Claim Missing Document
Check
Articles

IDENTIFICATION OF PHENOL COMPOUNDS OF LIQUID SMOKE SHELL OIL AT HIGH TEMPERATURE PYROLYSIS Desi Ardilla; Muhammad Tamrin; Basuki Wirjosentono; Eddiyanto ,
AGRIUM: Jurnal Ilmu Pertanian Vol 19, No 3 (2015)
Publisher : UNIVERSITAS MUHAMMADIYAH SUMATERA UTARA

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (389.906 KB) | DOI: 10.30596/agrium.v19i3.389

Abstract

The aim of this study was to determine the content of phenol in the liquid smoke palm kernel shells produced at a temperature 600ᵒC, 700ᵒC, 800ᵒC. Pyrolysis process was carried out by using a furnice that surrounding covered with fire-resistant white cement so that the smoke does not escape into the air and liquid smoke produced more leverage. Temperatures used 600ᵒC, 700ᵒC, 800ᵒC use with condenser-type spiral coil number of turns 30. Liquid smoke produced in deposited for 7 days and in the centrifuge with a rotation speed of 3800 rpm for 60 minutes, filtered and distilled at 125ᵒC temperature for 60 minutes. Liquid smoke analyzed (characterization) using GC-MS and phenol identified for each temperature 600ᵒC is 35.09%, the temperature 700ᵒC is 37.962% and 37.494% temperature 800ᵒC is.Keywords: Liquid Smoke, Phenol compounds, GC-MS
KAJIAN KANDUNGAN SENYAWA PHENOL DAN SENYAWA PAH PADA ASAP CAIR CANGKANG KELAPA SAWIT (ACCKS) REDESTILASI YANG DIHASILKAN PADA TEMPERATUR TINGGI Desi Ardilla; Muhammad Thamrin; Basuki WS; Eddiyanto ,
AGRIUM: Jurnal Ilmu Pertanian Vol 18, No 1 (2013)
Publisher : UNIVERSITAS MUHAMMADIYAH SUMATERA UTARA

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (424.074 KB) | DOI: 10.30596/agrium.v18i1.338

Abstract

Pyrolysis process is carried out in this study using a furnace, the temperature is set ranging from 600,700,800,900 ᵒ C using condenser cooling spiral type. Liquid smoke oil palm shell (ACCKS) produced centrifuge with speed 380 rpm for 30 min, filtered through filter paper and distilled at a temperature of 125 ᵒ C for 20 minutes ACCKS redestilasi analyzed the content of the compound phenol compound and polycyclic aromatic hydrocarbons (PAH) using a GCMS.To temperatures of 600 to 900ᵒC was not identified PAH compounds and the higher the temperature the lower the phenol compounds whereas the higher acetic acid compounds.Keuwords: ACCKS redestilation, phenol content, PAH, quality 
GRAFTING MALEAT ANHIDRAT PADA KARET ALAM SIKLIS (CYCLIC NATURAL RUBBER/CNR) DENGAN INISIATOR DICUMYL PEROKSIDA Eddiyanto ,; M. Said Siregar; Ichlas Rawo Syaputra
AGRIUM: Jurnal Ilmu Pertanian Vol 17, No 2 (2012)
Publisher : UNIVERSITAS MUHAMMADIYAH SUMATERA UTARA

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (464.07 KB) | DOI: 10.30596/agrium.v17i2.310

Abstract

AbstractThe research on the degree of grafting of maleic anhydride (MA) on Cyclic Natural Rubber/CNR with the initiator Dicumyl Peroxide (DCP) has done. Grafting process carried out by reflux in a flask technique coupled with the base of the condenser and oil bath at a temperature of (105-110)°C, variations in the concentration of MA (3, 6, 9, 12, 15) phr, DCP variation inisiator concentration (0.05; 0.1; 0.15) molar ratio and variation in time (15, 30, 60, 90) minutes. Determination of the degree of grafting is then performed by the method of titration and FTIR spectra analysis to determine the grafting of MA on CNR chain. The results showed that the MA-g-CNR occurs at 15 phr comparison with the degree of grafting of 0.12% for the variation of the concentration of MA; 0.15 molar ratio to the degree of grafting of 0.07% for the variation in concentration of DCP inisiatior; 90 minutes with a degree grafting of 0.14% for the time variation.Keywords: grafting, cyclic natural rubber, maleic anhydride, dicumyl peroxide
MODIFIKASI KIMIA KARET ALAM SIKLIS (CYCLIC NATURAL RUBBER/CNR) DENGAN TEKNIK GRAFTING: MENGGUNAKAN MONOMER METIL METAKRILAT DAN INISIATOR BENZOIL PEROKSIDA M. Said Siregar; Muhammad Thamrin; Basuki WS; Eddiyanto ,
AGRIUM: Jurnal Ilmu Pertanian Vol 17, No 3 (2012)
Publisher : UNIVERSITAS MUHAMMADIYAH SUMATERA UTARA

