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Analysis of Hg(II) Metal by Voltammetric Method Using a Carbon Electrode Modified with EDTA from Used Tire Waste Sukoma, Sukoma; Alva, Sagir; Safitri, Eka; Julinawati, Julinawati; Mustanir, Mustanir; Fonna, Syafrizal; Ihsan, Muhammad; Dara, Fitri; Dayanti, Meri; Arifin, Ahmad Kamal; Suhud, Khairi
Indonesian Journal of Chemistry Vol 24, No 6 (2024)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.97561

Abstract

Development of a carbon electrode sensor from used tire waste via pyrolysis, modified with ethylenediaminetetraacetic acid (EDTA) for mercury detection using the cyclic voltammetry (CV) method. EDTA plays a role in metal complexation due to its strong response to mercury metal. The FTIR results of the carbon electrode and EDTA show a C–N bond at a wavenumber of 1,217.08 cm−1, indicating the presence of EDTA. The SEM results reveal a clear difference between the unmodified carbon electrode and the EDTA-modified carbon electrode. The calibration graph is linear, with an R2 value of 0.9961, a sensitivity of 0.3472, as well as LoD and LoQ values of 0.03 and 0.08 ppm, respectively. The correlation coefficient is less than 2%, and the %recovery is within the allowable error range. Mercury measurements in Sungai Mas water samples, Aceh Barat, using voltammetry and AAS, exceed the threshold set by Indonesian Government Regulation (PPRI) No. 22 of 2021. The t-test results for the two Hg measurement methods at a 5% significance level (α) show that tcalculated < ttable (0.083 < 2.571). This indicates no significant difference between the voltammetry and AAS methods for measuring Hg concentrations in water.
Effect of Coconut Fiber and Coconut Shell Charcoal Composition on the Properties of PVC-Reinforced Composite Brake Pads Pandriana, Aap; Kurniawan, Kurniawan; Alva, Sagir
International Journal of Innovation in Mechanical Engineering and Advanced Materials Vol 7, No 1 (2025)
Publisher : Universitas Mercu Buana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22441/ijimeam.v7i1.31092

Abstract

The increasing concern over the health hazards associated with asbestos-based brake pads has driven the development of eco-friendly alternatives using natural fiber-reinforced composites. This study aims to fabricate and evaluate a sustainable brake pad material using coconut fiber as reinforcement, coconut shell charcoal powder as filler, and polyvinyl chloride (PVC) as the matrix. The composite was manufactured using the hot press method at a temperature of 180°C and a pressure of 7 MPa, conditions selected to optimize resin curing and interfacial bonding. A key focus of this research was to investigate the effect of solvent volume (cyclohexanone) used in the PVC resin preparation on the mechanical properties of the resulting composites. Three composite formulations were prepared with a constant composition of 70% coconut fiber, 5% charcoal powder, and 25% PVC resin, but with varying amounts of cyclohexanone solvent (200 mL, 150 mL, and 100 mL). The results revealed that reducing solvent content led to higher resin viscosity, which improved matrix–fiber bonding and increased both tensile strength and surface hardness. The optimal formulation—PVC Resin 3 with 100 mL of solvent—achieved a maximum tensile strength of 7.7 MPa and Shore D hardness of 72.2 HD, both of which meet the SAE J661-1997 standards for brake pad materials. This study confirms that solvent content is a critical factor influencing the density, strength, and durability of the composite. The findings support the feasibility of utilizing coconut-based agricultural waste in producing environmentally friendly brake pads with adequate mechanical performance.
Pengaruh Variasi Densitas Resin PVC terhadap Koefisien Gesek dan Mikrostruktur Komposit Kampas Rem Berbasis Serat Sabut Kelapa dan Serbuk Arang Pandriana, Aap; Alva, Sagir; Noviyanto, Alfian; Kurniawan, Kurniawan
Jurnal Rekayasa Energi dan Mekanika Vol 5, No 1 (2025): JREM
Publisher : Institut Teknologi Nasional, Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26760/JREM.v5i1.50

