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Empowering Sidomekar Village Community through orange peel-based body scrub production training Boy Arief Fachri; Bekti Palupi; Meta Fitri Rizkiana; Istiqomah Rahmawati; Devi Prayuga; Achmad Rodi Soleh; Icha Shofia Dihasti; Hosshofil Azhar Azizi; Lalu Dimas Putra Hermanto; Nabilla Widya Rahman; Ahmad Reza Maulufi
Abdimas: Jurnal Pengabdian Masyarakat Universitas Merdeka Malang Vol. 10 No. 3 (2025): August 2025
Publisher : University of Merdeka Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26905/abdimas.v10i3.15131

Abstract

One of the villages that already has a Memorandum of Understanding (MoU) as a fostered village of Jember University is Sidomekar Village located in Semboro District, Jember Regency, East Java. The problem of Sidomekar Village that is highlighted is the low selling price of Semboro oranges during the harvest season, sometimes only Rp2000 per kg, thus negatively impacting farmers' income. The solution to this problem is to utilize orange peel waste as an active ingredient in body scrub preparations so that it can be used as one of the village's superior products. This community service program aims to provide solutions to the problems faced by partners while increasing the Village Development Index, especially in terms of the Economic Resilience Index through the development of superior village products based on orange peel waste. This service program was carried out by providing socialization attended by 35 participants regarding the process of making and using tools to produce body scrubs from orange peels. The increase in knowledge and skills of participants increased by 90% based on the active participation in the socialization event during the question and answer session and practice of making body scrubs from orange peels.
Isotherm and Kinetics Adsorption of Ammonium using Cocopeat Biochar Activated Meta Fitri Rizkiana; Lilis Nurhasanah; Nanda Ayudiyah Andriani; Bekti Palupi; Boy Arief Fachri; Istiqomah Rahmawati; Helda Wika Amini; Endar Hidayat
CHEESA: Chemical Engineering Research Articles Vol. 8 No. 1 (2025)
Publisher : Universitas PGRI Madiun

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25273/cheesa.v8i1.22466.43-54

Abstract

Nitrogen recovery from wastewater is capable of preventing eutrophication, offering economic benefits, and reducing carbon footprint from synthetic fertilizer production. Biochar has been explored as adsorbent for ammonium (NH??) removal. Therefore, this study aimed to investigate the potential of biochar derived from cocopeat as adsorbent for NH?? removal. Cocopeat was modified by potassium hydroxide (KOH) and pyrolyzed at 500°C for 2 h to produce activated biochar. Kinetics and isotherm studies were conducted to examine adsorption mechanisms. Fourier Transform Infrared (FTIR) data showed that the resulting biochar after activation and adsorption contained hydroxyl O–H and C–O groups, while a new N–H band confirmed the interaction with NH?? ions. Biochar adsorbed NH?? ions with a maximum capacity of 0.3078?mg/g. FTIR spectra showed shifts and changes in the intensity of functional group bands, confirming the interaction between NH?? ion and the active sites on biochar surface. Adsorption followed Langmuir isotherm and pseudo-first-order kinetics model, with an optimal contact time of 5 h. These results suggested that cocopeat-based biochar had potential as an effective NH?? adsorbent.
Optimasi Ekstraksi Flavonoid dari Ulva lactuca dengan Kombinasi Cell Disruption dan Ultrasound-Assisted Hot Water Helda Wika Amini; Muhammad Rizky Kurniawan; Nida Ayu Salsabila; Boy Arief Fachri; Zuhriah Mumtazah; Meta Fitri Rizkiana; Istiqomah Rahmawati; Bekti Palupi; Yukti Nurani; Rekfa Wika Amini
ALCHEMY Jurnal Penelitian Kimia Vol 21, No 2 (2025): September
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.21.2.98141.284-295

