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Pemodelan Empirik Desulfurisasi Batubara Secara Flotasi Dengan Metode Rayleigh Andi Aladin
Journal of Chemical Process Engineering Vol 5, No 1 (2020)
Publisher : Universitas Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1033.643 KB) | DOI: 10.33536/jcpe.v5i1.567

Abstract

Model empirik penting untuk diciptakan berdasarkan data empirik berupa data penelitian atau pengamatan yang diperoleh guna mengungkapkan dalam bahasa matematik terhadap fenomena riil (empirik) yang diamati. Model empirik bermanfaat untuk mengeneralisasi suatu fenomena, sehingga dengan model empirik tersebut bisa dilakukan prediksi baik secara ekstrapolasi maupun intrapolasi hingga pada batas tingkat toleransi tertentu. Dalam artikel ini disajikan langkah-langkah menyusun model empirik berdasar data empirik hasil penelitian dengan contoh kasus fenomena desulfurisasi batubara dengan cara flotasi menggunakan surfaktan crud palm oil (CPO). Pemodelan empirik dilakukan berbasis analisis dimensi menggunakan metode Reyleigh. Diperoleh model empirik desulfurisasi batubara dengan tingkat validasi cukup baik ditandai dengan ralat cukup rendah yaitu 2,78%.
Penentuan Rasio Optimum Campuran CPO: Batubara Dalam Desulfurisasi dan Deashing Secara Flotasi Sistem Kontinyu Andi Aladin
Jurnal Rekayasa Proses Vol 3, No 2 (2009)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.567

Abstract

Salah satu problem penggunaan batubara Indonesia adalah kandungan sulfur dan abu yang relatif tinggi sehingga dapat berdampak pada kerusakan alat pembakar dan pencemaran lingkungan. Flotasi merupakan salah satu metode untuk mereduksi kandungan sulfur (anorganik) dan abu batubara. Penelitian desulfurisasi dan deashing batubara asal daerah Mallawa (Sulawesi) dilakukan dalam sebuah alat kolom flotasi dengan sistem kontinyu. Diamati beberapa variabel flotasi yang dapat memberikan hasil desulfurisasi yang maksimum, diantaranya adalah variabel rasio campuran surfaktan CPO (Crude Palm Oil) terhadap bahan batubara, dibahas dalam artikel ini. Diperoleh rasio campuran optimum adalah 1:4, berdasarkan kondisi optimum variabel lain yang telah diperoleh sebelumnya yaitu waktu tinggal 60 menit, laju alir udara 1,22 liter/menit, pH 6,5 dan ukuran partikel batubara 169 m. Pada kondisi optimum ini kandungan sulfur batubara dapat direduksi dari 3,3% menjadi 0,93% atau recovery sulfur 72% dan kandungan abu dapat diturunkan dari 11,25% menjadi 9,75% dengan nilai kalor dapat dipertahankan 6000 kkal/kg. Batubara hasil desulfurisasi dan deashing ini telah memenuhi kriteria untuk digunakan sebagai bahan bakar di industri. Kata kunci: abu, sulfur, flotasi, nilai kalor, kontinyu, rasio CPO:Batubara The problem related to the utilisation of Indonesian coal is the high sulphur and ash contents of the coal which may defect the combustor units and pollute the environment. Flotation is one of the methods to reduce the inorganic sulphur and ash in coal. Research on desulphurisation and deashing of coal from Mallawa (Sulawesi) was performed in a continuous flotation column. Variables which give maximum desulphurisation were studied and covered in this article, e.g. mixing ratio of crude palm oil (CPO) surfactant to coal. It was found that optimum mixing ratio of CPO to coal was 1:4, based on optimum conditions previously determined, i.e. resident time of 60 minutes, air flow rate of 1.22 l/min, pH 6.5 and coal particle size of 169 m. In these optimum conditions, the sulphur content was reduced from 3.3% to 0.93% or 72% sulphur recovery, while the ash content was reduced from 11.25% to 9.75%, the calorific value was maintained at 6000 kcal/kg. The desulphurised and deashed coal meets the specification criteria of the industrial fuel. Key words: ash, sulphur, continuous flotation, caloric valve, ratio CPO:coal
KESETIMBANGAN PROSES DESORPSI AMONIA DARI ARANG AKTIF HASIL PIROLISIS LIMBAH BIOMASSA Hasni Hasni; Syamsuddin Yani; Andi Aladin; Mimin Septiani
AL-ULUM: JURNAL SAINS DAN TEKNOLOGI Vol 5, No 2 (2020)
Publisher : Universitas Islam Kalimantan Muhammad Arsyad Al Banjari

