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PENENTUAN KUANTITATIF MORFIN DALAM URIN SECARA SPEKTROFOTODENSITOMETRI N. M. Suaniti; M. A. Hitapretiwi Suryadhi
Jurnal Kimia (Journal of Chemistry) Vol. 1, No. 2 Juli 2007
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

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Abstract

Quantitative determination of morphine in urine has been done by utilizing spectrophotodensitometry.Morphine standard in methanol 5 g/mL was spotted by linomat between 4-24 L in metal sheet thin layerchromatography spectrophotodensito-metry using morphine standard of 20.40.60.80.100.120. and 140 ng.Methode. statistically and validation analysis, showed a regression line of y = -69.21 + 8.06 x with r =0.992. Detection and quantitation limits of 18.02 ng and 60.06 ng respectively were measured at maximum wavelength of (maks) 287 nm with on recovery of 90.91 percent.
DRAFT GUIDELINE FOR MANUSCRIPT SUBMISSION Ni Made Suaniti
Jurnal Kimia (Journal of Chemistry) Vol. 12 No.1 Januari 2018
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

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ANALISIS 8-ISOPROSTAN DALAM URIN TIKUS JANTAN WISTAR SETELAH TERPAPAR ETANOL DAN ASAP ROKOK Agung Ari Chandra Wibawa; Ni Made Suaniti; Ni Komang Ariati
Jurnal Kimia (Journal of Chemistry) Vol. 8, No. 1 Januari 2014
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (255.263 KB) | DOI: 10.24843/JCHEM.2014.v08.i01.p09

Abstract

The 8-isoprostane compound can be used for a biomarker of oxidative stress  formed by lipid peroxidation in the form of arachidonic acid with free radical in the body. The purpose of this study was to analysis  urinary 8-isoprostane in male Wistar rats after sub-acute exposer to ethanol and cigarette smoke. Extraction method used was solid phase extraction and the analysis was conducted by TLC and spectrophotodensitometry. The results showed that the 8-isoprostane compound was not detected in the male Wistar rat’s urine as control rats and in those exposed to cigarette smoke. The average concentrations of 8-Isoprostane in the male Wistar rat’s urine exposed to ethanol and combination of ethanol-cigarette were 1.519 ± 1,386 and 2.063 ± 1,308 ppm respectively.
PENGARUH SISTEM REKLAMASI AIR LIMBAH TERHADAP KONSENTRASI BOD DAN COD EFFLUENT INSTALASI PENGOLAHAN AIR LIMBAH SUWUNG DENPASAR I D. G. Putra Prabawa; K. G. Dharma Putra; Ni Made Suaniti
Jurnal Kimia (Journal of Chemistry) Vol. 7, No. 2 Juli 2013
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (266.479 KB) | DOI: 10.24843/JCHEM.2013.v07.i02.p13

Abstract

The application of water reclamation system has been researched for the concentration of Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) in the effluent waste water treatment in Suwung Denpasar. The aims of the research were to determine the effect of each stage of water reclamation system on the BOD5 and COD of the effluent, the effectiveness of the water reclamation system and the quality of the reclaimed water. The results showed that each stage of water reclamation system can decrease the concentrations of BOD5 and COD from waste water treated with different percentage of  reduction. The percentages of the COD reduction by first stage (biological filtration systems) were 41.17% and 31.23% respectively BOD5 and COD. The second stage (pre-ozonation system) were 83.13% and 77.68% respectively. Moreover, the third stage (coagulation and membrane systems) reduced 29.25% and 8.02% respectively. The overall rate of effectivenes from the initial to final stages of waste water reclamation were 92,98% for BOD5 and 85,88% for COD.
ANALISIS FATTY ACID ETHYL ESTER PADA RAMBUT MENGGUNAKAN GAS CHROMATOGRAPHY- MASS SPECTROMETRY UNTUK MENDIAGNOSIS PENYALAHGUNAAN ETANOL N. M. Suaniti; I W. Wiratama; I. E. Suprihatin
Jurnal Kimia (Journal of Chemistry) Vol. 14, No. 2 Juli 2020
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24843/JCHEM.2020.v14.i02.p11

