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All Journal Reaktor International Journal of Renewable Energy Development METANA Jurnal Teknik ITS IPTEK Journal of Proceedings Series BERKALA SAINSTEK Jurnal Teknik Kimia Seminar Nasional Teknik Kimia Kejuangan The Journal of Pure and Applied Chemistry Research Journal of Engineering and Technological Sciences Indonesian Journal of Chemistry Communications in Science and Technology Prosiding Seminar Nasional Sains dan Teknologi Terapan Sewagati Bulletin of Chemical Reaction Engineering & Catalysis

Achmad Roesyadi

Chemical Engineering Department, Industrial Technology Faculty, Sepuluh Nopember Institute

Author-ID : 363031

Agriculture, Biological Sciences & Forestry Arts Humanities Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Control & Systems Engineering Education Energy Engineering Environmental Science Languange, Linguistic, Communication & Media Materials Science & Nanotechnology Mathematics Medicine & Pharmacology Physics Public Health Social Sciences Other

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TRANSESTERIFICATION OF VEGETABLES OIL USING SUBAND SUPERCRITICAL METHANOL Nyoman Puspa Asri; Siti Machmudah; Wahyudiono Wahyudiono; Suprapto Suprapto; Kusno Budikarjono; Achmad Roesyadi; Mitsuru Sasaki; Motonobu Goto
Reaktor Volume 14, Nomor 2, Oktober 2012
Publisher : Dept. of Chemical Engineering, Diponegoro University

A benign process, non catalytic transesterification in sub and supercritical methanol method was usedto prepare biodiesel from vegetables oil. The experiment was carried out in batch type reactor (8.8 mlcapacity, stainless steel, AKICO, JAPAN) by changing the reaction condition such as reactiontemperature (from 210°C in subcritical condition to 290°C in supercritical state with of 20°Cinterval), molar ratio oil to methanol (1:12-1:42) and time of reaction (10-90 min). The fatty acidmethyl esters (FAMEs) content was analyzed by gas chromatography-flame ionization detector (GCFID).Such analysis can be used to determine the biodiesel yield of the transesterification. The resultsshowed that the yield of biodiesel increases gradually with the increasing of reaction time atsubcritical state (210-230oC). However, it was drastically increased at the supercritical state (270-290oC). Similarly, the yield of biodiesel sharply increased with increasing the ratio molar of soy oilmethanolup to 1:24. The maximum yield 86 and 88% were achieved at 290oC, 90 min of reaction timeand molar ratio of oil to methanol 1:24, for soybean oil and palm oil, respectively.Proses transesterifikasi non katalitik dengan metanol sub dan superkritis,merupakan proses yang ramah lingkungan digunakan untuk pembuatan biodiesel dari minyak nabati.Percobaan dilakukan dalam sebuah reaktor batch (kapasitas 8,8 ml, stainless steel, AKICO, JAPAN),dengan variabel kondisi reaksi seperti temperatur reaksi (dari kondisi subkritis 210°C-kondisisuperkritis 290°C dengan interval 20°C), rasio molar minyak-metanol (1:12-1:42) dan waktu reaksi(10-90 menit). Kandungan metil ester asam lemak (FAME) dianalisis dengan kromatografi gasdengan detektor FID (GC-FID). Hasil Analisis tersebut dapat digunakan untuk menentukan yieldbiodiesel dari proses transesterifikasi. Hasil penelitian menunjukkan bahwa yield biodiesel meningkatsecara perlahan dengan meningkatnya waktu reaksi pada keadaan subkritis (210-230oC). Namun,yield biodiesel meningkat secara drastis pada kondisi superkritis (270-290oC). Demikian pula halnyadengan rasio molar minyak kedelai-metanol, dimana hasil biodiesel meningkat tajam denganmeningkatnya rasio molar minyak-metanol hingga 1:24. Yield maksimum dicapai pada 290oC, waktureaksi 90 menit dan rasio molar minyak terhadap metanol 1:24, yaitu sebesar 86% untuk minyakkedelai dan 88% untuk minyak sawit.

