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All Journal Jurnal Pengajaran Matematika dan Ilmu Pengetahuan Alam The Journal of Pure and Applied Chemistry Research Journal of Mechanical Engineering Education (Jurnal Pendidikan Teknik Mesin) IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Science and Technology Indonesia Jurnal Penelitian Sains IJEMS (Indonesian Journal of Environmental Management and Sustainability) VISI : Jurnal Ilmiah Pendidik dan Tenaga Kependidikan Pendidikan Non Formal Journal of Educational Research and Evaluation International Journal of Community Service Learning PengabdianMu: Jurnal Ilmiah Pengabdian kepada Masyarakat Molekul: Jurnal Ilmiah Kimia Edsence: Jurnal Pendidikan Multimedia Abdi: Jurnal Pengabdian dan Pemberdayaan Masyarakat Jurnal Abdi Insani Jurnal Paedagogy Jurnal Teknik Industri Terintegrasi (JUTIN) International Journal of Sustainable Transportation Technology Jurnal Pengabdian kepada Masyarakat Nusantara Jurnal Kependidikan: Jurnal Hasil Penelitian dan Kajian Kepustakaan di Bidang Pendidikan, Pengajaran dan Pembelajaran Jurnal Abmas Jurnal Industri dan Teknologi Samawa (JITSA) Jurnal Insinyur Profesional Jurnal Riset Rumpun Ilmu Teknik (JURRITEK) Jurnal Pepadu Jurnal Guru Komputer Jurnal Ilmiah Sistem Informasi
Dedi Rohendi
Universitas Pendidikan Indonesia
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Journal : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

 1 
Preparation And Characterization Of Cr/Activated Carbon Catalyst From Palm Empty Fruit Bunch Zainal Fanani; Dedi Rohendi; Tri Kurnia Dewi; Muhammad Dzulfikar A
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 1, No 2 (2016): June 2016
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v1.i2.35

Abstract

Preparation and characterization of Cr/activated carbon catalyst from palm empty fruit bunch had been done. The research were to determine the effect of carbonization temperature towards adsorption of ammonia, iodine number, metilen blue number, and porosity of activated carbon and Cr/activated carbon catalyst. The determination of porosity include surface area, micropore volume and total pore volume. The results showed the best carbonization temperature activated carbon and Cr/activated carbon catalyst at 700°C. The adsorption ammonia of activated carbon and Cr/activated carbon catalyst as 6.379 mmol/g and 8.1624 mmol/g. The iodine number of activated carbon and Cr/activated carbon catalyst as 1520.16 mg/g and 1535.67 mg/g. The metilen blue number of activated carbon and Cr/activated carbon catalyst as 281.71 mg/g and 319.18 mg/g. The surface area of activated carbon and Cr/activated carbon catalyst as 1527.80 m2/g and 1652.58 m2/g. The micropore volume of activated carbon and Cr/activated carbon catalyst as 0.7460 cm3/g and 0.8670 cm3/g. The total pore volume of activated carbon and Cr/activated carbon catalyst as 0.8243 cm3/g and 0.8970 cm3/g.Keywords : activated carbon, palm empty fruit bunch, porosity, catalyst, chromium
Analyses of Non-bonding Length, Partial Atomics Charge and Electrostatic Energy from Molecular Dynamics Simulation of Phospholipase A2 – Substrate Nirwan Syarif; Dedi Rohendi
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 1, No 3 (2016): October 2016
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v1.i3.72

