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Analisis Natrium Siklamat dalam Minuman Es Teh Menggunakan Metode HPLC: Hasil Pengembangan dan Validasi Wira Ayuriza; Budhi Oktavia
MASALIQ Vol 6 No 1 (2026): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v6i1.8752

Abstract

The high consumption of iced tea beverages in the community increases potential exposure to artificial sweeteners, particularly sodium cyclamate, whose use is regulated in Regulation of the National Agency of Drug and Food Control (BPOM) No. 11 of 2019. The use of cyclamate that does not comply with regulatory limits may pose health risks, thereby requiring effective monitoring through analytical laboratory methods that are accurate, precise, and validated. BPOM has established a standard method for the determination of sodium cyclamate using high performance liquid chromatography (HPLC); however, in practice there are still variations in HPLC operating conditions across laboratories, such as differences in column type, mobile phase composition, and detection parameters, which may affect analytical results. Therefore, this study aimed to develop and validate an HPLC method that is compatible with specific laboratory conditions while still meeting analytical performance requirements. The results showed that a new HPLC method was successfully developed and validated for the analysis of sodium cyclamate levels in iced tea beverages. This method met all validation parameters, including linearity, precision, accuracy, limit of detection (LOD), and limit of quantitation (LOQ), and is thus suitable for determining sodium cyclamate content. The use of a methanol–water mobile phase with a 5:95 ratio proved optimal, as it provided good separation efficiency, adequate analysis time, and simplified the testing procedure. Overall, the developed method offers a practical, economical, and reliable analytical alternative to support food safety surveillance related to the use of artificial sweeteners in iced tea beverages.
WATERMELON PEEL EXTRACT AS GREEN CORROSION INHIBITOR FOR ST-37 CARBON STEEL IN SEAWATER Sri Teguh Priharti; Umar Kalmar Nizar; Rita Sundari; Sri Benti Etika; Budhi Oktavia; Ananda Putra; Rini Anggraini
International Journal of Innovation in Mechanical Engineering and Advanced Materials Vol. 3 No. 3 (2021)
Publisher : Universitas Mercu Buana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22441/ijimeam.v3i3.13759

Abstract

Corrosion engineering has taken great interest in many industries that required high cost management to overcome the serious problems. This work has investigated the role of watermelon peel extract as green inhibitor to protect carbon steel in seawater. This investigation has studied the corrosion rate and inhibition efficiency applying weight loss method.  The laboratory result shows the optimum inhibition efficiency found to be 71.64% at 5% inhibitor concentration in 100 ml seawater at room temperature. The effects of temperature and immersion time on inhibition efficiency have also been examined.  This study has used Arrhenius equation based on activation energy to determine type of adsorption encountered with corrosion process. The result shows a chemical adsorption justified by its high adsorption heat and strengthened by FTIR and UV-Vis examinations. The phytochemical examination of watermelon peel extract gives positive response to flavonoid, alkaloid, and saponin. The finding is useful for many industries encountered with carbon steel corrosion in corrosive medium using green inhibitor.   
Aplikasi Resin Silika Gel-GPTMS (Glisidoksilpropiltrimetoksisilan) Termodifikasi Sulfonat sebagai Fasa Diam pada Analisis Ion Logam K⁺ Menggunakan Kromatografi Ion Sabay Agustiya; Budhi Oktavia
TSAQOFAH Vol 5 No 6 (2025): TSAQOFAH: Jurnal Penelitian Guru Indonesia
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/tsaqofah.v5i6.7743

Abstract

The limited adsorption capacity and chemical stability of pure silica pose challenges to the efficiency of metal ion separation via ion exchange mechanisms. This study aims to enhance the performance of silica by surface modification using γ-glycidyloxypropyltrimethoxysilane (GPTMS) and the introduction of sulfonate groups (–SO₃⁻) as active ion-exchange sites. The modification process involved a silanization reaction between silica and GPTMS, followed by functionalization with 4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid, resulting in sulfonate-modified silica gel-GPTMS material. The performance of the material was evaluated using Ion Chromatography (IC) with tartaric acid and methanesulfonic acid as mobile phases under various eluent types and concentrations, a flow rate of 0.2 mL/min, and 5-minute sonication prior to sample injection. The results showed that methanesulfonic acid provided the highest effectiveness due to its ability to maintain a stable H⁺ ion concentration, thereby enhancing ion exchange between the –SO₃⁻ groups on the resin and K⁺ metal ions in the sample. The modified silica material exhibited high structural stability, strong affinity for metal ions, and sharp, symmetrical chromatographic peaks. Thus, GPTMS- and sulfonate-based silica modification is proven effective in improving the selectivity and efficiency of K⁺ ion separation through ion exchange mechanisms.
Model Isoterm Adsorpsi Methylene Blue pada Silika Xerogel Termodifikasi EDA/Cu Nabilla; Nasra, Edi; Oktavia, Budhi; Riga; Gemasih, M.Iqbal Saputra
MASALIQ Vol 6 No 5 (2026): MASALIQ: Jurnal Pendidikan dan Sains
Publisher : Lembaga Yasin AlSys

