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Journal : International Journal of Renewable Energy Development

The Effect of Amine Types on Breakthrough Separation of Methane on Biogas Masruroh, Kuni; Cahyono, Rochim Bakti; Prasetyo, Imam; Ariyanto, Teguh
International Journal of Renewable Energy Development Vol 10, No 2 (2021): May 2021
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2021.33514

Abstract

Methane (CH4) and carbon dioxide (CO2) are the main components of a renewable energy source of biogas. Separation of CO2 from biogas is significantly important to improve biogas performance, due to heating value in biogas depends on the concentration of methane. One of the gas separation technologies that has been widely used in chemical industries is carbon molecular sieve (CMS). This research explores the potential of CMS for biogas purification. CMS was prepared by modification of palm kernel shell-derived porous carbon using amine groups such as monoethanolamine (MEA), 2-amino-2-methyl-1-propanol (AMP), and diethanolamine (DEA). The effect of amine types on the separation parameters was studied by using a breakthrough experiment to obtain the most potential CMS materials. The methods of this research include the process of carbon oxidation using hydrogen peroxide, impregnation with an amine group, characterization of the CMS material obtained, CO2 and CH4 gas separation testing with a breakthrough system. The CMS was characterized by using N2 sorption analysis, fourier transform infrared spectroscopy, and scanning electron microscopy. The breakthrough experiment showed that CMS-MEA had the highest performance for separating CO2 and CH4 gases. In addition, the results also showed that loading of amine groups on carbon caused an increase in the uptake capacity of CO2, and the highest capacity was achieved by CMS-MEA of 13.2 mg/g.
Co-Authors AA Sudharmawan, AA Achmad Vandian Nur, Achmad Vandian Ade Kurniawan Ainun Ikbal, Alif Andini, Susi Amalia Arifiyanto, Muhammad Aryudha, Fikky Atmanegara, Fenda Ramadhani Baginda Harahap Baihaki, Iqbal Bayu Wicaksono Briliansyah, Arditya Budi Satria Panandita BUDIYONO Budiyono Budiyono Cahyono, Rochim Bakti Dewi, Alfa Yuliana Dwi Kurniawan, Ari Dwiyani, Atikah Evila Purwanti Sri Rahayu, Theresia FADHOLI, MUHAMMAD Faizi, Ahmad Nur Farid Afrian, Muhammad Farlina Hapsari Faza, Aji Hufron Fazarima, Fitroh Firdan, Muhammad Firman Faradisi Firmansyah Firmansyah Gala, Kyla Amalia Hardaning Pranamuda Hardhianti, Meiga Putri Wahyu Henra Gurning Hery Widijanto Hufron Faza, Aji Ilham Ifliadi Indryani ineswenty mendrofa, lola Irfan Setiawan, Muhammad Irfan Zidni1, Muhammad Jeon, Sanghee Khalilullah, Aulia Rafif Khoirul Anam KHOIRUL ANAM Kholidah, Nur Kurniawan, Anggi Kurniawan, M. Risqi M. Ilham Fredian Syah , M. Ilham Marwan Effendy Maskhuri, Muhammad Masruroh, Kuni Maulana, Aqiem Maulana, Maisal Ardi Miftahul F., Ahmad Muhammad Rifqi Muhammad Sofwan Musyahar, Ghoni Ngudhi Raharjo, Rias Nulhakim, Lukman Nuniek Nizmah Fajriyah Nur Faqih, Mochamad Nurfaizi, Ahmad Nurhadi, A'an Perdana, Muhammad Faza Pohan, Adekasna Rosadi Prabowo, Joko Setyo Pradana, Nova Yoga Prasetyo, Yuda Prayogi, Yoga Priyanto, Teguh Pujiono, Akhmad Putra Pardana, Arfian R.Kurniawan Dwi Septiady Raharjo, Rias Ngudhi Rahmadani, Trias Ayu Rakhman, Dani Risnawati, Dhea Atika Rizkika, Afiana Khusnul Rochmadi Rochmadi Rozana, Monna Saputra, Daffa Dewa Saputro, , Iwan Saputro, Yoyo Sarjito Sarto Septiady, R Kurniawan Dwi Setiawan, Feri Setiawan, Muhammad Irfan Setiawan, Sofian Setyo Prabowo, Joko Shafiyurrhaman, Muhammad Faiz Shofa Rijalul Haq Siregar, Fhikry Ahmad Halomoan Suhaidi T Towijaya Tandio, Sugianto Teguh Ariyanto Ubaidillah, Akhmad Urmatul Waznah Valentino, Febi Wicaksono, Bhayu Widi Astuti Wiratni Budhijanto Yulianti, Fina Yuliyanti , Fina Zaky Khusniati, Isna Zuhria, Faida