Abstract

Abstract: This paper reports molecular dynamics simulation of phospholipase A2 (PLA2)– substrate that has been done. Non-bonding length, partial atomic charge and electrostatic energy were used to evaluation the interaction between PLA2 and substrate. The research was subjected for three types of PLA2 of different sources, i.e, homo sapien, bovinus and porcinus, by using computer files of their molecular structures. The files with code 3elo, 1bp2, dan 1y6o were downloaded from protein data bank.  Substrate structure can be found in 1y60 and was separated from its enzyme structure and docked into two other PLA2 structures for simulation purpose. Molecular dynamics simulations were done for 30000 steps with constant in number of molecules, volume and temperature (NVT). The results showed the existing of flip-flop mechanism as basic feature of PLA2 – substrate reactions. Interaction length analysis results indicated the presence of water molecules on the structures of 1bp2 and 3elo at the time of the simulation was completed. The existence of aspagine at the reaction site confirmed the theory that this amino acid is responsible for the survival of the reaction. the electrostatic energy increased substantially in the interaction after homo sapien PLA2 (3elo) and Bovinus (1bp2) with the substrate. Inverse effect took place in the PLA porcinus (1y6o).Keywords: flip flop, inflammation, in-silico, simulation Abstrak (Indonesian): Telah dilakukan penelitian tentang simulasi dinamika molekuler pada Situs Reaksi Phospholipase A2 (PLA2) dengan substratnya. Analisis panjang non-ikatan, muatan atom parsial dan energi elektrostatis digunakan untuk menilai interaksi antara PLA2 dan substratnya. Penelitian dilakukan pada tiga jenis sumber PLA2, yaitu homo sapien, bovinus dan porcinus dengan menggunakan file komputer untuk struktur molekul dengan kode 3elo, 1bp2, dan 1y6o. Pada file 1y60 terdapat struktur substrat yang dapat ditemukan secara alamiah. Kedua file lainnya tidak mengandung struktur molekul substrat. Simulasi dinamika molekul dilakukan untuk 30.000 langkah dengan konstan dalam jumlah molekul, volume dan suhu (NVT). Hasil penelitian menunjukkan keberadaan mekanisme flip-flop sebagai fitur dasar reaksi PLA2 - substrat. Hasil analisis panjang interaksi menunjukkan bahwa kehadiran molekul air pada struktur 1bp2 dan 3elo pada saat simulasi dilakukan. Keberadaan aspagine di lokasi reaksi menegaskan teori bahwa asam amino ini bertanggung jawab untuk kelangsungan hidup reaksi. energi elektrostatik meningkat secara substansial dalam interaksi setelah homo sapien PLA2 (3elo) dan Bovinus (1bp2) dengan substrat. efek terbalik terjadi di porcinus PLA (1y6o).Kata kunci: flip flop, inflamasi, peradangan, in-silico, simulasi
Hydrogen Production from Aluminum Waste Using the Aluminum-Water Method with Potassium as Activator Amelia, Icha; Rohendi, Dedi; Rachmat, Addy; Syarif, Nirwan; Yulianti, Dwi Hawa; Sya'baniah, Nyimas Febrika; Adhiyanti, Nurmalina; Adelia, Ory; Normah, Normah
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 9, No 2 (2024): June 2024
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v9.i2.111

Abstract

Research on hydrogen production from aluminum waste using the aluminum-water method using potassium as an activator has been successfully carried out. This research aims to determine the performance of the potassium activator in hydrogen production with variable water volume and potassium percentage. Hydrogen gas production is carried out using 60 mesh aluminum waste. Optimum conditions were achieved when a mass of 1 gram of aluminum was reacted with an additional volume of water of 1.5 mL, and 7% w/w of the activator mass, with the production of hydrogen gas of 553 mL at a production rate of 69 mL/minute.
Thermogravimetric Analysis of EFB and Palm Shells as Gasification Fuels: Kinetic and Activation Energy Study Komala, Ria; Rohendi, Dedi; Gulo, Fakhili; Faizal, Muhammad
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 10, No 1 (2025): February 2025
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v10.i1.37

