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TRANSESTERIFIKASI MINYAK DEDAK PADI SECARA IN-SITU DENGAN BANTUAN GELOMBANG MIKRO Rahkadima, Yulia Tri; A’yuni, Qurrota
Journal of Research and Technology Vol 3, No 2 (2017)
Publisher : Universitas Nahdlatul Ulama Sidoarjo

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (238.489 KB) | DOI: 10.5281/zenodo.2581815

Abstract

Rice bran as rice milling waste is very promising to be used as raw material of oil producer such as biodiesel oil. The production process with the assistant of microwaves has been studied in this research. The production process was carried out in-situ where the extraction process of rice bran oil and the biodiesel formation reaction occur simultaneously in microwave radiation. Rice bran was obtained from Lamongan area with IR 64 type. The reaction was carried out in microwaves that had been modified by variation of operating conditions including reaction times (10, 30 and 50 min) and weight ratio of rice bran to methanol (1:4, 1:8, 1:12, 1:16 and 1:20). The results obtained are then analyzed by product yield and free fatty acid content. The optimum condition is obtained when the highest yield of the product with the lowest free fatty acid. The results showed that the optimum condition was obtained at reaction time of 30 minutes with the ratio of rice bran: methanol at 1:12.
ISOLASI FITOSTEROL DARI BAWANG MERAH (Allium cepa L.) Aziz, A. Musonnifin; Syahriyah, Farikha Alfi; Ulumuddin, Ahmad Ihya'; A'yuni, Qurrota
Journal of Research and Technology Vol 5, No 1 (2019)
Publisher : Universitas Nahdlatul Ulama Sidoarjo

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (457.225 KB)

Abstract

Shallot is one of the kitchen spices that is often used by the community. Shallot contains several useful compounds and one of them is phytosterol. Along with the development of science and technology, phytosterol can be used to reduce blood cholesterol levels and prevent heart disease, so it is very beneficial for human health. In this study, phytosterol compounds were identified and isolated. The dried onion is then pureed and sifted to 100 mesh. The sieved powder is then extracted by reflux extraction method within 6 hours. The results of the extract were then isolated by column chromatography and identified by thin layer chromatography (TLC). The TLC test uses -sitosterol as a standard and anisaldehyde reagent as a stain appearance. The TLC plate which had stained appearance was then analyzed using the TLC Scanner method. The results of the TLC test showed that the extract of positive red onion was purple and contained fitosterol. The results of the TLC Scanner also show that the peak and spectrum of the samples are the same as the standard -sitosterol and positively contain fitosterol.
Impregnasi dan Karakterisasi Struktur Padatan Co3O4 pada Pendukung CaF2 Qurrota A’yuni; Irmina Kris Murwani
Jurnal Sains dan Seni ITS Vol 1, No 1 (2012): Jurnal Sains dan Seni ITS (ISSN 2301-928X)
Publisher : Lembaga Penelitian dan Pengabdian Kepada Masyarakat (LPPM), ITS

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (279.298 KB) | DOI: 10.12962/j23373520.v1i1.1432

Abstract

Pada penelitian ini dilakukan sintesis padatan berpendukung Co3O4/CaF2 melalui metode impregnasi dengan variasi loading Co pada CaF2 adalah 2,5; 5; 7,5; 10 dan 15% w/w. Padatan hasil sintesis dikarakterisasi strukturnya menggunakan difraktometer sinar-X (XRD). Struktur padatan CaF2 adalah sistem kubik. Struktur kobalt oksida yang muncul pada difraktogram padatan berpendukung sesuai dengan PDF 01-1152 yaitu Co3O4 heksagonal. Seiring dengan meningkatnya loading Co3O4 pada CaF2 maka intensitas puncak-puncak khas Co3O4 semakin tinggi misalnya pada 2q 36,87°, hal ini merupakan kebalikan dari intensitas CaF2 yang semakin menurun seperti yang terlihat pada 2q 46,97°.
Glycerol Acetylation Using Magnesium Fluoride Catalyst to Produced DAG and TAG Qurrota A’yuni; Syafsir Akhlus; Harsasi Setyawati; Irmina Kris Murwani
IPTEK Journal of Proceedings Series No 4 (2017): 2nd International Seminar on Chemistry 2016
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (734.884 KB) | DOI: 10.12962/j23546026.y2017i4.3076

