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Development of a Cr(VI) metal ion detection sensor using a modified pencil lead electrode (PLE) with a silver thin layer using the voltammetry method Nella Aulia Putri; Trisna Kumala Sari; Budhi Oktavia; Sherly Kasuma Warda Ningsih
Acta Chimica Asiana Vol. 9 No. 1 (2026)
Publisher : The Indonesian Chemical Society, Chapter Nusa Tenggara and The University of Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/aca.v9i1.251

Abstract

Chromium(VI) metal ions have harmful effects on the environment and organisms. Chromium(VI) particles can cause chromosomal abnormalities, cross-linking, disruption of the cell cycle, and DNA damage within cells. Therefore, due to its high toxicity, it is crucial to monitor the concentration of chromium(VI) metal ions in the environment. This study aims to detect Cr(VI) metal ions in a simple, rapid, and effective manner. Electrochemical methods are employed to investigate the performance of PLE and Ag/PLE electrodes and to determine the optimal conditions for electrodeposition cycles and supporting electrolyte concentrations in detecting Cr(VI) metal ions. The electrochemical method is based on the specific reaction of the analyte, which generates an electrical signal. The PLE surface is modified with a silver thin layer through electrodeposition using cyclic voltammetry. The silver thin layer used for electrode modification offers several advantages, including improved electron transport and enhanced electrocatalytic response. The results indicate that the performance of Ag/PLE is superior to that of PLE in detecting Cr(VI) metal ions under optimal supporting electrolyte conditions, specifically 0.1 M HNO₃ with one electrodeposition cycle. Calibration curve analysis for Cr(VI) ions yielded the regression equation y = 0.6688x + 0.0085, with a correlation coefficient (R²) of 0.9958 and a limit of detection (LOD) of 0.18 mM.
Development of Problem-Based Learning Student Worksheet Integrated with Ethnoscience on Acid-Base Material Emmilya Febri Marthin; Hardeli; Budhi Oktavia; Desy Kurniawati
Jurnal Penelitian Pendidikan IPA Vol 10 No 7 (2024): July
Publisher : Postgraduate, University of Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/jppipa.v10i7.7930

Abstract

This study aims to develop problem-based learning student worksheets integrated with ethnoscience on acid-base materials that are valid and practical. This research uses a development research method (Research and Development) with a 4-D model. The data of this study were collected through validity sheets completed by 4 validators, namely 2 chemistry lecturers and 2 chemistry teachers, and with a practicality questionnaire sheet completed by 2 chemistry teachers and by 35 students of SMAN 1 Batusangkar as respondents. Data were analyzed using quantitative descriptive method, using Aiken’s V. The result for content validity is 0.88 and construct validity is 0.90 with valid category. The result for teachers practicality is 0.95 and students practicality is 0.82 with practical category. Based on the results of the research that has been conducted, it can be concluded that the development of problem-based learning-based student worksheets integrated with ethnoscience on acid-base material is valid and practical.
Development of E-Module Acid-Base Based on Problem Based Learning Oriented Chemo-Entrepreneurship to Improve Student’s Critical Thinking Skills Hanna Salwa Putri; Budhi Oktavia; Yerimadesi; Alizar
Jurnal Penelitian Pendidikan IPA Vol 10 No 7 (2024): July
Publisher : Postgraduate, University of Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/jppipa.v10i7.7943

Abstract

Acid-base is one of the important materials in chemistry learning. Based on preliminary analysis, it is known that students have not properly understood the concept of acid-base. This study aims to develop an acid-base e-module, analyze its validity, practicality, and effectiveness on critical thinking skills. This research method is development research with the Plomp development model. The e-module was validated by 5 valitadors. The practicality test was conducted on 28 students and 3 teachers. The effectiveness of the e-module is seen from the increase in critical thinking test score from 57 students. Validity and practicality were analyzed using Aiken's V, while effectiveness was analyzed with N-Gain. The results showed that the developed e-module had a validity value of 0.89 with a valid category; a practicality value of 0.87 by students and 0.97 by teachers with a practical category. The effectiveness results show that the e-module has an effect on students' critical thinking skills, as evidenced by the N-Gain score of the experimental class of 0,7 with a fairly effective category while the N-Gain score of the control class is 0,4 with a less effective category. Thus, the developed e-module is declared valid, practical, and effective.
Pengembangan E-Modul Larutan Penyangga Berbasis Problem Based Learning Terintegrasi Etnokimia Untuk Meningkatkan Kemampuan Berpikir Kritis Peserta Didik Nadia; Desy Kurniawati; Alizar; Budhi Oktavia
Jurnal Penelitian Pendidikan IPA Vol 12 No 3 (2026)
Publisher : Postgraduate, University of Mataram

