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Journal : International Journal of Renewable Energy Development

Effect of Temperature on Plasma-Assisted Catalytic Cracking of Palm Oil into Biofuels Istadi, I.; Riyanto, Teguh; Buchori, Luqman; Anggoro, Didi Dwi; Saputra, Roni Ade; Muhamad, Theobroma Guntur
International Journal of Renewable Energy Development Vol 9, No 1 (2020): February 2020
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.9.1.107-112

Abstract

Plasma-assisted catalytic cracking is an attractive method for producing biofuels from vegetable oil. This paper studied the effect of reactor temperature on the performance of plasma-assisted catalytic cracking of palm oil into biofuels. The cracking process was conducted in a Dielectric Barrier Discharge (DBD)-type plasma reactor with the presence of spent RFCC catalyst. The reactor temperature was varied at 400, 450, and 500 ºC. The liquid fuel product was analyzed using a gas chromatography-mass spectrometry (GC-MS) to determine the compositions. Result showed that the presenceof plasma and catalytic role can enhance the reactor performance so that the selectivity of the short-chain hydrocarbon produced increases. The selectivity of gasoline, kerosene, and diesel range fuels over the plasma-catalytic reactor were 16.43%, 52.74% and 21.25%, respectively, while the selectivity of gasoline, kerosene and diesel range fuels over a conventional fixed bed reactor was 12.07%, 39.07%, and 45.11%, respectively. The increasing reactor temperature led to enhanced catalytic role of cracking reaction,particularly directing the reaction to the shorter hydrocarbon range. The reactor temperature dependence on the liquid product components distribution over the plasma-catalytic reactor was also studied. The aromatic and oxygenated compounds increased with the reactor temperature.©2020. CBIORE-IJRED. All rights reserved
Biofuels Production from Catalytic Cracking of Palm Oil Using Modified HY Zeolite Catalysts over A Continuous Fixed Bed Catalytic Reactor Istadi, I.; Riyanto, Teguh; Buchori, Luqman; Anggoro, Didi D.; Pakpahan, Andre W. S.; Pakpahan, Agnes J.
International Journal of Renewable Energy Development Vol 10, No 1 (2021): February 2021
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2021.33281

Abstract

The increase in energy demand led to the challenging of alternative fuel development. Biofuels from palm oil through catalytic cracking appear as a promising alternative fuel. In this study, biofuel was produced from palm oil through catalytic cracking using the modified HY zeolite catalysts. The Ni and Co metals were impregnated on the HY catalyst through the wet-impregnation method. The catalysts were characterized using X-ray fluorescence, X-ray diffraction, Brunauer–Emmett–Teller (BET), Pyridine-probed Fourier-transform infrared (FTIR) spectroscopy, and Scanning Electron Microscopy (SEM) methods. The biofuels product obtained was analyzed using a gas chromatography-mass spectrometry (GC-MS) method to determine its composition. The metal impregnation on the HY catalyst could modify the acid site composition (Lewis and Brønsted acid sites), which had significant roles in the palm oil cracking to biofuels. Ni impregnation on HY zeolite led to the high cracking activity, while the Co impregnation led to the high deoxygenation activity. Interestingly, the co-impregnation of Ni and Co on HY catalyst could increase the catalyst activity in cracking and deoxygenation reactions. The yield of biofuels could be increased from 37.32% to 40.00% by using the modified HY catalyst. Furthermore, the selectivity of gasoline could be achieved up to 11.79%. The Ni and Co metals impregnation on HY zeolite has a promising result on both the cracking and deoxygenation process of palm oil to biofuels due to the role of each metal. This finding is valuable for further catalyst development, especially on bifunctional catalyst development for palm oil conversion to biofuels.
Preparation of MgO-CaO/SiO2 catalyst from dolomite and geothermal solid waste for biodiesel production Widayat Widayat; Nadia Taradissa Maheswari; Wahyu Fitriani; Luqman Buchori; Hantoro Satriadi; K Kusmiyati; Norzita Ngadi
International Journal of Renewable Energy Development Vol 12, No 3 (2023): May 2023
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2023.51573