Abstract

Glycerol acetylation with acetic acid using magnesium fluoride catalyst have been investigated. Magnesium fluoride catalyst was prepared by sol-gel method with ethanol as gelating agent. The glycerol acetylation produced monoacetylglyceride (MAG), diacetylglyceride (DAG) and triacetylglyceride (TAG). The catalytic reaction carried out by thermal methods reflux under ambient conditions. The influence of reaction conditions such as the reaction time on the product distribution was investigated. The optimum of glycerol conversion was achieved at 5 hours of reaction time by 78.34% with selectivity of 30, 62 and 8% for MAG, DAG and TAG respectively. The reaction route over magnesium fluorides was observed by product as reactants, gradually. The results showed that the acetylation reaction of glycerol occurs via a parallel route to the first, followed by the consecutive route to produce DAG and TAG.
PRODUKSI BIODIESEL DARI DEDAK PADI SECARA IN SITU DENGAN TEKNOLOGI MICROWAVE Yulia Tri Rahkadima; Qurrota A'yuni
Jurnal Kimia Riset Vol. 4 No. 2 (2019): Desember
Publisher : Universitas Airlangga

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20473/jkr.v4i2.16047

Abstract

AbstrakProses produksi biodiesel dari dedak padi dengan memanfaatkan microwave secara in situ telah berhasil dilakukan. Pengaruh jumlah metanol dan waktu reaksi terhadap kandungan FAMEs dalam produk dipelajari dalam penelitian ini. Dedak padi , metanol dan katalis basa berupa NaOH 0.6 w% dimasukkan ke dalam labu alas datar dilengkapi dengan kondensor dan dimasukkan ke dalam reaktor microwave yang telah dimodifikasi.  Produk reaksi yang berupa campuran FAMEs, gliserol, reaktan yang tidak bereaksi dan komponen lainnya kemudian dicuci menggunakan n- heksana dan dilanjut dilakukan proses distilasi. Hasil penelitian menunjukan bahwa dengan menggunakan reaktor microwave, kandungan FAMEs lebih tinggi diperoleh dengan waktu reaksi yang lebih singkat. Gelombang mikro berhasil mempercepat terjadinya reaksi transesterifikasi. Kandungan FAMEs tertinggi yaitu 6.2036 % diperoleh pada waktu reaksi 10 menit, metanol 60 ml dan suhu reaksi 60oC.  Kata kunci : Biodiesel, In situ, Microwave, Dedak padi AbstractThe process of biodiesel production from rice bran using in situ microwaves has been successfully carried out. The effect of the amount of methanol and reaction time on the FAMEs content in the product was studied in this study. Rice bran, methanol and alkaline catalyst in the form of 0.6 w% NaOH are put into a flat bottom flask equipped with a condenser and put into a modified microwave reactor. The reaction product in the form of a mixture of FAMEs, glycerol, unreacted reactants and other components is then washed using n-hexane and contuining with the distillation process. The results showed that by using a microwave reactor, a higher FAMEs content was obtained with a shorter reaction time. Microwaves successfully accelerate the transesterification reaction. The highest FAMEs content of 6.2036% was obtained at a reaction time of 10 minutes, methanol 60 ml and reaction temperature 60oC.Keywords: Biodiesel, In situ, Microwave, Rice bran
Penggunaan Pektin Kulit Jeruk Manis (Citrus sinesis) sebagai Absorben untuk Mengurangi Kadar Ion Kromium (VI) pada Sampel Air Sungai Jagir Zjahra Vianita Nugraheni; Wahyu Prasetyo Utomo; Qurrota A'yuni; Nur Azizah Agustina; Januar Kholik; Chandra Puspita
Akta Kimia Indonesia Vol 3, No 1 (2018)
Publisher : LPPM, Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (676.825 KB) | DOI: 10.12962/j25493736.v3i1.3388

Abstract

Telah dilakukan penelitian mengenai kemampuan pektin kulit jeruk manis (Citrus sinensis) sebagai biosorben logam Cr (VI) pada sampel air sungai Jagir. Penelitian ini dilakukan untuk mengetahui daya serap optimum bubuk pektin sebagai biosorben pada logam Cr(VI) menggunakan AAS (Atomic Absorption Spectroscopy). Kadar Cr(VI) pada sampel sungai air Jagir sebesar 0,2532 ppm dengan suhu air 31°C dan pH 6,5. Setelah dilakukan absorbsi  menggunakan biosorben bubuk pektin didapat daya serap untuk penyerapan logam Cr(VI) adalah 98.06% dengan variasi massa pektin sebesar 1,5 gram dan waktu kontak selama  3 jam.
Desain dan Karakteristik Permukaan Kobalt Oksida pada Pendukung Katalis Qurrota A'yuni
Journal of Research and Technology Vol. 3 No. 1 (2017): JRT Volume 3 No 1 Jun 2017
Publisher : 2477 - 6165

