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Journal : Bulletin of Chemical Reaction Engineering

Hydrocracking of Non-edible Vegetable Oils with Co-Ni/HZSM-5 Catalyst to Gasoil Containing Aromatics Danawati Hari Prajitno; Achmad Roesyadi; Muhammad Al-Muttaqii; Lenny Marlinda
Bulletin of Chemical Reaction Engineering & Catalysis 2017: BCREC Volume 12 Issue 3 Year 2017 (December 2017)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.12.3.799.318-328

Abstract

Biofuel has been considered as one of the environmentally friendly energy sources to substitute fossil fuel derived from non-edible vegetable oil. This research aims to investigate the effect of the non-edible vegetable oil composition on a specific hydrocarbons distribution contained in biofuel and the aromatics formation through hydrocracking reaction with the Co-Ni/HZSM-5 catalyst. The formation of aromatics from non-edible vegetable oils, such as: Cerbera manghas, rubber seed, and sunan candlenut oils, containing saturated, mono- and polyunsaturated fatty acids is presented. The hydrocracking reaction was carried out in a pressure batch reactor, a reaction temperature of 350 oC for 2 h, reactor pressure of 15 bar after flowing H2 for 1 hour, and a catalyst/oil ratio of 1 g/200 mL. Liquid hydrocarbon product was analyzed by gas chromatography-mass spectrometry. Based on the GC-MS analysis, hydrocracking on three different oils indicated that polyunsaturated fatty acids were required to produce relatively high aromatics content. The sunan candlenut oil can be converted to gasoil range hydrocarbons containing a small amount of aromatic through hydrocracking reaction. Meanwhile, the aromatics in liquid product from hydrocracking of Cerbera manghas and rubber seed oils were not found. 
Nickel-Lanthanum Impregnated into Natural Zeolite as a Catalyst for Biofuel Production from Sunflower Oil via Hydrocracking Process Santiko, Erik Budi; Fauziah, Sarah; Priyanto, Sugeng; Yustinah, Yustinah; Marlinda, Lenny; Sudibyo, Sudibyo; Aziz, Abdul; Oktiarmi, Peri; Yati, Indri; Al Muttaqii, Muhammad
Bulletin of Chemical Reaction Engineering & Catalysis 2026: BCREC Volume 21 Issue 1 Year 2026 (April 2026)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.20503

Abstract

The increasing demand for crude oil or fossil fuel as a raw material for oil fuel has been steadily rising over time in line with the development that is taking place in Indonesia. However, biofuels are potential vegetable fuels that can be developed as alternative energy because they are renewable and can be renewed to overcome the energy crisis in the future. For this purpose, a double metal catalyst (impregnated with nickel and lanthanum), is used to make biofuels from sunflower seed oil. The effect of metal ratio on the yield of biofuel products is the concern in this study. The temperature of hydrocracking process was 250-330 ℃ with ratio of metal 5% and 10% (metal ratio 1:1 and 1:2). X-ray diffraction (XRD) shows that natural zeolite has a clinoptilolite phase, X-Ray Fluorescence (XRF) shows that acid and base activation increases the Si/Al ratio from 4.5 to 5, Scanning Electron Microscope – Energy Dispersive X-Ray (SEM-EDX) shows images of natural zeolite surfaces in the form of aggregate pieces, and Brunauer Emmett Teller (BET) shows that acid and base activation increases SBET from 29.96 to 49.73 m2/g and forms a hierarchical natural zeolite. The impregnation of Ni-La/Zeolite catalyst has been successfully carried out using the incipient wetness impregnation method and the best catalyst results were obtained, namely Ni-La/Zeolite 10% (1:2) with a surface area of 15.33 m2/gS. The addition of Nickel and Lanthanum metals caused a decrease in the surface area and average pore diameter of the zeolite. The lowest surface area and average pore diameter were found in the variation of the Ni-La/Zeolite 10% (1:2) catalyst, namely 15.33 m2/g and 13.99 nm. The highest hydrocarbon yield was found in the hydrocracking process with the Ni-La/Zeolite 10% (1:1) catalyst with gasoline, kerosene and gasoil fractions of 0.91; 0.39 and 8.32 (%wt), respectively. The hydrocarbon compound composition of the catalyst includes n-paraffin 4.43%, isoparaffin 0.21%, cycloparaffin 2.99% and olefin 2.71%. Copyright © 2026 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
Co-Authors . Rahmi, . Abdul Aziz Achmad Roesyadi Adriansyah, Riadi Al Muttaqii, Muhammad Al-Muttaqii, Muhammad Alkaf, Muhammad Rhezi Bayu Ishartono Danawati Hari Prajitno Denny Prabawa, Aditya Dewi, Aisha Andini Indira Dhian Eka Wijaya Diah Riski Gusti Dwi Cahyani, Silvia Dyah Puspitasari, Ratih Edwin Permana Edwin Permana Ermita Meisa Manulang Evrianti, Yuli Excel Emerlan Samiar Wasistha Ezra Bella Ramadhani Putri Fauziah, Sarah Fitri, Selta Hari Prajitno, Danawati Heriyanti Heriyanti, Heriyanti Heriyanti, Heriyanti Heriyanti, Septina Is Ignatius Gunardi Indra Lasmana Tarigan Intan Lestari Intan Lestari ira kusuma dewi Khadafi, Muhammad Reza Ladiva Adinda Lia Anggresani Madyawati Latief Malikhah, Wukhoidatul Marbun, Maja Pranata Mardhatillah Muhammad Al Muttaqii Muhammad Al Muttaqii Muhammad Al Muttaqii Muhammad Al-Muttaqii Muhammad Al-Muttaqii Munifilia Ekasari Murti, Sri Djangkung Sumbogo NEVIATY PUTRI ZAMANI Ngatijo Novianda, Cici Nuraini, Syafira NURUL AZIZAH Nurul Pratiwi Pane, Xena Maharani Peri Oktiarmi Putri Pandulu, Clara Raden Ilham Rahmat Basuki Rahmi Rahmi Rahmi Rahmi Rahmi Rahmi, Rahmi Reni Desriyanti Restina Bemis, Restina Reva Edra Nugraha Rif’at Syauqi Rimawan, Bagas Ritonga, Magdalena Ritonga, Magdalena Ritonga S.D. S. Murti Santiko, Erik Budi Septina Is Heriyanti Sri Djangkung Sumbogo Murti Sudibyo Sudibyo Sugeng Priyanto, Sugeng Sutrisno Tri Utami Vemileza Putri Wahyudi Zahar Wahyudi Zahar Wahyuningsih, Iga Wasistha, Excel Emerlan Samiar Wibimanyu, Putu Adityo Wiratama, Jarot yati, indri Yoga Andika, Oel Taradepa, Adhitya Eko Bagus Yuli Evrianti Br Rajagukguk Yusria Putri, Desta Yustia Wulandari Mirzayanti Yustinah Yustinah Zahar, Wahyudi