Abstract

Ulva lactuca merupakan biota laut yang berpotensi sebagai sumber bahan aktif kosmetik karena kandungan bioaktifnya seperti flavonoid, alkaloid, saponin, terpenoid, dan tanin. Penelitian ini bertujuan mengekstraksi flavonoid serta menganalisis nilai Sun Protection Factor (SPF) U. lactuca menggunakan kombinasi metode cell disruption dan ultrasound-assisted hot water (UAHW). Tiga metode perlakuan cell disruption (tanpa perlakuan, osmotic shock, dan hidrotermal dengan autoklaf) dikombinasikan dengan variabel UAHW yaitu suhu ultrasonik (40, 60, 80 °C) dan waktu ultrasonik (5, 10, 15 menit). Ekstraksi dilakukan menggunakan pelarut etanol 96% pada serbuk U. lactuca berukuran 60 mesh. Optimasi dilakukan menggunakan Response Surface Methodology (RSM) dengan Box–Behnken Design (BBD). Hasil menunjukkan bahwa total flavonoid dan nilai SPF tertinggi (33,23 mg QE/g dan SPF 20,80) diperoleh tanpa perlakuan cell disruption, pada suhu 80 °C dan waktu ekstraksi 10 menit. Penelitian ini menegaskan bahwa metode UAHW efektif meningkatkan ekstraksi flavonoid dan SPF meskipun tanpa cell disruption. Selain itu, pendekatan RSM terbukti efisien dalam optimasi proses. Studi ini memberikan kontribusi pada pengembangan bahan aktif alami U. lactuca untuk aplikasi kosmetik, khususnya sebagai agen pelindung sinar UV.Optimization of Flavonoid Extraction from Ulva lactuca Using a Combination of Cell Disruption and Ultrasound-Assisted Hot Water. Ulva lactuca is a marine organism with significant potential as a source of active ingredients for cosmetic applications, owing to bioactive compounds such as flavonoids, alkaloids, saponins, terpenoids, and tannins. This study aimed to extract flavonoids and evaluate the Sun Protection Factor (SPF) of U. lactuca using a combination of cell disruption methods and ultrasound-assisted hot water (UAHW) extraction. Three cell disruption treatments (no treatment, osmotic shock, and hydrothermal using an autoclave) were combined with UAHW variables, including ultrasonic temperature (40, 60, 80 °C) and ultrasonic time (5, 10, 15 minutes). The extraction was conducted using 96% ethanol as a solvent on U. lactuca powder sieved to 60 mesh. Optimization was performed using Response Surface Methodology (RSM) with a Box–Behnken Design (BBD). The highest total flavonoid content (33.23 mg QE/g extract) and SPF value (20.80) were obtained without cell disruption, at 80°C for 10 minutes. The study confirms that UAHW effectively enhances flavonoid extraction and SPF, even without cell disruption. Furthermore, the RSM approach proved efficient for process optimization. This study contributes to developing natural active ingredients from U. lactuca for cosmetic applications, particularly as UV-protective agents.
Quantitative Structure-Activity Relationship Study of Ester-Based Ferulic Acid Derivatives Against Cervical Cancer Cell (HELA) Helda Wika Amini; Istiqomah Rahmawati; Rizki Fitria Darmayanti; Boy Arief Fachri
JOBC Vol. 1 No. 1 (2020): Journal of Biobased Chemicals
Publisher : University of Jember

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Abstract

Quantitative structure-activity relationship (QSAR) has been studied for ferulic acid derivatives to determine the QSAR model able to predict anticancers. The subject of this research was a set of experimentally calculated IC50 value data of 6 ferulic acid derivatives against cervical cancer cells (HELA). QSAR analysis was based on multilinear regression calculation on fitting subset using log (1/IC50) as the dependent variable, and dipole moment, partition coefficient in the n-octanol/water, and atomic net charges of the aromatic carbons as independent variables. The values of the descriptors were obtained from semi-empirical PM3 quantum mechanics calculation. The relationship between log (1/IC50) and the descriptors was described by the result in the QSAR model. The QSAR model for ferulic acid derivatives against HELA cell lines was developed with the statistical parameters of R=0.998; R2=0.999; SE=0.00857;  and F=394. The calculated log (1/IC50) using the QSAR Hansch Model for ferulic acid derivatives has excellent agreement with the experimental data of Log (1/IC50).
Extraction of Antioxidant Compounds from Sargassum sp. Using Water and Ultrasound Assisted Extraction Method as A Derivation of Green Chemistry Principles Samantha Githa Ratna Sonia; Boy Arief Fachri; Bekti Palupi
JOBC Vol. 2 No. 1 (2022): Journal of Biobased Chemicals
Publisher : University of Jember