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (125.377 KB) | DOI: 10.30596/agrium.v17i3.316

Abstract

AbstractThe research of grafting methyl methacrylate (MMA) onto Cyclic Natural Rubber (CNR) has been carried out. Benzoyl Peroxide (BPO) was used as a inisiator and temperature condition at 90oC with variation of time 1 and 2 hours. Grafting process was done with technique of reflux in a tree-neck flask  with condenser and oil bath. Spectra analysis FTIR performed for determine the presence of grafted MMA on the backbone of CNR. The results showed that the product CNR-g-MMA was formed with the marked appearance of the absorption peak wave numbers at 1731 and 1730 cm-1 (carbonyl group absorption) typical for carbonyl (C = O) of metal methacrylate. The degree of grafting increased with the increasing time grafting.Keywords: grafting, cyclic natural rubber, mathylmetacrilate, benzoyl peroxide
PENCANGKOKAN METIL METAKRILAT PADA KARET ALAM SIKLIS DENGAN INISIATOR DIKUMIL PEROKSIDA: EFEK KONSENTRASI MONOMER Asmara Sari Nasution; Efi Said; Eddiyanto ,; M. Said Siregar
AGRIUM: Jurnal Ilmu Pertanian Vol 19, No 1 (2014)
Publisher : UNIVERSITAS MUHAMMADIYAH SUMATERA UTARA

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (161.97 KB) | DOI: 10.30596/agrium.v19i1.336

Abstract

The research of grafting methyl methacrylate onto Cyclized Natural Rubber  has been carried out. Dicumyl Peroxide was used as a inisiator and temperature condition at 90oC with variation of time 1 and 2 hours. Grafting process was done with technique of reflux in a tree-neck flask  with condenser and oil bath. Spectra analysis FTIR performed for determine the presence of grafted MMA on the backbone of CNR. The results showed that the product CNR-g-MMA was formed with the marked appearance of the absorption peak wave numbers at 1731 cm-1 (carbonyl group absorption) typical for carbonyl (C = O) of methyl methacrylate. The degree of grafting increased with the increasing time grafting.Keywords: grafting, cyclic natural rubber, mathylmetacrilate, dicumyl peroxide
PENINGKATAN PENDAPATAN MASYARAKAT MISKIN DESA MELALUIIBM BELUT ORGANIK Riski Elpari Siregar; Sempurna Peranginangin; Aida Fitriani Sitompul; Eddiyanto Eddiyanto
JURNAL PENGABDIAN KEPADA MASYARAKAT Vol 20, No 76 (2014)
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/jpkm.v20i76.3456

Abstract

Kegiatan IBM ini bertujuan mengatasi permasalahan masyarakat, dimana selama ini masyarakat desa rambungan I dan II yang selama ini kegiatannya kebanyakan bekerja sebagai buruh bangunan untuk menghidupi keluarganya, sehigga jika pekerjaan tidak ada maka mereka akan sangat kesulitan menghidupi keluaraganya, sehingga timbul ide untuk meningkatkan pendapata masayrakat melalui kegiatan budidaya belut dengan memadapatkan sampah organic untuk media hidup makanan tambahan agar belut dapat tumbuh dan berkembang dengan baik dan panen dengan hasil yang memuaskan. Untuk itu dibuat serangkaian kegiatan untuk meningkatkan pendapatan masyarakat melalui kegiatan pengabdian Iptek Bagi Masyarakat, hasil kegiatan ini adalah masyarakat memelihara belut dan cacing yang berguna untuk makanan belut dan umpan memancing. Namun secara keseluruhan kegiatan ini harus dilanjutkan lagi untuk mencapai tujuan awalnya. Kata kunci : Belut Organik, Masyarakat miskin.
KARAKTERISARI GUGUS FUNGSI DAN BOBOT MOLEKUL KARET MODIFIKASI LIQUID NATURAL RUBBER (LNR) MELALUI DEGRADASI OKSIDATIF FENIL HIDRAZIN/O2 DENGAN PENAMBAHAN EMULSIFIER TRITON-X 100 Eddiyanto Eddiyanto
PROSIDING SEMINAR KIMIA 2020: Prosiding Seminar Nasional Kimia Berwawasan Lingkungan (SNK-BL) 2020
Publisher : PROSIDING SEMINAR KIMIA

