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Rahayu, Aster
Ahmad Dahlan University
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The Utilization and Extraction Method of Nanocellulose: A Review Farrah Fadhillah Hanum; Aster Rahayu; Nafira Alfi Zaini Amrillah; Yoga Nawaki Helmi Mustafa
JURNAL SAINS NATURAL Vol. 13 No. 3 (2023): Sains Natural
Publisher : Universitas Nusa Bangsa

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31938/jsn.v13i3.565

Abstract

Currently, the use of nanocellulose is very broad in various fields, such as pharmaceuticals, cosmetics, and electronics industries. In its development, this nano-sized cellulose is widely used as a reinforcement nanocomposite nanofiller. Nanocellulose has several advantages, including its large surface area, very lightweight, easy to shape, ability to break through the performance limits of conventional materials, and having a high economic value. Nanotechnology develops based on new properties produced by nanomaterials as advanced materials. Therefore, the factor of the extraction process method must be considered to produce nanocellulose that has good quality and large quantity. Nanocellulose extraction can be accomplished in a variety of ways depending on the raw material but is generally done through a combination of chemical, mechanical, and biological treatments.
Combustion Quality Analysis of Bio-Briquettes from Mixture of Coconut Shell Waste and Coal with Tapioca Flour Adhesive Dhias Cahya Hakika; Siti Jamilatun; Shafa Zahira; Riska Setyarini; Aster Rahayu; Remmo Sri Ardiansyah
Indonesian Journal of Chemical Engineering Vol. 1 No. 1 (2023): Indonesian Journal of Chemical Engineering
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26555/ijce.v1i1.452

Abstract

Agroindustry residues can be utilized as a resource for alternative energy sources such as bio-briquettes. Using agro-industry residue is also a solution to reduce pollution caused by biomass waste in the environment. This article highlights the combustion quality analysis of biomass waste in the form of bio-briquettes with binding materials prepared from tapioca flour. The biomass used is a mixture of coconut shell charcoal and coal to improve the quality of the bio-briquettes. In this study, bio-briquettes were manufactured using a screw press system. The combustion quality of bio-briquettes with various percentage compositions (0:100, 25:75, 50:50, 75:25, 100:0) of coconut shell charcoal and coal was investigated, i.e., moisture content, ash content, combustion rate, and calorific value. Results show that the calorific value of most bio-briquettes produced in this study was higher than the standard calorific value according to  SNI Standard No.1/6235/2000 (≥ 5,000 cal/gr). The optimum composition to produce bio-briquette with good quality based on the standard is 75:25 (coconut shell charcoal: coal), which had a moisture content of 7.6325%, ash content of 6.9697%, combustion rate of 0.1833 gr/min, and caloric value of 5833.78 cal/gr.
Removal of Ion Nitrate and Phosphate Using Cocoa Shell Skin Modified With Functional Polymer Aster Rahayu; Nafira Alfi Zaini Amrillah; Nuraini Nuraini; Veranica Veranica; Siti Jamilatun
Elkawnie: Journal of Islamic Science and Technology Vol 9, No 2 (2023)
Publisher : Universitas Islam Negeri Ar-Raniry Banda Aceh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22373/ekw.v9i2.18260