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29303/jppipa.v12i3.14653

Abstract

This study aims to produce an electronic module (E-module) of buffer solutions based on ethnochemistry-integrated problem-based learning to improve students' critical thinking skills and analyze the level of validity, practicality, and effectiveness of the E-module on students' critical thinking skills. This type of research is Research and Development (R&D) with a 4-D development model. The 4-D development model consists of 4 stages of development, namely define, design, develop and disseminate. The results of the construct and content validity tests were 0.88, respectively, in the valid category. The results of the teacher and student practicality tests were 88.33% and 84.93%, respectively, in the very practical category. The N-Gain value analysis in the experimental and control classes was 0.71 and 0.46, respectively, in the high and medium criteria. The t-test results showed that students' critical thinking skills at SMAN 1 Bungo who used the E-module of buffer solutions based on ethnochemistry-integrated Problem-Based Learning were significantly higher than the control class that did not use the E-module. Thus, it can be said that the E-module on buffer solution material is valid, practical, and effective in significantly improving students' critical thinking skills.
Analisis Kadar Logam Fe pada Air Sungai Emas Kampar sesuai SNI 6989-84:2019 Dzakma Putri Alsa; Budhi Oktavia
MASALIQ Vol 5 No 4 (2025): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v5i4.6627

Abstract

This study is motivated by the critical importance of monitoring river water quality, particularly concerning heavy metal content such as iron (Fe), which poses potential risks to both human health and the environment. The objective of this research is to analyze the concentration of Fe in the water of the Kampar River using the Atomic Absorption Spectrophotometry (AAS) method. Water samples were collected from the Kampar River and subjected to a digestion process prior to measurement using AAS at a wavelength of 248.3 nm. The measurement results produced a calibration curve with a coefficient of determination (R²) of 0.9997, indicating a very strong linear relationship between concentration and absorbance. The analysis revealed that Fe concentrations in the samples ranged from 0.194 to 0.489 mg/L. While some samples exceeded the 0.3 mg/L threshold established by Government Regulation No. 82 of 2001 for Class II water quality, most remained within the permissible range. These findings demonstrate that the AAS method offers high sensitivity and accuracy in detecting Fe content in river water and can serve as a reliable tool for routine water quality monitoring.
Analisis BOD pada Limbah Industri: Perbandingan Kualitas Air di Inlet dan Outlet IPAL Putwi Ayu Faradila; Budhi Oktavia
MASALIQ Vol 5 No 5 (2025): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v5i5.6938

Abstract

This study is motivated by the issue of declining water quality due to increasing demand that is not matched by optimal waste management. The objective of the research is to determine the Biochemical Oxygen Demand (BOD) levels in industrial wastewater by comparing the BOD concentrations at the inlet and outlet points of a wastewater treatment system. A quantitative approach was employed, using two samples obtained through purposive sampling. Data were collected through field observation and analyzed descriptively and quantitatively. The results show a decrease in BOD levels from 3.99 mg/L at the inlet to 3.41 mg/L at the outlet, indicating that the treatment process effectively improves wastewater quality. The main conclusion of the study is that lower BOD levels in a body of water reflect higher oxygen availability, resulting in better water quality that poses less risk to aquatic life and human users. The implications of this research contribute to the existing literature on industrial wastewater BOD analysis and offer recommendations for industries and policymakers to enhance the effectiveness of wastewater treatment systems and implement ongoing water quality monitoring policies. The study also opens opportunities for further research on innovative wastewater treatment technologies and analysis of other water quality parameters such as COD, TSS, and heavy metals.
Analisis Ion Nitrit (NO₂⁻) pada Aplikasi Silika Gel Termodifikasi GPTMS-DMA secara Kromatografi Isra Hayati; Budhi Oktavia
MASALIQ Vol 5 No 6 (2025): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v5i6.7526