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

The research has been done the preparation of chemical modification natural rubber (Liquid Natural Rubber) by using latex high ammonia natural rubber (60 % drc), Triton X-100, phenylhydrazine, and oxygen. High ammonia natural rubber was diluted to 30 % by using 0.3 phr Triton X-100 as emulsifier at room temperature for 12 hours and continued oxidative degradation at 60oC using 1,75 x 10-1 mol phenylhydrazine and oxygen with flowrate 2 l/min for 24 hours until it became arising the decomposition with random cleavages and the macromolecular weight. The product of Liquid Natural Rubber has been result showing the significant infrared absorption with wavenumber 1665 cm-1and the molecular weight by using Ostwald viscosimetry 8.71 x 101 g/mol. Keywords : Chemical modification, Liquid Natural Rubber,Triton X-100, Ostwald viscosimetry.
STUDI SUHU TRANSISI GELAS PRODUK PENCANGKOKAN ANHIDRIDA MALEAT PADA KARET ALAM SIKLIS: METODE DIFFERENTIAL SCANNING CALORIMETRY Muhammad Said siregar; Enisa Cita Mentari; Desi Ardilla; Masura M D; Asmarasari Nasution; Eddiyanto Eddiyanto
JURNAL KIMIA MULAWARMAN Vol 19 No 1 (2021)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/jkm.v19i1.1076

Abstract

Pada penelitian ini dilaporkan perubahan suhu transisi gelas produk pencangkokan anhidrida maleat pada karet alam siklis. Pencangkokan anhidrida maleat pada karet alam siklis dilakukan dalam fase leleh dengan penambahan komonomer divinil benzen di dalam pencampur internal suhu 185oC dan kecepatan rotor 85 rpm. Konsentrasi anhidrida maleat yang digunakan dalam proses pencangkokan adalah 16 phr, tanpa penambahan dan dengan penambahan komonomer divinil benzen dengan variasi: 0,5, 1 dan 2 mol rasio. Produk pencangkokan dikarakterisasi dengan Differential Scanning Calorimetry untuk mempelajari perubahan suhu transisi gelasnya. Berdasarkan analisis dan pengolahan data menggunakan software thermal analysis diperoleh bahwa semakin banyak penambahan komonomer divinil benzene maka suhu transisi gelasnya semakin tinggi, yaitu: 69,46oC, 69,51oC, 70,08oC dan 70,56oC.
Isolasi Squalen Dari Asam Lemak Sawit Distilat (ALSD) Eka Nuryanto; Justaman A Karo Karo; Eddiyanto Eddiyanto; A. Gazali S. Sinaga; Retno Widiastuti
Jurnal Kimia dan Kemasan Vol. 38 No. 2 Oktober 2016
Publisher : Balai Besar Kimia dan Kemasan

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (558.131 KB) | DOI: 10.24817/jkk.v38i2.2674

Abstract

Asam lemak sawit distilat (ALSD) merupakan hasil samping dari pabrik minyak goreng kelapa sawit dan mengandung squalen sekitar 1%. Squalen dapat digunakan sebagai bahan dasar dalam industri kosmetika dan obat-obatan. Pada penelitian ini squalen diperoleh dari saponifikasi ALSD yang dilanjutkan dengan ekstraksi dan pencucian sehingga diperoleh cairan berwarna kuning yang kemudian dianalisis menggunakan gas chromatography (GC) dan Fourier Transform Infra Red (FTIR). Pemurnian cairan ini menggunakan kromatografi kolom dengan fase gerak heksan dan fase diam silika gel tipe 60. Hasil penelitian menunjukkan bahwa karakteristik ALSD adalah kadar air 0,30 %, asam lemak bebas (ALB) 90,56 %, bahan tak tersabunkan 9,03 %, bilangan penyabunan 223,23 mg KOH/g, bilangan peroksida 25,86 mek/Kg. Sementara komposisi asam lemak di dalam ALSD adalah asam laurat (C:12) 0,19 %, asam miristat (C:14) 1,03 %, asam palmitat (C:16) 48,59%, asam stearat (C:18) 3,71 %, asam oleat (C:18:1) 37,74%, asam linoleat (C:18:2) 7,97 %, dan asam linolenat (C:18:3) 0,21 %. Sementara itu kandungan squalen di dalam bahan tak tersabunkan adalah 139.000 ppm. Squalen yang diperoleh masih tidak murni terbukti dengan hasil analisis FTIR munculnya puncak pada bilangan gelombang 1700 cm-1 yang menunjukkan gugus C=O karbonil. Pemurnian dengan kromatografi kolom dapat memurnikan squalen hingga konsentrasi 239.000 ppm. 
Utilization of Glycerol from Used Oil as an Ester Glycerol Surfactant Dian Wardana; Ahmad Ramadhan; Dinda Prihatini Fitri Amne; Eddiyanto Eddiyanto
Indonesian Journal of Chemical Science and Technology (IJCST) Vol 2, No 2 (2019): July 2019
Publisher : Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24114/ijcst.v2i2.13999

