Nanda Saridewi, Nanda
Departement Of Chemistry Education, Faculty Of Educational Science, Syarif Hidayatullah State Islamic University Of Jakarta, Indonesia, 15412

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Journal : JURNAL KIMIA SAINS DAN APLIKASI

Catalytic Cracking of Crude Biodiesel into Biohydrocarbon Using Natural Zeolite Impregnated Nickel Oxide Catalyst Isalmi Aziz; Edra Aditya Fhilipia Ardine; Nanda Saridewi; Lisa Adhani
Jurnal Kimia Sains dan Aplikasi Vol 24, No 7 (2021): Volume 24 Issue 7 Year 2021
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (508.975 KB) | DOI: 10.14710/jksa.24.7.222-227

Abstract

Crude biodiesel is biodiesel that still contains impurities. A catalytic can improve the quality of biohydrocarbons (biogasoline, biokerosene, and green diesel). The catalyst used is nickel oxide impregnated natural zeolite (NiO/Zeolite). The use of nickel can increase the activity of the catalyst because it has an empty d orbital and a smaller molecular size. This study aims to determine the best catalyst that can exhibit the greatest selectivity toward biohydrocarbons. Natural zeolite was activated and impregnated by varying the concentration of NiO (1, 3, and 5% w/w). The characteristics of the catalyst were determined by the crystallinity (X-Ray Diffraction), surface area (Surface Area Analyzer), and functional group (Fourier Transform Infrared). The catalyst and crude biodiesel were put in an autoclave reactor and operated at a temperature of 375°C and 3 hours. The obtained product was tested with Gas Chromatography-Mass Spectroscopy. The results of the XRD analysis showed the presence of NiO at 2θ 37.23; 43.15; and 62.65°. Nickel oxide on the catalyst was detected at a wavenumber of 671.23 cm‑1. The highest surface area was obtained at a NiO/Zeolite 1% of 49.4 m2/g. 1% NiO/Zeolite catalysts gave the best results on catalytic cracking of crude biodiesel with a reaction conversion of 60.79% and selectivity of 9,73%; 29,64% and 9,18% for biogasoline, biokerosene, and green diesel, respectively.
Characterization and Antibacterial Activity Test of Green Synthetic ZnO Nanoparticles Using Avocado (Persea americana) Seed Extract Nanda Saridewi; Adelian Risa Adinda; Siti Nurbayti
Jurnal Kimia Sains dan Aplikasi Vol 25, No 3 (2022): Volume 25 Issue 3 Year 2022
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (476.521 KB) | DOI: 10.14710/jksa.25.3.116-122

Abstract

The ability of cotton fabrics to absorb water creates several problems, such as providing an environment for bacterial growth. Antibacterial properties of textiles can be conducted by coating with nanoparticles with antibacterial activity. This study aimed to synthesize ZnO via green process nanoparticles using avocado seed extract (Persea americana), then characterize and evaluate its antibacterial activity on cotton fabrics. This research began with extracting avocado seed powder with distilled water. Then the avocado seed extract was mixed with Zn(CH3COO)2.2H2O and heated in a water bath at 70°C. The mixture was stirred while NaOH was added until the mixture reached pH 7, 8, and 9. The FTIR measurement of the avocado seed extract showed the presence of free hydroxyl and amino groups that act as reducing agents, capping agents, and stabilizers in the synthesis of ZnO nanoparticles. The XRD pattern of synthesized ZnO nanoparticles was hexagonal. The SEM results showed that the morphology of ZnO nanoparticles was spherical, with a particle size of 19.965 nm. Antibacterial activity was carried out on the cotton cloth coated with ZnO nanoparticles, resulting in an inhibition zone of 1.8 cm against E. coli and 1.97 cm against S. aureus bacteria. This study result indicated that ZnO nanoparticles have antibacterial activity by producing inhibition against E. coli and S. aureus.
Utilization of Coconut Shell as Cr2O3 Catalyst Support for Catalytic Cracking of Jatropha Oil into Biofuel Isalmi Aziz; Yessinta Kurnianti; Nanda Saridewi; Lisa Adhani; Wahyu Permata
Jurnal Kimia Sains dan Aplikasi Vol 23, No 2 (2020): Volume 23 Issue 2 Year 2020
Publisher : Chemistry Department, Faculty of Sciences and Mathematics, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2981.468 KB) | DOI: 10.14710/jksa.23.2.39-45