Abstract

The limited research on the use of modified silica gel as a stationary phase in ion chromatography forms the basis of this study, particularly for the analysis of nitrite ions (NO₂⁻), which are toxic and pose risks to both human health and the environment. This study aims to apply glycidoxypropyltrimethoxysilane–dimethylamine (GPTMS–DMA) modified silica gel as a stationary phase in the analysis of nitrite ions. A quantitative experimental method was used, employing nitrite ion samples at concentrations of 100 ppm, 200 ppm, and 300 ppm. The analysis was conducted using a High Performance Liquid Chromatography (HPLC) system equipped with a UV detector and carbonate-based eluents consisting of Na₂CO₃ and NaHCO₃ at concentrations of 0.1 M, 0.05 M, and 0.01 M. The results showed that 0.1 M Na₂CO₃ produced the sharpest chromatogram peaks, highest intensity, and the most stable baseline. The resulting regression equation was y = 0.0093x + 0.1533 with a determination coefficient R² = 0.9939, indicating excellent linearity. The Limit of Detection (LOD) was 33.47 ppm, and the Limit of Quantification (LOQ) was 111.56 ppm, demonstrating adequate sensitivity. The study concludes that GPTMS–DMA silica gel effectively enhances the sensitivity and selectivity of nitrite ion analysis and shows strong potential for further development in the analysis of other inorganic ions.
Aplikasi Penggunaan Resin Silika Gel-GPTMS Termodifikasi Dimetilamina untuk Analisis Ion Klorida (Cl⁻) secara Kromatografi Ion Siska Maharani; Budhi Oktavia
MASALIQ Vol 5 No 6 (2025): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v5i6.7568

Abstract

The limited use of silica gel as an ion-exchange resin in ion chromatography columns forms the background of this study, despite its high potential as a stationary phase. This research aims to apply glycidoxypropyltrimethoxysilane–dimethylamine (GPTMS–DMA) modified silica gel as an ion-exchange resin in ion chromatography for the analysis of chloride ions (Cl⁻). A quantitative method was employed, using chloride ion concentrations of 100 ppm, 200 ppm, and 300 ppm. The analysis was conducted using High Performance Liquid Chromatography (HPLC) with a column packed with GPTMS–DMA silica gel and a mixed eluent of Na₂CO₃ and NaHCO₃ at concentrations of 0.1 M, 0.05 M, and 0.01 M. The results showed that 0.1 M Na₂CO₃ produced the most optimal chromatogram peaks, with a regression equation of y = 0.0004x and a determination coefficient R² = 0.9733, indicating high linearity. The study concludes that GPTMS–DMA modified silica gel is effective as a stationary phase for chloride ion analysis via ion chromatography and holds strong potential for further development as an ion-exchange resin in broader chemical analysis applications.
Penggunaan Silika Gel-GPTMS-DMA untuk Analisis Ion Bromida (Br⁻) secara Kromatografi Ion Vitratul Wirza; Budhi Oktavia
MASALIQ Vol 5 No 6 (2025): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v5i6.7589

Abstract

The limited research on the use of glycidoxypropyltrimethoxysilane–dimethylamine (GPTMS–DMA) modified silica gel as a stationary phase in ion chromatography serves as the background of this study, particularly in the context of bromide ion (Br⁻) analysis, which poses health risks due to its potential to form carcinogenic bromate compounds upon reacting with disinfectants. This study aims to evaluate the effectiveness of GPTMS–DMA modified silica gel as a stationary phase in ion chromatography columns for bromide ion separation. A quantitative experimental laboratory method was employed using bromide solutions at concentrations of 100 ppm, 200 ppm, and 300 ppm. Analysis was conducted using High Performance Liquid Chromatography (HPLC) equipped with a UV detector and eluents consisting of Na₂CO₃ and NaHCO₃ at concentrations of 0.1 M, 0.05 M, and 0.01 M. The results showed that the 0.1 M Na₂CO₃ eluent delivered the best performance, producing sharp chromatographic peaks, high intensity, and a stable baseline. The obtained regression equation was y = 0.0002x + 0.0807 with a determination coefficient R² > 0.9992, indicating excellent linearity. The Limit of Detection (LOD) was 12.28 ppm, and the Limit of Quantification (LOQ) was 40.93 ppm, demonstrating adequate sensitivity. The study concludes that GPTMS–DMA modified silica gel has high potential as an efficient and cost-effective alternative stationary phase for bromide ion separation. Its implications include theoretical contributions to the development of hybrid materials for ion separation and practical applications in producing more affordable ion chromatography columns. The research also opens opportunities for further studies on the separation of other inorganic ions using similar materials.
Perbandingan Metode Spektrofotometri dan ICP dalam Penentuan Kesadahan Air Fahilatul Syukro; Budhi Oktavia
MASALIQ Vol 5 No 6 (2025): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v5i6.7598

