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PENGARUH SUHU AKTIVASI CO2 TERHADAP KAPASITANSI SPESIFIK ELEKTRODA KARBON SUPERKAPASITOR DARI TANDAN KOSONG KELAPA SAWIT E. Taer; W.S. Mustika; R. Taslim
PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) Vol 5 (2016): PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) SNF2016
Publisher : Program Studi Pendidikan Fisika dan Program Studi Fisika Universitas Negeri Jakarta, LPPM Universitas Negeri Jakarta, HFI Jakarta, HFI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (526.484 KB) | DOI: 10.21009/0305020209

Abstract

Effect of CO2 activation temperature in production of carbon electrode supercapacitor against specific capacitance has been investigated and analyzed. Carbon electrodes in this study were produced from oil palm empty fruit bunches (EFB) waste derived from people's plantations. The electrodes production were begun with cutting the cob into small flake of EFB into 5 cm length, followed by a milling process, chemical activation used a 0.3 M KOH, hydraulic pressing and followed by carbonization process at a temperature of 800 oC. The physical activation was carried out at a temperature of 800, 850, and 900 oC in CO2 gas environment. Specific capacitance was determined by cyclic voltammetry method and its found to be as high as 39.77 Fg-1, 65.84 Fg-1, 45.06 Fg-1, 41.30 Fg-1 for activation temperature of 0, 800, 850, and 900 oC, respectively . The results showed that the temperature of 800 oC was the best activation temperature in production of carbon electrodes from EFB. In addition, also calculated physical properties such as mass, thickness, and diameter were measured to determine the density of the electrode. The density of each electrode for temperature activation of 0, 800, 850, and 900 oC were 2.664 g cm-3, 1.891 g cm-3, 2.045 g cm-3, 2.131 g cm-3, respectively. As a complement, the electrode structure has also analyzed by using X-Ray Difraction method. Keywords : activated carbon , oil palm empty fruit bunches , activation of CO2 , supercapacitor.
PENGARUH JENIS AKTIVATOR KIMIA TERHADAP DENSITAS DAN KAPASITANSI SPESIFIK ELEKTRODA KARBON AKTIF DARI SERBUK GERGAJI KAYU KARET E. Taer; A. Ira; Sugianto Sugianto; R. Taslim
PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) Vol 5 (2016): PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) SNF2016
Publisher : Program Studi Pendidikan Fisika dan Program Studi Fisika Universitas Negeri Jakarta, LPPM Universitas Negeri Jakarta, HFI Jakarta, HFI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (591.079 KB) | DOI: 10.21009/0305020215

Abstract

Supercapacitor electrodes from rubber wood sawdust based on various of chemichal activation agent of KOH, NaOH and ZnCl2 by a concentration of 0.4 M has been analyzed. The production of activated carbon electrodes was started with the process of pre-carbonization and continued with milling process. Sampel were carbonized at temperature 600 oC and followed by physical activation process in CO2 gas atmosphere at the constant temperature of 900 oC. Measurement data of mass, diameter and thickness were collected at a every step such as: (i) before carbonization, (ii) after carbonization and (iii) after physical activation processed to obtained the density values. The density of activated carbon electrodes with different of activating agent of KOH, NaOH and ZnCl2 were 0.813 g/cm3, 0.737 g/cm3 and 0.870 g/cm3, respectively. The electrochemical properties of activated carbon electrodes were analyzed by using cyclic voltammetry (CV) method for various of activating agent of KOH, NaOH and ZnCl2 were 60.650 F/g, 59.619 F/g and 103.570 F/g, respectively. As a conclution, the activated carbon with ZnCl2 activating agent has the highest of density and spesific capacitance value. As a addition the termogravimetri analysis given the information in the produce of the heating process. Keywords: Sawdust Wood Rubber, Specific Capacitance, Density, Chemical Activation.
PEMBUATAN DAN KARAKTERISASI SIFAT FISIKA GREEN CARBON PAPER TANPA PEREKAT MENGGUNAKAN LIMBAH BIOMASSA E. Taer; Desmawati Desmawati; Sugianto Sugianto; R. Taslim
PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) Vol 4 (2015): PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) SNF2015
Publisher : Program Studi Pendidikan Fisika dan Program Studi Fisika Universitas Negeri Jakarta, LPPM Universitas Negeri Jakarta, HFI Jakarta, HFI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (289.72 KB)