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (395.638 KB) | DOI: 10.31602/ajst.v5i2.2803

Abstract

Ammonia which is bound to the adsorbent can interfere adsorption process, so that release the compound can be done by desorption process. This research intends to know appropriate equilibrium models to determine maximum capacity of active carbon for desorption ammonia. The method which used in desorption process are Langmuir and Freundlich isotherm models. The research was performed with variation of active carbon mass and variation of contact time. The concentration of ammonia on the desorption process was determined using spectrophotometer at λ 420 nm. The experiment result showed that the more the active carbon dosage is used, the more the concentration of ammonia is increased. Optimum contact time during 7 hours with desorption percentage 94-96%. This research of ammonia desorption by active carbon followed the Langmuir equilibrium model R2 0.954 and Freundlich equilibrium model R2 0.952. The equilibrium equation is used Langmuir equation y = -0.015x + 3.185, maximum desorption capacity is 66.67 mg/g.
Blending Batubara Dengan Limbah Biomassa Tongkol Jagung Untuk Mengurangi Ketergantungan Sumber Energi Tidak Terbarukan Syukrika Putri; Takdir Syarif; Andi Aladin
Journal of Chemical Process Engineering Vol 7, No 2 (2022)
Publisher : Universitas Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33536/jcpe.v7i2.807

Abstract

Cadangan batubara sebagai sumber energi tidak terbarukan semakin menipis. Untuk mengurangi laju pemakaian bahan bakar batubara maka dilakukan penelitian blending batubara dengan sumber energi terbarukan berupa biomassa seperti tongkol jagung. Dalam penelitian ini diamati pengaruh rasio tongkol jagung terhadap batubara untuk mendapatkan kualitas campuran bahan bakar terbaik yang memenuhi syarat untuk diaplikasikan pada industri dan pembangkit listrik. Parameter kualitas campuran batubara dan tongkol jagung yang diamati adalah nilai kalor dan kadar sulfur. Bahan bakar batubara yang digunakan dalam penelitian ini memiliki nilai kalor  8403 cal/gram dan kadar sulfur 0.71%. Sedangkan tongkol jagung memiliki nilai kalor 3409.64 cal/gram dan kadar sulfur 0.14%. Dari penelitian ini diperoleh pencampuran terbaik dengan rasio tongkol jagung terhadap batubara sebesar 75% yang memberikan nilai kalor 4741.54 cal/gram dan kadar sulfur 0.26%. Kualitas pencampuran batubara dan tongkol jagung ini memenuhi syarat untuk diaplikasikan pada Pembangkit Listrik Tenaga Uap (PLTU). Pemanfaatan hasil pencampuran bahan bakar ini dapat mengurangi laju pemakaian batubara sebanyak 75%. 
Utilization of Papaya Seed Powder as a Bioadsorben to Reduce Total Iron (Fe) in Wastewater Munira Munira; Andi Aladin; Perwitasari Perwitasari; Nur Aulia Hamza; St Umrah Tulzhaliza
Eksergi Vol 19, No 3 (2022)
Publisher : Prodi Teknik Kimia, Fakultas Teknologi Industri, UPN "Veteran" Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31315/e.v19i3.8007

Abstract

Papaya is a tropical plant that is widely cultivated in Indonesia. Papaya seeds have a high cellulose content, so that papaya seeds can be used as raw material for adsorbents (biosorbents). Biosorbent is used to reduce environmental pollution through the absorption of various types of liquid waste including heavy metals. Fe is an essential heavy metal if in excess amounts can cause toxic effects. One of the methodes to reduce  of iron ion in wastewater is  the adsorption method is using papaya seed biosorbents. The aim of study was to determine the effectivness of using papaya seedd as bioadsorbent  to reduce of iron ion in the wastewater. Papaya seed as the adsorbent agent activated ones was used in five particle size and contact time variations in order to determine the optimum particle size and contact time of papaya seed powder to absorb the heavy metals. The results show that the optimum adsorbent particle size was 100 mesh and the optimum contact time was 60 minute. The adsorption efficiency of (Fe) metal ions in wastewater was 60%, the adsorption capacity value was 0.365 mg/g.  Kinetic modelling of adsorption process is  pseudo second order.
POTENSI PEMANFATAN LIMBAH BIOMASSA SERBUK GERGAJI KAYU BESI (Eusideroxylon zwageri) MENJADI ASAP CAIR MELALUI PROSES PIROLISIS Muzdalifah Muzdalifah; Takdir Syarif; Andi Aladin
ILTEK : Jurnal Teknologi Vol. 15 No. 02 (2020): ILTEK : Jurnal Teknologi
Publisher : Fakultas Teknik Universitas Islam Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.47398/iltek.v15i02.28