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.58578/masaliq.v6i5.11538

Abstract

Methylene blue is a cationic dye that has the potential to contaminate aquatic environments and therefore requires an effective treatment method, one of which is adsorption. This study aimed to analyze the adsorption isotherm characteristics of methylene blue on EDA/Cu-modified silica xerogel and determine the most appropriate isotherm model. The study was conducted experimentally by varying the initial methylene blue concentration from 400 to 1,100 mg/L under optimum adsorption conditions. The adsorption equilibrium data were analyzed using the Langmuir and Freundlich isotherm models through a linear regression approach. The results showed that the Langmuir model exhibited a higher goodness of fit, with an R² value of 0.9967, than the Freundlich model, which obtained an R² value of 0.5763. Analysis using the Langmuir model yielded a maximum adsorption capacity (Qm) of 235.63 mg/g and a Langmuir constant (KL) of 0.201 L/mg, whereas the Freundlich model yielded a Kf constant of 109.3 and an n value of 6.44. These findings indicate that the adsorption of methylene blue on EDA/Cu-modified silica xerogel is better described by the Langmuir isotherm model, indicating the formation of a monolayer on the relatively homogeneous adsorbent surface. This study strengthens the understanding of the equilibrium adsorption mechanism of dyes on modified silica materials and demonstrates the potential of EDA/Cu-modified silica xerogel as an adsorbent for treating dye-containing wastewater.
Co-Authors Afifi, Rayhanil Afrilia, Yoni Ahmad Fauzi Ali Amran Alizar Alizar, Alizar Ananda Putra Andreas Difa Andromeda Anggraini Mardhatillah, Leonyta Anisa Nahari Auzakiyah, Sabella Ayu Azizah Bahrizal Bahrizal Berlian, Syakhinah Burma, Resna Chindikia, Ilmy Deasy Liestianty Delfitri Delfitri Deni Marlina Desy Kurniawati DESY KURNIAWATI Desy Kurniawati Deva Indriyani Devita Efri Dewi Kristina Dipnorita Retno Dwi Putri, Vika Trisna DWI RAMADHANI Dzakma Putri Alsa Edi Nasra Elvina Elvina Elvina Yulistia Erwan Emmilya Febri Marthin Fadhilatu Zikra Fahilatul Syukro Fajriah Azra Firmansyah Khairul Kamal Fitrah Mey Harmi Siregar Fitri Amelia Fitriningsih, Annisa Gemasih, M.Iqbal Saputra Guspatni Guspatni Habibur Rahman Dafnaz Hafis, Muhamad Hainunnisa Syafitriza Hanna Salwa Putri Hardeli Hardeli Hardeli Hardeli Hardeli Harmaiyani, Risky Harnas, Dolla Mulyana Hary Sanjaya Hary Sanjaya Hellena Ditasya Hesty Parbuntari Ibrahim Rahmat Illa Ramadhani Indang Dewata Isra Hayati Kauri, Desrike Khairani - Khairani - Latisma Latisma Lubis, Amalia Putri Ma’a, Yustini Masrid Pikoli Maulana, Febrina Mawardi Meri Novia Nurman Miftahul Khair Miftahul Khair Miftahurrahmi, Miftahurrahmi Minda Azhar Muhammad Amin Muhammad Farhan Mulia, Melindra Mutiara Oksyarni Nabilla Nadia Nahdiah Amin Nella Aulia Putri Nilu Gussarsi Nizar, Umar Kalmar Nofri Yuhelman Nur Hafni Hasibuan Nuzulia Rahma Yona Parbuntari, Hesty Patricia Helena Pebriani Pebriani Pernadi, Niza Lian Putra, Ananda Putri Fatimah Putri, Reza Athia Putri, Yunisa Anugrah Putwi Ayu Faradila Rahadian Zainul Rahardian Z Rahmi, Fathaniah Raviqa Randy Lesmana Putra Rela Faradina Reviana Ervita Riga Riga, Riga Rini Anggraini Rita Sundari Riva Silvia Romy Dwipa Yamesa Away Sabay Agustiya Sabrina, Joya Sari, Trisna Kumala Septya Anggraini Setiowati, Fiqih Sekar Sherly Kasuma Warda Ningsih Sherly Kasuma Warda Ningsih Sintha Hafizhah Yonel Siska Maharani Sri Benti Etika Sri Benti Etika Sri Teguh Priharti Sundari, Rita Suryelita . Syamsi Aini Syifa Rahma Ayunda Takdib, Manajer Jurnal Tarmizi Tarmizi Tarmizi Tarmizi Trihanto Setiadi Trisna Kumala Sari Ulianas, Alizar Umar Kalmar Nizar Umar Kalmar Nizar Usman Bakar Visca Alisia Arianti Vitratul Wirza Vivi Chaniasi Warni Arfin Wira Ayuriza Yani Puspita Yani Yanti, Desvila Ramadha Yerimadesi yuda pratama Yulia Mona Liza Yunisya, Dinda Yustini Ma’a Zulmariko