Nanda Saridewi, Nanda
Departement Of Chemistry Education, Faculty Of Educational Science, Syarif Hidayatullah State Islamic University Of Jakarta, Indonesia, 15412

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Journal : VALENSI

Sintesis Nanomaterial Mangan Oksida dengan Metode Bebas Pelarut Nanda Saridewi; Syukri Arif; Admin Alif
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 1, No. 2, November 2015
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v0i0.3147

Abstract

Manganese dioxide (MnO2) known as manganese oxide which has a variety polimorfi crystal structure, such as β-, α-, δ- and γ- MnO2. Each of manganese oxide material comprises a tunnel structure. With the structure of the tunnel which is owned by manganese oxide material is widely used as selective catalysts, ion exchange, and the exchange of molecules. Manganese oxide is synthesized using free methods solvent. Synthesis process is performed with a temperature variation of 90, 120, and 150 °C. The results was characterized by XRD and SEM. XRD diffraction patterns produced showed that the manganese oxide that is formed is a β-MnO2 (pyrolusite) with an optimum temperature of 120 °C. The resulting material also has a range of nanoparticles that reach 14:08 nm crystal size. Mangan shaped morphology produced oxide can degrade dye rhodamine B.DOI: http://dx.doi.org/10.15408/jkv.v0i0.3147.  
Biosynthesis of ZnO Nanoparticles Using Pumpkin Peel Extract (Cucurbita moschata) and its Applications as Semiconductor in Dye Sensitized Solar Cell (DSSC) Nanda Saridewi; Dzikri Anfasa Firdaus; Isalmi Aziz; Biaunik Niski Kumila; Dasumiati Dasumiati
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 7, No. 2, November 2021
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v7i2.21046

Abstract

ZnO nanoparticles are semiconductor materials that can be used in Dye Sensitized Solar Cells (DSSC). ZnO nanoparticles can be synthesized using pumpkin peel extract (Cucurbita moschata) which functions as a reducing agent, stabilizer, and capping agent. Zn(CH3COO)2.2H2O precursor was used with a concentration of 0.15 M at various pH 7, 8, and 9 reacted with pumpkin peel extract. The functional groups of pumpkin peel extract were characterized using Fourier Transform Infrared Spectroscopy (FTIR), the samples were analyzed by TEM and XRD. The resulting ZnO nanoparticles were used as semiconductors in Dye Sensitized Solar Cell (DSSC) using dyes from mangosteen peel.The FTIR results showed the presence of functional groups O-H hydroxy, CH2, secondary amides (R-CO-NR2, C-H and phosphate (PO43-). XRD results showed that ZnO produced wurzhite crystals with a hexagonal system and the smallest crystal size was 18.99 nm. TEM results showed that ZnO synthesized at a concentration of 0.15 M and pH 8 had a spherical particle shape with a size of 24.90 nm, while the DSSC test results had an efficiency of 9.06 x 10-4%.
Synthesis of ZnO-TiO2 Nanoparticles by Sol-Gel Process and its Application for Solar Cell Semiconductor Saridewi, Nanda; Riyanti, Aditya; Aziz, Isalmi; Niski Kumila, Biaunik; Lian Risa Adinda, Ade
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 9, No. 2, November 2023
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v9i2.32206

Abstract

ZnO-TiO2 semiconductor can be used in Dye-Sensitized Solar Cell (DSSC) devices as an alternative to renewable energy. This semiconductor can be synthesized by sol-gel method. The objective of this study is synthesizing the TiO2-doped ZnO nanoparticle semiconductors for DSSC devices with mangosteen peel extract dye. Avocado seeds were extracted with water, as a capping agent in the synthesis of ZnO-TiO2 (TiO2 ratio of 0,3,5,7 and 10% to ZnO). XRD results show the success of ZnO-TiO2 doping, due to the 2θ shift and changes in the crystal lattice. The average crystal size obtained was 33.7972 nm. The SEM results showed that the particle size of ZnO ranged from 45-100 nm. The UV-Vis dye measurements of mangosteen peel extract showed an absorption peak at 296-483 nm wavelength, with a corresponding band gap energy value of 3.04 eV. The UV-Vis DRS ZnO-TiO2 measurements have an average band gap energy of 3.1425 eV and ZnOof 3.1915 eV. The highest DSSC efficiency value is 2.15 x 10-2% at 7% ZnO-TiO2 semiconductor.
Synthesis and Characterization of Bioplastic from Macroalgae Padina australis Putri, Lily Surayya Eka; Saridewi, Nanda; Farah, Sabrina
Jurnal Kimia Valensi Jurnal Kimia VALENSI Volume 9, No. 2, November 2023
Publisher : Syarif Hidayatullah State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v9i2.32906