EFEKTIFITAS KATALIS Co/Mo PADA HYDROCRACKING MINYAK NYAMPLUNG Rismawati - Rasyid; Ricco Aditya S. W; Devita Dian.L; Mahfud Mahfud; Achmad Roesyadi
Reaktor Volume 15 No.4 Oktober 2015
Publisher : Dept. of Chemical Engineering, Diponegoro University

THE EFFECTIVTY OF Co/Mo CATALYSTS IN HYDROCRACKING OF NYAMPLUNG OIL. Hydrocracking process of Nyamplung Oil was presented using Co and Mo as metal catalysts. Ratio of CoMo metals in catalysts, can give better catalytic activity for Nyamplung Oil conversion. In this process, we used Co/Mo ratio (0.264/0.64), (0.62/1.61), and (1.23/3.22) towards SiO2 dan γ-Al2O3. This catalyst has made by wet impregnation method with drying temperature at 383 K during 8 hours and was calcined at 773 K for 5 hours. This catalyst was characterized by X-Ray Diffraction (XRD) and showed Co3O4, MoO3 and CoMoO4 substances that was deposited at CoMo/SiO2 catalyst surface. Then, Co3O4, MoO3, MoO2 and CoMoO4 substances was also appeared at CoMo/γ-Al2O3 catalyst surface. That all phases which is deposited at both of this catalyst surface, is appropriate with International Centre for Diffraction Data (ICDD standards). Then, this catalyst was used for hydrocracking process of Nyamplung Oil that takes place at batch reactor. That process was carried out at 3 MPa and 623 K over 2 hours. C5-C11 dan C12-C18 products was produced from Nyamplung Oil conversion using this process. Both of this products is increased correspond to the addition of Co and Mo metals ratio. The highest yield that was achieved is C5-C11 (24.30%) and C12-C18 (61.28%) when using Co/Mo (1.23/3.22)/γ-Al2O3 catalyst. Meanwhile, Co/Mo (1.23/3.22)/ SiO2 catalyst can produce C5-C11 (19.52%) and C12-C18 (53.55%). Keywords: CoMo catalyst; hydrocracking; nyamplung oil Abstrak Rasio katalis CoMo sebagai katalis logam memiliki aktivitas yang baik dalam mengkonversi minyak nyamplung. Proses hydrocracking menggunakan rasio Co/Mo (0,24/0,64), (0,62/1,61), dan (1,23/3,22) terhadap SiO2 dan γ-Al2O3. Katalis tersebut menggunakan metode impregnasi basah dengan suhu pengeringan 383 K selama 8 jam dan dikalsinasi selama 5 jam pada suhu 773 K. Karakterisasi katalis menggunakan XRD (X-ray diffraction) menunjukkan komponen Co3O4, MoO3 dan CoMoO4 terdeposisi pada permukaan katalis CoMo/SiO2. Kemudian untuk katalis CoMo/γ-Al2O3 terdapat Co3O4, MoO3, MoO2 dan CoMoO4 dipermukaan katalis. Fase yang terdeposisi pada permukaan kedua katalis disesuaikan dengan standar ICCD (International Centre for Diffraction Data). Hasil uji aktivitas katalis tersebut menggunakan reaktor batch dengan tekanan 3 MP dan temperatur 623 K, proses reaksi dilakukan selama 120 menit. Konversi minyak nyamplung ada proses hydrocracking diperoleh produk C5-C11 dan C12-C18. Persentase yield kedua jenis produk meningkat sesuai dengan penambahan rasio Co dan Mo. Produk dengan yield tertinggi pada katalis Co/Mo (1,23/3,22)/ SiO2 dengan C5-C11 (19,52%) dan C12-C18 (53,55%). Sementara untuk katalis Co/Mo (1,23/3,22)/ γ-Al2O3 diperoleh C5-C11 (24,30%) dan C12-C18 (61,28%). Kata kunci: katalis CoMo; hydrocracking; minyak nyamplung

KINETIKA REAKSI PADA PROSES PRODUKSI DIETIL ETER DARI ETANOL DENGAN KATALIS H-ZEOLIT Widayat Widayat; Achmad Roesyadi; Muhammad Rachimoellah
Reaktor Volume 14, Nomor 2, Oktober 2012
Publisher : Dept. of Chemical Engineering, Diponegoro University

