Lukman Atmaja Lukman Sugiharto Wijaya M. Nadjib M M. Nadjib Mujahid M. Rachimoellah M. Rachimoellah Maulida Fitriyyah Meliana Wahyuningtyas Miranti Widi Puspita Ayu Mujahid, M. Nadjib Mujahid, Muhammad Nadjib Nadjib, Muhammad Nia Nurfitria Novesar Jamarun Nugraheni, Zjahra Vianita Nurul Jadid Pusparatu Pusparatu Putri, Endah Mutiara Marhaeni Putri, Rizka Berliana R. Arizal Firmansyah R. Arizal Firmansyah R. Arizal Firmansyah R. Arizal Firmansyah, R. Arizal Ramadhan, Zein Firdaus Rhiby Ainur Basit Hariyanto Riandra, Fina Riandra, Fina Ridho Bayuaji Rizka, Rizka Berliana Rurini Retnowati Sholihah, Sovia Masfuri Walidatus Silvana Dwi Nurherdiana Sosrowidjojo, Imam B. Sosrowidjojo, Imam B. Sovia Masfuri Walidatus Sholihah Spanton, Perdana Ixbal Subaer - Supiana Dian Nurtjahyan Supriadi, Warih Syekhfani Syekhfani Titik Andriani Wahyu Prasetyo Utomo Wijaya, Lukman Sugiharto Zein Firdaus Ramadhan Zetra, Yulfi Zetra, Yulfi Zjahra Vianita Zjahra Vianita Nugraheni