Abstract

Synthetic plastics are one of the more significant contributors to waste in the environment. Bioplastic is a type of plastic that is environmentally friendly because it is made from biomass. In this study. brown macroalgae. Padina australis. is one of the potential raw materials found in large quantities in Indonesian waters and used to produce bioplastics with filtration technique. The aim of this study was to synthesis bioplastics using P. australis alginate with glycerol plasticizer.The alginate macroalgae were mixed with glycerol as a plasticizer in the following proportions: 1:15. 1:25. 2:15. and 2:25. with the quality determined through tensile strength measurements. water solubility. and degradation time. On day 12. the tensile strength of P. australis bioplastic was 3.24-7.33 MPa. the water solubility was 61.79-65.19%. and the biodegradability rate was 0.1-20.0%. When the macroalgae alginate and glycerol formulation was 2:25. the best bioplastic film produced had a tensile strength of 7.33 MPa and a water solubility of 61.79%. which was lower than the Indonesia National Standard number 7818/2016 for bioplastic products. P. australis. however. has the potential to be a promising alternative bioplastic product that contributes to the reduction of petroleum-based plastic pollution in the environment. Furthermore. as a preliminary study. it will be improved to meet industrial standards or find the products that match these characteristics.
Natural Zeolite as Mo and MoP Catalysts Support for Catalytic Deoxygenation of Jatropha Oil Aziz, Isalmi; Farhan, Muhammad; Saridewi, Nanda; Azizah, Yulyani Nur; Muawanah, Anna; Nurbayti, Siti; Dwiatmoko, Adid Adep; Adhani, Lisa
Jurnal Kimia Valensi Jurnal Kimia VALENSI, Volume 11, No. 1, May 2025
Publisher : Department of Chemistry, Faculty of Science and Technology Syarif Hidayatullah Jakarta State Islamic University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15408/jkv.v11i1.45272

Abstract

Non-edible oil, such as Jatropha oil, is an interesting feedstock for the development of renewable diesel (green diesel). Catalytic deoxygenation using natural zeolite-supported Mo-based catalysts is a promising process for the conversion of Jatropha oil to green diesel. Mo and MoP catalysts supported on natural zeolite were synthesized by wet impregnation at a concentration of 5% (w/w). The catalysts were characterized by XRD, XRF, SAA and NH3-TPD. The catalysts were successfully synthesized with the appearance of Mo and MoP peaks on the catalyst diffractogram. XRF results also showed that Mo and P were present in the catalyst. Metal impregnation decreased the surface area and pore volume of the catalyst, but increased the average pore diameter. The NH3-TPD profile of the catalyst showed that the weak acid sites of both catalysts were larger than the strong acid sites. Based on the activity test of catalytic deoxygenation of Jatropha oil, the MoP/HZ catalyst produced a higher conversion (67%) and liquid product yield (79%) than Mo/HZ. This is associated with a larger pore diameter, so that the distribution of reactants on the catalyst surface is more optimal. However, the highest green diesel selectivity of 82% is produced by the Mo/HZ catalyst. The Mo/HZ catalyst is more oriented towards the HDO reaction, whereas the MoP/HZ catalyst is more oriented towards the DCO/DCO2 reaction.
Co-Authors Achmad Yandi Rahmatul Fajri Adawiah Adawiah Adawiah Adawiah Adawiah Adawiah adawiah adawiah, adawiah Adelian Risa Adinda Admin Alif Agustino Zulys Ai Fiyani Aini Nadhokhotani Herpi Anna Muawanah Aqsha Pandia Swangganegara Aulia, Hanna Bahriah, Evi Sapinatul Bale, Uly Fitria Biaunik Niski Kumila Buchori Muslim Buchori Muslim Dasumiati Dasumiati Dede Sukandar Dedi Irwandi Desy Rositasari Dila Fairusi Dila Salsabila Dinnah Raihanah Dwiatmoko, Adid Adep Dwie Annisa Dzikri Anfasa Firdaus Edra Aditya Fhilipia Ardine Erica Anna Pratiwi Fadhilla, Rizka Fajri, Achmad Yandi Rahmatul Farah, Sabrina Farhan Maulana Azhar Farishi, Salman Fitri Febriyani Fitria, Shella Humaeroh, Ika Iman, Nurul Isalmi Aziz Latifah Tulhusna Lian Risa Adinda, Ade Lily Surayya Eka Putri, Lily Surayya Eka Lisa Adhani Lisa Adhani Lisa Adhani Luki Yunita Mardiyah, Farah Fathiaty Muhammad Farhan Muhammad Shofyan Gunawan Nabila Fauziah Nine Novita Cahya Niski Kumila, Biaunik Nur Azizah, Dinda Nur Hikmah Nur Hikmah Nurhasni Nurhasni Rahayu, Putri Ramadhan, Fitri Nur Ramli, Munasprianto Ricky Gunawan, Ricky Ridla Bakri Rifki, Abdul Risma Nur Fitria Riyanti, Aditya Rizki Nurhidayah Rizkyani, Arivia Monique Rizqy Nur Solihat Saeful Rohman Salamah Agung, Salamah Sari, Nur Nilam Selviana Rustanti Siti Nurbayti Siti Nurbayti Siti Nurbayti Siti Nurbayti Siti Suryaningsih, Siti Solly Aryza Sri Komala Sri Komala Suryadi, Joko Susilo, Ahmad Syukri Arif Tonih Feronika, Tonih Tulhusna, Latifah Wahyu Permata Wulandari Oktavia Yessinta Kurnianti Yulyani Nur Azizah