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All Journal JURNAL KIMIA SAINS DAN APLIKASI POSITRON Bulletin of Chemical Reaction Engineering & Catalysis Konversi Jurnal Fisika FLUX JC-T (Journal Cis-Trans): Jurnal Kimia dan Terapannya Indonesian Journal of Chemistry Jurnal Pengabdian Kepada Masyarakat (Mediteg) Jurnal Ilmiah Berkala: Sains dan Terapan Kimia JOURNAL OF WETLANDS ENVIRONMENTAL MANAGEMENT Bulletin of Chemical Reaction Engineering & Catalysis
Rodiansono Rodiansono
Chemistry Study Program, Faculty Of Mathematics And Natural Sciences, Lambung Mangkurat University, Banjarbaru
Agriculture, Biological Sciences & Forestry Humanities Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Earth & Planetary Sciences Economics, Econometrics & Finance Education Energy Engineering Environmental Science Materials Science & Nanotechnology Physics Social Sciences

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Journal : Bulletin of Chemical Reaction Engineering

 1 
Selective Hydrogenation of Biomass-derived Furfural over Supported Ni3Sn2 Alloy: Role of Supports Rodiansono Rodiansono; Maria Dewi Astuti; Syahrul Khairi; Shogo Shimazu
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 1 Year 2016 (April 2016)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.11.1.393.1-9

Abstract

A highly active and selective hydrogenation of biomass-derived furfural into furfuryl alcohol was achieved using supported single phase Ni3Sn2 alloy catalysts. Various supports such as active carbon (AC), g-Al2O3, Al(OH)3, ZnO, TiO2, ZrO2, MgO, Li-TN, and SiO2 have been employed in order to understand the role of the support on the formation of Ni3Sn2 alloy phase and its catalytic performance. Supported Ni3Sn2 alloy catalysts were synthesised via a simple hydrothermal treatment of the mixture of aqueous solution of nickel chloride hexahydrate and ethanol solution of tin(II) chloride dihydrate in presence of ethylene glycol at 423 K for 24 h followed by H2 treatment at 673 K for 1.5 h, then characterised by using ICP-AES, XRD, H2- and N2-adsorption. XRD profiles of samples showed that the Ni3Sn2 alloy phases are readily formed during hydrothermal processes and become clearly observed at 2θ = 43-44o after H2 treatment. The presence of Ni3Sn2 alloy species that dispersed on the supports is believed to play a key role in highly active and selective hydrogenation of biomass-derived furfural towards furfuryl alcohol. Ni3Sn2 on TiO2 and ZnO supports exhibited much lower reaction temperature to achieved >99% yield of furfuryl alcohol product compared with other supports. The effects of loading amount of Ni-Sn, reaction conditions (temperature and time profile) on the activity and selectivity towards the desired product are systematically discussed. 
Selective Hydrogenation of Stearic Acid to 1-Octadecanol Using Bimetallic Palladium-Tin Supported on Carbon Catalysts at Mild Reaction Conditions Rodiansono Rodiansono; Elisa Hayati; Atina Sabila Azzahra; Maria Dewi Astuti; Kamilia Mustikasari; Sadang Husain; Sutomo Sutomo
Bulletin of Chemical Reaction Engineering & Catalysis 2021: BCREC Volume 16 Issue 4 Year 2021 (December 2021)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.16.4.11895.888-903

Abstract

Bimetallic palladium-tin catalysts supported on microporous carbon (denoted as Pd-Sn(x)/C, loading amount of Pd = 5 wt% and x = Pd/Sn molar ratio; c.a. 3.0; 1.5; and 1.0) showed high selectivity in the hydrogenation of stearic acid towards 1-octadecanol (stearyl alcohol) under mild reaction conditions. Pd-Sn(x)/C catalysts were synthesized via the hydrothermal method at temperature of 150 °C for 24 h, and reduced with H2 at 400 °C for 3 h. Pd-Sn(1.5)/C catalyst exhibited the highest yield of stearyl alcohol (1-octadecanol) (up to 73.2%) at 100% conversion of stearic acid at temperature 240 °C, initial H2 pressure of 3.0 MPa, a reaction time of 13 h, and in 2-propanol/water solvent. The high selectivity of alcohols over Pd-Sn(1.5)/C catalyst can be attributed to the formation of bimetallic Pd-Sn alloy phases (e.g. Pd3Sn and Pd3Sn2) as obviously depicted by XRD analysis. The presence of co-promotor Sn and the formation of bimetallic may play a pivotal role in the high selectivity of 1-octadecanol. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
One-pot Selective Conversion of Biomass-derived Furfural into Cyclopentanone/Cyclopentanol over TiO2 Supported Bimetallic Ni-M (M = Co, Fe) Catalysts Maria Dewi Astuti; Ditya Kristina; Rodiansono Rodiansono; Dwi Rasy Mujiyanti
Bulletin of Chemical Reaction Engineering & Catalysis 2020: BCREC Volume 15 Issue 1 Year 2020 (April 2020)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.15.1.6307.231-241