Abstract

Solid waste from palm oil industry such as EFB and palm kernel shells pose environmental challenges if not properly managed. This study investigated the thermal characteristics and decomposition kinetics of EFB and palm kernel shells through proximate analysis and thermogravimetric analysis (TGA). The results indicate that palm kernel shells have a greater fixed carbon content (21.03–21.35%) than does EFB (19.60–20.06%), whereas EFB has a greater ash content (4.74–5.38%) than does palm kernel shells (1.25–1.31%). EFB showed a weight loss of 94.67% after 233.33 minutes of heating, whereas it was 99% for the palm kernel shells. The peak temperatures reached were 936.67 °C for the EFB and 930 °C for the palm kernel shells. At 600°C, EFB produced more syngas than palm kernel shells did. The calculated activation energies were 4482.19 J/mol for EFB and 4484.97 J/mol for palm kernel shells. This research enhances the understanding of the gasification efficiency of these materials, aiding in the optimization of eco-friendly energy production.Keywords: Empty fruit bunches, palm kernel shells, activation energy, thermogravimetric analysis, gasification
The Influence of Hydrogen Flow Rate and Humidifier Temperature on Performance of a PEMFC with Ti-Co/C Catalyst Adhiyanti, Nurmalina; Rohendi, Dedi; Utama, Muhammad Prima; Syarif, Nirwan; Rachmat, Addy; Yulianti, Dwi Hawa; Normah, Normah
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 10, No 3 (2025): October 2025
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

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Abstract

This study explores the effect of hydrogen flow rate and humidifier temperature on the performance of the Membrane Electrode Assembly (MEA) using Ti-Co/C catalyst at the cathode and Pt/C at the anode in a single-cell Proton Exchange Membrane Fuel Cell (PEMFC). MEAs were fabricated by the spraying method and characterized using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) to determine their electrochemical surface area (ECSA) and conductivity. The results showed that the optimized ECSA value reached 8.38 cm2/g, and the electrical conductivity was 3.76 × 10-8 S/cm. The best performance was achieved at a hydrogen flow rate of 100 mL/min and room temperature humidification. Under the hydrogen flow rate test, the maximum power density reached 0.364 mW/cm2, while in the humidifier temperature variation, a maximum power density of 0.375 mW/cm2  was obtained at a current density 2.4 mA/cm2. These findings suggest that Ti-Co/C is a promising low-cost catalyst alternative to Pt and that operational conditions play a critical role in MEA performance
Preparation of Palm Kernel Shell Binchotan for Radio Frequency Energy Harvesting Sya'baniah, Nyimas Febrika; Syarif, Nirwan; Rohendi, Dedi; Rachmat, Addy; Syahputra, Rio Aldo
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 10, No 3 (2025): October 2025
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

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Abstract

Research on the development of radio frequency energy harvesting slabs from palm kernel shells binchotan has been done. The slabs were characterized by using XRD and FTIR intrumentations to determine their crystallography and functional groups. The electrical response of slabs was measured on impedance spectroscopy instrumentation. The conductivity, impedance, and dielectric constant were calculated from impedance spectroscopy data. Diffractograms showed crystalline carbon and confirmed with the existence of peaks, at 2θ, 24.5° and 44.56°. FTIR analysis showed that carbon palm shells have the absorption length is in the range of wave numbers 1100 – 1200 cm-1 for CO of carboxylic acid, aldehyde, ketone and ester, from 1475 to 1600 cm-1 for C=C aromatic ring and double peaks in 1900 – 2100 cm-1 for conjugated C-C. The slabs conductivity varies from 1 to 7 mScm-1. Impedance values for the slabs vary from 1.5 to 2.4 ohm. Dielectric constants for the slabs range from 0.42 to 140.
Effect of Hydrogen Flow Rate on MEA Performance with a Three-Catalyst-Layer Pt/C Configuration Yulianti, Dwi Hawa; Rohendi, Dedi; Budiman, Rahmadi; Firanda, Dera Okta; Rachmat, Addy; Sya'baniah, Nyimas Febrika
IJFAC (Indonesian Journal of Fundamental and Applied Chemistry) Vol 10, No 2 (2025): June 2025
Publisher : IJFAC (Indonesian Journal of Fundamental and Applied Chemistry)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24845/ijfac.v10.i2.146