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Abstract

The content of bioactive compounds in Sargassum sp. has already been used in various fields. The Ultrasound Assisted Extraction (UAE) method and water solvent have met the principles of green chemistry, so it is used in this study to extract antioxidant compounds contained in Sargassum sp. The principle of green chemistry primarily aims to reduce or eliminate the impact of environmental damage. This research was conducted with several process variables, including the ratio of the sample mass to the volume of solvent (0.05 – 0.15 g/mL), time (30 – 40 minutes), and power (170 – 180 W) using the UAE method and water solvent (Aquadest) on the total phenol value of Sargassum sp. Analysis of variance was carried out with the help of Design Expert software, Response Surface Method - Central Composite Design, to determine the effect of the process variables carried out in the extraction process on the total phenol yield. The analysis of variance in this study shows the suitability between the research design and the study results, which is indicated by an R2 value of 0.9785. The highest results were obtained with a variable ratio of sample mass to solvent volume of 0.18 (g/mL), time of 40 minutes, and power of 180 W, with a total phenol yield of 212.8 mg GAE/g and antioxidant activity of 12.3%.
Effect of Ethanol Solvents in the Extraction Process of Bioactive Compounds from Brown Seaweed (Sargassum sp.) with the Ultrasound Assisted Extraction Method Slamet Pujianto; Boy Arief Fachri; Erna Subroto; Istiqomah Rahmawati
JOBC Vol. 2 No. 2 (2022): Journal of Biobased Chemicals
Publisher : University of Jember

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Abstract

Sargassum sp., part of brown algae, is traditionally used as animal feed. Nonetheless, Sargassum contains phenolic compounds that promise to be the raw material of natural antioxidants. The work is to extract phenolic compounds from Sargassum sp. in ethanol and to investigate the effect of the process on phenol yields. Several dried Sargassum sp. are milled in a certain size and extraction using ultrasound assisted extraction with ethanol solvent. Process variables are the extraction time (30-50 minutes) and the Ratio of Sargassum sp. to ethanol which is 5:100-15:100 (b/v), and power of 170-190 watts. Phenol compounds are quantified using the error acid method. The DPPH method is performed to check the antioxidant activity. To investigate the influence of the process, surface response methods based on central composite designs are applied in this work. 153.334 mgGAE/g in 30-minute extraction conditions, 170 watts of power, and a ratio between masses and solvents of 0.05. The antioxidant activity (IC50) of Sargassum sp. extract is 87.57 ppm.
Microwave-Assisted Hydrolysis of Ulva sp. Using HCl to Produce Bioethanol Raw Materials Bekti Palupi; Nadia Ayumna Fa’iqoh; Alifia Rahma Putri Neysella; Boy Arief Fachri; Ditta Kharisma Yolanda Putri; Lukman Nulhakim; Maulida Septiyana
JOBC Vol. 2 No. 2 (2022): Journal of Biobased Chemicals
Publisher : University of Jember