DiEtil Eter diproduksi dari etanol dengan proses dehidrasi. Penelitian ini bertujuan untukmempelajari kinetika reaksi proses dehidrasi etanol dengan katalis H-zeolit. Katalis H-zeolitdisintesis dengan proses dealuminasi dan kalsinasi dan impregnasi dengan logam Al dan prosesreduksi dan kalsinasi. Proses produksi DiEtil Eter dilaksanakan dengan proses adsorpsi dan reaksikatalitik sedangkan proses studi kinetika reaksi menggunakan pendekatan Langmuir-Hinshelwood.Proses analisis kinetika reaksi menggunakan perangkat lunak MATLAB. Model kinetika reaksi prosesdehidrasi etanol menjadi DiEtil Eter dan etilen dengan katalis H-zeolit pada konsentrasi umpanetanol 85-95% dan rentang temperatur 140-240oC, dimana reaksi permukaan yang mengontrol reaksiglobal adalahDiEthyl Ether is produced by using ethanol dehydrationprocess. The objective of this research was to study the reaction kinetic of ethanol dehydrationprocess by H-zeolite catalyst from natural zeolite. The H-zeolite catalyst was prepared bydealumination, calcination, impregnation with Al and reduction processes. DiEthyl Ether productionwas produced by using adsorption-catalytic reaction. The kinetic study was did with MATLABsoftware. Kinetic model of ethanol dehydration processes into DiEthyl Ether and ethylene with Hzeolitecatalyst and ethanol feed concentration among 85-95% and temperature between 140-240oCunder surface reaction is shown by

KONVERSI KATALITIK MINYAK SAWIT UNTUK MENGHASILKAN BIOFUEL MENGGUNAKAN SILIKA ALUMINA DAN HZSM-5 SINTESIS Nurjannah Nurjannah; Achmad Roesyadi; Danawati Hari Prajitno
Reaktor Volume 13, Nomor 1, Juni 2010
Publisher : Dept. of Chemical Engineering, Diponegoro University

Terbatasnya sumber energi fosil menyebabkan perlunya pengembangan energi terbarukan yang berasal dari alam dan dapat diperbaharui. Penggunaan bahan bakar minyak bumi, baik dari penggunaan berupa alat transportasi maupun dari penggunaan oleh industri sangat mencemari lingkungan karena tingkat polusi yang ditimbulkan sangat tinggi sehingga perlu mencari bahan bakar alternatif pengganti bahan bakar gasoline, solar, dan kerosene dari minyak nabati. Penelitian dilakukan dalam dua tahapan yaitu sintesa katalis dan proses katalitik cracking. Silika alumina disintesa menggunakan metode Latourette dan HZSM-5 disintesa menggunakan metode Plank. Hasil sintesa dikarakterisasi dengan Penyerapan Spektroskopi Atomis (AAS) menunjukkan bahwa silika alumina dan HZSM-5 mempunyai Si/Al 198 dan 243. Luas permukaan silika alumina dan HZSM-5 diperoleh dari analisa Brunauer Emmet Teller (BET) yaitu 149,91-213,35 m2.g-1 dan ukuran pori rata-rata adalah 13oA. Perengkahan katalitik dilakukan dalam suatu mikroreaktor fixed bed pada temperatur 350-500°C dan laju alir gas N2 100-160 ml.min-1 selama 120 min. Hasil perengkahan dianalisa dengan metode gas kromatografi. Hasil yang diperoleh untuk katalis HZSM-5 fraksi gasoline dengan yield tertinggi 28,87%, kerosene 16,70%, dan diesel 12,20% pada suhu reaktor 4500C dan laju gas N2 100 ml/menit.

Biofuel Produced from Nyamplung Oil Using Catalytic Cracking Process with Zn-HZSM-5 Catalyst Agus Budianto; Danawati Hari Prajitno; Kusno Budhikarjono; Achmad Roesyadi; Ratna Ediati
IPTEK Journal of Proceedings Series Vol 1, No 1 (2014): International Seminar on Applied Technology, Science, and Arts (APTECS) 2013
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j23546026.y2014i1.257

Indonesia Presidential Regulation No. 5/2006 on National Energy Policy suggests that the government should speed up the implementation of the use of alternative energy or fuel substitution. Biofuel synthesis is one way to overcome the shortage of energy and reduce global warming due to the use of fossil fuel. Biofuel can be produced from a variety of vegetable oil. Beside palm oil, nyamplung oil can be used to produce biofuel. The technically main obstacle in producing biofuel is the availability of the catalyst. The availability catalyst are only imported and expensive. Researchers have tried to engineer a new type of catalyst that complete the weakness of zeolite based catalyst. The study was conducted through experimental approaches, testing and observations and conducted the correlation of experiment variables with the quality of the resulted catalyst. The experiment was done by synthesizing catalyst and testing it to produce biofuel from nyamplung oil. The focus of the research is directed to the effect of operating variables on the composition of the resulted biofuel and obtain catalyst performance condition and optimum condition to produce biofuel in the fixed bed reactor. The resulted catalyst can change the nyamplung oil into biofuel. Biofuel from nyamplung oil cracking process showed that the composition is biogasoline, biokerosene and biodiesel. Biodiesel fraction is the highest fraction of the biofuel produced. The highest percentage of biodiesel at a temperature of 400°C was 60%, while the lowest percentage of biodiesel at a temperature of 300°C was 48%. Products density was in the range of 0.81 to 0.86 g/ml. The highest density occured at a reactor temperature of 300 °C was 0.86g/ml. The higher the nitrogen gas flow rate the more the biodiesel formed. At a temperature of 300°C and a nitrogen flow rate of 100 ml/min, the composition solar achieved was 60%.