Abstract

Abstract: Cocoa is a plant that is widely cultivated in Indonesia, one of which is in the Yogyakarta area. On the outside of the cocoa fruit, it is known as the cocoa shell skin. Cocoa shell skin is an agricultural waste that is a simple, cheap, and environmentally friendly development that is used as an adsorbent for nitrate and phosphate removal. This article discusses the observation of the ability of the cacao shell against ion nitrate and phosphate adsorption and then compares it after being modified with a functional polymer. Modification of the surface of cacao shell skin with 2-[(methacryloyloxy)ethyl]trimethylammonium chloride (META) resulted in an improvement; the percentages of removal of ion nitrate and phosphate were 89.67% and 92%, respectively. In addition, this study compared the characterization of materials resulting from the absorption of Cocoa Shell Skin (CH) and Cocoa Shell Skin Modified META (CH-META) for nitrate and phosphate ions using Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). The modification with META could improve the C-N group and N-H groups on the surface of cacao shell skin. Abstrak: Kakao merupakan tanaman yang banyak dibudidayakan di Indonesia salah satunya di daerah Yogyakarta. Bagian luar buah kakao dikenal dengan kulit cangkang kakao. Kulit cangkang kakao merupakan limbah pertanian yang merupakan pengembangan sederhana yang murah dan ramah lingkungan serta digunakan sebagai adsorben penyerap nitrat dan fosfat. Artikel ini membahas tentang observasi kemampuan kulit cangkang kakao terhadap adsorpsi ion nitrat dan fosfat kemudian adanya perbandingan dengan cangkang cacao setelah dilakukan modifikasi dengan polimer fungsional. Modifikasi permukaan kulit cangkang kakao dengan META menghasilkan peningkatan persentase penyerapan ion nitrat dan fosfat masing-masing sebesar 89,67% dan 92%. Selain itu, penelitian ini membandingkan karakterisasi bahan hasil penyerapan Cocoa Shell Skin (CH) dan Cocoa Shell Skin – Modifikasi META (CH-META) untuk ion nitrat dan fosfat menggunakan Fourier-Transform Infrared (FTIR) dan Scanning Electron Microscopy (SEM). Modifikasi dengan META dapat meningkatkan gugus C-N dan gugus N-H pada permukaan kulit cangkang kakao.
Application of Cellulose Acetate Propionate Biopolymer Membrane in The Treatment of Textile Wastewater Containing Remazol Dye Amilia, Amilia; Maryudi, Maryudi; Rahayu, Aster; Hakika, Dhias Cahya; Suradi, Siti Samahani
Jurnal Bahan Alam Terbarukan Vol 13, No 1 (2024): June 2024 [Nationally Accredited Sinta 2]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v13i1.50294

Abstract

Textile liquid waste is pollution resulted from textile industry activities that often produce hazardous and toxic materials. Therefore, appropriate processing techniques are needed. There are many processing methods that can be used in treating this textile liquid waste, one of which is using membrane technology with phase inversion techniques. Membrane technology has advantages over other processing methods such as, being biopolymeric, relatively lower energy consumption, does not use chemicals in the processing process, and does not cause new waste in the processing process.  In this study, 3 variations of cellulose acetate propionate (CAP) concentration were carried out in the manufacture of membranes including, 13% CAP; 14% CAP; and 15% CAP. Membranes that have been made are then carried out several analyses, namely porosity analysis; flux analysis; rejection analysis; and color concentration reduction analysis. The results in this study found that the highest porosity value, rejection value and flux value were found in the CAP membrane with a concentration of 13%.  The CAP membrane has the best rejection value on reducing the remazol concentration of 43% with a membrane of 13% CAP.
Combustion Quality Analysis of Bio-Briquettes from Mixture of Coconut Shell Waste and Coal with Tapioca Flour Adhesive Hakika, Dhias Cahya; Jamilatun, Siti; Zahira, Shafa; Setyarini , Riska; Rahayu, Aster; Sri Ardiansyah, Remmo
Indonesian Journal of Chemical Engineering Vol. 1 No. 1 (2023)
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26555/ijce.v1i1.452

Abstract

Agroindustry residues can be utilized as a resource for alternative energy sources such as bio-briquettes. Using agro-industry residue is also a solution to reduce pollution caused by biomass waste in the environment. This article highlights the combustion quality analysis of biomass waste in the form of bio-briquettes with binding materials prepared from tapioca flour. The biomass used is a mixture of coconut shell charcoal and coal to improve the quality of the bio-briquettes. In this study, bio-briquettes were manufactured using a screw press system. The combustion quality of bio-briquettes with various percentage compositions (0:100, 25:75, 50:50, 75:25, 100:0) of coconut shell charcoal and coal was investigated, i.e., moisture content, ash content, combustion rate, and calorific value. Results show that the calorific value of most bio-briquettes produced in this study was higher than the standard calorific value according to  SNI Standard No.1/6235/2000 (≥ 5,000 cal/gr). The optimum composition to produce bio-briquette with good quality based on the standard is 75:25 (coconut shell charcoal: coal), which had a moisture content of 7.6325%, ash content of 6.9697%, combustion rate of 0.1833 gr/min, and caloric value of 5833.78 cal/gr.
Heavy Metal Phytoremediation: Plant Hyperaccumulators and Clean Strategies for the Environment Nurmustaqimah; Jamilatun, Siti; Rahayu, Aster; Hakika, Dhias Cahya; Muthadin , Akhmad Sabilal; Taufiqurahman , Muhamad Akmal
Indonesian Journal of Chemical Engineering Vol. 2 No. 1 (2024)
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26555/ijce.v2i1.672

