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Sintesis dan Karakterisasi Edible Film dari Pati Singkong dan Kitosan menggunakan Madu sebagai Plasticizer alami Sapria, Thasha; Daulay, Abdul Halim; Husnah, Miftahul
JISTech (Journal of Islamic Science and Technology) Vol 10, No 2 (2025)
Publisher : UIN Sumatera Utara Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30829/jistech.v10i2.26291

Abstract

Penelitian ini bertujuan untuk mensintesis dan mengkarakterisasi edible film berbahan dasar pati singkong dan kitosan dengan penambahan madu sebagai plasticizer alami, sebagai alternatif kemasan pangan biodegradable pengganti plastik sekali pakai. Edible film disintesis melalui metode pencampuran larutan pati singkong 5%, larutan kitosan 2% dalam asam asetat 1%, serta madu dengan variasi komposisi pati singkong (100; 90; 80; 70 mL), kitosan (0; 10; 20; 30 mL), dan madu tetap sebesar 3 mL. Karakterisasi yang dilakukan meliputi pengujian ketebalan, kadar air, kelarutan air, kuat tarik, dan elongasi, yang kemudian dibandingkan dengan standar Japanese Industrial Standards (JIS) dan Standar Nasional Indonesia (SNI). Hasil penelitian menunjukkan bahwa penambahan kitosan berpengaruh signifikan terhadap peningkatan sifat mekanik dan ketahanan air edible film. Peningkatan konsentrasi kitosan menyebabkan ketebalan dan kuat tarik meningkat, serta menurunkan kelarutan air, namun pada konsentrasi tinggi dapat menurunkan elastisitas film. Formulasi terbaik diperoleh pada sampel B dengan komposisi 90 mL pati singkong, 10 mL kitosan, dan 3 mL madu, yang menunjukkan keseimbangan optimal antara kekuatan mekanik, fleksibilitas, dan stabilitas fisik. Seluruh parameter pada sampel B memenuhi standar mutu yang ditetapkan, sehingga berpotensi diaplikasikan sebagai kemasan pangan ramah lingkungan yang aman dikonsumsi.
Sintesis dan Karakterisasi Nanokomposit Fe3O4/PANI sebagai Komponen Anoda Baterai Harahap, Balkis Br; Lubis, Ridwan Yusuf; Daulay, Abdul Halim
Panthera : Jurnal Ilmiah Pendidikan Sains dan Terapan Vol. 6 No. 1 (2026): January
Publisher : Lembaga Pendidikan, Penelitian, dan Pengabdian Kamandanu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36312/panthera.v6i1.988

Abstract

Magnetic materials such as Fe₃O₄ have high potential as conductive materials and energy stores. However, its limited electrical properties require modification through the addition of conductive polymers to improve its performance. The combination of Fe₃O₄ and Polyanillin (PANI) is expected to improve conductivity and capacitance through the formation of Fe₃O₄/PANI nanocomposites. In this study, Fe₃O₄/PANI nanocomposites were synthesized using a co-precipitation method with local iron sand-based materials, then combined through an in situ polymerization method using aniline monomer volume variations of 4 mL, 6 mL, 8 mL, and 10 mL, coded PA1, PA2, PA3, and PA4, respectively. The results of characterization using X-Ray Diffraction (XRD) showed the formation of two main phases, namely magnetite (Fe₃O₄) and maghemite (γ-Fe₂O₃). Scanning Electron Microscopy (SEM) analysis showed that increased volume of aniline monomer resulted in a more homogeneous composite surface, although excessive volume led to overpolymerization. The test results using the LCR Meter showed an increase in capacitance and electrical conductivity values to reach optimal conditions in the PA3 sample, with a crystal size of 50.94 nm, capacitance of 8.9 F, resistance of 1.0 Ω, and conductivity of 127.4 S/m. These results prove that the variation in aniline monomer volume has a significant effect on the structural and electrical properties of Fe₃O₄/PANI nanocomposites. The optimum composition of PA3 shows high potential as an anode material or conductive energy storage electrode that supports the development of environmentally friendly and sustainable energy technology.
Pemanfaatan Selulosa Ampas Tebu Sebagai Bahan Baku Dalam Pembuatan Bioplastik Berbasis Pati Umbi Talas Mawar, Mawarni; Daulay, Abdul Halim; Husnah, Miftahul
Rekayasa Material, Manufaktur dan Energi Vol 9, No 1: JANUARI 2026
Publisher : Fakultas Teknik UMSU

