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All Journal Reaktor International Journal of Science and Engineering (IJSE) International Journal of Renewable Energy Development TEKNIK METANA Jurnal Ilmu Lingkungan JURNAL TEKNOLOGI KIMIA DAN INDUSTRI IPTEK The Journal for Technology and Science Prosiding Seminar Nasional Sains Dan Teknologi Fakultas Teknik Bulletin of Chemical Reaction Engineering & Catalysis Seminar Nasional Teknik Kimia Kejuangan Journal of Engineering and Technological Sciences Majalah Ilmiah MOMENTUM Science and Technology Indonesia Indonesia Journal of Halal Abdimas UNWAHAS : Jurnal Pengabdian Masyarakat UNWAHAS Jurnal Profesi Insinyur Indonesia Journal of Emerging Science and Engineering Bulletin of Chemical Reaction Engineering & Catalysis Advance Sustainable Science, Engineering and Technology (ASSET)

Luqman Buchori

Departemen Teknik Kimia, Fakultas Teknik, Universitas Diponegoro Jl Prof Sudharto, SH, Tembalang, Semarang, 50275, Telp/fax: (024)7460058

Author-ID : 243501

Religion Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Economics, Econometrics & Finance Education Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Medicine & Pharmacology Physics Social Sciences Transportation

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OPTIMASI PROSES POLIMERISASI MINYAK KULIT JAMBU METE (CNSL, CASHEW NUT SHELL LIQUID) DENGAN FORMALDEHID Buchori, Luqman
TEKNIK Volume 31, Nomor 2, Tahun 2010
Publisher : Diponegoro University

Jambu mete represents the crop which is a lot of its benefit. From various benefit of jambu mete, there is onepart of which not yet been exploited in an optimal that is husk. Whereas in its husk is contain oil so-calledCashew Nut Shell Liquid (CNSL) about 32-36%. This oil can be used as natural source phenol and alternativelysubstitution phenol from petroleum. This phenol is reacted by formaldehyde will form the phenol formaldehyderesin. Besides containing natural phenol, CNSL also contain the other bunch like karboksilat bunch, alkylbunch and alkenes bunch. This bunch will influence process of forming of phenol formaldehyde resin as aconsequence have an effect on characteristic and quality of resin so that require to be searched the optimumcondition in making of phenol formaldehyde resin. Objective of this research is to look for the optimumcondition in making of phenol formaldehyde resin of novolac type and also know the influence of comparison ofreactant and operating temperature for to resin yielded. Dependent variables in this research are reactorvolume (500 ml) with the volume bases 250 ml, catalyst acid HCl, mixing speed (200 rpm), operating time (90minute), pH (2) and operating pressure (1 atm). Independent variables are CNSL/formaldehyde ratio andoperating temperature. Perceived parameter is free rate formaldehyde. Method is used to design and processdata is RSM (Response Surface Methodology) method constructively the Static program. Result of this researchindicates that the most effect on variable is ratio CNSL/formaldehyde. Optimum condition are obtained at F/Cratio of 0.65-0.85 and temperature of 75-850C with the conversion of 0.55. The biggest rate resin obtained atF/C ratio 0.75/1 and temperature 80oC. This resin is very jell and have best sticky and also drug after runningdry. This novolac resin is applicated as furniture coating. Coating yielded have well sticky with the auburncolor.

THE PERFORMANCE OF REVERSE OSMOSIS MEMBRANE IN WATER TREATMENT Budiyono, Budiyono; Buchori, Luqman
TEKNIK Volume 29, Nomor 1, Tahun 2008
Publisher : Diponegoro University

Membrane technology has led to a new focus on water and wastewater treatment. This is due to severaldrawback of the conventional water treatment i.e release the toxic and carcinogenic materials. In thisresearch, the use Reverse Osmosis (RO) membrane for treating river and well water to obtain clean anddrinking water was studied. The variables studied were effect of pressure and operation time to themembrane flux. The pressure was varied from 1 to 7 bar and the operation time was varied from 15 to 60minutes. The content of Total Dissolved Solid (TDS) in the permeate product was analyzed. The resultsshown that the increase of pressure would increase the membrane flux and decrease TDS. The increaseof the operation time would decrease membrane flux and TDS. The reverse osmosis membrane wassuccessfully applied to treat the river and well water. The product fulfill national standard quality ofdrinking water by viewpoint of the TDS content

KINETIKA TRANSESTERIFIKASI BIODIESEL JARAK PAGAR Luqman, Buchori; Setia, Budi Sasongko
TEKNIK Volume 33, Nomor 2, Tahun 2012
Publisher : Diponegoro University

