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Journal : International Journal of Renewable Energy Development

Optimizing the Synthesis of Lignin Derivatives from Acacia mangium to Improve the Enzymatic Hydrolysis of Kraft Pulp Sorghum Bagasse Fatriasari, Widya; Hamzah, Fajar Nur; Pratomo, Bagas Ikhasan; Fajriutami, Triyani; Ermawar, Riksfardini Annisa; Falah, Faizatul; Laksana, Raden Permana Budi; Ghozali, Muhammad; Iswanto, Apri Heri; Hermiati, Euis; Winarni, Ina
International Journal of Renewable Energy Development Vol 9, No 2 (2020): July 2020
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.9.2.227-235

Abstract

The present study is aimed at optimizing the synthesis of Amphipilic lignin derivatives (A-LD) from the isolated lignin of A.mangium black liquor (BL), using the one and two step acid isolation method, and commercial lignin (LS) was used as comparison. The experimental design was conducted using Taguchi method, which consisted of four parameters and two level factors, with reference to the matrix orthogonal array, L8, including temperature, reaction time, amount of polyethylene glycol diglycidylethers (PEGDE) and Kraft lignin (KL). Furthermore, the kraft pulp of sweet sorghum bagasse (SSB) was used as substrate in the enzymatic hydrolysis (NREL method), with addition of A-LD, whose functional group and surface tension were then characterised using ATR-FTIR and surface tension equipment. Conversely, an improvement in the reducing sugar yield (RSY) compared to the control was observed after adding various A-LDs to the substrate during enzymatic hydrolysis. This product was more prospective for L2S than others products under milder circumstances, due to the fact that it possesses the lowest surface tension. Also, Taguchi analysis demonstrated the treatment at 60 °C for 1 h with 3.0 g and 1.0 g of PEDGE and lignin, respectively as the optimum condition, while the amount of lignin present was included as a factor with the propensity to significantly affect A-LD L1S and LS. Therefore, it was established that the A-LDs from A. mangium kraft lignin require milder synthesis conditions, compared to other existing methods and despite the differences in optimum experimental condition for L2S and LS, the functional groups in the IR spectra possessed very identical characteristics. 
Co-Authors Achmad Siddik Toha Adrian Hilman Agus Purwoko Ahmad Baiquni Rangkut Ahmad Baiquni Rangkuti Ahmad Baiquni Rangkuti Ahmad Sadeli Alfan Gunawan Ahmad Andi Hermawan Andrianta Ginting Anita Zaitunah Anita Zaitunah Arida Susilowati Iswanto Arif Nuryawan Arif NURYAWAN Bagas Ikhasan Pratomo Bejo Slamet Bora Jeong Cut Yulia Maghfirah Dede Hermawan Deni Elfiati Deni Elfiati Deni Elfiati Eddy Mirwandhono Erman Munir Erni Jumilawaty Euis HERMIATI Euis Hermiati Faizatul FALAH Faizatul Falah Fajar Nur Hamzah Fajriutami, Triyani Fauzi Febrianto Fitrianum, Fadilah Guido Simbolon Hafizah Arinah Hafizah Arinah hamzah, fajar nur Hardiansyah Tambunan Harisyah Manurung Imam Wahyudi Indrawan, Imam Wahyudi Ina Winarni Ina Winarni, Ina Irawati AZHAR Irawati AZHAR Irawati Azhar Iwan RISNASARI Iwan Risnasari Jajang Sutiawan Jajang Sutiawan Janrahman Simarmata Johanna Christina Malau Kaya Muda Lubis Kurniawansyah Effendy Laksana, Raden Permana Budi Lubis, Muhammad Adly Rahandi Luthfi Hakim Luthfi Hakim Ma'rifatin Zahrah Manggar Arum Aristri Mariah Ulfa Mariah Ulfa Maulana, Muhammad Iqbal Moehar Maraghiy Harahap Mohammad Basyuni Muhammad Ghozali Muhammad Ghozali Nurdin Sulistiyono Oding Affandi OK Hasnanda Syahputra OK Hasnanda Syahputra Pindi Patana Prabuningrum, Dita Sari Pratomo, Bagas Ikhasan Purwoko, Agus Raden Permana Budi Laksana Ridwanti Batubara Riksfardini Annisa ERMAWAR Riksfardini Annisa Ermawar Rita Kartika Sari Rudi Hartono Rudi Hartono Rudi Hartono Rudi Hartono Rudi Hartono Rudy Hartono Sipahutar Ryzki Pebriansyah Samsuri Samsuri Samsuri, Samsuri Sucipto, Tito Supriyanto Supriyanto Supriyanto Supriyanto Surdiding RUHENDI Suri Fadhilla Syahroni Hasan Siregar Tati Vidiana Sari Tito Sucipto Triyani Fajriutami Wahyu Hidayat Widya Fatriasari Widya Fatriasari Widya FATRIASARI Winda Martogi Situmeang Yulia Siti Maisaroh Yunus Afifuddin Yusuf Sudo Hadi Zahrial COTO