Effect of Calcination at Synthesis of Mg-Al Hydrotalcite Using co-Precipitation Method Niar Kurnia Julianti; Tantri Kusuma Wardani; Ignatius Gunardi; Achmad Roesyadi
The Journal of Pure and Applied Chemistry Research Vol 6, No 1 (2017): Edition of January - April 2017
Publisher : Chemistry Department, The University of Brawijaya

The use of hydrotalcite in catalysis has wide attention in academic research and industrial parties. Based on its utilization, hydrotalcite can be active catalyst or support. This research is focused on the investigation of characteristic like spesific surface area of Mg-Al hydrotalcite which is prepared with different temperature of calcination. Synthesis of Mg-Al hydrotalcites with Mg/Al molar ratio 3:1 were prepared by co-precipitation method. Mg(NO3)3.6H2O and Al(NO3)3.9H2O as precursors of Mg-Al hydrotalcite. Na2CO3 was used as precipitant agent and NaOH was used as buffer solution. The solution was mixed and aging for 5 hours at 650oC. The dried precipitate was calcined at 2500oC, 3500oC, 450oC, 550oC and 650oC. The characterization of functional group was determined by Fourier Transform Infra Red (FT-IR). The Identical peaks diffractogram were analyzed by X-Ray Diffraction (XRD). The spesific surface area was determined by adsorption-desorption of nitrogen. The largest surface area that obtained from the calcination temperature of 650oC is 156.252 m2/g.

Pembuatan Glukosa dan Sukrosa dari Rumput Laut dengan Metode Hidrolisa Menggunakan Katalis SiO2 Fatma Putrinta Devi; Delfimelinda Nurul Riyadi; Firman Kurniawansyah; Himawan TBM Petrus; Widi Astuti; Achmad Roesyadi
Prosiding Seminar Nasional Sains dan Teknologi Terapan 2020: Memberdayakan Riset dan Inovasi untuk Teknologi yang Berkelanjutan
Publisher : Institut Teknologi Adhi Tama Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar

Indonesia berada pada posisi pertama eksportir rumput laut, Namun pada posisi ke-7 dari sisi harga. Karbohidrat pada rumput laut dihidrolisis dengan katalis asam akan menghasilkan sejumlah monosakarida. Dalam hal ini, katalis berperan penting untuk menghasilkan produk. Memproses dengan katalis asam homogen memiliki beberapa kekurangan, salah satunya ialah sulit dalam proses pemisahan antara katalis dan produk akhir. Oleh karena itu dalam penelitian ini dilakukan dengan menggunakan bantuan katalis heterogen yaitu silika (SiO2). Tujuan penelitian ini adalah untuk mempelajari proses pembuatan sukrosa dan glukosa yang terbentuk dari rumput laut dan mempelajari reaksi proses hidrolisa rumput laut dengan katalis heterogen. Metodologi yang digunakan yaitu hidrolisa untuk pembuatan sukrosa dan glukosa dengan variabel katalis SiO2 komersil sulfonat dan SiO2 geothermal sludge sulfonat. Hasil analisa XRD mendapatkan sudut difraksi pada katalis SiO2 komersil sulfonat bersifat amorf dan katalis SiO2 geothermal sludge (GS) sulfonat bersifat kristal. Glukosa yang dihasilkan pada reaksi hidrolisis katalitik dengan katalis SiO2 komersil sulfonat lebih besar yaitu sebesar 0,0143(b/b) dari variabel katalis yang lain. Dan memiliki kadar sukrosa lebih tinggi sebesar 1,5 %. Sehingga dapat disimpulkan bahwa katalis SiO2 komersil sulfonat merupakan katalis yang menghasilkan glukosa dan kadar sukrosa lebih banyak dibandingkan dengan katalis lainnya.