Abstract

Penelitian ini bertujuan mengembangkan kampas rem ramah lingkungan berbahan komposit dengan menggunakan serat sabut kelapa sebagai penguat, serbuk arang batok kelapa sebagai pengisi, dan resin polivinil klorida (PVC) sebagai matriks. Proses pembuatan komposit dilakukan melalui metode hot press pada suhu 180 °C dan tekanan 7 MPa. Variasi resin PVC diperoleh dari perbedaan rasio pelarut cyclohexanone terhadap serbuk PVC, yaitu G01 (1,036 g/ml), G02 (1,069 g/ml), dan G03 (1,136 g/ml). Pengujian yang dilakukan meliputi pengukuran massa jenis, koefisien gesek, serta pengamatan struktur mikro menggunakan mikroskop optik. Hasil menunjukkan bahwa meningkatnya densitas resin sebanding dengan peningkatan massa jenis dan nilai koefisien gesek komposit. Spesimen G03 dengan densitas resin tertinggi menghasilkan nilai koefisien gesek tertinggi, yaitu 0,19. Hal ini menunjukkan bahwa kekuatan ikatan antar material semakin baik seiring peningkatan kandungan resin. Pengamatan struktur mikro memperlihatkan bahwa resin PVC lebih merata dan menyelimuti serat dengan lebih baik pada spesimen G03, yang mengindikasikan distribusi material yang lebih homogen dan ikatan antar fase yang lebih kuat. Hasil pengujian menunjukkan bahwa koefisien gesek meningkat seiring dengan peningkatan kandungan resin dan spesimen komposit G03 masuk dalam standar SAE J661-1997. (0,14–0,27), kondisi ini diduga disebabkan oleh pengujian yang dilakukan pada temperatur rendah. Secara keseluruhan, komposit ini memiliki potensi untuk digunakan sebagai kampas rem non-asbes yang aman, ringan, dan memiliki sifat mekanik serta mikrostruktur yang mendukung performa pengereman yang baik.
Analysis of The Effect of Temperature Variations and Natural Gas Flow on Zinc Oxide (Zno) Quality Results Using The French Method Suyadi, Yadi; Alva, Sagir
Jurnal Teknik Mesin (Journal Of Mechanical Engineering) Vol 14, No 2 (2025)
Publisher : Universitas Mercu Buana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22441/jtm.v14i2.31993

Abstract

This study aims to analyze the effect of temperature and gas flow variations on the quality of Zinc Oxide (ZnO) produced in terms of particle size and product purity using the French method. The French method is a standard production technique used to manufacture ZnO, which utilizes the oxidation of zinc metal at high temperatures. The problem in the ZnO manufacturing process is determining what natural gas temperature and flow will be used to obtain the best quality, considering fuel consumption and production efficiency. In this study, temperature variations of 900°C, 1000°C, and 1100°C and natural gas flow using CNG (Compressed Natural Gas) with variations of 50 m3/hour, 55m3/hour, 60m3/hour were applied to understand how these parameters affect the properties of the resulting ZnO, characterization of the results was carried out using the complexometric titration method with ethylenediaminetetraacetic acid (EDTA) solution to determine the purity of the resulting ZnO and using a laser diffraction instrument to examine the size of ZnO particles. The results showed that the process temperature significantly affected the purity of ZnO. At a temperature of 1100 °C, the purity of ZnO reached 99.94%, which is the testing value in this study. At a gas flow of 60 m3/h, the purity of ZnO tends to be stable at a value of 99.93–99.94%. Meanwhile, the results of particle measurements at a temperature of 900°C with a gas flow of 50 m3/h, D50 reached 1.235 µm. At a temperature of 1100°C with a gas flow of 60 m3/h, D50 decreased to 1.089 µm. This particle size indicates that high temperatures encourage agglomeration reduction, resulting in finer ZnO particles. This study concludes that temperature and gas flow parameters play an important role in controlling the quality of ZnO produced through the method, with oxygen gas flow at high temperatures giving optimal results.
STUDY OF FINITE DIFFERENCE METHOD IN HEAT FLOW SIMULATION OF TWO-CHAMBER THERMOS SEPARATOR MADE OF POLYPROPYLENE USING MATLAB APPLICATIONS Pandriana, Aap; Pudjiwati, Sri; Alva, Sagir; Tarigan, Kontan; Sudarma, Andi Firdaus; Khaerudini, Deni Shidqi
Jurnal Teknik Mesin (Journal Of Mechanical Engineering) Vol 13, No 2 (2024)
Publisher : Universitas Mercu Buana