Abstract

One-pot selective conversion of biomass-derived furfural (FFald) into cyclopentanone (CPO) or cyclopentanol (CPL) using bimetallic nickel-based supported on TiO2 (denoted as Ni-M(3.0)/TiO2; M = Co and Fe; 3.0 is Ni/M molar ratio) have been investigated. Catalysts were synthesized via a hydrothermal method at 150 °C for 24 h, followed by H2 reduction at 450 °C for 1.5 h. X-ray Diffraction (XRD) analysis  showed that the formation of Ni-Co alloy phase at 2θ = 44.2° for Ni-Co(3.0)/TiO2 and Ni-Fe alloy at 2θ = 44.1° for Ni-Fe(3.0)/TiO2. The amount of acid sites was measured by using ammonia-temperature programmed desorption (NH3-TPD). Ni-Co(3.0)/TiO2 has three NH3 desorption peaks at 180 °C, 353 °C, and 569 °C with acid site amounts of 1.30 µmol.g-1, 1.0 µmol.g-1, and 2.0 µmol.g-1,        respectively. On the other hand, Ni-Fe(3.0)/TiO2 consisted of NH3 desorption peaks at 214 °C and 626 °C with acid site amounts of 3.3 µmol.g-1and 2.0 µmol.g-1, respectively. Both Ni-Co(3.0)/TiO2 and Ni-Fe(3.0)/TiO2 catalysts were found to be active for the selective hydrogenation of FFald to furfuryl alcohol (FFalc) at low temperature of 110 °C, H2 3.0 MPa, 3 h with FFalc selectivity of 81.1% and 82.9%, respectively. High yields of CPO (27.2%) and CPL (41.0%) were achieved upon Ni-Fe(3.0)/TiO2 when the reaction temperature was increased to 170 °C, 3.0 MPa of H2, and a reaction time of 6 h. The yield of CPO+CPL on the reused catalyst decreased slightly after the second reaction run, but the activity was maintained for at least three consecutive runs. Copyright © 2020 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Effect of Precursor and Temperature Annealing on the Catalytic Activity of Intermetallic Ni3Sn2 Alloy Rodiansono Rodiansono; Atina Sabila Azzahra; Sadang Husain; Pathur Razi Ansyah
Bulletin of Chemical Reaction Engineering & Catalysis 2022: BCREC Volume 17 Issue 4 Year 2022 (December 2022)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17.4.15923.743-754

Abstract

The effect of nickel precursors and the temperature annealing to obtain intermetallic Ni3Sn2 alloy catalysts on its activity and selectivity in the selective hydrogenation of biomass-derived furfural (FFald) were investigated. Two types of nickel precursors (c.a., i) nickel metal (Ni°) derived from Raney®nickel and ii) nickel ion (Ni2+) derived from nickel chloride) were employed as the starting materials via hydrothermal at 423 K for 24 h followed by reduction with H2 at the elevated temperature of 573-873 K for 1.5 h. The physico-chemical properties of the intermetallic Ni3Sn2 were characterized by XRD, N2-, and H2-adsorption, ICP-AES, and NH3-TPD. The intermetallic Ni3Sn2 alloy catalysts, both bulk and supported, demonstrated high activity and selectivity towards hydrogenation of FFald. The activity and selectivity of g-Al2O3 and AA-supported Ni3Sn2 alloy catalysts in the hydrogenation of FFald to furfuryl alcohol (FFalc) were maintained even after annealing at up to 873 K, but that of bulk Ni3Sn2 drastically dropped. Ni-Sn alloy catalysts which were obtained from Raney®Ni precursor showed more stable than that of nickel salts during hydrogenation of furfural to furfuryl alcohol. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Selective Conversion of 2-Methylfuran to 1,4-Pentanediol Catalyzed by Bimetallic Ni-Sn Alloy Rodiansono Rodiansono; Astuti Maria Dewi; Sadang Husain; Agung Nugroho; Sutomo Sutomo
Bulletin of Chemical Reaction Engineering & Catalysis 2019: BCREC Volume 14 Issue 3 Year 2019 (December 2019)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.14.3.4347.529-541

Abstract

The selective conversion of 2-methylfuran (2-MeF) to 1,4-pentanediol (1,4-PeD) over bimetallic nickel-tin alloy catalysts in the ethanol/H2O solvent mixture was studied. By using bulk Ni-Sn(x); x = 3.0 and 1.5 catalysts, a maximum yield of 1,4-PeD (49%) was obtained at 94% conversion of 2-MeF. The dispersion of Ni-Sn(x) on the aluminium hydroxide (AlOH) or g-Al2O3 supports allowed to an outstanding yield of 1,4-PeD (up to 64%) at 433 K, 3.0 MPa of H2 within 12 h. Ni-Sn(3.0)/AlOH catalyst was found to be reusable and the treatment of the recovered Ni-Sn(3.0)/AlOH catalyst with H2 at 673 K for 1 h restored the catalyst’s original activity and selectivity. 
Screening Support of Bimetallic Ruthenium-Tin Catalysts for Aqueous Phase Hydrogenolysis of Furfuryl Alcohol to 1,5-Pentanediol Rodiansono, Rodiansono; Azzahra, Atina Sabila; Mikrianto, Edi; Ridhoni, Arif; Mustari, Ikhsan; Nurfitriani, Anggita; Bodoi, Thea Seventina Desiani; Sanjaya, Rahmat Eko; Suarso, Eka; Ansyah, Pathur Razi
Bulletin of Chemical Reaction Engineering & Catalysis 2025: BCREC Volume 20 Issue 2 Year 2025 (August 2025)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20357