Biodiesel were produced by trans-etherification of castor oil with alcohol in the presence of NaOH catalyst. Thereaction mechanism and model of castor oil trans-etherification isA + 3B C + 3 DA, B, C, and D were castor oil, alcohol, glycerol, and ester. The reaction rate equation was r=-dCA/dt =k1(CA)(CB)3â€“k2(CC)(CD)3. In this study was used two measurement method of free fat acid as the rest content ofcastor oil with SNI 01-3555-1998 and AOAC (Association of Analytical Chemist). It found that SNI 01-3555-1998 method was the easier and the acurate measurement. The classification of alcohol used was methanol andethanol to compare the action both of them. Methanol produces the higher conversion than ethanol. The reactionin a batch reactor with temperature 40, 50, and 60Â°C in atmospheric pressure as the operation condition tolooking for kinetics parameter of trans-etherification. Coefficient reaction rate and activation energy were lookinto kinetics study. Reaction rate was a mathematics model as a function of concentration and time which solvedby Runge-Kutta, multivariable optimization and SSE (some square error) method using Matlab. The activationenergy (Ea) and impact factor (A) obtained by linier regression method. The result of study obtained the kineticsparameter of trans-etherification with methanol k1=1.9313x1031exp (-41.940/RT) average error 0.0010 andk2=2.7678x1025exp(-37.362/ RT) average error 0.0003. While kinetics parameter of trans-etherification withethanol obtained k1=1.168x1019exp(-24.588/ RT) average error 0.0306 and k2=4.9966x106exp(-10.328/RT)average error 0.1589. It means, more reactive alcohol then bigger the value of kinetics parameter.

BIOBRIKET DARI CAMPURAN LIMBAH KULIT BIJI METE, SEKAM DAN JERAMI SERTA BUNGKIL JARAK, SEKAM DAN JERAMI Setia Budi, Faleh; Buchori, Luqman
TEKNIK Volume 34, Nomor 1, Tahun 2013
Publisher : Diponegoro University

The petroleum is the fuel derived from fossil which can not be renewable and the deposit in the earth is not morenow. In the middle 2008, the price of petroleum achieved US$ 147/Barrel because the supply of petroleum toworld market was reduced. This situation forced the appearance of the alternative energy which can replace thefossil fuel in the future. Their result of combustion has low emission so that they can be reduced the pollutionand were environment friendly. Biobriquette is the one alternative energy which expected to be able to replacethe kerosene and LPG. This research aims to get the exactly composition and type in manufacturing ofbiobriquette from cashew nut shell and jatropa shell waste. The variables choose as the independence variablewas the type of waste (cashew nut shell and jatropa shell) and the compositions (40, 60, 80 and 100%). Theothers are the fixed variable such as the size of briquette 4 cm and the total weight/biquette 25 g. The responseor parameters observed in the experiment were the color, the value of calor, the length of combustion and thecolor of fire. The result of experiment showed that composition of the material greatly affected the quality ofbriquette produced. The composition 100% owns the highest calor of combustion. The calor of Jatropa wastewas higher than that of cashew nut shell.

PEMBUATAN BIODIESEL DARI MINYAK GORENG BEKAS DENGAN PROSES CATALYTIC CRACKING Buchori, Luqman; Widayat, Widayat
TEKNIK Volume 28, Nomor 2, Tahun 2007
Publisher : Diponegoro University

Crude oil is a source of energy which is not be renewable. This fact motivates so much countries ineconomizing on fuel. Many researches have been done to gets another fuel substitute the crude oil.Biodiesel is represented as fuel instead of diesel fuel, and it is produced from vegetable oil. In the otherside, ex-cooking oil is waste-product from food industry, restaurant and household which is potential tobe alternative fuels because of the high contents of carbon and hydrogen atoms. Commonly the biodieselmade from vegetable oil by esterification and transesterification process. But if using esterification andtransesterification process to ex-cooking oil material, it is not economically feasible because the processmakes another reaction between alkaly catalist and oil to produce soap. One of biodiesel process iscatalytic cracking of the ex-cooking oil. This research is aimed to analyze zeolite catalist size effect(0.125mm; 0.3375mm; 0.425mm; 0.85mm; 1.18mm), and acid concentration on the product (2N; 3N;4N). This result shows that at 4N acid concentration and 0.125 mm zeolite catalist size is optimal whichcan reach diesel specification.

