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Journal : Reaktor

KOMBINASI ULTRAFILTRASI DAN DISSOLVED AIR FLOTATION UNTUK PEMEKATAN MIKROALGA I Nyoman Widiasa; A A Susanto; B Budiyono
Reaktor Volume 15, No.1, APRIL 2014
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (654.848 KB) | DOI: 10.14710/reaktor.15.1.43-50

Abstract

Abstrak Mikroalga merupakan mikroorganisme fotosintetik prokariotik atau eukariotik yang dapat tumbuh dengan cepat. Pemanfaatan mikroalga tidak hanya berorientasi sebagai pakan alami untuk akuakultur, tetapi terus berkembang untuk bahan baku produksi pakan ternak, pigmen warna, bahan farmasi (β-carotene, antibiotik, asam lemak omega-3), bahan kosmetik, pupuk organik, dan biofuel (biodiesel, bioetanol, biogas, dan biohidrogen. Studi ini bertujuan untuk menginvestigasi kombinasi ultrafiltrasi (UF) – dissolved air flotation (DAF) untuk pemekatan mikroalga skala laboratorium. Hasil penelitian menunjukkan bahwa penurunan fluks membran UF secara tajam sebagai akibat dari deposisi sel mikroalga terjadi pada 20 menit pertama proses filtrasi. Backwash pada interval 20 menit selama 10 detik dengan tekanan 1 bar memberikan pengendalian fouling yang efektif dalam nilai kestabilan fluks yang layak. Membran UF yang digunakan dapat memberikan selektivitas pemisahan biomassa mikroalga ~ 100%. Kualitas permeat sangat stabil, yaitu kekeruhan < 0,5 NTU, kandungan organik < 10 mg/L, dan warna < 10 PCU. Lebih lanjut, pemekatan retentat membran dengan DAF pada tekanan saturasi 6 bar dapat menghasilkan pasta mikroalga dengan konsentrasi 20 g/L. Koagulan PAC perlu ditambahkan kedalam umpan DAF dengan dosis 1,3–1,6 mg PAC/mg padatan tersuspensi.   Kata Kunci: ultrafiltrasi; dissolved air flotation; pemanenan mikroalga; pemekatan mikroalga   Abstract COMBINATION OF Ultrafiltration and Dissolved Air Flotation for Microalgae CONCENTRATION. Microalgae is a prokaryotic photosynthetic microorganism or eukaryotic microorganism  that proliferate rapidly. Cultivation of the microalgae is not only oriented  as natural food for aquacultures, but also developed  for animal food, color pigment, pharmaceutical raw material (β-carotene, antibiotic, fatty acid omega-3), cosmetic raw material, organic fertilizer, and biofuels (biodiesel, bioethanol, biogas, and biohydrogen. This study is aimed to investigate the potential of combination of ultrafiltration (UF) and dissolved air flotation  (DAF) for concentration of microalgae in laboratory scale. The experimental results showed that fluxes of the UF membrane decreased sharply due to deposition of microalgae biomass during first 20 minutes of filtration. Periodically backwash using the UF permeate (backwash  interval = 20 minutes;  backwash duration = 10 seconds;  backwash pressure = 1 bar) gave an effective fouling control to maintain reasonable stable fluxes. In addition,  the UF membrane gave separation of microalgae biomass ~ 100%. Permeate quality is strongly stable in which turbidity < 0.5 NTU, organic content < 10 mg/L, and color < 10 PCU.  Moreover, concentration of the UF retentate by DAF under saturation pressure of 6 bars was able to produced microalgae feedstock having 20 g/L dry microalgae. PAC is required for DAF feed with dosage of 1.3–1.6 mg PAC/mg suspended solids.
SINTESIS MEMBRAN ULTRAFILTRASI NON FOULING UNTUK APLIKASI PEMPROSESAN BAHAN PANGAN Luqman Buchori; Heru Susanto; Budiyono Budiyono
Reaktor Volume 13, Nomor 1, Juni 2010
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (963.398 KB) | DOI: 10.14710/reaktor.13.1.10-15