Abstract

Fatty acid ethyl ester (FAEE) merupakan salah satu biomarker konsumsi etanol. Penelitian ini bertujuan untuk menganalisis senyawa FAEE dalam sampel rambut secara kualitatif dengan GC-MS. Pada penelitian ini dibuat campuran standar FAEE (Etil Pamlitat dan Etil Oleat) 100 ppm dengan perbandingan 1:1 kemudian dibuat variasi konsentrasi. Metode validasi standar FAEE diukur menggunakan GC-MS. Sampel rambut dipreparasi dengan cara didekontaminasi kemudian diekstraksi dan diinjeksikan ke sistem GC-MS. Hasil validasi diperoleh persamaan regresi linier yaitu, y = 240713,507x-147471,2353 untuk etil palmitat dan y = 58361,45x+242,5 untuk etil oleat dengan nilai koefisien korelasi (r2) berturut-turut sebesar 0,9996 dan 0,9999. Batas deteksi diperoleh sebesar 2,5522 ppm dan 0,0189 ppm, dengan batas kuantitasi sebesar 8,5073 ppm dan 0,0630 ppm. Nilai koefisien variansi diperoleh sebesar 3,59% dan 8,65 x 10-4%, dengan persen perolehan kembali sebesar 100,05% dan 100,08%. Hasil analisis menunjukkan, sampel rambut semua sukarelawan mengandung etil palmitat dan etil oleat pada waktu retensi 22,03 menit dan 23,83 menit. Kata kunci: Fatty acid ethyl esters, Etil Palmitat, Etil Oleat, Alkohol, Etanol, Biomarker, GC-MS
ANALISIS KUALITATIF SENYAWA PARASETAMOL (ACETAMINOPHEN) PADA URIN DAN RAMBUT MENGGUNAKAN KROMATOGRAFI GAS – SPEKTROMETRI MASSA (GC-MS) Komang Ari Gunapria Darmapatni; A. A. Bawa Putra; Ni K. Ariati; Ni M. Suaniti
Jurnal Kimia (Journal of Chemistry) Vol. 8, No. 2 Juli 2014
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (57.54 KB) | DOI: 10.24843/JCHEM.2014.v08.i02.p18

Abstract

Paracetamol (acetaminophen) is one of analgesic-antipyretic drugs which can be commercially obtained. The research aimis to analyze qualitatively the presence of paracetamol (acetaminophen) in urine and human hair by gas chromatography-mass spectrometry (GC-MS). Urine and human hair sample were obtained from patients (volunteers) who consume paracetamol in therapeutic dose without consumption patterns change. Extraction of paracetamol in urine used ethyl acetate and in human hair used methanol. The extract was then derivatized with BSTFA and 1% TMCS and analyzed using gas chromatography-mass spectrometry (GC-MS). The result showed that urine samples after 1, 2, and 3 hours consuming paracetamol contained acetaminophen-TMS. Those after 24, 168, and 720 hours after consuming paracetamol did not contain acetaminophen-TMS.  In human hair, the acetaminophen-TMS was found in samples of 1, 2, 3, 24, 168, and 720 hours after consuming paracetamol.
DETEKSI ETANOL SETELAH KONSUMSI ARAK DALAM URIN DENGAN GAS CHROMATOGRAPHY N. M. Suaniti; I. A. R. Astiti Asih; N. P. Widya Astuti
Jurnal Kimia (Journal of Chemistry) Vol. 6, No. 2 Juli 2012
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