Abstract

Increasing urbanization and industrialization have led to serious heavy metal pollution problems, detrimental to the environment and human health. Phytoremediation, which utilizes hyperaccumulator plants such as Indian mustard and water hyacinth, presents an efficient and sustainable alternative. Despite having the advantages of low cost and utilization of renewable natural resources, phytoremediation also carries risks, such as contamination of consumable plant parts and limited efficiency. Therefore, selecting the right hyperaccumulator plants and having an in-depth understanding of phytoremediation mechanisms are the keys to increasing their success. Phytoremediation mechanisms, such as phytoextraction, hemofiltration, and phytostabilization, can be implemented by considering environmental conditions and contaminants. Factors such as the nature of the medium, root zone, and environmental conditions play a crucial role in determining the effectiveness of phytoremediation. Although challenges still exist, phytoremediation remains a promising approach to treating heavy metal pollution in an economical and environmentally friendly manner.
Study of Ethylene 1-Hexene Addition on Elongation, Tensile Strength and Cling Values of Stretch Wrap Plastics Helmi Mustafa, Yoga Nawaki; Hanum, Farrah Fadhillah; Rahayu, Aster; Febriani, Annisa Vada
Indonesian Journal of Chemical Engineering Vol. 2 No. 1 (2024)
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26555/ijce.v2i1.693

Abstract

Stretch wrap plastic is a very important packaging material on a variety of scales. It provides flexibility, strength, and transparency that make it indispensable for packaging goods efficiently. This research aims to investigate the effect of stretch wrap plastic thickness on its mechanical properties and analyze the impact of ethylene 1-hexene addition on these properties. The research was conducted using stretch wrap plastic samples made from linear low-density polyethylene (LLDPE) with varying thickness and percentage of ethylene 1-hexene addition. The test method involved elongation, tensile strength, and cling testing using a Universal Testing Machine (UTM). The results showed that the thickness of stretch wrap plastic affects its mechanical properties. The thicker the plastic, the higher the elongation and tensile strength values, while the stickiness tends to decrease.  The optimal thickness of stretch wrap plastic is 20 µm. The addition of ethylene 1-hexene also has a positive effect on the elongation and tensile strength properties, with the optimal percentage of addition at 55% with respect to components such as density and melt index
A Review: Analysis Atomic Absorption Spectrometry (AAS) of Heavy Metal Content in Crude Palm Oil Veranica; Rahayu, Aster; Maryudi; Lim , Lee Wah; Anggresani, Lia
Indonesian Journal of Chemical Engineering Vol. 2 No. 1 (2024)
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26555/ijce.v2i1.694

Abstract

Indonesia, the world's largest producer of crude palm oil (CPO), turns its oil through a series of refinement processes that include degumming, bleaching, and deodorization before it is used as cooking oil. Still, heavy metals are the main focus of CPO research. Elements known as heavy metals can have harmful effects on the human body, even in small doses. Making sure the amount of metal in CPO doesn't go over the limit is crucial. To find out how much this ingredient contributes to the heavy metal contamination in crude palm oil, more research is required. The CPO refining process is carried out with the aim of reducing free fatty acids and removing dirt or metals dissolved in CPO, which can affect the quality of cooking oil. AAS can detect metals in small amounts and provide analytical differences of up to 0.006 mg/kg.
Review: Biomassa Sebagai Adsorbent untuk Pengolahan Logam Berat Pada Air Limbah Industri Veranica, Veranica; Rahayu, Aster; Maryudi, Maryudi
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2023: PROSIDING SNTKK 2023
Publisher : Seminar Nasional Teknik Kimia "Kejuangan"