Abstract

Membran ultrafiltrasi (UF) telah terbukti sebagai proses yang menjanjikan untuk aplikasi di bidang pemprosesan bahan pangan. Namun, peristiwa fouling dapat menurunkan kinerja membran secara signifikan. Meskipun banyak metode pengendalian fouling telah diusulkan, dalam banyak kasus kinerja proses sangat dipengaruhi oleh membran sebagai jantung dari proses. Dalam makalah ini pengendalian fouling dilakukan dengan memodifikasi permukaan membran dengan teknik kopolimerisasi foto-grafting. Acrylic acid (AA), acrylamido methylpropane sulfonic acid (AMPS), poly(ethylene glycol) methacrylate (PEGMA), dan N,N-dimethyl-N-(2-methacryloyloxyethyl-N-(3sulfopropyl)ammonium betaine sebagai senyawa zwitterion (ZI) digunakan sebagai monomer fungsional. Pengaruh waktu iradiasi terhadap efektifitas modifikasi telah diamati. Kinerja membran hasil modifikasi kemudian diuji dengan menggunakan berbagai model larutan foulant yang meliputi larutan protein, larutan polisakarida dan larutan polifenol. Hasil penelitian menunjukkan bahwa sifat non fouling membran sangat jelas dapat ditingkatkan baik dengan PEGMA maupun dengan ZI. Secara umum, modifikasi menggunakan PEGMA menunjukkan kinerja yang lebih baik. Larutan polifenol menunjukkan karakter foulant yang paling kuat diantara model foulant.
FOULING BEHAVIOR OF MODIFIED CELLULOSE ACETATE ASYMMETRIC MEMBRANES FOR DIFFERENT BRACKISH WATER TREATMENT Tutuk Djoko Kusworo; B Budiyono; Eva Sofiana; Ulfah Nurul Aulia Rochyani; Dani Puji Utomo
Reaktor Volume 17 No.1 Maret 2017
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (31.232 KB) | DOI: 10.14710/reaktor.17.1.43-52

Abstract

Water treatment technology which is being widely developed is membrane technology as an alternative technology with sieving mechanism principle.The main purposes of this research are to investigate the effects of additives and thermal treatment on the cellulose acetate membrane morphology and performance in treating brackish water.The membrane was fabricated by preparation of dope solution consits of cellulose acetate and acetone. The membrane was casted via NIPS method using mechanic casting knife. Dope solution was prepared by varying the PEG concentration of 1 and 5wt-% and the annealing temperature at 60°C and 25°C for 10 seconds. The backwash technique was used to solve fouling mechanism in this system .The results of SEM and FTIR showed that theb higher PEG addition to the dope solution resulted in larger membrane pore size and increase the hydrophilic properties of membrane. However the higher temperature and the longer annealing timg, the skin layer of membrane become denser. The result was also shown that back wash technique can reduced fouling phenomenon in the membrane. 
SYNTHESIS AND CHARACTERIZATION OF POLYIMIDE-ZEOLITE MIXED MATRIX MEMBRANE Budiyono Budiyono; Tutuk Djoko Kusworo; Ahmad Fauzi Ismail; I Nyoman Widiasa; Seno Johari; Sunarso Sunarso
Reaktor Volume 12, Nomor 4, Desember 2009
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1285.674 KB) | DOI: 10.14710/reaktor.12.4.245 – 252

Abstract

Biogas has become an attractive alternative energy source due to the limitation of energy from fossil. In this study, a new type of mixed matrix membrane (MMM) consisting of polyimide-zeolite was synthesized and characterized for biogas purification. The MMM consists of medium concentration of polymer (20% wt polyimide), 80% N-Methyl-2-pyrrolidone (NMP) and 25% zeolite 4A in total solid were prepared by a dry/wet phase inversion technique.  The fabricated MMM was characterized using SEM, DSC, TGA and gas permeation. Post treatment coating procedure was also conducted. The research showed that surface coating by 3% silicone rubber toward MMM PI 20% gave the significant effect to improve membrane selectivity. The ideal selectivity for CO2/CH4 separation increased from 0.99 for before coating to 7.9 after coating for PI-Zeolite MMM, respectively. The results suggest that PI-Zeolite MMM with good post treatment procedure will increase the membrane selectivity and permeability with more saver polymer requirement as well as energy saving due to low energy for mixing.