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Abstract

Ethanol is an alcohol which is in particular concentration allowed existing in beverages. One of alcoholic beverages that is popular in Bali is arak. This kind of beverage may contain ethanol in various concentrations depending on the distillation process carried out. The aim of this study was to detect the alcohol contents in urine collected from some volunteer who have consumed arak for two weeks with the technique of Gas Chromatography Flame Ionization Detector (GC-FID). The standard solutions employed were methanol, ethanol and acetic acid, while buthanol was used as the internal standard solution. The urine samples were collected in various sampling times after two weeks arak consumption. The ethanol contents obtained after 4, 8, 12, 16, 28, and 20 hours from the last consumption were (8.86 – 8.98) x 10-2 , (8.06 – 8.46) x 10-2, (8,81 – 8.93) x 10-2, (7.47 – 7.73) x 10-2, (8.76 – 8.89) x 10-2, and (8.15 – 8.27) x 10-2% (b/v), respectively.
BERBAGAI WAKTU PENYIMPANAN SECARA SPEKTROFOTOMETRI UV-VIS Dewa Ayu Ika Pramitha; Ni Made Suaniti; I Wayan Suarsa
Jurnal Kimia (Journal of Chemistry) Vol. 8, No. 1 Januari 2014
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (172.377 KB) | DOI: 10.24843/JCHEM.2014.v08.i01.p10

Abstract

This paper describes the determination of lamivudine content in pulveres by UV-Vis spectrophotometry. The purpose of this study was to determine the stability of lamivudine in various storage times. In this study, the validation of the method of the determination of lamivudine standard was also investigated with the following results: the linear regression equation y = 0.045x - 0.005 with correlation coefficient (r2) of 0.9998. Furthermore the detection limits obtained was of 0.46 µg/mL, quantitation limit of 1.53 µg/mL, the coefficient of variation of 0.23%, accuracy of 3.59%, and the recovery was of 96.41%. The stability of lamivudine in the samples decreased during the observation period i.e. 0, 7, 14, 21, and 28 days, during which the contents of lamivudine obtained were 87.46%, 86.22%, 84.44%; 76, 87%, 79.38%, respectively.
UJI SIFAT VIRGIN COCONUT OIL (VCO) HASIL EKSTRAKSI ENZIMATIS TERHADAP BERBAGAI PRODUK MINYAK KELAPA HASIL PUBLIKASI Ni M. Suaniti; Manuntun Manurung; Nadya Hartasiwi
Jurnal Kimia (Journal of Chemistry) Vol. 8, No. 2 Juli 2014
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (66.729 KB) | DOI: 10.24843/JCHEM.2014.v08.i02.p05

Abstract

A complete mixture of waste unripe peels and leaves derived from papaya (Carica papaya) can be used to obtain enzymatic VCO. Enzymatic VCO has been generated and investigated by several detailed determination. Chemical and physical properties characterization of VCO in this process obtained density then viscosity at temperature 40?C achieved value 909,3 kg/m3 and 26,2094 mm2/s (40?C), whereas physical appearance seen as greenish yellow color, natural fresh coconut scent, free from rancid odor and taste. Iodine value, saponification value, ester value, and % FFA about 5,1601 g Iodine/100 g oil; 271,0596 mg-KOH/g oil; 271,2286 mg-KOH/g oil; 0,1725 %. Degree of VCO purity analyzed by use of TLC separation each for eluent 1 or 2 derived around 0,67 and 0,71, in other experiment standard Rf value for methyl laurate attained 0,74.
KAPASITAS ANTIOKSIDAN DAN KADAR FENOLIK TOTAL DALAM SARI BUAH MENGKUDU TERFERMENTASI Anak Agung Sagung Desy Dwi Martayani Martayani; Ni Made Suaniti; Wahyu Dwijani Sulihingtyas
Jurnal Kimia (Journal of Chemistry) Vol. 11. No.2 Juli 2017
Publisher : Program Studi Kimia, FMIPA, Universitas Udayana (Program of Study in Chemistry, Faculty of Mathematics and Natural Sciences, Udayana University), Bali, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (243.256 KB) | DOI: 10.24843/JCHEM.2017.v11.i02.p02