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Abstract

The challenges faced by the Indonesian state are increasing greenhouse gases, climate change, and depleting fossil fuel reserves. This requires the exploration of alternative energy that is environmentally friendly and sustainable. Algae biomass, especially Ulva sp., is one of the resources that has the potential for bioethanol production as an alternative energy source. The purpose of this study is to determine the potential of Ulva sp. as a raw material for bioethanol and to determine the effect of particle size, solvent concentration, and power on the hydrolysis process. This study used Ulva sp. as a raw material. hydrolyzed with HCl solvent using the microwave-assisted hydrolysis method. Hydrolysis with HCl concentrations of 0.1 N, 1 N, 2 N, variations of microwave power 150 watts, 300 watts, 450 watts, and particle sizes of 60 mesh, 80 mesh, and 100 mesh. Measurement of reducing sugar levels was carried out using the dinitrosalicylic acid (DNS) method. The results showed that the best conditions for hydrolysis were when the HCl concentration was 0.1 N, the microwave power was 450 watts, and the particle size was 80 mesh, which resulted in a reducing sugar content of 20.751 mg/mL.
Extraction of Phenolic Active Compounds from Coffee Leaves (Coffea sp.) Using the Ultrasound-Assisted Extraction Method and Total Phenol Analysis Nur Aini Dwi Alfinaini; Boy Arief Fachri; Pratamai Shelli; Helda Wika Amini; Istiqomah Rahmawati
JOBC Vol. 3 No. 1 (2023): Journal of Biobased Chemicals
Publisher : University of Jember

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Abstract

Coffea sp. is one of the largest plantation commodities in Indonesia, especially coffee leaves containing phenolic compounds. This research was conducted to extract phenolic compounds using the Ultrasound-Assisted Extraction method with ethanol solvent, which aims to determine the optimum operating conditions of extraction and the influence of variations in amplitude, time, and ratio of solvents used. The experimental design used Design Expert 13 software with the response surface method box-Behnken design. The research variables used were amplitude variations (50%, 60%, and 70%), time (10, 20, and 30 minutes), and solvent ratios (0.1, 0.15, and 0.2 g/mL). Based on our study, these parameters affect the total phenolic content. The model equation for the total phenolic content of coffee leaves obtained is Y = 0.1349 – 0.0016 A – 0.0505 B + 0.0010 C + 0.0018 AB + 0.0043 AC – 0.0018 BC – 0.0004 A2 + 0.0178 B2 – 0.0014 C2 (R2 = 0.9758) with the optimum total phenolic content located in the 17th running of 0.209 mg GAE/g under conditions of 20 minutes, the ratio of material to solvent is 0.2 g/mL, and an amplitude of 50%.
Extraction of Anthocyanins from Dragon Fruit Peel Using Solvent Extraction Method Mohammad Fathur Rohman Y.; Shariska Putri Devina; Boy Arief Fachri; Istiqomah Rahmawati; Zuhriah Mumtazah
JOBC Vol. 4 No. 1 (2024): Journal of Biobased Chemicals
Publisher : University of Jember

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Abstract

Dragon fruit skin contains 26.4587 mg/L anthocyanins. Anthocyanins have benefits such as natural coloring agents in the food sector and are used as an alternative to synthetic dyes which are of course also safer for health. The purpose of this study was to determine the effect of extraction variables (time, solvent concentration, and particle size) on the anthocyanin content of dragon fruit skin from the extraction results with the Solvent Extraction method. The definition of Solvent Extraction is the separation of materials from a solid or liquid with the help of a solvent. The extraction process starts from the agglomeration of the extract with the solvent then contact occurs between the material and the solvent so that on the flat plane of the interface of the extraction material and the solvent there is mass deposition by diffusion. The extraction process starts with 25 grams of dragon fruit peel powder with a variety of particle sizes (30, 60, and 80 mesh) then put into an Erlenmeyer tube. Then, the citric acid solution with various concentrations (0.1 M; 0.2 M; and 0.3 M) was added as much as 250 ml. After that, the Erlenmeyer was placed on a stirrer to stir for (90, 120, and 150 minutes). After that, the extraction results were filtered using filter paper to produce a filtrate. Then the filtrate was precipitated to obtain anthocyanin extract. After that, it was analyzed using the spectrophotometric method to calculate anthocyanin content. In this study, the best results were obtained at 11.439 mg/L in conditions without repetition. The optimum conditions of extraction were obtained at a particle size of 60 mesh, a time of 150 minutes, and a solvent concentration of 0.5 M citric acid.
Kinetics of Extraction of Arabica Coffee Bean (Coffea arabica) Lailatul Fatma; Nabilah Lu’aili Fauziah; Boy Arief Fachri; Zuhriah Mumtazah; Helda Wika Amini
JOBC Vol. 4 No. 2 (2024): Journal of Biobased Chemicals
Publisher : University of Jember