Abstract

Water is a vital resource whose quality must be ensured for safe consumption and industrial use. One critical parameter in assessing water quality is hardness, typically caused by the presence of calcium (Ca²⁺) and magnesium (Mg²⁺) ions. High levels of hardness can lead to negative effects such as scale formation on equipment, reduced efficiency of boilers and turbines, and potential health issues. This study aims to compare water hardness analysis results obtained using two instruments—Spectrophotometer DR 3900 and Inductively Coupled Plasma (ICP) Perkin Elmer 3800—to identify the strengths and limitations of each method. The research was conducted experimentally using soft water samples collected from boiler piping. Spectrophotometric analysis was based on the Lambert-Beer law by measuring absorbance after adding a complexing reagent, while ICP analysis involved nebulization of filtered and acidified samples using concentrated HNO₃. The results showed that the concentrations of Ca and Mg in the samples were below the hardness threshold (<1 ppm). The highest total hardness measured using the spectrophotometer was 0.524 ppm, while the highest value obtained via ICP was 0.652 ppm. Although both methods produced comparable data, ICP demonstrated superior sensitivity and accuracy, albeit with higher costs and procedural complexity. The study concludes that ICP is recommended for high-sensitivity hardness analysis, whereas the spectrophotometer is more suitable for routine, efficient, and cost-effective testing.
Co-Authors Afifi, Rayhanil Afrilia, Yoni Agustiya, Sabay Ahmad Fauzi Ali Amran Alizar Alizar, Alizar Ananda Putra Andreas Difa Andromeda Anggraini Mardhatillah, Leonyta Anisa Nahari Auzakiyah, Sabella Ayu Azizah Bahrizal Bahrizal Berlian, Syakhinah Burma, Resna Chindikia, Ilmy Deasy Liestianty Delfitri Delfitri Deni Marlina Desy Kurniawati DESY KURNIAWATI Desy Kurniawati Deva Indriyani Devita Efri Dewi Kristina Dipnorita Retno Dwi Agustini, Dwi Dwi Putri, Vika Trisna DWI RAMADHANI Dzakma Putri Alsa Edi Nasra Elvina Elvina Elvina Yulistia Erwan Emmilya Febri Marthin Fadhilatu Zikra Fahilatul Syukro Fajriah Azra Firmansyah Khairul Kamal Fitrah Mey Harmi Siregar Fitri Amelia Fitriningsih, Annisa Guspatni Guspatni Habibur Rahman Dafnaz Hafis, Muhamad Hainunnisa Syafitriza Hanna Salwa Putri Hardeli Hardeli Hardeli Hardeli Hardeli Harmaiyani, Risky Harnas, Dolla Mulyana Hary Sanjaya Hary Sanjaya Hellena Ditasya Hesty Parbuntari Ibrahim Rahmat Illa Ramadhani Indang Dewata Isra Hayati Kauri, Desrike Khairani - Khairani - Latisma Latisma Lubis, Amalia Putri M.Iqbal Saputra Gemasih Ma’a, Yustini Masrid Pikoli Maulana, Febrina Mawardi Meri Novia Nurman Miftahul Khair Miftahul Khair Miftahurrahmi, Miftahurrahmi Minda Azhar Muhammad Amin Muhammad Farhan Mulia, Melindra Mutiara Oksyarni Nabilla Nadia Nahdiah Amin Nella Aulia Putri Nilu Gussarsi Nizar, Umar Kalmar Nofri Yuhelman Nur Hafni Hasibuan Nuzulia Rahma Yona Parbuntari, Hesty Patricia Helena Pebriani Pebriani Pernadi, Niza Lian Putra, Ananda Putri Fatimah Putri Permatasari, Putri Putri, Reza Athia Putri, Yunisa Anugrah Putwi Ayu Faradila Rahadian Zainul Rahardian Z Rahmi, Fathaniah Raviqa Randy Lesmana Putra Rela Faradina Reviana Ervita Riga Riga, Riga Rini Anggraini Rita Sundari Riva Silvia Romy Dwipa Yamesa Away Sabrina, Joya Sari, Trisna Kumala Septya Anggraini Setiowati, Fiqih Sekar Sherly Kasuma Warda Ningsih Sherly Kasuma Warda Ningsih Sintha Hafizhah Yonel Siska Maharani Sri Benti Etika Sri Benti Etika Sri Teguh Priharti Sundari, Rita Suryelita . Syamsi Aini Syifa Rahma Ayunda Takdib, Manajer Jurnal Tarmizi Tarmizi Tarmizi Tarmizi Trihanto Setiadi Trisna Kumala Sari Ulianas, Alizar Umar Kalmar Nizar Umar Kalmar Nizar Usman Bakar Visca Alisia Arianti Vitratul Wirza Vivi Chaniasi Warni Arfin Wira Ayuriza Yani Puspita Yani Yanti, Desvila Ramadha Yerimadesi yuda pratama Yulia Mona Liza Yunisya, Dinda Yustini Ma’a Zulmariko