Abstract

Penelitian ini tentang pengujian kapasitas antioksidan dan kandungan fenolik total sari buah mengkudu terfermentasi dengan penambahan sari jahe dan gula merah. Tujuan penelitian ini adalah untuk menganalisis perubahan kapasitas antioksidan dan kandungan fenolik total dalam sari buah mengkudu sebelum dan setelah difermentasi selama beberapa hari. Kapasitas antioksidan dalam sari buah mengkudu semakin kecil setelah fermentasi yaitu dari 38,10 mgGAE/100 g (sebelum ditambahkan sari jahe, gula merah, tanpa difermentasi) menjadi 30,18; 28,68; dan 23,97 mgGAE/100 g berturut-turut setelah 2, 4, dan 6 hari fermentasi. Penurunan juga terjadi pada kadar fenolik total yaitu dari 54,46 menjadi 45,54; 39,39; dan 34,82 mgGAE/100 g.
Co-Authors A. A. B. Putra A. A. Bawa Putra A. A. I. S. J. Dewi A. A. S. D. Saraswati Abdul Rahim Agung Ari Chandra Wibawa Anak Agung Gede Sudewa Djelantik Anak Agung Istri Agung Mayun Laksmiwati Anak Agung Sagung Desy Dwi Martayani Martayani Ariati, N. K. Ayu Kasmita Dewi Darma Yanti, N. M. D. Dewa Ayu Ika Pramitha Dewi Yuliana Dita Rizkiyanti Dwi Anggraeni Putri Suandi H. Purnomo Hendra Wijaksana I D. G. Putra Prabawa I G. Mustika I G.N.O. Suputra I Gede Budiartawan I GEDE PUTU WIRAWAN I Gusti Ayu Kunti Sri Panca Dewi I Gusti Komang Dwijana I Ketut Budiarta I Ketut Suastika I Ketut Suastika I Made Agus Gelgel Wirasuta I Made Dira Swantara I Made Sudarsana I Nengah Suarnadwipa I Nengah Suweden I Nengah Wirajana I NYOMAN MANTIK ASTAWA I W. Wiratama I Wayan Bandem Adnyana I Wayan Suarsa I. A. R. Astiti Asih I. E. Radiati I. Mahmudi I.P. Widiarta Ida Ayu Okarini Ida Bagus Putra Manuaba Ika Paramitha, Dewa Ayu Iryanti Eka Suprihatin James Sibarani Ketut Gede Dharma Putra Ketut Ratnayani Khairul Mahfuz Komang Ari Gunapria Darmapatni M. M. Manurung M. Manurung M. Sucipta M.Pd S.T. S.Pd. I Gde Wawan Sudatha . Made Ayu Hita Pretiwi Suryadhi Made Suarda Mahardika Aprilia Iflahah Mahardika Aprilia Iflahah Manuntun Manurung Maryana, Himayari Nufus Mirah Surya Dewi, Ni Putu Pande N. G. Indriyaningsih N. P. Widya Astuti N. P. Widya Astuti N. W. Bogoriani Nadya Hartasiwi Ni G. A. M. Dwi Adhi Suastuti Ni Komang Ariati Ni Luh Kasih Ariani Ni Luh Rustini Ni Made Meryana Utari Ni Made Puspawati Ni Made Rai Suarni Ni Made Sukma Sanjiwani Ni Nyoman Nadia Angela Kusuma P. Ni Pt. Pande Mirah Surya Dewi Ni Putu Diantariani Ni Putu Widya Astuti Ni Wayan Sri Sukmarianti Noviyanti, Ni Putu O. Ratnayani O. Ratnayani Oka Ratnayani Oka Ratnayani Oktavia, Fadilla Raisyah Anjani Riyadi, T. Rr. Anisa Hernindya S. A. Sari Sagung Ngurah Mayuni Setianingsih, Ni Luh Putu Putri Turmuzi Tammi Wahyu Dwijani Sulihingtyas Wira Adi Capayanti WIWIK SUSANAH RITA