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30596/rmme.v9i1.26910

Abstract

Synthetic plastics are made from materials that come from petroleum. These materials do not break down easily and are not affected by chemicals or microbes. Because of this, they last a long time and are hard to get rid of in the environment. Most of these plastics are used only once, which causes a lot of waste over time. It can take up to 1,000 years for these plastics to break down on their own. This study looked at using cellulose from sugarcane bagasse as a material added to bioplastics made from taro starch. Glycerol was used to make the plastic more flexible. Different amounts of cellulose (0 g, 0.5 g, 1 g, and 1.5 g) were mixed with 5 g of taro starch and 2 ml of glycerol. The mixture was then dried. The bioplastics were tested for water absorption, how well they break down, how strong they are, how much they stretch, and their chemical structure using FTIR analysis. The results showed that adding cellulose changed the bioplastics' properties. More water was absorbed, they became stronger and more stretchy, but they broke down less. The best results came when 1.5 g of cellulose was added. This gave a tensile strength of 1.54 MPa, which meets the ASTM E8M standard, and an elongation of 66.7%, which meets the ASTM D882-12 standard. Overall, mixing taro starch with sugarcane bagasse cellulose made better bioplastics, especially in terms of strength and stretch, although the rate at which they break down was lower.
Peningkatan Mutu Kertas Cetak A Berbasis Kulit Talas Dan Serat Sawit Pada Sifat Fisis Sari, Devi Kumala; Jumiati, Ety; Daulay, Abdul Halim
Rekayasa Material, Manufaktur dan Energi Vol 9, No 1: JANUARI 2026
Publisher : Fakultas Teknik UMSU

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30596/rmme.v9i1.26666

Abstract

Paper is a thin material in the form of sheets that is one of the basic needs used by the community, paper is produced from the compression of fibers derived from pulp containing cellulose. This study aims to determine the characteristics of the paper produced and to determine the effect of the composition of the mixture of taro peel pulp and oil palm fruit fiber on paper quality. This study used the soda method, with variations in the weight of samples A (65%: 35%), B (45%: 55%), and C (25%: 75%). Taro peel and oil palm fruit fiber were first cooked with a 10% acetic acid solution, then bleached using a 10% H₂O₂ solution, then dried. The characterization results of the samples showed that sample C was the optimum sample with a grammage test value of 88 g/m2, a bulk test value of 1.25 cm3/g, and a SEM test value of 9,7089. This value shows that sample C has fulfilled some of the standard of SNI 7274:2008, so it can be concluded that the composition of taro peel pulp and oil palm fruit fiber produces paper with quite good quality.
Pemanfaatan Pati Kentang dan Selulosa Batang Jerami Padi sebagai Bahan Baku Pembuatan Bioplastik yang Ramah Lingkungan Nasution, Mutia Fadilah; Daulay, Abdul Halim; Lubis, Ridwan Yusuf
Panthera : Jurnal Ilmiah Pendidikan Sains dan Terapan Vol. 6 No. 1 (2026): January
Publisher : Lembaga Pendidikan, Penelitian, dan Pengabdian Kamandanu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36312/panthera.v6i1.1020

Abstract

This study aims to overcome the weaknesses of starch-based bioplastics by utilizing cellulose extracted from rice straw stalks. The increasing amount of conventional plastic waste that is difficult to decompose has created an urgent environmental problem, so that bioplastics have emerged as an environmentally friendly alternative. However, bioplastics from potato starch have low water resistance and less than optimal mechanical properties. Rice straw stalks were chosen because of their abundant availability and high cellulose content (32-47%). The process of making bioplastics was carried out with variations in the composition of potato starch and rice straw stalk cellulose (100%: 0%; 87.5%: 12.5%; 75%: 25%; and 62.5%: 37.5%), with the addition of chitosan (2 g) and glycerol (2 ml) as additives. The characterizations conducted included water absorption test (ASTM D570-98), biodegradation test, tensile strength test (ASTM E8M), percent elongation (ASTM D882-12), and identification of functional groups using FTIR (Fourier Transform Infrared). The results showed that the addition of rice straw cellulose had a positive effect on the characteristics of bioplastics. The best water absorption test was obtained in sample C (75% Starch: 25% Cellulose) with a value of 13% which meets the ASTM D570-98 standard. The best biodegradation test was obtained in sample B (87.5% Starch: 12.5% ​​Cellulose) with a value of 62%. The maximum tensile strength value was recorded at 1.23 MPa in sample C, and the maximum percent elongation value was 99.2% in sample D. FTIR analysis confirmed the presence of main functional groups (O-H, C-H, N-H, C-O) which indicated an effective interaction between potato starch, rice straw cellulose, and chitosan. Overall, this composite bioplastic shows optimal potential and characteristics as an environmentally friendly material.
Pengaruh Penambahan Asam Oleat terhadap Karakteristik Nanopartikel Magnetit dengan Metode Kopresipitasi Damayanti, Della; Lubis, Ridwan Yusuf; Daulay, Abdul Halim
Panthera : Jurnal Ilmiah Pendidikan Sains dan Terapan Vol. 6 No. 1 (2026): January
Publisher : Lembaga Pendidikan, Penelitian, dan Pengabdian Kamandanu