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Abstract

Coffee beans are the seeds of the coffee plant and a source of coffee beverages. Arabica coffee beans contain oil, which has many benefits. Extracting oil (solute) from coffee can be done through solvent extraction (leaching). The coffee bean oil extraction process uses n-hexane as a solvent because it can dissolve compounds with the same properties. This research aimed to study the extraction of essential oil from Arabica coffee beans and determine the kinetic model of extraction of essential oil from Arabica coffee beans by leaching. The process of separating coffee oil and solvent using thermogravimetric analysis with a temperature of 80 ℃ until the sample mass is constant. The variables used were temperature and time. The extraction time is 2 hours, with retrieval time every 10 minutes. The temperature used is 30, 40, and 50 ℃ with a ratio of material and solvent 1:10. The results showed that the kinetics of arabica coffee extraction followed the second-order extraction kinetics model. The second-order kinetic parameter values of arabica coffee essential oil extraction, namely extraction capacity (Cs) at 30, 40, and 50 ℃ were 5.45836, 5.46, and 5.46001 g L-1, respectively, the rate of the initial extraction (h) was 0.00762718, 0,00756716, and 0,0104452 gL-1minute-1, the extraction rate constant (k) was 0.000256, 0.000254, and 0.00035 g-1L-1minute-1, and determination values (R square) of 0.9965, 0.9967 and 0.9983.
Co-Authors Abdul Fatah Ismail Abdul Malik Karim Amrullah Achmad Rodi Soleh Adelina, Saltsabita Nourin Adrian, Febri Afred, Merymistika Yufrani Afwal, Diza Raudhatul Agus Rahman Ahmad Reza Maulufi Ahmad Syuhri Akbar Anugrah Ikhsani Al Fajri, Maktum Muharja Alex Ttesa Elsyamba Alfinaini, Nur Aini Dwi Alfinaini Alfun Ni’matil Husna Alifia Rahma Putri Neysella Amalia Ramadhan Anak Agung Nabilla Azzahrah Anggraini, Ranita Anggi Annisa, Yasmin Ansori Ansori ansori ansori Ansori Ansori Ardila Dwi Tresna Ari Susanti Arief Budiman Aris Zainul Muttaqin Asshofy , Muhammad Agil Atiqa Rahmawati Atiqa Rahmawati Azizi, Daffa Hafiziaulhaq Badril Azhar Badril Azhar Bekti Palupi Bimo Bayu Aji Danang Muharyanto Devi Prayuga Dianavita Fatimah Digdo Listyadi, Digdo Dihayat, Icha Shofia Dini Rahmawaty Ditta Kharisma Yolanda Ditta Kharisma Yolanda Putri Ditta Putri Doddy Parningotan Dwi Intan Noer Aini Elida Novita Elisah, Nor Elsyamba, Alex Ttesa Endar Hidayat Erna Subroto Farwah, Zilma Aliyah Fatimah, Dianavita Felix Arie Setiawan Firmansyah, Muhammad Sahrul Gavinda Tsubutul Akmal Ghina Shofiah Adibah Khoirunnisa Gregah Pangayoman Hartanto P Habibatul Inayah Harti Arini Helda Wika Amini Helda Wika Amini