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All Journal The Journal of Pure and Applied Chemistry Research JURNAL MUQODDIMAH : Jurnal Ilmu Sosial, Politik dan Hummaniora Walisongo Journal of Chemistry Indonesian Journal of Chemical Analysis (IJCA) Molekul: Jurnal Ilmiah Kimia Journal of Appropriate Technology for Community Services JURNAL BIOSHELL Jurnal Abdimas Kartika Wijayakusuma COMSERVA: Jurnal Penelitian dan Pengabdian Masyarakat Jurnal Indonesia Sosial Teknologi Gunung Djati Conference Series Nanggroe: Journal Of Scholarly Service Nanggroe: Journal of Scholarly Service Bohr: Jurnal Cendekia Kimia
Sari, Meiyanti Ratna Kumala
Universitas Palangka Raya, Kalimantan Tengah, Indonesia
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Journal : Molekul: Jurnal Ilmiah Kimia

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Cation Sensing Capabilities of A Nitrophenyl Cinnamaldehyde Derivative Suryanti, Venty; Wibowo, Fajar Rakhman; Marzuki, Ahmad; Sari, Meiyanti Ratna Kumala
Molekul Vol 15, No 3 (2020)
Publisher : Universitas Jenderal Soedirman

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (344.005 KB) | DOI: 10.20884/1.jm.2020.15.3.654

Abstract

The cationic chemosensor based on organic compound bearing an aminophenol moiety as a receptor for metal analyte and a cinnamaldehyde moiety as chromophoric fragment has been developed. In this work, we report the colorimetric sensing of nitrophenyl cinnamaldehyde derivative, namely methyl-3-(2-hidroxy-5-nitrophenyl amino)-3-phenylpropanoate, towards a variety of metal cations, such as Cu2+, Fe3+, Ni2+ and Zn2+. The cation sensing abilities of the sensor were observed for Cu2+and Fe3+ with a color change from colorless to pink and faint yellow, respectively, The characteristic UV-Vis spectra changes were observed upon addition of Cu2+and Fe3+ cations. The hypsochromic absorption spectra shifts were obtained, indicating the cations and sensor complexations had formed. A metal-to-ligand-charge-transfer (MLCT) had occurred and the charge density of the sensor changed resulting in appearance of new absorption peaks in the UV-Vis spectra and color changes of the sensor solution upon addition of the Cu2+and Fe3+.  
Co-Authors Adiwijaya, Saputra Anasthasya Isaura Silalahi Annisa Istiqomah, Annisa Ardi Sandriya Ariska, Risya Chuchita Chuchita, Chuchita Dongoran, Junita Elfrida Ratnawati Fajar Rakhman Wibowo Fariz Noorrahman, Nabil Gracia, Amanda Natania Hanna Esrani Togatorop Husna Syaima Imelya, Marsya Iqbal, Rendy Muhamad Irmawan, Muhammad Jeddah Yanti Jesika Nababan Jumiati Kalalinggi, Septaria Yolan Maknun, Luluil Mokhamat Ariefin Nababan, Jesika Nafisah, Zahrotun Ozi Adi Saputra, Ozi Adi Paksi, Pandu Gizta Rapi Pramudita, Dimas Pratika, Remi Ayu Purwanto, Ferry Qonita Awliya Hanif Rafsanjani, Muhamad Arief Rafsanjani, Muhammad Arief Rahman, Sudarman Riandy Putra Rizki Rachmad Saputra Safitriono, Wahyu Nur Simangunsong, Sri Yulandari Simanjuntak, Elfrida Roulina Simarmata, Sari Namarito Sipayung, Ronald Regen Siska, Amelia Siti Unvaresi Misonia Beladona Sugiyani, Tina Sulistiawati, Putri Tampubolon, Mulani Jeni Lestari Tesalonika, Lidya Venty Suryanti Wenika Simbolan Wulandari, Oktavia Rahmi Ysrafil, Ysrafil Yuni Damayanti Nainggolan Zahrotun Nafisah Zimon Pereiz