Abstract

The selective aqueous phase hydrogenolysis of furfuryl alcohol (FFalc) to 1,5-pentanediol (1,5-PeD) using supported bimetallic ruthenium-tin (Ru-Sn) catalysts on various metal oxide supports (e.g., TiO2, ZnO, ZrO2, Nb2O5, g-Al2O3) and its combination were investigated systematically. The catalysts were prepared via coprecipitation-hydrothermal at 150 oC for 24 h, followed by reduction with H2 at 400 oC for 2 h. Supported Ru-Sn on TiO2(A), g-Al2O3, and ZrO2 catalysts exhibited higher yield of 1,5-PeD (55-69%) than that other catalysts at 180 oC, H2 10-30 bar for 3-5 h. However, those supported catalysts showed poor recyclability after the first reaction run, and therefore further examination on g-Al2O3 supported Ru-Sn was performed. The Ru-Sn catalyst supported on g-Al2O3-metal oxide composites (metal oxides: ZrO2, TiO2(A), TiO2(R), ZnO, Nb2O5, and C) afforded higher FFalc conversion and yield of 1,5-PeD than that of unmodified g-Al2O3 at 180 oC, H2 30 bar for 3 h. Among them, the Ru-Sn/g-Al2O3-TiO2(A) (33%) catalyst could afford the highest yield of 1,5-PeD (80%) at 99% conversion FFalc at 180 oC, H2 10 bar for 5 h. Around 95% of this catalyst can be recycled after the second reaction run and the activity can be restored to initial after reactivation with H2 at 400 oC for 2 h with a 69% yield of 1,5-PeD at 97% FFalc conversion. Copyright © 2025 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Co-Authors A.A. Ketut Agung Cahyawan W Abdul Ghofur Abdul Ghofur Abdullah A. Abdullah Abdullah Abdullah Abdullah Abdullah Abdullah Abdullah Adi Maulana Agung Nugroho Agus Riyanto Ahmad Budi Junaidi Anggono Wijaya Anggono Wijaya Anggono Wijaya Annisa Annisa Asma Fauziah Atina Sabila Azzahra Atina Sabila Azzahra Azidi Irwan Azzahra, Atina Sabila Bodoi, Thea Seventina Desiani Budi Junaidi, Budi Chairul Irawan Citra Ariyanti Dahlena Ariyani Dewi Umaningrum Dewi Umaningrum Ditya Kristina Dwi Rasy Mujiyanti Dwi Rasy Mujiyanti Dwi Rasy Mujiyanti Dwi Rasy Mujiyanti Edi Mikrianto Elisa Hayati Faisal F. Faisal Hasanah Hasanah Heny Puspita Dewi Husain, Sadang Ina Risnawati Jaka Darma Jaya Joko Santoso Kamilia Mustikasari Kamilia Mustikasari Karlini Karlini Kiky C SEMBIRING Kiky C. Sembiring Kurnia Putri Leo Saputra Maria Dewi Astuti Muhammad Agus Muljanto Muhammad Iqbal Pratama Mustari, Ikhsan Nana Widyastuti Ninis Hadi Haryanti, Ninis Hadi Nobuyuki Ichikuni Nur Firda Trianda Nurfitriani, Anggita Paradilla Catur Wulabdari Paradilla Catur Wulandari Pathur Razi Ansyah Puput Nopitasari Radhina Oktari Rahmat Eko Sanjaya Rahmidah Ulfah R. Rahmida Ulfah Reda Ariyantie Ridhoni, Arif Risnu Aritofa Sadang Husain Sadang Husain Sadang Husain Sadang Husain Sadang Husain Sepfina Monica Hutasoit Shimazu Shogo Shogo Shimazu Shogo Shimazu Suarso, Eka Sudarningsih Sudarningsih Sulfi Adam Sunardi, Ph.D., Sunardi Suryajaya Suryajaya Susi Susi Sutomo Sutomo Sutomo Sutomo Sutomo Sutomo Syahrul Khairi Takayoshi Hara Takayoshi Hara Tantriati T. Tantriati Tetti Novalina Manik Triyono Triyono Triyono Triyono Umi Baroroh Lili Utami Uripto Trisno Santoso Uripto Trisno Santoso Uripto Trisno Santoso Wega Trisunaryanti Wega Trisunaryanti Wega Trisunaryanti