Helda Wika Amini Helda Wika Amini Heni Pujiastuti Herdianto, Dimas Nur Hidayat, Debby Aurellia Hilda Huril Ainia Hilda Huril Ainia Hosshofil Azhar Azizi Husnul Khotimah I Made Arimbawa Icha Shofia Dihasti Ilyas Arya Pratama Indrayani, Lilin Intan Hardiatama Istiqomah Rahmawati Istiqomah Rahmawati Istiqomah Rahmawati Istiqomah Rahmawati Jovita Labibah Kristianta, Franciscus Xaverius Lailatul Fatma Lalu Dimas Putra Hermanto Lestari, Afrila Tutut Dwijati Lilis Nurhasanah Lukman Nulhakim Lumbantoruan, Sri Lestari Lutfia Pradisha Budiarti M Edoward Ramadhan M Yuda Pratama M Zikrillah Maharani, Regita Gustiayu Pramisti Mahfud Mahfud Mahfud Mahfud Mahros Darsin Maktum Muharja Maulida Septiyana Megasari, Tri Elok Setya Merymistika Yufrani Afred Meta Fitri Rizkiana Meta Fitri Rizkiana Meta Fitri Rizkiana Mizanurafi’ Ghifarhadi Prasiefa Moch Irgi Fadhilal Abi Mochamad Edoward Ramadhan Mochamad Ghaza Al Ghifari Moh. Nurkoyim Kustanto Mohammad Fathur Rohman Y. Mohammad Nor Muhammad Ilham Muhammad Nabil Suryagama Muhammad Reza Muhammad Reza Muhammad Rizky Kurniawan Muharja, Maktum Mukhammad Fauzi Nabilah Lu’aili Fauziah Nabilla Widya Rahman Nadia Ayumna Fa’iqoh Naily Fatimatuz Zaroh Nanda Ayudiyah Andriani Nayyara Aida Buana Nida Ayu Salsabila Nikita Meidi Nirina Indi Naraismanti Nova Chintya Kurniawati Nova Chintya Kurniawati Nugraha, Briantara Agung Nugroho, Yeremia Prasetya Nur Aini Dwi Alfinaini Nur Karima Nur Karima Nurtsulutsiyah Nurtsulutsiyah Nurtsulutsiyah Nurtsulutsiyah Nurtsulutsiyah, Nurtsulutsiyah Ocita Galuh Permatasari Pradipta, Shima Nuril Pratamai Shelli Pravitasiwi, Nanda Tricya Julia Purimahua, Amanda Augre Maharani Puspita Sari Putri Ayu Salsabila Putri Hartini, Lidia Putri, Navisa Ayudia Putri, Salsabila Ananda R Rochmadi Rafly Surya Permana Rahman, Agus Ramadana, Ifan Ratnasonia, Samantha Githa Ratri Sekaringgalih Ratri Sekaringgalih Regita Gustiayu Pramisti Maharani Reinaldi Rizky Pratama Rekfa Wika Amini Rekfa Wika Amini Renald Rochman Mauludy Reswara Musyafa Richa Febyola Surya Putri Rizalluddin, Muhammad Rizki Abdus Syatar Rizki Fitria Darmayanti Rizki Fitria Darmayanti Rizky Pratama, Reinaldi Rumaisha-Zuhriansyah, Rayya Safira Nur Oktavia Samantha Githa Ratna Sonia Santoso Mulyadi Sa’roni, Achmad Sella Violina Anggraeni Septianti, Kiki Shabrina, Nadhilah Shariska Putri Devina Sholeha, Irdatus Slamet Pujianto Sonya Hakim Raharjo Sutarsi, Suratsi Syatar, Rizki Abdus Tri Elok Setya Megasari Udroto, Firsta Retnaningtyas Uzinuzulla, Yunita Virda Wardani, Salza Belila Kusuma Wardhani, Maharani Tri Watiningsih, Lusi Karlina Wibowo, Jihan Nafila Wiwik Pratiwi Yakub Hendrikson Manurung Yeremia Prasetya Nugroho Yukti Nurani Zakia Luthfiana Zuhriah Mumtazah