Sintesis, Karakterisasi dan Pengujian Katalis CaO-MgO/Fe2O3 dari Dolomit dan Pasir Besi untuk Pembuatan Biodiesel dari Minyak Goreng Bekas Widayat, Widayat; Arman, Mhd. Adithia Perdana; Syarief, Elijah; Buchori, Luqman; Sulardjaka, Sulardjaka
TEKNIK Vol. 45, No. 1 (2024): May 2024
Publisher : Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/teknik.v45i1.56423

Pengembangan katalis CaO-MgO/Fe2O3 dari dolomit dan pasir besi dilakukan pada penelitian ini. Penelitian bertujuan untuk mengetahui karakteristik kimia dan fisika katalis CaO-MgO/Fe2O3 serta kinerjapada produksi biodiesel. Sintesis katalis dilakukan dengan metode impregnasi, dimana fasa CaO-MgO terlebih dahulu didapatkan dari dolomit dengan metode kalsinasi. Fe2O3 dihasilkan dari pasir besi dengan metode ko-presipitasi yang melibatkan larutan asam dan basa. Pengaruh komposisi CaO-MgO dan Fe2O3 terhadap yield biodiesel dikaji dengan melakukan variasi rasio CaO-MgO : Fe2O3 sebesar 1:1, 2:1 dan 3:1. Variasi temperatur kalsinasi katalis dilakukan pada 800oC, 900oC dan 1000oC untuk mengetahui pengaruh karakteristik fisik terhadap produksi biodiesel. Karakterisasi katalis dengan menggunakan metode SEM-EDX menunjukkan struktur morfologi dan komposisi elemen pada katalis. Biodiesel yang diproduksi dengan katalis CaO-MgO/Fe2o3 memiliki standar mutu sesuai SNI 7182: 2015. Katalis dengan rasio CaO-MgO : Fe2O3 sebesar 3:1 yang dikalsinasi pada temperatur 900oC menghasilkan yield biodiesel tertinggi yaitu 54,2%. Katalis CaO-MgO/ Fe2O3 dapat digunakan dalam produksi biodiesel dengan reaksi esterifikasi dan trans esterifikassi secara simultan dan dibutuhkan peningkatan kinerja lebih lanjut sehingga lebih ekonomis.

Co-Authors . Widayat Amin Nugroho Anggun Kurniawan Anindita Indriana Aprilina Purbasari Ardian D. Yudhistira Aris Bagus Pradana, Aris Bagus Arman, Mhd. Adithia Perdana Arum Sakti Prasetyo Astrilia Damayanti B Budiyono Berkah Fajar Bintang Ayu Kalimantini Boby Gusman Irianto Samosir Budi Sasongko Setia Budiyono Budiyono Chusnul Khotimah Dewi Fatmawati Didi D. Anggoro Didi D. Anggoro Didi Dwi Anggoro Dinda Labibah Ubay Dyah Hesti Wardhani Dyah Hesti Wardhani Fachmy Adji Pangestu Setiawan Faleh Setia Budi Faleh Setia Budi Faleh Setia Budi Fegi Yuliandri Fradriyan Aulia Giveni Christina Silaen Hadiyanto Hantoro Satriadi Hargono Hargono Harum Nissaulfasha Herawati Oktavianty Heri Cahyono Heru Susanto I Nyoman Widiasa I. Istadi I.G.B Ngurah Makertihartha Indro Sumantri Inshani Utami Istadi Istikhoratun, Titik JD Ryan Christy S Khonsa Syahidah Kusmiyati Kusmiyati Laeli Kurniasari M. Dani Supardan M. Dani Supardan M. Djaeni Maria Augustine Graciafernandy Meitiandari Mutiara Mhd. Shaumi Al Anshar Muhamad, Theobroma Guntur Muhammad Ulil Absori Nadia Taradissa Maheswari Ndaru Okvitarini Ngadi, Norzita Nita Aryanti Norzita Ngadi Nur Hidayati Nurjati Solikhin Nurul Aishah Aishah Nurushofa, Faustina Alda Okryreza Abdurrachman P Purwanto Pakpahan, Agnes J. Pakpahan, Andre W. S. Pratama, Pambudi Pajar Pratama, Wahyu Diski Pratiwi, Wahyu Zuli Purwanto Purwanto Purwanto Purwanto Putri Diliyan Shakti Ratnawati Ratnawati Resti Nur Utami Riko Rikardo Putra Riyanto, Teguh Rizki Andre Handika Roikhatus Solikhah Salsabila, Unik Hanifah Saputra, Roni Ade Setia Budi Sasongko Setia Budi Sasongko Setiadi, Iqfan Dwi Silviana Silviana Siswo Sumardiono Suherman Suherman Suherman Suherman Sulardjaka Sulardjaka Sulardjaka, S Syarief, Elijah Teguh Riyanto Teuku Irfan Maulana Titik Istirokhatun Udin Mabruro Wahyu Fitriani Widayat Widayat Widayat Yayuk Astuti Yazid Bindar Yazid Bindar Yudha Duta Utama

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