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TRANSESTERIFIKASI PALM OIL DENGAN VARIASI MASSA CO-SOLVENT DAN WAKTU REAKSI Elvianto Dwi Daryono; Erni Junita Sinaga
SENTIA 2016 Vol 8, No 2 (2016)
Publisher : SENTIA 2016

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (509.228 KB)

Abstract

Palm oil is very potentially for turned in to biodiesel. In the process of making biodiesel with transesterification conventional required a long time because the reaction takes places in two phase. Adding the co-solvent can be a solution to makes the reaction time shorter. Methyl ester can be used as a co-solvent to makes the reaction in single phase between the oil and methanol so decrease the reaction time in biodiesel process. Methyl ester as a co-solvent is not need to separate after the last process because methyl ester is the main product of the reaction. The purpose of this research is to find out the effect of addition of co-solvent methyl ester and catalyst NaOH to produced the biodiesel from palm oil which has the good standard. According to the result was obtained that the best results of this process achieved at mass of co-solvent of 15% and reaction time of 20 minutes with mass of FAME 28.06 gr. Methyl ester density and acid value regards with SNI 04-7182-2006.
PEMBUATAN LILIN AROMA TERAPI BERBASIS BAHAN ALAMI Faidliyah Nilna Minah; Tri Poespowati; Siswi Astuti; Muyassaroh Muyassaroh; Rini Kartika; Elvianto Elvianto; Istnaeny Hudha; Endah Kusuma Rastini
Industri Inovatif : Jurnal Teknik Industri Vol 7 No 1 (2017): inovatif Vol. 7 No. 1
Publisher : Prodi Teknik Industri S1 Institut Teknologi Nasional Malang

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Abstract

Indonesia merupakan negara yang kaya akan sumber daya alam hayati sehingga dijuluki negara agraris namun sampai saat ini masih belum bisa memanfaatkan sumberdaya hayati secara optimal, salah satunya tanaman penghasil minyak atsiri. Indonesia menghasilkan 40–50 jenis tanaman penghasil minyak atsiri dari 80 jenis minyak atsiri yang diperdagangkan di dunia dan baru sebagian dari jenis minyak atsiri tersebut yang memasuki pasar dunia, diantaranya nilam, sereh wangi, gaharu, cengkeh, melati, kenanga, kayu putih, cendana, dan akar wangi. Melihat akan hal ini, potensi usaha melalui ekstrak minyak atsiri tanaman sangat terbuka lebar. Salah satu metode sederhana dan peluang usaha yang sangat bagus adalah mengekstrak minyak atsiri dari tanaman dan hasilnya dapat dimodifikasi menjadi aroma terapi. Untuk objek dasar dari terciptanya aroma terapi adalah lilin. Lilin adalah sumber penerangan yang terdiri dari sumbu yang diselimuti oleh bahan bakar padat,dimana lilin yang digunakan adalah juga merupakan bahan dari alam yaitu lilin lebah. Dengan demikian lilin aroma terapi yang dihasilkan pada penelitian ini adalah yang ramah lingkungan
SINTESIS α-PINENE MENJADI α-TERPINEOL MENGGUNAKAN KATALIS H2SO4 DENGAN VARIASI SUHU REAKSI DAN VOLUME ETANOL Elvianto Dwi Daryono
Jurnal Teknik Kimia USU Vol. 4 No. 2 (2015): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (539.981 KB) | DOI: 10.32734/jtk.v4i2.1463

Abstract

This study is intended to explore the optimum temperature reaction and volume of ethanol in the synthesis of α-pinene to α-terpineol. Turpentine oils that is used in this study contains α-pinene by 79.05%. In this study the variables used is the reaction temperature (60º, 70º, and 80ºC) and the volume of ethanol (105, 115, 125, 135 and 145 mL). Synthesis is done during 4 hours using a three-neck flask, condenser, hot plate, a magnetic stirrer, and a thermometer with a stirring speed of scale 7(350-700 rpm). After that, the results is neutralized to pH 7 using NaOH 5% then it is diluted with ethanol in 250 mL volumetric flask. Synthesized samples were analyzed by Gas Chromatography method. In this study, the highest concentration of α-terpineol obtained 57.05% with yield 67,79% at temperature reaction 70oC and the volume of ethanol is 135 mL.
One-phase Transesterification of Palm Oil in to Biodiesel with Co-solvent Methyl Esters: The Effect of Adding Co-solvent to Kinetic Energy and Dipole Moment Elvianto Daryono; Lalu Mustiadi
Reaktor Volume 22 No. 1 April 2022
Publisher : Dept. of Chemical Engineering, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (244.212 KB) | DOI: 10.14710/reaktor.22.1.7-13