Hydrocracking of Coconut Oil over Ni-Fe/HZSM-5 Catalyst to Produce Hydrocarbon Biofuel Muhammad Al-Muttaqii; Firman Kurniawansyah; Danawati Hari Prajitno; Achmad Roesyadi
Indonesian Journal of Chemistry Vol 19, No 2 (2019)
Publisher : Universitas Gadjah Mada

This present study was aimed to investigate the hydrocracking of coconut oil using Ni-Fe/HZSM-5 catalyst in a batch reactor at three reaction temperatures (350, 375, and 400 °C). The Ni-Fe/HZSM-5 catalyst was prepared by using incipient wetness impregnation. The Ni-Fe/HZSM-5 catalyst was characterized using XRD, BET, and SEM-EDX. From XRD results, the loading of Ni and Fe did not change the crystalline structure of HZSM-5 catalyst. The surface area of HZSM-5 was 425 m2/g and decreased after the addition of metals (Ni and Fe) into HZSM-5 support. These changes implied that Ni and Fe particles were successfully dispersed on the HZSM-5 surface and incorporated into HZSM-5 pore. The product of hydrocarbon biofuel was analyzed using GC-MS. The GC-MS results of hydrocarbon biofuel showed the highest compounds for n-paraffin and yield for gasoil was 39.24 and 18.4% at a temperature of 400 °C, respectively. The reaction temperature affected the yield and the composition of hydrocarbon biofuel. At this reaction temperature condition, decarboxylation and decarbonylation were favored; lead to the formation of n-alkanes with an odd number of carbon atoms chain length.

Identifikasi Kandungan Boraks dan Formalin pada Makanan dengan Menggunakan Scientific Vs Simple Methods Siti Nurkhamidah; Ali Altway; Sugeng Winardi; Achmad Roesyadi; Yeni Rahmawati; Siti Machmudah; Widiyastuti; Tantular Nurtono; Siti Zullaikah; Lailatul Qadariyah
Sewagati Vol 1 No 1 (2017)
Publisher : Pusat Publikasi ITS

Seiring dengan meningkatnya kebutuhan akan bahan makanan yang tidak mudah rusak, boraks banyak sekali digunakan dalam industri makanan, seperti: dalam pembuatan mie basah, lontong, ketupat, tahu, bakso, sosis, dan lain-lain. Selain boraks, formalin juga banyak digunakan sebagai bahan pengawet makanan. Padahal zat-zat kimia tersebut merupakan bahan beracun dan bahan berbahaya bagi manusia sehingga sangat dilarang digunakan sebagai bahan baku makanan. Oleh karena itu, diperlukan metode identifikasi yang sederhana (simple method) untuk kedua bahan berbahaya tersebut dalam makanan. Sehingga, dapat dilakukan oleh konsumen terutama para ibu rumah tangga dengan mudah. Untuk menguji validitas dari simple method tersebut, maka hasil ujinya perlu dibandingkan dengan scientific method. Hasil uji kandungan boraks pada makanan dengan menggunakan simple method telah dilakukan di Laboratorium dan hasil uji menunjukaan bahwa dari 28 sampel yang di uji, ada dua sample yang positif mengandung boraks. Hasil dari metode nyala api yang merupakan scientific method untuk uji kandungan boraks menunjukkan hasil yang sama dengan hasil uji menggunakan simple method. Sedangkan pada uji formalin, baik menggunakan scientific method menunjukkan hasil bahwa terdapat tujuh sampel yang positif mengandung formalin dari 28 sampel yang diuji dan sebagian besar sampel tersebut merupakan ikan asin. Hasil dari uji tersebut telah disosialisasikan kepada masyarakat sekitar Institut Teknologi Sepuluh Nopember (ITS), yaitu ibu-ibu PKK di Perumahan Sukolilo Dian Regency RT 8 dan 9, RW 2 Kelurahan Keputih Kecamatan Sukolilo Surabaya pada 26 Juni 2016 dan dilakukan sosialisasi kedua pada tanggal 30 Juli 2016 untuk melihat tingkat keberhasilan dan keberlanjutan dari sosialisasi yang pertama.