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Industrial wastewater generally contains heavy metalssuch as lead, cadmium, arsenic, nickel, chromium and mercury. Contamination of water with these elements is very dangerous and will pollute the environment, so a suitable waste water treatment is required. This review aims to find out the efficient methods of handling industrial wastewater and the benefits of biomass. Many scientific methods are used in this regard, including adsorption, chemical precipitation, ion exchange, electrochemical treatment, membrane filtration, coagulation and flocculation. However, some of these techniques have drawbacks such aswill produce a large amount of metal sludge, making it difficult to recycle metal, and the formation of toxic sludge or other wastes. Of all these techniques, adsorption with adsorbent biomasshas been widely known because it is an economical, effective and environmentally friendly processing technique, so this method is suitable for treating industrial wastewater. The use of biomass as an adsorbent is intendedto help reduce dependence on fossil raw materials and greenhouse gas emissions that contribute to climate change.
The Comparison Effects of NaOH and KOH as Solvents for Silica Extraction from Two Different Coal Fly Ashes Hanum, Farrah Fadhillah; Rahayu, Aster; Hapsauqi, Iqbal
Indonesian Journal of Chemical Research Vol 10 No 1 (2022): Edition for May 2022
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2022.10-far

Abstract

One of the environmental problems is the waste from the coal combustion process from coal power plants or other industries that use coal as an energy source. The combustion process produces coal fly ash, which will accumulate in the environment. Subsequently, much research about the utilization of coal fly ash has been developed. Silica extraction from coal fly ash is one of the methods that can be used to utilize coal fly ash. This study carried out silica extraction using the Direct Alkaline Leaching (DAL) method. The coal ash was contacted with alkaline solvents (KOH and NaOH) with the variations of concentrations and the leaching time. The leaching solution filtrate will be precipitated with the addition of HCl. The characteristics of this silica from CFA and CFA B were analyzed by using Scanning Electron Microscopy (SEM). Based on the results, it could be known that each of the coal fly ashes has different results for both alkaline solvents. CFA A has relatively less silica extraction results in both types of solvents. Meanwhile, CFA B gave higher silica extraction results with coal fly ash and solvent contact time for one hour.
Co-Authors Agus Aktawan, Agus Alliya BalqisViratu Hapsari Althaf Irfan Fachrezy Amelia, Shinta Amilia Amilia, Amilia Amillia, Amillia Amrillah, Nafira Alfi Zaini Areeprasert, Chinnathan Awaluddin Nurmiyanto, Awaluddin BalqisViratu Hapsari, Alliya Chusna, Firda Mahira Alfiata Dewi Wulandari, S.Hut., M.Agr., Ph.D Dhias Cahya Hakika Dhias Cahya Hakika Dhias Cahya Hakika Dita Permata Putri Endah Sulistiawati Erna Astuti Fajri, Joni Aldilla Farah Fadillah Hanum Farrah Fadhillah Hanum Farrah Fadhillah Hanum Febriani, Annisa Vada Firda Mahira Alfiata Chusna Hanum, Farrah Fadhillah Hapsauqi, Iqbal Helmi Mustafa, Yoga Nawaki Ikko Nirwana Luthfiani Imam Santosa Irwan Mulyadi Jamilatun, Siti Jamilatun Joko Pitoyo Joni Aldilla Fajri Lee Wah Lim Lee Wah Lim Lee Wah Lim Lia Anggresani Lim , Lee Wah Lindi Juliantri Lukman Hakim Marlena, Yuni Maryudi Maryudi Maryudi Maryudi - Maryudi Maryudi Maryudi Maryudi Maryudi Mohammed, Hamad Khudhair Muhammad Kresna Islami Muhammad Kresna Islami Muhammad Kunta Biddinika Mulyadi, Irwan Muthadin , Akhmad Sabilal Nafira Alfi Zaini Amrillah Nafira Alfi Zaini Amrillah Ningsih, Devi Yogi Noviana Nuraini Nuraini Nuraini Nuraini Nuraini Nuraini Nuraini Nurmustaqimah Nurmustaqimah, Nurmustaqimah NURUL WULANDARI Rahma Yunita Amalia Refah Syauqi Refah Syauqi Remmo Sri Ardiansyah Riska Setyarini Ryan Sutedja S. Salamah Sari, Hutri Puspita Sartika Selang Setya Wardhana, Budi Setyarini , Riska Shafa Zahira Shinta Amelia Siti Jamilatun Siti Salamah Siti Salamah Soedjatmiko Sri Ardiansyah, Remmo Suradi, Siti Samahani Taufiqurahman , Muhamad Akmal Toyohide Takeuchi Ulung Muhammad Sutopo Ummi Khasanah Veranica Veranica Veranica Veranica Veranica, Veranica Vivi Sisca Winda Dwi Anggraini Yoga Nawaki Helmi Mustafa Zahira, Shafa Zahrul Mufrodi, Zahrul