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SINTESIS BIO-OIL DARI BONGGOL JAGUNG MENGGUNAKAN PROSES PIROLISIS Cakradetha, Ivenda Sasquea; Suriyanto, Suriyanto; Santi, Sintha Soraya; Utami, Isni; Sutiyono, Sutiyono
BRILIANT: Jurnal Riset dan Konseptual Vol 10 No 2 (2025): Volume 10 Nomor 2, Mei 2025
Publisher : Universitas Nahdlatul Ulama Blitar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.28926/briliant.v10i2.2023

Abstract

Bio-Oil is a raw material that can be produced through various methods, one of which is the biomass pyrolysis process. Biomass pyrolysis has been extensively studied and has shown promising potential as an alternative fuel due to its lignocellulose content. In Indonesia, corn production reaches 23.1 million tons, resulting in waste in the form of corn cobs. This study employed the fast pyrolysis method to convert corn cobs into Bio-Oil. The pyrolysis process was conducted in a sealed reactor, externally heated to a temperature of 400°C. The corn cobs used as raw material were first crushed and sieved to achieve a uniform particle size of 20 mesh. Subsequently, the corn cobs were placed into the pyrolysis reactor, with residence times varied at 40, 60, 80, 100, and 120 minutes. Upon completion of the pyrolysis process, the resulting products, consisting of Bio-Oil, charcoal, and pyrolysis gas, were separated and analyzed for Bio-Oil yield, density, viscosity, and calorific value. Chemical composition analysis was performed using Gas Chromatography-Mass Spectrometry (GC-MS) to identify the main compounds present in the Bio-Oil. The highest yield was obtained with a particle size of 20 mesh and a residence time of 120 minutes, resulting in a yield of 72.4632%, a density of 1.3018 kg/m³, a viscosity of 1.6712 mm²/s, and a calorific value of 6.640 Kcal/kg. GC-MS analysis revealed an acetic acid content of 37.49% and a methyl ester content of 22.19%.
Characterization Bio-Based Edible Film from Mango Seed Starch and Semi-Refined Carrageenan (Euchema cottonii) Using Sorbitol Plasticizer for Potential Food Contact Materials Santi, Sintha Soraya; Puspitawati, Ika Nawang; Pasang, Tim
Jurnal Penelitian Pendidikan IPA Vol 10 No 10 (2024): October
Publisher : Postgraduate, University of Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/jppipa.v10i10.8601

Abstract

Meanwhile, Semi-Refined Carrageenan (SRC) could be combined with starch as the base material for edible film fabrication to increase its tensile strength. This study aimed to identify edible film by synthesizing SRC and mango seed starch with plasticizer sorbitol, which could be safe for consumption in food packaging. The process of making edible film consists of three steps: extracting Eucheuma cottonii seaweed, making starch from mango seeds, and making edible film. The method used was the solution casting method, with a ratio of SRC: starch of mango seeds, namely 1: 0; 0.7: 0.3; and 0: 1 (w / w) and sorbitol concentrations of 20, 30, 40, 50, and 60% (w/w). This research shows that increasing sorbitol could decrease the tensile strength but increase the elongation and solubility of the edible film. As well as the combination of SRC and mango seed starch can produce edible films with higher characteristics than edible films based only on SRC or mango seed starch. The results of selecting the best conditions for an edible film based on the Japanese Industrial Standard (JIS) are the concentration ratio of SRC: mango seed starch (0.7: 0.3) and 30% sorbitol concentration with a thickness value of 0.22 mm, tensile strength 4.81 MPa, 28.50% elongation and 68.44% solubility
Synthesis of Ammonium Silicate Liquid Fertilizer from Rice Husk Ash Santi, Sintha Soraya; Pramuji, Faiq Hawaari Ahmad; Juventino, Syahdhan Adiyah Islami; Puspitawati, Ika Nawang
AJARCDE (Asian Journal of Applied Research for Community Development and Empowerment) Vol. 9 No. 3 (2025)
Publisher : Asia Pacific Network for Sustainable Agriculture, Food and Energy (SAFE-Network)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29165/ajarcde.v9i3.822