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36312/panthera.v6i1.1043

Abstract

This study discusses the use of natural iron sand in the manufacture of magnetite nanoparticles with oleic acid. The purpose of the study is to produce nano-sized magnetite as an alternative photocatalyst material. Magnetite nanoparticles were synthesized with variations of oleic acid (0.75 ml, 1.5 ml, 2.25 ml, 3 ml) and the addition of 7.5 ml of diethylamine. Synthesis was carried out using XRF to determine the elements contained in the iron sand, SEM to determine the surface morphology, and UV-Vis to determine the size of the bandgap. The results showed that increasing the oleic acid content significantly increased agglomeration due to the large number of particles that merged with each other, while increasing the bandgap value. The results showed that the addition of oleic acid had an effect on the iron sand. The highest XRF test of 88.234% was obtained in the iron sand sample before processing, the lowest SEM test was 0.9 μm, and the highest UV-Vis test was 2.644 eV indicating an increase in the bandgap energy value due to the role of oleic acid as a surfactant. The novelty of this research lies in the use of natural iron sand combined with a fixed proportion of oleic acid (up to 3 ml) and diethylamine (7.5 ml). A good bandgap for the photocatalyst is 2.638 eV which is influenced by the addition of oleic acid as a surfactant. These magnetite nanoparticles show optimal potential and characteristics as photocatalyst materials.
OPTIMALISASI PENENTUAN POSISI SUDUT PANEL SURYA DALAM KEADAAN STATIS DAN DINAMIS Hidayat, Taufiq; Daulay, Abdul Halim; Masthura, Masthura
FISITEK: Jurnal Ilmu Fisika dan Teknologi Vol 9, No 2 (2025)
Publisher : Universitas Islam Negeri Sumatera Utara Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30821/fisitekfisitek.v9i2.25538

Abstract

Research has been carried out which aims to produce a solar panel positioning system based on the Arduino microcontroller, and to find out the optimal power measurement results based on the position of the solar panels. The research tools used in this research were the Arduino microcontroller as a tracking system, the LDR sensor as a tracker of the sun's movement, the MG966R servo motor as an actuator or driving system to follow the sun's tracks, and a 5 WP solar panel as a light source. The approach or method used in this study is scientific, namely an approach based on science and technology. The test method used is the direct test method. In a system that has been successfully designed, four LDR sensors act as input data which will be converted as tracking. From the test results of the Dual axis solar tracker the average voltage without and with the tracking system is 7.74 volts and 8.56 volts with the average current without and with the tracking system being 0.35 A and 0.44 A. The optimal angle obtained based on testing using the system is in the second test phase where the angle formed is 84 with a voltage obtained of 9.4 V and a current of 0.53 A with the power generated is 4.10 Watt
RANCANG BANGUN INSTRUMEN PENGUKUR pH DAN TDS BERBASIS MIKROKONTROLER SECARA REALTIME Hidayat, Roma; Daulay, Abdul Halim; Nasution, Nazaruddin
FISITEK: Jurnal Ilmu Fisika dan Teknologi Vol 9, No 2 (2025)
Publisher : Universitas Islam Negeri Sumatera Utara Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30821/fisitekfisitek.v9i2.23328