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Material surface characteristics are the main criteria to be considered in catalyst design. The surface area and catalyst porosity determine activity and selectivity in catalytic reactions. In this research, synthesis of cobalt oxide, calcium fluoride and calcium fluoride cobalt oxide has been done. Characterization of solid sufaces is analyzed by using Nitrogen Gas Adsorption Method. The surface area of solids is analyzed by using SBET and SBJH Methods. Identification of mesoporous both qualitative and quantitative is analyzed by using BJH Method. The result of synthetic solid shows the pattern of isotherm adsorption type IV which is typical for mesoporous material. Surface measurements show the presence of cobalt oxide on a catalyst support marked by decreasing surface area, pore size and pore volume of catalyst support material.
Pelatihan Pembuatan Hand Sanitizer Menuju Desa Cerdas Kesehatan Di Desa Cangkir, Kecamatan Driyorejo, Kabupaten Gresik Qurrota A'yuni; Alfa Akustia Widati; Harsasi Setyawati; Atik Widiyanti; Purkan Purkan; Miratul Khasanah; Tokok Ardiarto; A. Budi Prasetyo; Aning Purwaningsih; Siti Wafiroh; Sri Sumarsih; Rico Ramadhan; Sofijan Hadi; Kariza Makanty; Ahlan Riwahyu Habibi; Aulianitha Salsabella
Bubungan Tinggi: Jurnal Pengabdian Masyarakat Vol 4, No 2 (2022)
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/btjpm.v4i2.5253

Abstract

Hand sanitizer merupakan cairan atau gel pembersih tangan yang memiliki sifat sebagai antibakteri dalam menghambat hingga membunuh bakteri. Dengan demikian hand sanitizer lebih efektif dalam membasmi kuman. Berdasarkan penelitian The Centers for Disease Control and Prevention (CDC), hand sanitizer dengan kandungan alkohol minimal 60% dapat berfungsi sebagai antibakteri maupun antivirus. Hand sanitizer pernah menjadi barang langka di puncak pandemi pada tahun 2020, karena pembelian yang masif dari masyarakat Indonesia. Langkanya hand sanitizer di beberapa toko dan apotek membuat harganya menjadi mahal. Kegiatan Pengabdian Kepada Masyarakat ini bertujuan untuk meningkatkan pengetahuan akan pentingnya kesehatan dan kemungkinan penyebaran kuman terutama virus dan bakteri serta upaya untuk mengantisipasinya. Tujuan yang lain yaitu untuk meningkatkan keterampilan masyarakat dalam pembuatan hand sanitizer. Rangkaian kegiatan ini diselenggarakan di Desa Cangkir, Kecamatan Driyorejo, Kabupaten Gresik pada Bulan November-Desember 2021 secara luring dengan menerapkan protokol kesehatan dengan peserta Ibu-Ibu PKK dan Kader PKK. Kegiatan ini dilakukan melalui metode pendampingan dan demonstrasi dengan presentasi materi dan praktik langsung. Kegiatan ini memberikan dampak yang positif bagi masyarakat Desa Cangkir dalam menghadapi Pandemi Covid-19 saat ini. Hand sanitizer is a liquid or gel that has antibacterial properties to inhibit and kill bacteria. Thus, hand sanitizer is more effective in eradicating germs. Based on research from The Centers for Disease Control and Prevention (CDC), alcohol-based hand sanitizers that contain at least 60% alcohol can function as both antibacterial and antivirus. Hand sanitizer was once a scarce item at the height of the pandemic in 2020, due to massive purchases from the Indonesian people. The scarcity of hand sanitizers in some shops and pharmacies makes the price expensive. This Community Service activity aims to increase knowledge of the importance of health and the possibility of spreading germs, especially viruses and bacteria, and efforts to anticipate them. Another aim is to improve community skills in making hand sanitizers. This series of activities were held in Cangkir Village, Driyorejo District, Gresik Regency in November-December 2021 via offline by implementing health protocols with PKK women and PKK Cadres as participants. This activity is carried out through mentoring and demonstration methods with presentations and hands-on practice. This activity has a positive impact on the Cangkir Village community in dealing with the current Covid-19 Pandemic. 
EDUKASI PEMANFAATAN BAHAN ALAM SEBAGAI OBAT TRADISIONAL UNTUK PENCEGAHAN PENYAKIT DAN PERAWATAN KESEHATAN Fatiha Khairunnisa; Qurrota A’yuni; Kautsar Ul Haq; Harsasi Setyawati; Ahmadi Jaya Permana; Rico Ramadhan; Yanuardi Raharjo; Mulyadi Tanjung; Sri Sumarsih; Hartati; Handoko Darmokoesoemo
Jurnal ABDI: Media Pengabdian Kepada Masyarakat Vol. 8 No. 1 (2022): Vol.8, No.1(2022)
Publisher : Universitas Negeri Surabaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26740/abdi.v8i1.15268