Abstract

In the transesterification process, the problem is the low solubility of oil in methanol, so the reaction will run slowly. The solution to this problem is to add a co-solvent to increase the solubility so that a one-phase reaction will be formed. The co-solvent methyl ester is the right choice because it is a product of the reaction itself so that it does not require a separation process. The operating conditions of the study were mass of palm oil 250 g, mass of NaOH catalyst 0.8%wt, stirring speed 100 rpm, reaction temperature 60oC, the molar ratio of oil:methanol = 1:6, reaction time (5,10,15,20,25,30 minutes), and the mass of co-solvent (0,5,10,15%wt). The first stage of the research was to make co-solvent, then proceed with the transesterification reaction by adding  co-solvent which was carried out according to the research operating conditions. The optimum condition of the study was obtained at reaction time 30 minutes and the addition of co-solvent 5%, with yield 97.4171%. The density of FAME 0.88 g/mL and the concentration of FAME 99.963% which complied with SNI 7185-2015. The simulation results of ChemDraw for components of triglyceride+methanol+NaOH+co-solvent obtained kinetic energy 3479.0264 kJ/mol and dipole moment 43279.8007 debyes.
PENGGUNAAN METANOL SISA REAKSI SEBAGAI REAKTAN PADA PROSES TRANSESTERIFIKASI MINYAK KELAPA SAWIT MENJADI BIODIESEL Elvianto Dwi Daryono; Febriara Fassa Aulia Rahman; Zukhriyah Zukhriyah
Jurnal Teknologi Vol 14, No 2 (2022): Jurnal Teknologi
Publisher : Fakultas Teknik Universitas Muhammadiyah Jakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24853/jurtek.14.2.155-162

Abstract

In the process of making biodiesel with a transesterification reaction, an effective, efficient and inexpensive raw material is palm oil because of its abundant availability. In the transesterification process, the addition of methanol is deliberately exaggerated so that the reaction shifts towards the product and the reaction is more perfect and the excess methanol reagents in the process can be reused as reactants. This research was conducted to obtain optimal levels and yield of methyl esters by utilizing the residual methanol reaction. The transesterification process is carried out at 65°C, the molar ratio of palm oil: methanol is 1: 6, the mass of NaOH catalyst is 1% oil mass and the stirring speed is 150 rpm. The residual methanol from the transesterification reaction is used as a reactant in the subsequent transesterification reaction by varying the mass of the remaining methanol addition of the reaction which is 5%, 10% and 15% of the mass of the initial methanol and also varying the reaction time of 15, 30, 45, 60 and 75 minutes. From the results of the research, it was obtained the optimum conditions for the addition of 5% residual reaction methanol and 60 minutes reaction time, get a yield of 90.60% and a concentration of methyl ester 97.69% (meet SNI 7182: 2015). Methyl ester products at the optimum process conditions also meet SNI 7182: 2015 for densities of 0.85 gr / ml and acid valuesof0.42mg-KOH/gr.
PRODUKSI BIODIESEL DARI MINYAK KELAPA SAWIT DENGAN CO-SOLVENT FAME (FATTY ACID METHYL ESTERS) DAN APLIKASINYA PADA MOTOR BAKAR Elvianto Dwi Daryono; Lalu Mustiadi
Jurnal Rekayasa Mesin Vol. 13 No. 2 (2022)
Publisher : Jurusan Teknik Mesin, Fakultas Teknik, Universitas Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/jrm.v13i2.1056

