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KARAKTERISASI BIODIESEL DARI MINYAK KEMIRI SUNAN DENGAN KATALIS HETEROGEN SILIKA TERIMPREGNASI KALSIUM OKSIDA (CaO/SiO2 ) Haryono; Yati B. Yuliyati; Atiek Rostika Noviyanti; Mochammad Rizal; Sarifah Nurjanah
Jurnal Penelitian Hasil Hutan Vol. 38 No. 1 (2020): Jurnal Penelitian Hasil Hutan
Publisher : BRIN Publishing

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20886/jphh.2020.38.1.10-20

Abstract

Commercial biodiesel of oil palm is controversial as the palm oil is classified as food oil and palm plantation utilizesfertile land. One potential type of vegetable oil as biodiesel raw material is kemiri sunan (Reutealis trisperma(Blanco) Airy Shaw) oil. This research aimed to prepare a heterogeneous solid catalyst in the form of an impregnatedSiO2by CaO catalyst (CaO/SiO2), to study the effect of the esterification stage on free fatty acid (FFA) content ofoil, and to test the activity of the CaO/SiO2catalyst during the trans-esterification stage for biodiesel formation. CaO/SiO2catalysts were prepared by sol-gel method made from natural materials (egg shells and rice husk). The FFAcontent of kemiri sunan oil was determined through various esterification stages namely 1; 1.5; and 2 hours in thepresence of H2SO4catalyst. While the trans-esterification stage was carried out under reaction temperature of 60°C,oil to methanol ratio of 1:9, reaction time of 2 hours and CaO/SiO2catalyst content of 3%. The results showed thatthe esterification stage for 1; 1.5; and 2 hours reduced the FFA content from 12.5% (without esterification) to 0.65%;0.58%; and 0.54% respectivaly. Biodiesel made from kemiri sunan oil which was synthesized with the addition ofCaO/SiO2catalyst at optimal conditions of trans-esterification stage fulfilled SNI 7182-2015: Biodiesel based ondensity, viscocity, moisture content, iodine number, and cetane number.
Effect of Preparation Acetone on Fish Bones Synthesized Through Sintering Method to Improve Hydroxyapatite Characteristics Kusumawardani, Ratna; Noviyanti, Atiek Rostika; Nurhadi, Mukhamad; Umar, Akrajas Ali
al Kimiya: Jurnal Ilmu Kimia dan Terapan Vol. 10 No. 2 (2023): al Kimiya: Jurnal Ilmu Kimia dan Terapan
Publisher : Department of Chemistry, Faculty of Science and Technology, UIN Sunan Gunung Djati Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15575/ak.v10i2.29422