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22441/jtm.v13i2.27803

Abstract

Heat transfer can be defined as transfer of energy from one area to another as a result of temperature differences in objects. This indicates heat transfer not only explains how heat energy is transferred from one object to another, but can also predict the rate of heat transfer that occurs under certain conditions. In this case, what is related to the heat flow model equation is two-chamber thermos separator where the separator is made of polypropylene. This separator functions to prevent the flow of heat from one side to the other side of the thermos tube. Polypropylene is included in the insulator category, although heat transfer still occurs. The heat transfer will be calculated using the finite difference method in parabolic partial differential equations using the Matlab application. The heat transfer process is assumed to occur by conduction, with a separator length of 1 cm. Assume the first side of the divider has a right temperature of 100°c, and the other side 20°c. The temperature point measured on the separator is located in the center of the separator. After completing the solution using the Matlab application with the finite difference method, a heat transfer flow simulation was obtained in the two-chamber thermos separator which shows the heat flow transfer at any time. At 0.1 seconds the temperature at T1 is 2.4°c, while at 10 seconds  is 65.9704°c. Then at 0.1 seconds the temperature at T4 is 0.48°c, while at 10 seconds 19.5436°c. The conclusion is in the separator of the two-chamber thermos there is significant heat flow from the side of the first tube to the other side.
Socialization Of Waste To Energy Transformation: Innovation And Future Opportunities In Penang Island Ayu Arwati, I G.; Nurato , Nurato; Feriyanto, Dafit; Hidayat, Imam; Fitri , Muhammad; Pranoto, Hadi; Alva, Sagir; Ginting, Dianta; Ruhyat, Nanang; Noviyanto, Alvian
International Journal Of Community Service Vol. 5 No. 3 (2025): August 2025 (Indonesia - Rusia - Malaysia)
Publisher : CV. Inara

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51601/ijcs.v5i3.872

Abstract

Effective waste management is a major challenge in the modern era, especially with the increasing volume of waste produced by society. Transforming waste into energy offers an innovative solution that not only reduces environmental impact but also opens up economic and social opportunities. Through technologies such as biogas, incineration, pyrolysis, and gasification, waste can be converted into sustainable renewable energy sources. This socialization aims to increase public and stakeholder awareness of the importance of innovative waste management and its benefits for the environment and future economy.By understanding the technology, opportunities, and challenges that exist, it is hoped that the community and government can play an active role in supporting the mission towards more environmentally friendly waste management and reducing carbon emissions.
Menentukan nilai Energi Stacking Fault Paduan Baja Mangan Fe-Mn-C-Cr Menggunakan Persamaan Termodinamika Wahyudi, Haris; Pratiwi, Swandya Eka; Alva, Sagir; Subekti, Subekti
ROTASI Vol 27, No 2 (2025): VOLUME 27, NOMOR 2, JULI 2025
Publisher : Departemen Teknik Mesin, Fakultas Teknik, Universitas Diponegoro