Abstract

This study aims to synthesise liquid ammonium silicate fertiliser ((NH?)?SiO?) from rice husk ash and to determine the effects of varying ammonium hydroxide (NH?OH) concentration and reaction temperature on the resulting silica (Si) and nitrogen (N) content. Rice husk ash is used as a silica source because it contains high levels of SiO?, up to 82%. The research process includes three main stages: raw material preparation; silica extraction using 10% NaOH at 80°C for 120 minutes; and a synthesis reaction between the extracted silica and an NH?OH solution (5–25%) at 30–110°C for 60 minutes. Silica content analysis was carried out using UV-Vis spectrophotometry, while nitrogen content was analyzed using the Kjeldahl method. The results showed that increasing NH?OH concentration and reaction temperature significantly increased silica content, while increasing temperature tended to decrease nitrogen content due to ammonia volatility. The best conditions were obtained at a NH?OH concentration of 25%, a reaction temperature of 70°C, a silica content of 5.2701%, and a nitrogen content of 17.1637%. The results meet the SNI 02-6681-2002 standard for liquid macro compound fertilizers, which requires a minimum content of 4% for silica and nitrogen. Thus, rice husk ash has great potential as an alternative raw material for the manufacture of environmentally friendly ammonium silicate liquid fertilizers. Contribution to Sustainable Development Goals (SDGs):SDG 2: Zero HungerSDG 9: Industry, Innovation, and InfrastructureSDG 12: Responsible Consumption and ProductionSDG 13: Climate Action
Sintesis dan Karakterisasi Katalis Aluminosilikat dari Kaolin Zafirah, Shakanti 'Aqilah; Windhy Mutiara Salsabillah; Sintha Soraya Santi; Nurul Widji Triana; Susilowati
Jurnal Serambi Engineering Vol. 11 No. 1 (2026): Januari 2026
Publisher : Faculty of Engineering, Universitas Serambi Mekkah

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

This study aims to synthesize and characterize aluminosilicate catalysts derived from Indonesian kaolin through the hydrothermal method with variations in surfactant type and aging temperature. Kaolin served as the main source of silica and alumina, while CTABr (cationic) and PEG (non-ionic) acted as structure-directing agents that guided the formation of the catalyst pore framework. The synthesis was carried out at aging temperatures of 25°C, 40°C, 50°C, 65°C, and 70°C to investigate their effects on the functional groups and crystallinity of the catalysts. FTIR analysis revealed the presence of main Si–O–Si and Al–O–Si functional groups in all samples, with additional organic peaks attributed to the surfactants. Samples synthesized with CTABr showed sharper spectral peaks, indicating a more ordered structure. XRD analysis showed that the aluminosilicate catalyst synthesized with CTABr at 50°C exhibited the highest diffraction intensity (2615 cts), representing higher crystallinity compared to the PEG-based sample, which remained amorphous. SEM observations demonstrated that PEG produced smoother and more porous particle morphology, while CTABr resulted in agglomerated particles. Overall, the combination of CTABr surfactant and 50°C aging temperature yielded the best synthesis result with a stable semi-crystalline structure. This research highlights the great potential of local kaolin as a sustainable and efficient raw material for aluminosilicate catalyst production.
 Peningkatan Kadar Be Air Laut Untuk Mempercepat Produksi Garam Dengan Metode Evaporasi Talang Berlubang Oktavianingrum, Mursyidah; Aisah Putri Maharani; Sintha Soraya Santi; Caecilia Pujiastuti; Ketut Sumada
Jurnal Serambi Engineering Vol. 11 No. 2 (2026): April 2026
Publisher : Faculty of Engineering, Universitas Serambi Mekkah

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Abstract

Indonesia sebagai negara maritim memiliki potensi besar dalam produksi garam, namun metode konvensional masih memerlukan waktu lama untuk mencapai kadar Baume (°Be) yang sesuai dengan standar. Penelitian ini bertujuan untuk mengkaji pengaruh debit aliran, variasi diameter lubang talang, serta kondisi suhu dan kelembaban terhadap laju evaporasi air laut dengan menggunakan metode evaporasi talang berlubang. Proses penelitian dilakukan dengan memompa air laut sebanyak 250 liter pada kadar awal 4°Be ke dalam talang berlubang dengan variasi diameter lubang 0,2 cm; 0,3 cm; 0,4 cm; 0,5 cm dan 0,6 cm serta debit aliran 147,60 liter/jam; 169,20 liter/jam; 183,60 liter/jam; 194,40 liter/jam; 205,20 liter/jam. Hasil penelitian menunjukkan bahwa semakin kecil diameter lubang dan semakin besar debit aliran, maka laju evaporasi semakin tinggi. Kondisi suhu yang meningkat dan kelembaban rendah turut mempercepat penguapan. Hasil terbaik diperoleh pada diameter lubang 0,2 cm dan debit 210,9 L/jam dengan kadar akhir 23°Be, yang dapat menguapkan air hingga 206,5 liter, serta laju evaporasi 0,002176 m³/m²/s. Dengan demikian, metode evaporasi talang berlubang efektif dalam mempercepat peningkatan kadar Be air laut untuk mempercepat produksi garam, dengan peralatan yang sederhana dan mudah diaplikasikan oleh masyarakat.
The Effect of Substrate Concentration and Bacterial Loading on Biobutanol Production from Molasses Using Clostridium acetobutylicum Putri , Zahra Dzaki Roofia; Destyano, Azel; Sari, Ni Ketut; Triana, Nurul Widji; Santi, Sintha Soraya
G-Tech: Jurnal Teknologi Terapan Vol 10 No 2 (2026): G-Tech, Vol. 10 No. 2 April 2026
Publisher : Universitas Islam Raden Rahmat, Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.70609/g-tech.v10i2.9288