Abstract

In the development of advanced materials and various technological applications, the preparation and sintering processes have become two important factors in determining material characteristics. This research focuses on two main aspects, namely the effect of fish bone preparation by soaking in acetone and the surface area of the material in the sintering process as part of the process of developing better materials. This research aims to determine the effect of soaking fish bone powder with acetone and the effect of the surface area of sintered fish bones to produce hydroxyapatite (HA). The immersion process with acetone is included in the sample preparation stage, while the sintering process is included in the material synthesis stage. These two things can affect the characteristics of the HA produced after analysis from the X-ray diffraction test. The HA structure obtained from all samples is hexagonal with cell parameter values a = b ≠ c and space group P 63 / m, where all samples have a value range of a = b = 9,42 Å and c = 6,88 Å. HA crystallinity was identified through the XRD peak at 2θ = 25,8 (002); 31,7 (211); 32,1 (112); 32,8 (300); 34,0 (202); 39,7 (310); 46,6 (222); 49,4 (213); 50,4 (321). The PAF-900 and CAF-900 samples are similar to HA in JCPDS 01-089-4405 whose compound formula is Ca5(PO4)3(OH) while the PWAF-900 sample is similar to HA in JCPDS 01-075-3727 whose compound formula is Ca5(PO4)3(CO3)0.01(OH)1.3. The percentage of crystallinity of PAF-900, CAF-900, and PWAF-900 respectively was 84,767; 73,506; and 71,962% with HA grain sizes of 0,8964; 0,6808, and 0,7398 nm. The HA density of PAF-900 and CAF-900 samples is 3,149 g/cm3 while PWAF-900 is 3,146 g/cm3. Based on this description, it can be concluded that the soaking preparation stage with acetone produces HA with the chemical formula Ca5(PO4)3OH with a higher percentage of crystallization and is denser compared to HA obtained without going through the soaking preparation stage with acetone. The sintering stage also plays an important role in increasing the crystallization percentage. The surface area of the material being sintered also influences the percentage of crystallization and the grain size of the resulting HA. Sintered fish bone powder produces a greater percentage of crystallization and grain size than fish bone chunks
EVALUATION OF MINERAL-BASED HYDROXYAPATITE/ZnO COMPOSITES AS PHOTOCATALISTS FOR METHYLEN BLUE DEGRADATION Hardian, Arie; Nafisah, Aulia Zakiyatun; Karya, Teguh; Halim, Riyan; Murniati, Anceu; Syarif, Dani Gustaman; Noviyanti, Atiek Rostika; Nurhayati, Mita; Jasmansyah, Jasmansyah; Reza, Muhammad
al Kimiya: Jurnal Ilmu Kimia dan Terapan Vol. 11 No. 2 (2024): al Kimiya: Jurnal Ilmu Kimia dan Terapan
Publisher : Department of Chemistry, Faculty of Science and Technology, UIN Sunan Gunung Djati Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15575/ak.v11i2.37886

Abstract

The use of dyes in the textile industry has increased significantly, raising concerns about their potential to pollute the environment and harm human health. Methylene blue is a widely used synthetic dye, necessitating effective methods for its degradation. Photodegradation is a promising approach to decompose dyes into simpler, less harmful compounds. In this study, hydroxyapatite combined with ZnO was employed as a photocatalyst material to enhance photocatalytic performance. The research aims to degrade methylene blue using a Hydroxyapatite/ZnO (HAp/ZnO) nanocomposite through photodegradation. The optimization of the photodegradation process was investigated by varying irradiation time, methylene blue concentration, and pH. The optimum degradation of methylene blue was achieved using 20 mg of HAp/ZnO nanocomposite at an irradiation time of 120 minutes, an initial methylene blue concentration of 5 ppm, and pH 7. Adsorption isotherm modeling revealed that the process followed the Langmuir isotherm model, with a maximum adsorption capacity (qmax) of 0.3353 mg/g. The degradation followed pseudo-second-order kinetics with a reaction rate constant of 4.0026×105 L/mol·s.
Photoluminescent Carbon Dots for Intelligent Food Packaging: A Review on Sensing Mechanisms and Applications Maqsudi, Shobir Muntahal; Mardawati, Efri; Noviyanti, Atiek Rostika; Hardian, Arie; Ma’Amor, Azman
Jurnal Kartika Kimia Vol 8 No 2 (2025): Jurnal Kartika Kimia (In Progress)
Publisher : Department of Chemistry, Faculty of Sciences and Informatics, University of Jenderal Achmad Yani