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/rotasi.27.2.77-83

Abstract

Deformasi plastis pada baja austenit terjadi melalui salah satu dari tiga mekanisme deformasi yaitu transformasi martensit, dislokasi dan twinning. Perilaku plastisitas baja paduan terkait erat dengan energi stacking fault (SFE) fasa austenit.  Perhitungan nilai SFE secara langsung bisa dilakukan menggunakan Transmission Electron Microscopy (TEM). Akan tetapi, metode TEM perlu tahapan panjang, mahal, dan tidak mudah. Oleh karena itu, perhitungan berdasarkan model termodinamika menjadi alternatif cara yang digunakan untuk menghitung SFE pada baja Fe-Mn-Si dan Fe-Mn-C. Tujuan dari penelitian ini adalah untuk mendapatkan nilai SFE berdasarkan persamaan termodinamik untuk paduan baja mangan Fe-Mn-C-Cr. Metode yang digunakan yaitu studi literatur untuk mendapatkan parameter setiap unsur penyusun baja mangan antara lain Fe, Mn, C, Cr, dan Si. Nilai SFE dari persamaan termodinamika akan dibandingkan dengan persamaan empiris yang sudah diusukan oleh beberapa peneliti. Selain itu, nilai SFE akan dibandingkan nilainya dari database yang diperoleh dari eksperimen misal melalui TEM dan XRD. Nilai SFE dari hasil perhitungan menggunakan persamaan termodinamika diperoleh nilai 24±10 mJ/m2. Nilai SFE hasil perhitungan persamaan empiris menunjukkan nilai yang bervariasi dengan nilai terkecil 46,77 mJ/m2 dan terbesar adalah 510,16 mJ/m2. Nilai SFE hasil perhitungan persamaan termodinamika memiliki nilai mendekati nilai SFE di literatur yaitu 21 mJ/m2. Hasil ini membuktikan bahwa perhitungan nilai SFE menggunakan persamaan termodinamika lebih akurat dengan mempertimbangkan unsur penyusunnya.
Co-Authors Adelfy Dara Arianti Agnes Hanna Patty, Armin Naibaho, Singgih Fitra Utama, Ahmad Ariri Ahmad Kamal Arifin Aiman Sajidah Abd Aziz Aiman Sajidah binti Abdul Aziz Albert Phak Jie Wong Ali Rinaldi Andi Firdaus Sudarma Arianti, Adelfy Dara Arifin, Ahmad Kamal Ariri, Ahmad Asadullah, Mas'ud Asep Setia Kristanto Ayu Arwati, I G. Baihaqi Baihaqi Basyari, Aziz Binawati Ginting Dafit Feriyanto Dayanti, Meri Deni Shidqi Khaerudini Edy Herianto Majlan Eka Safitri Eka Safitri Elin Yusibani Elly Sufriadi Fidi Fidi Fidi, Fidi Fitri , Muhammad Fitri Dara Fonna, Syafrizal G. Ayu Arwati, I Ginting, Dianta Hadi Pranoto Hadi Pranoto Hasbullah, Siti Aishah I Gusti Ayu Arwati Ibdal Satar Imam Hidayat Iqhrammullah, Muhammad Julinawati Julinawati Julinawati, Julinawati KHAIRI SUHUD Khairi Suhud Kurniawan Kurniawan Leni Heliawati Marysca Shintya Dewi Mas&#039;ud Asadullah Mas’ud Asadullah Mohd Ismahadi bin Syono Muhammad Farhan Muhammad Fitri, Muhammad Muhammad Ihsan Muhammad Isa Mustanir Mustanir Nanang Ruhyat Noviyanto, Alfian Noviyanto, Alvian Nurato , Nurato Nurul Islami, Nurul Pandriana, Aap Popy Yuliarty Pudjiwati, Sri Resista Vikaliana Resmi Bestari Muin Rinaldi, Ali Rini Anggraini Rita Sundari Robi Suherman Rohadi Satrio Budi Utomo Sawarni Hasibuan Siti Aishah Hasbullah Subekti Subekti Sudarma, Andi Firdaus Suhud, Khairi Sukoma, Sukoma Sundari, Rita Supaat Zakaria Surbakti, Muhammad Syukri Suyadi, Yadi Swandya Eka Pratiwi, Swandya Eka Syafrizal Fonna Tarigan, Kontan Teddy Kurniawan Thasyah Pitanova Vivi Friliandita Vivi Friliandita Wahyu Irwansyah Wahyudi, Haris Wan Adil bin Wan Jamil Wan Adil Wan Jamil Winnugroho Wiratman, Manfaluthy Hakim, Tiara Aninditha, Aru W. Sudoyo, Joedo Prihartono Wiwit Suprihatiningsih Zakaria Zakaria Zulnazri, Z