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Journal : International Journal of Engineering, Science and Information Technology

Synthesis of Cellulose Stearate Ester as Wet Strength Agent for Synthesis of Bio-polybag from Oil Palm Empty Fruit Bunch Kurniawan, Eddy; Mulyawan, Rizka; Tri Agusna PA, Angga; Armadani, Wika; Ginting, Zainuddin
International Journal of Engineering, Science and Information Technology Vol 2, No 2 (2022)
Publisher : Department of Information Technology, Universitas Malikussaleh, Aceh Utara, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (752.502 KB) | DOI: 10.52088/ijesty.v2i2.227

Abstract

Biodegradable polybags are an alternative to overcome the weakness of synthetic polybags because of their degradation properties. Oil palm empty fruit bunches contain a lot of cellulose so that they can be used as a biodegradable polybag. Wet Strength serves to increase the physical strength of bio-polybags when exposed to water (in wet conditions) so that water content stability is required. In this study, Cellulose Stearate Esters were synthesized in an effort to increase the stability of the water content in bio-polybags. Cellulose Stearate Esters are synthesized through a transesterification reaction between -Cellulose isolated from Oil Palm Empty Fruit Bunches (EFB) with methyl stearate. The synthesis of cellulose stearate esters was carried out by refluxing for 2 hours using methanol solvent with various catalysts Na2CO3 5, 10, 15, 20 mg and with volume variations of methyl stearate 5, 10, 15. And the best variation was determined based on the degree of substitution test, namely with variations Na2CO3 catalyst 20 mg and volume of methyl Stearate 15 ml, amounting to 1.95. The result of the synthesis, namely cellulose stearate, was tested for functional groups by FT-IR spectroscopy and surface morphology using SEM. The formation of cellulose stearate is supported by the FT-IR spectrum in the wavenumber region of 3468.01 cm-1 indicating an OH group, 3062.96 cm-1 indicating a CH stretching group, 1695.43 cm-1 indicating a C=O group, cm-1 indicating a CH bending group, 1095.57cm-1 indicates a COC group, 609.51cm-1 indicates a (CH2)n4 group. The results of surface morphology analysis using SEM showed that the surface of cellulose stearate looked homogeneous, more regular and had denser cavities than -Cellulose
Compositional Engineering of Chitosan–Potato Starch–Kaolin Biocomposites: Tuning Physicochemical Properties for Wound Dressing Applications Suryati, Suryati; Mulyawan, Rizka; Meriatna, Meriatna; Khairunnisa, Cut; Maulinda, Leni; Hasfita, Fikri
International Journal of Engineering, Science and Information Technology Vol 5, No 3 (2025)
Publisher : Malikussaleh University, Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.52088/ijesty.v5i3.1001

Abstract

An investigation has been made to predict the effects of various Kaolin fillers with different concentrations from 4 to 10 percent on the properties of Chitosan and Potato Starch Bio-composite for wound dressing applications. The procedure was to prepare the chitosan and starch in equal proportions, apply the filler to the hydrogel, dry it, and characterize it. The characterizations of the synthesized bio-composite were its absorption percentage, mechanical test, presented functional groups, and antibacterial test. It was found out that the bio-composite with the highest swelling percentage 6% Kaolin, showed 128.65% swelling. Moreover, the highest percentage of bio-composite absorption was 65.62% with 8% Kaolin added. In addition to that, adding 4% Kaolin produced the highest tensile strength with the value of 75.6 MPa. Besides, the most significant elongation percentage was 151.60% in the addition of 4% Kaolin. Qualitatively, the synthesized bio-composites exhibited functional groups of OH, alkynes, and carboxylic acid. Finally, the bio-composite with Kaolin filler significantly performed in antibacterial activities.