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26874/jkk.v8i2.950

Abstract

Ensuring food safety and quality has become a global priority, demanding innovative solutions to detect early signs of spoilage or contamination. Intelligent food packaging systems offer a promising approach through real-time monitoring of food quality. Among various sensing materials, carbon dots have emerged as a novel class of fluorescent nanomaterials with exceptional optical properties, high water solubility, low toxicity, and tunable photoluminescence. This review discusses the synthesis strategies of CDs particularly focusing on green synthesis using biomass waste and their photoluminescence mechanisms including quantum confinement, surface state, carbon core state, and molecular state emissions. The application of CDs in smart packaging is highlighted, especially in detecting spoilage indicators such as ammonia, hydrogen sulfide, Total Volatile Basic Nitrogen, and pH changes. Various studies demonstrate the ability of CDs embedded in biopolymer matrices to produce distinct color changes in response to food spoilage, making them effective visual sensors. These findings support the development of eco-friendly, sensitive, and low-cost nano sensors for next-generation intelligent packaging technologies.
Co-Authors Adhitya Pratama Adzkia, Qurratu Aini Alya Akrajas Ali Umar Akrajas Ali Umar Alfian Nur Firdaus Alfian Raymondo Sinurat Amal, Alfi Ikhlasul Anceu Murniati Anni Anggraeni Anni Anggraeni, Anni Arie Hardian Arini Nurisydayanti Gumilar Asman Asman Ayu Wanda Marita Azhari Yusuf Azhari Yusuf Azmi Prasasti Bambang Prijamboedi Basril Simbarta Tarigan Budi Adiperdana Budiman, Yudha Prawira Cecep Kusmana Chicilia, Novia Dani Gustaman Syarif Dayu Kusuma, Hersandy Diana Rakhmawaty Diana Rakhmawaty Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Diana Rakhmawaty Eddy Dickry Abil Barry Pratama Diding Mandala Putra Dini Fitriani, Dini Dini Janati Diyanthi, Erlinda Widyasmara E Evy Ernawati Eddy, Diana Rakhmawaty Efri Mardawati Eko Prabowo Hadisantoso, Eko Prabowo Eleonora Agustine Engela Evy Ernawati Engela Evy Ernawati Fajar Firmansyah Ferli Septi Irwansyah Firmansyah, Fajar Gani Abdilah Gerald Tamuntuan Ghaissani Nur Maulani Gustaman Syarif, Dani Hajar Kirana, Kartika Halim, Riyan Hanapratiwi, Reinanda HARYONO Haryono Haryono Haryono Haryono Haryono Haryono Haryono Haryono Haryono Haryono Haryono MT Hemzah, Sabila Aulia Hersandy Dayu Kusuma I Nyoman Marsih Iman Rahayu Irwan Kurnia Irwan Kurnia Ismunandar Ismu Iwan Hastiawan Iwan Hastiawan Iwan Hastiawan Jasmansyah, Jasmansyah Juliandri Juliandri Karya, Teguh Kurnia, Irwan Laelaturrohmah Laelaturrohmah Lestari, Putri Rizka Lubis, Rubianto A. Ma'Amor, Azman Bin Malik, Yoga Trianzar Maqsudi, Shobir Muntahal Maryani, Eneng Mastuti Widi Lestari Mastuti Widi Lestari, Mastuti Widi Ma’amor, Azman Meliani, Tiara Ayu Mochammad Rizal Mochammad Rizal Mohammad Rofik Usman Muhamad Rozaq Nur Fauzi Muhammad Raihan Gemilang Muhammad Reza Muhammad Rizky Ridwansyah Muhammad, Irfan Handi Mukhamad Nurhadi, Mukhamad Nafisah, Aulia Zakiyatun Nisrina, Aniqa Novella, Indrika Nur Azizah Ferdiana Nurhayati, Mita Pandu, Rinal Pramudya Sulaeman, Allyn Rahmadona, Nova Ratna Kusumawardani, Ratna Reinanda Hanapratiwi Rihan Amila Putri Rinal Pandu Risdiana Risdiana RISDIANA RISDIANA, RISDIANA Rizka Endah Roekmiati Tjokronegoro Roekmiati Tjokronegoro, Roekmiati Rofifah, Sinthia Anis Rubianto A. Lubis Rukiah Rukiah Rukiah Rukiah Rukiah Rukiah Rukiah Rukiah Rukiah Rukiah Rustaman Rustaman S SOLIHUDIN S Solihudin, S S. Suryana Sahrul Hidayat Sarifah Nurjanah Seli Listiani Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin Solihudin, Solihudin Solihudin, Solihudin Sovia Islamiah Syamsiyatul Fajriyah TATI NURHAYATI Titin Siti Fatimah Titin Siti Fatimah Wahyu Safriansyah Walim Lili Yashfi, Difa Muhammad Yati B Yuliyati YATI B YULIYATI Yati B Yuliyati Yati B Yuliyati Yati B Yuliyati, Yati B Yati B. Yuliyati Yati B. Yuliyati Yeni Wahyuni Hartati Yuli Andriani Yusi Deawati