Abstract

An essential component in Proton Exchange Membrane Fuel Cells (PEMFCs) is the Membrane Electrode Assembly (MEA), which facilitates the electrochemical reaction between hydrogen and oxygen to generate electrical energy. This study examines the effect of varying hydrogen gas flow rates on the performance and durability of a Pt/C-based MEA. The MEA used in this research measures 6.5 cm × 30 cm with a catalyst loading of 2 mg/cm². The electrode is constructed in three layers of catalysts to maximize interfacial contact within the catalyst layer. The tested hydrogen flow rates were 100, 200, 300, and 400 mL/min. Performance evaluation was conducted through polarization (I–V) and power (I–P) curve measurements. The results indicated optimal performance at a 200 mL/min flow rate, with a maximum power density of 3.563 mW/cm² and a current density of 10.256 mA/cm². Durability testing was carried out under a constant current of 2 A for 12 hours and showed a voltage drop of 24.35% after 10 hours of operation. Electrochemical characterization using Cyclic Voltammetry (CV), Electrochemical Impedance Spectroscopy (EIS), and Linear Sweep Voltammetry (LSV) yielded an Electrochemical Surface Area (ECSA) of 1.477 × 10⁻⁵ m²/g, electrical conductivity of 3.218 × 10⁻⁴ S/cm, and an electric charge of 4.2 × 10⁻⁶ C.
Co-Authors ACHEAMPONG, KENNEDY Addy Rachmat Ade Gafar Abdullah, Ade Gafar Ade Gaffar Abdullah, Ade Gaffar Adelia, Ory Adhiyanti, Nurmalina Agus Setiawan Aldes Lesbani Amelia, Icha Ana Arrumaisha, Nissa Asep Yudi Permana Assaidah, Assaidah Barlin Barlin Bijak Riyandi Ahadito Budhi Setiawan Budi Mulyanti Budiman, Rahmadi Dedy Suryadi Dewi, Claudia Edy Herianto Majlan, Edy Herianto Eka Daryanto, Eka Fakhili Gulo Fatma Fatma Fatmawati Fatmawati Fauzan, Mochamad Patra Bani Fauzan, Mochamad Rizal Felicity, Felicity Firanda, Dera Okta Gigin Gantini Putri Hanapi, Zaliza Hanissa Okitasari Hanissa Okitasari Hary Widjajanti Heri Sutarno Hikmawan, Rizki Indriana Sari Soleha Iskandar, Naufal Nadhif Rabbani Iwa Kuntadi Jefri Jefri Kamin Sumardi Kamin Sumardi Koehler, Thomas Larutama, Wiku Menik Setyowati Mokhamad Syaom Barliana Muhammad Adli Rizqulloh Muhammad Dzulfikar A Muhammad Faizal MUHAMMAD SAID Muhammad Said Muktiarni Mustika Nuramalia Handayani Nirwan Syarif Nirwan Syarif, Nirwan Normah Normah, Normah Nugraha, Agri Triya Oduro-Okyireh, George Oduro-Okyireh, Theodore Permana, Muhammad Aditya Poedji Loekitowati Hariani Pramudita, Resa Purnawan Purnawan Rahmah, Dea Ramadhan, Muhammad Oka Rasim, R Ria Komala Risfidian Mohadi Roer Eka Pawinanto, Roer Eka Salni Saripudin Saripudin Septiadi, Jaka Shandyka, Muhammad Fajar Siregar, Batu Mahadi Sri Haryati Steven Julianto Situmeang Suamrdi, Kamin Subarna, Bambang Sudarsono, Wulandari Sya'baniah, Nyimas Sya'baniah, Nyimas Syabaniah, Nyimas Febrika Syahputra, Rio Aldo Syarif, Nirwan Syarif, Nirwan Syarif, Nirwan Syarif, Nirwan Sya’baniah, Nyimas Febrika Tarmizi Taher Tri Kurnia Dewi Utama, Muhammad Prima Wong, Wai Yulianti, Dwi Yulianti, Dwi Hawa Yulinar Adnan Zainal Fanani