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All Journal Seminar Nasional Teknik Kimia Kejuangan Konversi Jurnal Kimia Terapan Indonesia Akta Kimia Indonesia Walisongo Journal of Chemistry ALKIMIA : Jurnal Ilmu Kimia dan Terapan Jurnal Crystal : Publikasi Penelitian Kimia dan Terapannya Journal of Appropriate Technology for Community Services Journal of Community Service and Empowerment Jurnal Abdimas Kartika Wijayakusuma Jurnal Kaharati DEVOTE: Jurnal Pengabdian Masyarakat Global Journal of Peat Science and Innovation (JPSI) Bulletin of Chemical Reaction Engineering & Catalysis Jurnal Sains Materi Indonesia Bohr: Jurnal Cendekia Kimia NAWASENA: Journal of Community Service
Riandy Putra
Department Of Chemistry, Faculty Of Mathematics And Natural Sciences, Universitas Palangka Raya, Indonesia
Agriculture, Biological Sciences & Forestry Humanities Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Education Electrical & Electronics Engineering Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Mechanical Engineering Public Health Social Sciences Other

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Journal : Bulletin of Chemical Reaction Engineering

 1 
Fe/Indonesian Natural Zeolite as Hydrodeoxygenation Catalyst in Green Diesel Production from Palm Oil Riandy Putra; Witri Wahyu Lestari; Fajar Rakhman Wibowo; Bambang Heru Susanto
Bulletin of Chemical Reaction Engineering & Catalysis 2018: BCREC Volume 13 Issue 2 Year 2018 (August 2018)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.13.2.1382.245-255

Abstract

The Petroleum diesel-based fossil fuel remains the primary source of energy consumption in Indonesia. The utilization of this unrenewable fuel depletes fossil fuels; thus, an alternative, renewable fuel, such as one based on biohydrocarbon from biomass-green diesel-could be an option. In this work, green diesel was produced through the hydrodeoxygenation from palm oil and processed in a batch-stirred autoclave reactor over natural zeolite (NZ) and NZ modified with 3 wt.% Fe metal (Fe/NZ) as heterogeneous catalyst. NZ showed high crystallinity and suitability to the simulated pattern of the mordenite and clinoptilolite phases according to X-ray diffraction (XRD) analysis. The presence of Fe metal was further confirmed by XRD, with an additional small diffraction peak of Fe0 that appeared at 2θ = 44-45°. Meanwhile, NZ and Fe/NZ were also characterized by Scanning electron microscopy (SEM) with Energy Dispersive X-ray (EDX), X-ray Fluorescence (XRF), and Surface Area Analyzer (SAA). The obtained materials were tested for the conversion of palm oil into diesel-range hydrocarbons (C15-C18) under conditions of 375 °C and 12 bar H2 for 2 h. NZ and Fe/NZ produced a liquid hydrocarbon with straight-chain (C15-C18) alkanes as the most abundant products. Based on Gas Chromatography-Mass Spectrometry (GC-MS) measurement, a higher conversion of palm oil into diesel-like hydrocarbons reached more than 58% and 89%, when NZ and Fe modified NZ (Fe/NZ), respectively were used as catalysts. 
Co-Authors 'Adany, Fildzah Alfanaar, Rokiy Amalia, Tasya Amalia, Tasya Bambang Heru Susanto, Bambang Heru Carissa Hertiningtyas, Carissa Damsyik, Akhmad Damsyik, Akhmad Deni Shidqi Khaerudini Devi Yuliantina Dewi, Rey Kamala Didik Krisdiyanto Elda Alyatikah Elfrida Ratnawati Elfrida Roulina Simanjuntak F. Adany Fajar Rakhman Wibowo Ferry Purwanto Fildzah 'Adany Hakim, Muh. Supwatul hernanda, muhammad Hidayat, Nurul Ici Nitriany Idam Sulastri Telaumbanua Indri Susanti Iqbal, Rendy Muhamad Iqbal, Rendy Muhamad Iqbal, Rendy Muhamad Irwan Nugraha Isaura, Anasthasya Jumiati Junita Dongoran Kalalinggi, Septaria Yolan Khamidinal Khamidinal Lilis Rosmainar Marvin Horale Pasaribu Meiyanti Ratna Kumalasari Miranda Silaban, Eka Miranti Maya Sylvani Nababan, Jesika Nitriany, Ici Pramudita, Dimas Pramudita, Dimas Rahmita Sari Rasidah Ratnalisti, Putri Raya Uli Sitorus Remi Ayu Pratika Remi Ayu Pratika Rendy Muhamad Iqbal Retno Agnestisia Rey Kamala Dewi Riaa Safitri Rini Marlina, Rini Rizki Rachmad Saputra Safira, Ersa Aini Saputri, Risma Dewi Sari Namarito Simarmata Sari, Luffiya Yulia Sari, Meiyanti Ratna Kumala Septaria Yolan Kalalinggi Septia Sametri, Ni Wayan Simanjutak, Elfrida Roulina Simarmata, Sari Namarito Simbolon, Wenika Sinaga, Tiara Cristy Sinaga, Tiara Cristy Agatha Siti Unvaresi Misonia Beladona Siti Unvaresi Misonia Beladona Sitorus, Raya Uli Sugiyani, Tina Sylvani, Miranti Maya Telaumbanua, Idam Sulastri Witri Wahyu Lestari Wulandari, Ika Octavia Wulandari, Oktavia Rahmi Yuneta, Yuneta