Abstract

Energy demand will increase along with the increase in population. The current energy demand is dominated by non-renewable energy as it could reduce dependence on fossil energy sources; hence, it is imperative to be developed. Biodiesel with waste cooking oil as its raw material is one of the renewable energies currently being developed. Catalyst can be utilized to improve the quality of biodiesel product and process. The major content in solid waste of geothermal power plant is silica oxide, while dolomite contains magnesium oxide and calcium oxide. This study aims to test the MgO-CaO/SiO2 catalyst performance from geothermal waste and dolomite in biodiesel production. The results of catalyst characterization based on FTIR, SEM, and BET tests indicates a successful impregnation method in MgO-CaO/SiO2 catalyst production. The result shows that the best variable to produce biodiesel is at the ratio of MgO-CaO: SiO2 is 15:85. The conversion of biodiesel using this variable is 92.63%. The overall results of biodiesel obtained in this study have a good quality and is in accordance with SNI 7182-2015.
Co-Authors . Widayat Amin Nugroho Anggun Kurniawan Anindita Indriana Aprilina Purbasari Ardian D. Yudhistira Aris Bagus Pradana, Aris Bagus Arman, Mhd. Adithia Perdana Arum Sakti Prasetyo Astrilia Damayanti B Budiyono Berkah Fajar Bintang Ayu Kalimantini Boby Gusman Irianto Samosir Budi Sasongko Setia Budiyono Budiyono Chusnul Khotimah Dewi Fatmawati Didi D. Anggoro Didi D. Anggoro Didi Dwi Anggoro Dinda Labibah Ubay Dyah Hesti Wardhani Dyah Hesti Wardhani Fachmy Adji Pangestu Setiawan Faleh Setia Budi Faleh Setia Budi Faleh Setia Budi Fegi Yuliandri Fradriyan Aulia Giveni Christina Silaen Hadiyanto Hantoro Satriadi Hargono Hargono Harum Nissaulfasha Herawati Oktavianty Heri Cahyono Heru Susanto I Nyoman Widiasa I. Istadi I.G.B Ngurah Makertihartha Indro Sumantri Inshani Utami Istadi Istikhoratun, Titik JD Ryan Christy S Khonsa Syahidah Kusmiyati Kusmiyati Laeli Kurniasari M. Dani Supardan M. Dani Supardan M. Djaeni Maria Augustine Graciafernandy Meitiandari Mutiara Mhd. Shaumi Al Anshar Muhamad, Theobroma Guntur Muhammad Ulil Absori Nadia Taradissa Maheswari Ndaru Okvitarini Ngadi, Norzita Nita Aryanti Norzita Ngadi Nur Hidayati Nurjati Solikhin Nurul Aishah Aishah Nurushofa, Faustina Alda Okryreza Abdurrachman P Purwanto Pakpahan, Agnes J. Pakpahan, Andre W. S. Pratama, Pambudi Pajar Pratama, Wahyu Diski Pratiwi, Wahyu Zuli Purwanto Purwanto Purwanto Purwanto Putri Diliyan Shakti Ratnawati Ratnawati Resti Nur Utami Riko Rikardo Putra Riyanto, Teguh Rizki Andre Handika Roikhatus Solikhah Salsabila, Unik Hanifah Saputra, Roni Ade Setia Budi Sasongko Setia Budi Sasongko Setiadi, Iqfan Dwi Silviana Silviana Siswo Sumardiono Suherman Suherman Suherman Suherman Sulardjaka Sulardjaka Sulardjaka, S Syarief, Elijah Teguh Riyanto Teuku Irfan Maulana Titik Istirokhatun Udin Mabruro Wahyu Fitriani Widayat Widayat Widayat Yayuk Astuti Yazid Bindar Yazid Bindar Yudha Duta Utama