Abstract

The development of biodiesel which is currently increasing has helped increase glycerol as a by-product. The glycerol can be obtained from a transesterification reaction in either vegetable or animal oils or fats and even used cooking oil. Glycerol buildup without further processing can reduce the selling price of glycerol. One solution to overcome this is to convert it to surfactants such as glycerol esters which are widely used in various industries such as chemistry, food, cosmetics, medicine and textiles. This study aims to utilize used cooking oil as a source of glycerol used in the synthesis of glycerol ester surfactants, as well as to compare the quality of glycerol ester surfactants produced by the use of commercial glycerol. The process begins by isolating glycerol from used cooking oil and then purifying it to improve its quality. Then glycerol ester was synthesized by using stearic acid, palmitic acid and oleic acid at reaction times of 120, 150 and 180 minutes. The highest yield of ester glycerol produced was at the reaction time of 180 minutes for each use of fatty acids. The test results showed that the glycerol ester produced was able to reduce the surface tension of the water. The value of hydrophylic-lipophylic balance (HLB) is not much different in the range of 5, and the use of various fatty acids and different sources of glycerol results in % of the stability of different emulsions.
Co-Authors ,, Sabani -, Sabani ., Julinawati A. Gazali S. Sinaga Abdullah, Herkules Ahmad Nasir Pulungan Ahmad Ramadhan Ahmad Ramadhan Ahmad Ramadhan Ahmad Ramadhan Aida Fitriani Sitompul Ajat Sudrajat Alkhafi Maas Siregar Ambarita, Graceana Andreas Nababan April Sinaga Ardiansyah Farabi Asmara Sari Nasution Astri Devi Br Pakpahan Ayu Rahmi Ayuandiva, Nabilla Sri Bangun, Prihatni Yoshepine BASUKI WIRJOSENTONO Basuki Wirjosentono Basuki WS Boni Mariska Ratnawati Br Gurusinga, Dinda Natalisa Dea Gracella Siagian Derita Munte, Sitti Darna Desi Ardilla Dian Arsita Fitri Dian Wardana Dian Wardana Dian Wardana Dian Wardana Dinda Prihatini Fitri Amne EFI SAID ALI Eka Nuryanto Enisa Cita Mentari Eva Marito Daulay Fadhilla, Vina Farras, Hammid Al Grecy Kristina Tampubolon Herlinawtati, Herlinawati Ichlas Rawo Syaputra ICHWANA RAMLI Irfandi Irfandi, Irfandi Irwan Harun Isnaini Prihatiningsih J. Sinaga, Zevi Junifa Layla Sihombing Justaman A Karo Karo Karo Karo, Justaman A Khairunisa, Dira Leny Novita Lita Sirait, Agustina Ruth Lukman, Isna Rezkia Maas Siregar, Alkhafi Mahmud Mahmud Manalu, Yuli Santika Manihar Situmorang Marini Damanik Martua Haojahan Saragih Masura M D Masyura M.D Masyura M.D Misril Fuadi Muhammad Said Siregar Muhammad Tamrin Muhammad Thamrin Munthe, Sitti Darna Naainggolan, Bajoka Nainggolan, Mangido Neneng Windayani Noor, Nasruddin M Noor, Nasruddin M. Nurfajriani Nurfajriani Nurfajriani, Nurfajriani Nurhadi Syahputra Nuryanto, Eka Pasaribu, Elfrida Pasaribu, Elfrida Romaito Purwoko, Agus Putri Rosida Rahayu Rahayu Rahayu rahayu Ramlan Silaban Reni Puji Astuti Retno Widiastuti Riska Ritonga Riski Elpari Siregar Rizka Alfi Fadhilah Rizka Fahreza Rizqi Rizaldi Hidayat S. Sinaga, A. Gazali Sabani . Sabani Sabani, Sabani Saharman Gea Saharman Gea Salsabila Afani Saragih, Martua Haojahan Saronom Silaban SARONOM SILABAN Satria Mihardi Saud Salomo Sempurna Peranginangin Serli Wijaya Sipahutar, Rezwan Mulya Taufik Hidayat Tita Juwitaningsih Vina Fadhilla Wardana, Dian Widiastuti, Retno Yaya Rukayadi Yuli Santika Manalu