Abstract

Biobutanol is a promising alternative fuel due to its high energy content and compatibility with existing fuel infrastructure. This study evaluates the effects of molasses substrate concentration and Clostridium acetobutylicum loading on biobutanol production via the Acetone–Butanol–Ethanol (ABE) fermentation process. Molasses concentration was varied at 3%, 4%, 5%, 6%, and 7%, while bacterial loading ranged at 1%, 2%, 3%, 4%, and 5%. Fermentation was performed under anaerobic conditions at 37 °C for 4 days with CaCO₃ as a buffering agent. Unlike previous studies that investigated these parameters individually, this work examines their combined influence using a statistical optimization approach. The highest experimental biobutanol concentration of 6.06% was obtained at a substrate concentration of 6% and a bacterial loading of 5%. Optimization using Response Surface Methodology (RSM) produced a statistically significant quadratic model (p < 0.0001) with good predictive performance (R² = 0.9045; predicted R² = 0.8153). The optimal conditions were predicted at a substrate concentration of 5.220% and a bacterial loading of 4.580%, yielding a biobutanol concentration of 6.087%. These results highlight the importance of simultaneous parameter optimization for improving molasses-based biobutanol production.
Co-Authors Aisah Putri Maharani Amalia Azzahroh Andriani, Silvia Desy Anjuda, Adli Putra Ardya Pramesti Regita Cahyani Ari Suwito Putra Ramadhon Ariesta Artamevia, Nazwa Azzahra, Tsania Putri Bintang Arya Sena Caecilia Pujiastuti Cakradetha, Ivenda Sasquea Chamida, Rida Damayanti, Savira Farizqy Destyano, Azel Dyah Suci Perwitasari Erliyanti, Nove Kartika Erwan Adi Saputro Erwan Adi Saputro Febriansyah, Harris Foni Putri Sandi Hamzah Fansuri Haque, Annisa Mutiara Salma Hariyanto, Ayu Puspita Kandhi Hartono, Muhamad Dendy Ika Nawang Puspitawati Indah Dwi Asti Irawati , Febriana ISNI UTAMI Juventino, Syahdhan Adiyah Islami Kesuma, Destha A. Ketut Sumada Ketut Sumada Khonsa Rezkania, Gita Kindriari Nurma Wahyusi Kusumawati, Yuly Milenia, Bella Mohd Hafiz Dzarfan Othman Muhammad Aji Pangestu Mutasim Billah Muthiah, Dewi Muzdalifah, Muzdalifah Nandini , Atika Nelvira Juanmara Ardyansa Ni Ketut Sari Novel Karaman Nur Aini Fauziyah Nuraffandy, Achmad Naufal Nurfita, Etti Nurhediana, Silvana Dwi Nurul Widji Triana Oktavianingrum, Mursyidah Pangestu, Titan Obby Pasang, Tim Pasang, Timotius Pramuji, Faiq Hawaari Ahmad Prastica, Nita Purwanto Purwanto Puspitasari, Kurnia Putranto, Thomas T. Putri , Zahra Dzaki Roofia Rahmani, Tara Puri Ducha Reva Edra Nugraha Ristikawati, Anita Rohman Rosida Rosida Rosida Rosida Rosida Rosida Rosida, Rosida - S Suprihatin Salfana, Dian Rizka Sani Sania, Nabilla Silvana Dwi Nurherdiana Silvy Indah Safitri Sri Redjeki SRIE MULJANI Suriyanto Suriyanto, Suriyanto Susilowati sutiyono sutiyono Sutiyono, Sutiyono Syafsir Akhlus Tasya Vyra Putri Ariyani Trianna, Nurul Widji Utama, Shanita Agitiya Wahyudi, Bambang Wahyusi, Kindriari Nurma Winandri, Kautsar Rahman Windhy Mutiara Salsabillah Yahya A. Yogaswara, Rachmad Ramadhan Zafirah, Shakanti 'Aqilah