Abstract

Coconut shell waste is a waste that has a high carbon content. Carbon in coconut shell waste can be converted into activated carbon having a large surface area. This potential property is suitable to apply the coconut shell as catalyst support. To increase the catalytic activity, metal oxides such as Cr2O3 are impregnated. The purpose of this study is to synthesize Cr2O3/carbon catalyst and test its catalytic activity on catalytic cracking of Jatropha oil. The first stage was the synthesis of activated carbon and the determination of its proximate and ultimate. The second step was impregnation to produce Cr2O3/carbon catalyst. Furthermore, X-Ray Diffraction to determine crystallinity, Surface Area Analyzer to identify its surface area and Fourier Transform Infrared to analyze functional groups. Then the catalytic activity was tested on the catalytic cracking of Jatropha oil. In addition, the chemical compound composition and biofuel selectivity of the catalytic cracking product was determined using Gas Chromatography-Mass Spectrometer. Proximate analysis results showed that activated carbon contains 9%, 1%, 23%, and 67% of water, ash, evaporated substances, and bound carbon, respectively. The results of the ultimate analysis resulted in carbon (C), hydrogen (H), and nitrogen (N) contents of 65.422%, 3.384%, and 0.465%, correspondingly. The catalyst crystallinity test showed the presence of Cr2O3 peaks at 2θ: 24.43°; 33.47° and 36.25° according to JCPDS No. 84-1616. In the absorption area of 400-1000 cm-1 and the range of 2000 cm-1 showed the presence of Cr-O stretching due to Cr2O3 adsorbed into the activated carbon structure. The surface area of activated carbon and Cr2O3/carbon catalysts with a concentration of 1.3, and 5% was 8.930 m2/g; 47.205 m2/g; 50.562 m2/g; and 38.931 m2/g, respectively. The catalytic activity test presented that the best performance was showed by Cr2O3/carbon catalyst with a concentration of 5% indicated by conversion of Jatropha oil into biofuel of 67.777% with gasoline selectivity, kerosene, and diesel of 36.97%, 14.87%, and 15.94%, correspondingly.
Co-Authors Achmad Yandi Rahmatul Fajri Adawiah Adawiah Adawiah Adawiah Adawiah Adawiah adawiah adawiah, adawiah Adelian Risa Adinda Admin Alif Agustino Zulys Ai Fiyani Aini Nadhokhotani Herpi Anna Muawanah Aqsha Pandia Swangganegara Aulia, Hanna Bahriah, Evi Sapinatul Bale, Uly Fitria Biaunik Niski Kumila Buchori Muslim Buchori Muslim Dasumiati Dasumiati Dede Sukandar Dedi Irwandi Desy Rositasari Dila Fairusi Dila Salsabila Dinnah Raihanah Dwiatmoko, Adid Adep Dwie Annisa Dzikri Anfasa Firdaus Edra Aditya Fhilipia Ardine Erica Anna Pratiwi Fadhilla, Rizka Fajri, Achmad Yandi Rahmatul Farah, Sabrina Farhan Maulana Azhar Farishi, Salman Fitri Febriyani Fitria, Shella Humaeroh, Ika Iman, Nurul Isalmi Aziz Latifah Tulhusna Lian Risa Adinda, Ade Lily Surayya Eka Putri, Lily Surayya Eka Lisa Adhani Lisa Adhani Lisa Adhani Luki Yunita Mala, Farhah Syahidatul Mardiyah, Farah Fathiaty Muhammad Farhan Muhammad Shofyan Gunawan Nabila Fauziah Nine Novita Cahya Niski Kumila, Biaunik Nur Azizah, Dinda Nur Hikmah Nur Hikmah Nurhasni Nurhasni Rahayu, Putri Ramadhan, Fitri Nur Ramli, Munasprianto Ricky Gunawan, Ricky Ridla Bakri Rifki, Abdul Risma Nur Fitria Riyanti, Aditya Rizki Nurhidayah Rizkyani, Arivia Monique Rizqy Nur Solihat Saeful Rohman Salamah Agung, Salamah Sari, Nur Nilam Selviana Rustanti Siti Nurbayti Siti Nurbayti Siti Nurbayti Siti Nurbayti Siti Suryaningsih, Siti Solly Aryza Sri Komala Sri Komala Suryadi, Joko Susilo, Ahmad Syukri Arif Tonih Feronika, Tonih Tulhusna, Latifah Wahyu Permata Wulandari Oktavia Yessinta Kurnianti Yulyani Nur Azizah