Abstract

The process of transesterification is slow due to the low solubility of triglycerides in methanol. The limitation of mass transfer can be overcome by adding a co-solvent. Co-solvent FAME is the right choice because it is the product of the reaction itself so that it does not require a separation process. The purpose of this study was to examine the use of FAME as a co-solvent in the transesterification of palm oil and its application to the combustion engine. The operating conditions were palm oil mass of 250 gr, NaOH catalyst 1.2% wt, stirring speed 100 rpm, reaction temperature 70oC, ratio molar of oil:methanol =1:6, reaction time (5,10,15,20,25,30 minutes), and co-solvent (0,5,10,15% wt). After the optimum conditions are obtained, the next step is to make biodiesel on a semi pilot plant scale. Oil, methanol, NaOH and co-solvent were put into a stirred reactor and heated at a reaction temperature of 70⁰C. After the reaction is complete then it is flowed into the separator for separation by adding hot water to form 2 layers. The top layer is biodiesel which was analyzed and performance test on the combustion engine. The optimum condition of the process is a reaction time of 10 minutes and the addition of 10% co-solvent, with a yield of 76.7783%. The results of the analysis of SNI 7182:2012 states that biodiesel meets almost all requirements. From the biodiesel performance test on the combustion engine, B10 got quite satisfactory results for the torque and opacity test parameters.
BIODIESEL FROM PALM OIL WITH INTERESTERIFICATION PROCESS USING BIO-CATALYST CAJUPUT OIL Elvianto Dwi Daryono; Rini Kartika Dewi
Konversi Vol 11, No 2 (2022): OKTOBER 2022
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v11i2.13982

Abstract

Proses interesterifikasi yang telah dilakukan menggunakan katalis homogen maupun heterogen yang perlu proses pemisahan di akhir reaksi. Minyak atsiri merupakan alternatif pilihan katalis yang lebih efisien sebab tidak perlu proses pemisahan di akhir reaksi karena berfungsi sebagai antioksidan untuk biodiesel dan lebih ramah lingkungan. Tujuan penelitian adalah untuk mendapatkan proses pembuatan biodiesel yang lebih efektif dan efisien yaitu dengan tahapan proses yang lebih sedikit sehingga akan mengurangi biaya produksi. Pada penelitian ini reaksi interesterifikasi minyak kelapa sawit dengan metil asetat untuk menghasilkan metil ester dan triasetin, dilakukan dengan bio-katalis  minyak kayu putih. Kondisi operasi penelitian adalah massa minyak kelapa sawit 250 gram, rasio molar minyak kelapa sawit:metil asetat adalah 1:6, suhu reaksi 60oC, kecepatan pengadukan 300 rpm, massa katalis 0,75% massa minyak kelapa sawit dan waktu reaksi (15, 30, 45, 60, dan 75 menit). Minyak kelapa sawit, metil asetat dan katalis direaksikan dalam labu leher tiga sebagai reaktor sesuai dengan kondisi operasi penelitian. Setelah waktu reaksi tercapai, sample sebanyak 50 gram diambil untuk dilakukan proses pemisahan. Hasil penelitian mendapatkan kondisi terbaik proses interesterifikasi minyak kelapa sawit dengan bio-katalis minyak kayu putih pada waktu reaksi 75 menit dengan crude yield 65,88% dan angka asam 0,426 mg KOH/gr sampel yang memenuhi SNI 7182:2015.
PELATIHAN PEMBUATAN PUPUK ORGANIK CAIR DENGAN BIOAKTIVATOR ALAMI DARI LIMBAH SAYUR DI DESA SUMBEREJO KOTA BATU: Pelatihan Pembuatan POC di Sumberejo Batu Istnaeny Hudha Mohammad; Nanik Astuti Rahman; Rini Kartika Dewi; Elvianto D. Daryono; Jimmy
Jurnal Penamas Adi Buana Vol 6 No 02 (2023): Jurnal Penamas Adi Buana
Publisher : LPPM Universitas PGRI Adi Buana Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36456/penamas.vol6.no02.a6772