Abstract

Limbah serbuk kayu hasil proses penggergajian ataupun limbah dari penghalusan kayu memilki banyak manfaat bila diproses lebih lanjut. Salah satu yang dapat dilakukan yaitu dengan memanfaatkan limbah serbuk gergaji kayu menjadi asap cair. Penelitian ini dilakukan dengan tujuan untuk mengetahui potensi pemanfaatan limbah biomassa serbuk gergaji kayu besi menjadi asap cair melalui proses pirolisis. Metode penelitian ini dilakukan dengan cara menyiapkan sampel limbah serbuk gergaji kayu besi sebanyak 1000 gram, kemudian dilanjutkan dengan metode pirolisis selama 120 menit dan temperatur pirolisis yang dipertahankan yaitu 400 oC, hasil pirolisis diperoleh tiga produk yaitu asap cair, charcoal dan sedikit tar, asap cair yang dihasilkan kemudian ditimbang dan diukur volumenya, analisa dilakukan dengan metode MC-GS. Hasil penelitian ini menunjukan bahwa secara batch diperoleh kandungan total Phenol 49% area. Kandungan total Benzen sebesar 12% area. Kandungan total asam sebesar 11% area. Yield asap cair sebesar 38%. Dari hasil analisa yang telah dilakukan, tidak ditemukan adanya senyawa benzopyren, yang berarti bahwa asap cair yang dihasilkan bagus digunakan sebagai bahan pengawet pangan.
Pengaruh Aliran Nitrogen Kontinyu ke Dalam Reaktor Pirolisis Limbah Biomassa Serbuk Gergaji Batang Kelapa (Cocos Nucifera) Terhadap Nilai Kalor. Syarwan Hamid; Andi Aladin; Basri Modding; Takdir Syarif; Lastri Wiyani; Muh Arman
Journal of Chemical Process Engineering Vol 8, No 1 (2023)
Publisher : Universitas Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33536/jcpe.v8i1.1504

Abstract

AbstractThe potential amount of coconut sawdust biomass in Indonesia is very abundant, so far it has not been utilized optimally and tends to be wasted as waste. Coconut sawdust with the main composition of carbon contains heat equivalent to light coal, which is around 4400 kcal/kg. Even though its calorific value is still low, it has the potential to be used as a solid fuel source or an alternative energy source. The calorific value of coconut sawdust can be increased through the pyrolysis process. A study has been carried out on the effect of nitrogen inert gas flowing continuously into the pyrolysis reactor of coconut sawdust biomass waste (Cocos nucifera) on the calorific value of the resulting charcoal. The aim of the research is to determine the effect and optimum flow path of nitrogen inert gas which gives the maximum calorific value of charcoal product. From this study it was concluded that the continuous flow of inert nitrogen gas into the pyrolysis reactor had an effect on increasing the calorific value of the charcoal product by up to 4% compared to not using the inert gas. The optimum nitrogen gas flow rate is 2 L/minute giving a maximum effective calorific value of 7200 kcal/kg
Penentuan Waktu Optimum Pirolisis Limbah Biomassa Serbuk Gergaji Batang Kelapa Menggunakan Gas Inert Argon Takdir Syarif; Andi Aladin; Basri Modding; Resky Alqadri Rahmatullah; Nurul Makka Mustafa
Journal of Chemical Process Engineering Vol 8, No 1 (2023)
Publisher : Universitas Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33536/jcpe.v8i1.1687

