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Journal : International Journal of Renewable Energy Development

Nickel-vanadium impregnated to hydrotalcite for hydrocracking of waste cooking oil Marlinda, Lenny; Priyanto, Sugeng; Oktiarmi, Peri; Marbun, Maja Pranata; Dewi, Aisha Andini Indira; Sudibyo, Sudibyo; Yati, Indri; Aziz, Abdul; Nugraha, Reva Edra; Al Muttaqii, Muhammad
International Journal of Renewable Energy Development Vol 15, No 3 (2026): May 2026
Publisher : Center of Biomass & Renewable Energy (CBIORE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.61435/ijred.2026.61972

Abstract

Hydrotalcite (HT) is a type of clay mineral belonging to the group of layered double hydroxides (LDHs) or anionic clays, which has a layered structure like brucite (Mg(OH)₂), but some of the divalent cations (such as Mg²⁺) are replaced by trivalent cations (such as Al³⁺). HT as a heterogeneous catalyst is particularly attractive because it is easy to separate and resistant to high temperatures. HT as a catalyst can be used in hydrocracking reaction to produce biofuel. Metal impregnation on HT is very promising to enhance catalytic activity especially with the bifunctional mechanism of catalyst. Ni-V metal impregnation has been successfully carried out on HTc using wet impregnation method which is indicated by the results of X-Ray Diffraction (XRD) which shows the emergence of typical peaks of both metals and HTc in 2θ = 35‒70⁰ for HTc, 2θ = 37.22⁰ (NiO) and 37.35⁰ (V2O5) regions, 2θ = 43.58⁰ for NiO, 2θ = 61.26⁰ (V) and 63.07⁰ (Ini). Scanning Electron Microscopy-Energy Dispersive X-ray (SEM-EDX) show a shape that is consistent with the characteristics of HT, namely the shape of the particles layered overlapping each other. In addition, the particle size of HTc is quite small with a scale of 1 μm indicating a particle size of hundreds of nanometers. EDX mapping shows that Ni and V have been dispersed evenly on the HTc surface. Based on the results of N2 adsorption-desorption isotherms, it shows that mesopores are formed which are characterized by hysteresis loops. Ni-V metal impregnation increases the surface area up to 19.915 m2/g and the pore diameter up to 37,642 nm. The results of the Waste Cooking Oil (WCO) hydrocraking reaction show that Ni-V metal impregnation can reduce the carboxylic acid composition up to 67.81% and increase hydrocarbons up to 15% at 10% Ni-V/HTc 1:2. 
Co-Authors . Rahmi, . Abdul Aziz Achmad Roesyadi Adriansyah, Riadi Al Muttaqii, Muhammad Al-Muttaqii, Muhammad Alkaf, Muhammad Rhezi Bayu Ishartono Danawati Hari Prajitno Denny Prabawa, Aditya Dewi, Aisha Andini Indira Dhian Eka Wijaya Diah Riski Gusti Dyah Puspitasari, Ratih Edwin Permana Edwin Permana Ermita Meisa Manulang Excel Emerlan Samiar Wasistha Ezra Bella Ramadhani Putri Fauziah, Sarah Fitri, Selta Hari Prajitno, Danawati Heriyanti Heriyanti, Heriyanti Heriyanti, Septina Is Ignatius Gunardi Indra Lasmana Tarigan Intan Lestari Intan Lestari ira kusuma dewi Khadafi, Muhammad Reza Ladiva Adinda Lia Anggresani Madyawati Latief Malikhah, Wukhoidatul Marbun, Maja Pranata Mardhatillah Muhammad Al Muttaqii Muhammad Al Muttaqii Muhammad Al Muttaqii Muhammad Al-Muttaqii Muhammad Al-Muttaqii Munifilia Ekasari Murti, Sri Djangkung Sumbogo NEVIATY PUTRI ZAMANI Ngatijo Novianda, Cici Nuraini, Syafira NURUL AZIZAH Nurul Pratiwi Pane, Xena Maharani Peri Oktiarmi Putri Pandulu, Clara Raden Ilham Rahmat Basuki Rahmi Rahmi Rahmi Rahmi Rahmi Reni Desriyanti Restina Bemis, Restina Reva Edra Nugraha Rif’at Syauqi Ritonga, Magdalena Ritonga, Magdalena Ritonga S.D. S. Murti Santiko, Erik Budi Septina Is Heriyanti Sri Djangkung Sumbogo Murti Sudibyo Sudibyo Sugeng Priyanto, Sugeng Tri Utami Vemileza Putri Wahyudi Zahar Wahyudi Zahar Wahyuningsih, Iga Wasistha, Excel Emerlan Samiar Wibimanyu, Putu Adityo Wiratama, Jarot yati, indri Yoga Andika, Oel Taradepa, Adhitya Eko Bagus Yuli Evrianti Br Rajagukguk Yusria Putri, Desta Yustia Wulandari Mirzayanti Yustinah Yustinah Zahar, Wahyudi