Abstract

Sumberejo merupakan salah satu desa di Kota Batu yang memiliki potensi dibidang pertanian. Sekitar tahun 2020 dicanangkan sebagai desa wisata petik sayur. Untuk mewadahi dan memfasilitasi kegiatan para petani dibentuklah Badan Usaha Milik Desa (Bumdes) Barokah. Meningkatnya permintaan sayur dipasaran menuntut produksi pertanian juga harus ditingkatkan. Konsekuensinya kebutuhan pupuk akan bertambah. Selama ini kebanyakan menggunakan pupuk kimia dan dalam waktu yang panjang. Hal ini akan menimbulkan ketidakseimbangan unsur hara dalam tanah. Untuk itu diperlukan suatu tindakan guna mencari solusi guna memperbaiki unsur hara di lahan pertanian tersebut. Salah satunya adalah memanfaatkan limbah sayur dan limbah organik lainnya sebagai bahan pembuatan pupuk organik cair. Pelatihan ini melibatkan mahasiswa yang terlibat dalam program Abdimas 2022 sebanyak 12 mahasiswa. Dimana mereka akan memberikan tahapan pelatihan mulai dari pemberian materi pelatihan dan praktek langsung pembuatan pupuk organik cair (POC). POC dibuat dari limbah sayur, limbah keju (whey) dan bioaktivator (Molika) dan ember kapasitas 20 L. Pelatihan ini diikuti oleh anggota BUMDES sebanyak 15 orang, 3 dosen pendamping lapangan. Hasil kegiatan pelatihan ini adalah meningkatnya pengetahuan dan keterampilan anggota Bumdes untuk memanfaatkan limbah sayur untuk membuat pupuk organik cair.
Ekstraksi Minyak Atsiri Jahe (Zingiber officinale) dengan Proses Distilasi: Pengaruh Jenis Jahe dan Metode Distilasi Daryono, Elvianto Dwi; Hutasoit, Gading F
Eksergi Vol 21, No 2 (2024)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v21i2.11625

Abstract

Minyak atsiri jahe merupakan salah satu komoditas ekspor Indonesia yang sangat potensial untuk dikembangkan. Minyak atsiri jahe banyak digunakan dalam berbagai industri, seperti industri parfum, kosmetik, essence, farmasi dan flavoring agent. Mutu minyak atsiri yang rendah merupakan kendala mengapa minyak atsiri jahe Indonesia kurang laku di pasaran luar negeri. Penelitian ini bertujuan untuk mempelajari pengaruh jenis jahe (jahe gajah, jahe emprit dan jahe merah) serta metode destilasi (distilasi air dan distilasi uap-air) untuk mendapatkan minyak jahe dengan kualitas yang baik. Penelitian dilakukan dengan pengecilan ukuran jahe yang telah dibersihkan, pengeringan irisan jahe dan proses distilasi. Minyak hasil distilasi yang telah dipisahkan kemudian dianalisa. Dari hasil analisa dan perhitungan menunjukkan bahwa setiap jenis jahe mempunyai komposisi dan kandungan minyak jahe yang berbeda. Jahe merah mempunyai rendemen terbesar yaitu 0,342 % dengan kandungan minyak (sineol) sebesar 11,39 %. Metode penyulingan mempengaruhi rendemen dan kualitas minyak jahe yang dihasilkan, dimana metode yang paling baik adalah metode penyulingan air dan uap. Jahe merah mempunyai kualitas minyak jahe terbaik yaitu massa jenis 0,8828 g/mL, bilangan asam 1,136 mg KOH/g, bilangan ester 7,980 mg KOH/g serta memenuhi standart SNI 06-1312-1998.
Produksi Biodiesel tanpa Gliserol dari Minyak Kelapa Sawit dengan Variasi Massa Co-solvent dan Waktu Reaksi Elvianto Dwi Daryono; Puji Prasetyo, Angga; Bahri, Syaiful; Maya Sista, Eliya
Jurnal Teknik Kimia USU Vol. 9 No. 2 (2020): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v9i2.4006

Abstract

Petroleum fuels are increasingly reduced in line with the increasing industry and population. A potential alternative renewable energy source to replace fuel is biodiesel. The process of making biodiesel that is commonly done is the process of transesterification with glycerol byproducts which is difficult to separate. The method used in this study is the method of interesterification, namely by replacing the methyl alcohol group with a methyl group from methyl acetate with triacetin byproducts. The operating conditions of the process are 250 grams of palm oil mass, 1% wt KOH catalyst mass. oil, reaction temperature 60 ⁰C, stirring speed 800 rpm, mass of co-solvent methyl ester (0, 5, 10, 15, 20% wt. oil) and reaction time (30 minutes, 60 minutes, 90 minutes). The results of the research have been obtained the highest yield with the addition of co-solvent methyl ester of 20% by weight of oil in the reaction time of 30 minutes is 92.43 %.The biodiesel product produced meets SNI 7182:2015 which is an acidic value <0.5 mg-KOH/g.