Hydrocracking of Non-edible Vegetable Oils with Co-Ni/HZSM-5 Catalyst to Gasoil Containing Aromatics Danawati Hari Prajitno; Achmad Roesyadi; Muhammad Al-Muttaqii; Lenny Marlinda
Bulletin of Chemical Reaction Engineering & Catalysis 2017: BCREC Volume 12 Issue 3 Year 2017 (December 2017)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.12.3.799.318-328

Biofuel has been considered as one of the environmentally friendly energy sources to substitute fossil fuel derived from non-edible vegetable oil. This research aims to investigate the effect of the non-edible vegetable oil composition on a specific hydrocarbons distribution contained in biofuel and the aromatics formation through hydrocracking reaction with the Co-Ni/HZSM-5 catalyst. The formation of aromatics from non-edible vegetable oils, such as: Cerbera manghas, rubber seed, and sunan candlenut oils, containing saturated, mono- and polyunsaturated fatty acids is presented. The hydrocracking reaction was carried out in a pressure batch reactor, a reaction temperature of 350 oC for 2 h, reactor pressure of 15 bar after flowing H2 for 1 hour, and a catalyst/oil ratio of 1 g/200 mL. Liquid hydrocarbon product was analyzed by gas chromatography-mass spectrometry. Based on the GC-MS analysis, hydrocracking on three different oils indicated that polyunsaturated fatty acids were required to produce relatively high aromatics content. The sunan candlenut oil can be converted to gasoil range hydrocarbons containing a small amount of aromatic through hydrocracking reaction. Meanwhile, the aromatics in liquid product from hydrocracking of Cerbera manghas and rubber seed oils were not found.

Co-Authors . Widayat A.A. Ketut Agung Cahyawan W Abdul Aziz Adrianto Prihartantyo Agus Budianto Aini, Afrida Nur Aini, Apsari Puspita Airlangga, Bramantyo Al-Muttaqii, Muhammad Ali Altway Anindita Pramesti Putri Nugroho Aparamarta, Hakun Wirawasista Arief Budiman Aushaf, Faishal Danawati Hari Prajitno Darmawan, Raden Delfimelinda Nurul Riyadi Desty Rusdiana Sari Devi, Fatma Putrinta Devita Dian.L Dini Fathmawati Dwi Fitriyanto Fatma Putrinta Devi Fika Anjana Fika Anjana Firman Kurniawansyah Firman Kurniawansyah H Hadiyanto H M Rachimoellah H Satriadi Hafshah Hafshah Hafshah Hafshah Hari Prajitno, Danawati Himawan TBM Petrus Himawan Tri Bayu Murti Petrus Ignatius Gunardi Izza Aliyatul Muna, Izza Aliyatul Jimmy Jimmy Kurniawansyah, Firman Kurniawansyah, Firman Kusno Budhikarjono Kusno Budikarjono Kusno Budikarjono Kusno Budikarjono Kusno Budikarjono Kusuma, Heri Septya Lailatul Qadariyah Lenny Marlinda M. Renardo Prathama Abidin M. Yogi Riyantama Isjoni Mahfud Mahfud Mahfud Mahfud Mahfud Mahfud Marbun, Maja Pranata Mitsuru Sasaki Motonobu Goto Motonobu Goto Muhammad Al Muttaqii Muhammad Al Muttaqii Muhammad Al-Muttaqii Muhammad Al-Muttaqii Muhammad Al-Muttaqii Muhammad Al-Muttaqii Muhammad Rachimoellah Niar Kurnia Julianti Nurjannah Nurjannah Nurjannah Nurjannah Nurkhamidah, Siti Nyoman Puspa Asri Oktarinda Damayanti Pamungkas, Gagas Rachmaniah, Orchidea Rahmaniah Malik Rahmaniah Malik Rahmi Ratna Ediati Renanto Handogo Ricco Aditya S. W Rismawati Rasyid Riyadi, Delfimelinda Nurul Riza Alviany S. Suprapto Santi Dyah Savitri Semuel Pati Senda Semuel Pati Senda Silvy Eka Andansari Siti Machmudah Siti Machmudah Siti Machmudah Siti Machmudah Siti Zullaikah Sri Rachmania Juliastuti, Sri Rachmania Sumarno . Suprapto Suprapto Tantri Kusuma Wardani Tantular Nurtono W. Wahyudiono Wahono Sumaryono Wahyudiono Wahyudiono Widi Astuti Widi Astuti Widiyastuti Widya Rosa Oktaviani Winardi, Sugeng Yazid Bindar Yazid Bindar Yeni Rahmawati, Yeni Yuanita Gustanti Yustia Wulandari Mirzayanti Zulnazri, Z

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