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Journal : Bulletin of Chemical Reaction Engineering

In Search of Magnetic Properties of Samarium Cobalt (Sm2Co17) within a Low-Temperature Sintering Process Poppy Puspitasari; A. Muhammad; A. A. Permanasari; T. Pasang; S. M. S. N. S. Zahari; N. A. Ahmad
Bulletin of Chemical Reaction Engineering & Catalysis 2021: BCREC Volume 16 Issue 3 Year 2021 (September 2021)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.16.3.10482.517-524

Abstract

Samarium cobalt is known as super high density magnetic material with large magnetic anisotropy energy. Samarium–cobalt exhibits manipulative magnetic properties as a rare-earth material which has different properties in a low sintering temperature. It is therefore of paramount importance to investigate samarium cobalt (Sm2Co17) magnetic properties in the low temperature sintering condition. Sm2Co17, which is utilized in this research, is synthesized via the sol–gel process at sintering temperatures of 400, 500, and 600 °C. Subsequently, the crystallites indicate the formation of a single-phase Sm2Co17 on all the samples in all temperature variations. Moreover, the peaks in the X-ray diffraction analysis of crystallite sizes calculated using the Scherrer equation are 17.730, 15.197, and 13.296 nm at 400, 500, and 600 °C. Through scanning electron microscopy, the particles are found to be relatively large and agglomerated, with average sizes of 143.65, 168.78, and 237.26 nm. The functional groups are also analyzed via Fourier-transform infrared spectroscopy, which results in the appearance of several bonds in the samples, for example, alkyl halides, alkanes, and esters with aromatic functional groups on the fingerprint area and alkynes, alkyl halides, and alcohol functional groups at a wavelength of above 1500 cm. The test results of the magnetic properties using vibrating-sample magnetometer (VSM) revealed high coercivity and retentivity in the samples sintered at 400 °C. However, the highest saturation occurs in the samples sintered at 600 ℃. At a low sintering temperature (below 1000 °C), samarium cobalt shows as the soft magnetic material. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Co-Authors A. A. Permanasari Abdillah, Hartawan Abdillah, Hartawan Abdillah Abdul Basit Abdul Basit Achmadin, Wahyu Nur Adi Mulyadi Adi Mulyadi Afandi, M. Bayu Agung Fitrahadi Ahmad Fauzan Ahmad Fauzan Ahmad Iskandar Rahmansyah Ahmad Izzuddin Akbar Anugrah Ikhsani Andi Sanata Andrianata, Mufid Andrie Angga Prasmana Aprillia, Wulan Asrori, Tamam Asrori, Tamam Asrori Audiananti Meganandi Kartini Citra Suardi Dani Hari Tunggal Prasetiyo Dewi Izzatus Tsamroh Dewi, Indah Noor Dwi Kusuma Dini, Joko Sugiono Eka Prasetya Djoko Wahyudi Djoko Wahyudi Djoko Wahyudi Djoko Wahyudi Eva Kurnia Yulyawan Fathuddin Noor, Muhammad GAMMA ADITYA RAHARDI Hartawan Abdillah Helsinky, Mava Nurhaliza Hendra, Joni Hermanto Hermanto Hermanto Hermawan, Nanang Indah Noor Dwi Kusuma Dewi Indah Noor Dwi Kusuma Dewi Indayani, Sulis Dyah Candra Iswardani, Kurnia Isyuniandri, Dzaky Jibril Maulana Joni Hendra Judi , Suharsono Kurniawan, Tri Nanda Indra Linda Kurnia Linda Kurnia Supraptiningsih Luthfi, Nur Ahmad Mas Ahmad Baihaqi Mas Ahmad Baihaqi Mas, Ahmad Baihaqi Mochamad Fani Nur Umri Mochammad Rizky Kurniawan Mufid Andrianata Muhammad Muhammad Zainal Roisul Amin MutindaTeguh Widayanto N. A. Ahmad Nafis, Raihan Nasrul Ilminnafik Nisak, Indani Khoirun Noor, Muhammad Fathuddin Novan Fithrianto Prasetiyo, Dani Hari Tuggal Putri, Salsabillah Widya Eka Putro Adi Pamungkas Rr. Poppy Puspitasari S. M. S. N. S. Zahari Saeful Bakhri Setyawati, Ika Setyo Pambudi Siti Masluha Suharsono, Judi T. Pasang Tamam Asrori Tamam Asrori Trifiananto, Muhammad Triyastutik, Annisa Ayu Wahyu Nur Achmadin Wahyu Nur Achmadin Wahyu Nur Achmadin Winda Ayu Mundari Yazirin, Cepi Yulyawan, Eva Kurnia