Abstract

This study aims to determine the effect of argon inert gas and pyrolysis time variations on the quality of charcoal produced from the pyrolysis of coconut sawdust waste. This research was carried out in a pyrolysis reactor operating at 400 oC, with an inert gas rate of 2 liters/minute with time variations of 60, 90, 120, 150, and 180 minutes. The results of the research obtained products in the form of charcoal and liquid smoke. Pyrolysis using inert gas has a heating value of 7229 kcal/kg. While the treatment without inert gas has a calorific value of 7050 Kcal/kg. This complies with SNI 1683-2021 concerning Wood Charcoal, which is a minimum of 6500 Kcal/kg. The optimum time obtained is 150 minutes with the characteristics of charcoal: (1) the volatile matter of 16.85% wt, (2) moisture of 2.47% wt, (3) ash content of 4.11% wt, and (4) fixed value carbon 76.57%wt.
Penentuan Suhu Optimum Pirolisis Serbuk Gergaji Batang Kelapa: Determination of the Optimum Temperature of the Pyrolysis of Coconut Trunk Sawdust Waste Andi Aladin; Takdir Syarif; Andi Suryanto; Andi Magefira; Ardan
KOVALEN: Jurnal Riset Kimia Vol. 9 No. 2 (2023): August Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2023.v9.i2.16482

Abstract

Research has been carried out on the utilization of biomass waste of coconut trunk sawdust using the pyrolysis method to produce two products simultaneously, namely charcoal and liquid smoke. In order to obtain charcoal products with optimum calorific value, it is necessary to understand the optimum pyrolysis conditions. One of the optimum conditions, namely pyrolysis temperature, was studied in this research. Pyrolysis was carried out in a simultaneous pyrolysis reactor at a flow rate of argon inert gas into the reactor of 2 liters/minute and a pyrolysis time of 2.5 hours with pyrolysis temperature variations of 350, 400, 450, and 500°C, respectively. The study showed that the optimum temperature of 400oC was obtained which gave a yield of 34% charcoal with a calorific value of 7229 kcal/kg. Compared to the calorific value of the raw material for coconut sawdust which is 4400 kcal/kg, there was an increase in the calorific value of the pyrolysis product by 64%. Based on the optimum temperature condition, liquid smoke as a by-product was also obtained with a yield of 45%. Charcoal can be used as a solid fuel or as a bioadsorbent in the treatment of liquid waste or clarification of liquid food products such as virgin coconut oil (VCO). Grade 3 liquid smoke can be used as a biopesticide, while grade 1 liquid smoke can be used as a food preservative. Given the benefits of the two pyrolysis products, both of the products from the current research have a promising market value.
Utilization of Industrial Flour Waste as Biobriquette Adhesive: Application on Pyrolysis Biobriquette Sawdust Red Teak Wood Wahyuni, Harini; Aladin, Andi; Kalla, Ruslan; Nouman, Muhammad; Ardimas, Ardimas; Chowdhury, MD. Shahariar
International Journal of Hydrological and Environmental for Sustainability Vol 1, No 2 (2022): International Journal of Hydrological and Environmental for Sustainability
Publisher : CV FOUNDAE

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1021.317 KB) | DOI: 10.58524/ijhes.v1i2.74

Abstract

Biobriquette is one of the alternative fuels derived from biomass. The biomass used in this research is red teakwood charcoal. This research purposes to utilize red teakwood charcoal as alternative fuels and then to knows best characters compressive strength, ignition power and caloric value according to Indonesian quality standards (SNI 01-6235-2000). Characteristics of biobriquettes are known by test ash content, moisture content, volatile matter, fix carbon, compressive strength, ignition power and caloric value. The materials used are red teakwood plus industrial flour waste. The process of making biobriquette begins with drying the material, pyrolysis during 150 minutes at a temperature of 400 oC, sieved with 40 mesh. The briquetting was using a cube-shaped mold with manual pressure which was then dried in an oven to a constant weight and tested its characteristics by the ASTM (American standard Testing and material) method. The results showed that the added adhesive was very take effect in producing the best briquettes. The characteristics of briquettes with the best optimum adhesive composition produce is adhesive 5% charcoal 95% produce ash content 5.49% , moisture content 4.26 %, volatile matter 26.89 %, fix carbon 63.12%, compressive strength 3.64 kgf/cm2, caloric value 7038 kcal/kg, and ignition power 0.03 gram/minute categorized as passing the specifications for the quality requirements briquettes of SNI 01-6235-2000.