Abstract

Telah dilakukan penelitian yang betujuan untuk menghasilkan instrumen mengukur kualitas air (pH dan TDS) berbasis mikrokontroler secara realtime dan mengetahui unjuk kerja dari instrumen yang dihasilkan.. Rancangan alat menggunakan ATmega328 sebagai mikrokontrolernya, Menggunakan LCD 2x16 untuk penampilan display, Operasional Instrumen menggunakan tegangan Direct Current (DC) dan Instrumen ini digunakan untuk mengukur kualitas air menggunakan sensor pH dan TDS. Rancang bangun instrumen pengukur pH dan TDS berbasis mikrokontroler secara realtime berhasil dibuat, instrumen yang di hitung dapat mengukur kadar pH dan TDS dengan sangat baik. Instrumen pengukur pH dan TDS memiliki tingkat presisi yang sangat baik, hal ini di tunjukkan dari pembacaan yang tidak begitu berbeda dari instrumen sejenis yang sudah ada di pasaran, tingkat error pembacaan untuk instrumen pH dan TDS masing-masing adalah sebesar 2,27 % dan 2,1 %Kata-kata Kunci : Air, pH, TDS, dan Mikrokontroler
Co-Authors Adelyna Oktavia Nasution Ahmad Nuruddin Aida Febriana Tanjung Amanda, Syahna Dwi Anggun Hermi Palupi Apriyana, Resi Armais Mutiah Abdul Hidayat Arninda Pratiwi asnitha aritonang Aulia Farihanum Aulia Khusnul Arif Z.A Ayu Saputri Saragih Bambang Sunendar Purwasasmita Bharata Dewanto Daulay, Zubair Aman Daulay, Zubair Aman Della Damayanti, Della Dickiy Akbar Dita Khairunnisa endang sagita ritonga Ependi, Fadli Ety Jumiati Ety Jumiati Ety Jumiati Fadhilah, Elsa Harahap, Balkis Br Harahap, Gery Syahputra harahap, mira yanti Haryu Wanda Desgira Heni Puspita Sari Hidayat, Roma Husna, Afifah Husna, Afifah Husnah, Miftahul Hutauruk, Siti Aulia Indah Sawitri Irmawati Koto Jefri Ardiansyah Nasution Jumiati, Ety Jumiati, Ety Juwita Juwita Kartika Manalu Khairiah, Khairiah Khairiah, Khairiah Khairiah, Khairiah Khairul, Fikri Khairunnisa, Devi Khobir, Mustofa Lailatul Husna Lubis Lansari Daulay Laras Ashari Setiawan Leli Mariati Situmorang Lespita, Jeni Dhea Lisa Astari Lisa Herdiana Sinurat Lubis, Fadilah Azzahra Lubis, Hilwa Salsabila Lubis, Lailatul Husna Lubis, Ridwan Yusuf Lubis, Rizky Wahyuni Masthura Masthura Masthura Masthura, Masthura Mawar, Mawarni Miftahul Husnah Miftahul Husnah Miftahul Jannah Daulay Miftahul Jannah Daulay Minta Ito Muhammad Amrin Siregar Muhammad Amrin Siregar Mulkan Iskandar Nasution Mulkan Iskandar Nasution Nadilla Putri Nadjara Yolanda Nanda Putri Afrilda Nasution, Annisa Wulan Dhari Nasution, Mutia Fadilah Nasution, Nazaruddin Nasution, Nazaruddin Nazaruddin Nasution Nita Zahara Nasution Nur'aini Fadillah Nurainun Br Pasaribu Nurhayati Nurhayati Nurika Khalila Daulay Nurmaisah Harahap Ong, Russell Pasaribu, Adella Ayu Putri Pinem, Lela Feranita Prabowo, Diki Purnama Indah Lase Putra, Tyas Hermawan Putri Dwi Ananda Putri Indah Sari Putri Rabiatul Amalia Sitorus Rahmasari Pohan Ramidin, Ramidin Ratni Sirait Ratni Sirait Reflina Reflina Ria Muliyana Ridwan Yusuf Lubis Rika Ramtika Rika Safitri Riri Angriani Nasution Rosari, Ruri Sahdinal Adi Sapria, Thasha sari, Bella Novita Sari, Devi Kumala selvia, niki Sholihatul Hamidah Daulay Sihombing, Zulkarnain Sirait, Ratni Siregar, Shinta Marito Siska Siska Siti Hawa Hasibuan Siti Maysarah Siti Nur Aisyah Siti Rahma Daulay Sitorus, Widia Arti Syafitri Sri Wahyuni Ritonga Sucitawati, Nopita Sugeng Sugeng Susanto Sigit Rahardi Susi Nurindah Taufiq Hidayat Tri Ninda Malika Tunjiah , ufik eliati tumanggor Utari, Dinda Widia Arti Syafitri Widya, Eka Zafira Amalia Nasution Zubair Aman Daulay