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SUSTAINABLE LIGNIN EXTRACTED FROM BANANA STEM BIOMASS AS A FUNCTIONAL UV-BLOCKING INGREDIENT IN SUNSCREEN Sheryl Ayesha; Nanda Aurelia Salsabila S; Teguh Pambudi; Hasti Asfarina; Hilman Imadul Umam; Fajar Amelia Rachmawati Putri
Jurnal Crystal : Publikasi Penelitian Kimia dan Terapannya Vol. 8 No. 1 (2026): Literasi Artikel Penelitian Kimia
Publisher : Program Studi Kimia, Fakultas MIPA, Universitas PGRI Banyuwangi

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.36526/jc.v8i1.7005

Abstract

Banana stem biomass, an abundant agricultural by-product, contains significant lignin content and offers strong potential for valorization through green extraction technologies. In this study, lignin was extracted using an environmentally friendly Deep Eutectic Solvent (DES) composed of choline chloride and citric acid and subsequently incorporated into sunscreen cream formulations at concentrations of 2%, 3%, and 4%. The photoprotective performance of the formulations was evaluated through UV–Vis spectrophotometry, while pH measurements ensured compliance with SNI 16-4399-1996. FTIR analysis was conducted to compare the structural characteristics of DES-extracted lignin with those obtained using conventional NaOH extraction. The results revealed that all lignin-based formulations effectively absorbed UVA (320–400 nm) and UVB (280–320 nm) radiation, with UV absorbance increasing alongside lignin concentration; the 4% formulation showed the strongest UV-blocking capability. All samples maintained a skin-compatible pH of approximately 6. FTIR spectra further indicated that DES-extracted lignin preserved aromatic structures more effectively than NaOH-extracted lignin. Overall, the findings highlight the potential of banana stem-derived lignin as a natural UV-blocking and antioxidant ingredient for eco-friendly sunscreen products, supporting the advancement of sustainable cosmetic innovation.
Sustainable Valorization of Corncob Residues through Green Lignin Extraction for Functional Sunscreen Applications Teguh Pambudi; Hilman Imadul Umam; Fajar Amelia Rachmawati Putri; Alifa Rahma Zuhri; Nanda Aurelia Salsabila S.; Melisa Nur Halimah; Sheryl Ayesha Bruning; Elzandra Imola Vioniken
Biology, Medicine, & Natural Product Chemistry Vol 15, No 1 (2026)
Publisher : Sunan Kalijaga State Islamic University & Society for Indonesian Biodiversity

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14421/biomedich.2026.151.119-125

Abstract

Corncob residues represent an abundant agricultural biomass rich in cellulose, hemicellulose, and lignin. Lignin, an aromatic biopolymer containing benzene and ketone functional groups, exhibits inherent ultraviolet (UV) absorption, positioning it as a promising bio-based ingredient for sustainable sunscreen formulations. In this study, lignin was extracted from corncob residues—comprising 18.5% hemicellulose, 23.5% cellulose, and 16.5% lignin—using a green deep eutectic solvent (DES) system composed of choline chloride and citric acid, and benchmarked against conventional alkaline extraction using NaOH. FTIR analysis revealed attenuated peak intensities in DES-extracted lignin, indicating lower recovery and partial structural alteration relative to the NaOH-derived counterpart. Extraction yields were 10.06% for the DES method and 16.19% for the NaOH method. Sunscreen formulations containing 2%, 3%, and 4% lignin exhibited appreciable UV absorption, particularly within the UVA region, with the highest performance observed at 4% lignin loading. These results highlight the feasibility of valorizing corncob biomass through environmentally benign lignin extraction to produce functional bio-based materials for sustainable sunscreen applications.