Abstract

One of the ways to maintain the personal health during an emergency condition as the current COVID-19 is the utilization of natural ingredients. It can be processed into traditional medicines. Jamu as a type of traditional medicine as well as natural heritage has been widely used by Indonesian to prevent the body from disease and to treat the health issue. This community service aimed to provide education for society regarding the chemical content and efficacy of natural ingredients such as empon-empon. The techniques to process it into traditional medicine for family healthcare was also delivered. The activity was carried out through face-to-face meeting while still applying the health protocols. The level of success and usefulness of the activity was known from the response of the participants. In general, the PKM activities in the scheme of theory and practical session has been carried out well. The materials presented in theory session was understandable. Meanwhile, the techniques used in practical session was easy to be replicated. The activity was expected to increase the knowledge and skills of the society in terms of natural ingredients that have good chemical content and the techniques to process them into nutritious drinks for families.
Peningkatan Kesehatan Masyarakat melalui Edukasi Pemanfaatan Tanaman Obat di Pondok Pesantren An-Nidhomiyah Ngelom Sidoarjo Qurrota A'yuni; Fatiha Khairunnisa; Kautsar Ul Haq; Yanuardi Raharjo; Mulyadi Tanjung; Pratiwi Pudjiastuti; Purkan Purkan; A. Budi Prasetyo; Sofijan Hadi; Hamizah Haula'; Diana Merna; Eksan Ar Rasyid
Bubungan Tinggi: Jurnal Pengabdian Masyarakat Vol 5, No 1 (2023)
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/btjpm.v5i1.7115

Abstract

Tanaman obat merupakan jenis tanaman yang memiliki khasiat sebagai obat serta dapat dimanfaatkan sebagai bahan pembuatan obat tradisional yaitu jamu untuk membantu masyarakat dalam pemeliharaan kesehatan, pencegahan penyakit dan perawatan kesehatan terutama di era new normal dan post-pandemi Covid-19. Beberapa khasiat dari obat tradisional yang umumnya dimanfaatkan masyarakat antara lain meringankan gejala flu, batuk, sakit tenggorokan, sakit kepala, nyeri haid, dan lain-lain. Tanaman obat dapat dibudidayakan di lingkungan sekitar tempat tinggal seperti rumah atau pondok pesantren. Kegiatan pengabdian kepada masyarakat (PkM) ini bertujuan untuk memberikan edukasi publik khususnya di lingkungan pondok pesantren mengenai manfaat tanaman obat sebagai upaya untuk meningkatkan pengetahuan, keterampilan, dan kesehatan masyarakat. Rangkaian kegiatan ini diselenggarakan di Pondok Pesantren An-Nidhomiyah pada Bulan Juli 2022. Kegiatan ini diselenggarakan secara luring dengan tetap memenuhi protokol kesehatan. Peserta kegiatan ini yaitu santri putra dan putri pondok pesantren An-Nidhomiyah yang berjumlah 30 peserta. Kegiatan ini dilakukan melalui metode pendampingan dan workshop dengan pemaparan materi, praktik pembuatan obat tradisional, dan penanaman tanaman obat di halaman pondok. Kegiatan ini mendapatkan antusiasme yang besar dari peserta. Hasil survei kepuasan peserta menunjukkan trendline sebesar 87% yang termasuk dalam kategori sangat memuaskan untuk semua aspek, yang berarti sebagian besar peserta sangat puas terhadap kegiatan PkM ini, baik dari segi materi, metode, narasumber, hingga fasilitas yang diberikan. Medicinal plants are plants that have efficacy for medicinal and can be used as ingredients for making traditional medicines, namely herbs, to help the community in health care, disease prevention, and health care, especially in the new normal era and the post-pandemic Covid-19. Some of the benefits of traditional medicine commonly used by the community include relieving symptoms of flu, cough, sore throat, headache, menstrual pain, and others. Medicinal plants can be cultivated around the residence, such as in houses or Islamic boarding schools. This community service activity aims to provide public education, especially in Islamic boarding schools, about the benefits of medicinal plants to improve knowledge, skills, and public health. This activity was held at the An-Nidhomiyah Islamic Boarding School in July 2022. This activity was held offline by implementing health protocols. The participants of this activity were students of the An-Nidhomiyah Islamic boarding school, totaling 30 participants. The activity is carried out through mentoring and workshop methods, including presentations, traditional medicine production practices, and planting medicinal plants in the boarding school yard. This activity received great enthusiasm from the participants. The participant satisfaction survey results show a trendline of 87%, which is included in the very satisfied category for all aspects, which means that most of the participants were very satisfied with this PkM activity in terms of topics, methods, speakers, and facilities provided.