Abstract

Preparation and characterization of green carbon paper (GCP)without adhesive material using waste biomass has been successfully created. (GCP) made using biomass material from banana peels. GCP-The production of GCP was begins with the grinding process with a time of 5 and 15 minutes. After grinding process followed by casting used a container with an area of ​​each 18 cm x 8 cm, 12 cm x 8 cm and 9 cm x 7 cm respectively. The next process is followed by a drying process at a temperature of 140o C for 24 hours. Characterization of physical properties are performed on samples GCP ware used Scanning electron microscopy (SEM) to determine the topology and surface morphology, energy dispersive X-ray (EDX) to determine the content of the element, and the X-ray diffraction to determine the degree of cristalinity. Measurements of weight, thickness and wide of sample GCP also perfomed to calculate density values. Based on dimention and weight measurements have been calculated the density value for various milling of GCP ware 0.825 g /cm3 and 0.698 g/cm3respectively. Characterization XRD showed GCP amorphous carbon is characterized by the presence of peaks at angles 2θ = 23,936o and 48,939o. Based on SEM measurements indicated that the particles are the building blocks of the GCP in the form of aglomerate. Keywords : Green Carbon Paper, Banana Peel, Physical Properties.
VARIASI UKURAN KARBON TEMPURUNG KELAPA SEBAGAI ALAT KONTROL KELEMBABAN E. Taer; S. Aiman; Sugianto Sugianto; R. Taslim
PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) Vol 4 (2015): PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) SNF2015
Publisher : Program Studi Pendidikan Fisika dan Program Studi Fisika Universitas Negeri Jakarta, LPPM Universitas Negeri Jakarta, HFI Jakarta, HFI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (521.321 KB)

Abstract

Studied on humidity control at testing room has been carie out by using carbon from coconut shell. The carbon is then milled using a ball milling equipment and sieved to obtained various of particle size of a variation of the size of 10 𝛍m, 53 𝛍m, and 38 𝛍m. The results showed that forthe carbon with particle size 100 μmshow the humidity of testing room was 88%, carbon 53 μm produce humidity of 86%, and carbon 38 μm produce humidity of 85%, Without carbon the humidity in the testing room show of 90%. X-ray diffraction characterization of the carbon 38 μm showed a decrease on the interlayer spacing (d002 and d100), stack height (Lc), and the stack widht (La) compared with the carbon of 100 μm. Scanning electron microscopy (SEM) shows the carbon surface morphology, particle size and pore distribution of carbon. Kararakterisasi EDX results showed levels of carbon contained in coconut shell by 93.19%. Testing of carbon as humidity control device showed the maximum results when using carbon 38 μm compared to 53 μm carbon, and carbon 100 μm. Key words: coconut shell karbon, characterization, activated carbon, humidity.
KARAKTERISASI SIFAT FISIKA KARBON AKTIF TEMPURUNG KELAPA DENGAN VARIASI KONSENTRASI AKTIVATOR SEBAGAI KONTROL KELEMBABAN E. Taer; T. Oktaviani; R. Taslim; R. Farma
PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) Vol 4 (2015): PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) SNF2015
Publisher : Program Studi Pendidikan Fisika dan Program Studi Fisika Universitas Negeri Jakarta, LPPM Universitas Negeri Jakarta, HFI Jakarta, HFI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (341.786 KB)

Abstract

Has successfully carried out a study of the effect of different concentrations of KOH activator in coconut shell charcoal as a humidity control. KOH concentration on the activation process of coconut shell charcoal varied as much as 1 M, 2 M and 3 M. The activation process is done for two hours at room temperature. The activated carbon is washed using distilled water until the pH of the washing water became neutral and then followed by drying for 24 hours at a temperature of 100ËšC. Physical properties was studiod suchasi, surface morphology, element content and degree of cristalinity using a Scanning Electron Microscope, Energy Dispersive X-Ray and X-Ray Diffraction instrumen. Coconut shell activated carbon used as the coating material for tosting chamber. The study of humidity charavationtic with time priode of 15 minutes for 2 hours. Humidity value at the end of 2 hours of testing for concentration of carbon with 1, 2 and 3 M KOH is 89%, 88% and 85% respectively. This study shows the activation of KOH concentration depending on coconut shell carbon effect on humidity test chamber. Keywords: coconut shell, potassium hydroxide, Humidity.
ANALISA SIKLIS VOLTAMETRI SUPERKAPASITOR MENGGUNAKAN ELEKTRODA KARBON AKTIF DARI KAYU KARET BERDASARKAN VARIASI AKTIVATOR KOH E. Taer; Zulkifli Zulkifli; Sugianto Sugianto; R. Syech; R. Taslim
PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) Vol 4 (2015): PROSIDING SEMINAR NASIONAL FISIKA (E-JOURNAL) SNF2015
Publisher : Program Studi Pendidikan Fisika dan Program Studi Fisika Universitas Negeri Jakarta, LPPM Universitas Negeri Jakarta, HFI Jakarta, HFI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (536.44 KB)

Abstract

Has successfully analyzed the carbon electrode supercapacitor from rubber wood using cyclic voltammetry method. Making the samples of early stage through the process of cutting, drying, carbonization and polishing to form pellets. Variations activator KOH and HNO3 is used to increase the surface area of ​​the electrode. Variations KOH used was 1 M, 3 M, 5 M HNO3 solution while being used is 25%. Methods of measurement of cyclic voltammetry carried out using a Solatron 1280 with a potential window of 0 to 1 Volt at the scan rate variation 1 mV/s, 5 mV/s, 10 mV/s, 30 mV/s, 50 mV/s and 100 mV/s. From data analized has found that the highest specific capacitance values ​​occur at the rate of induced 1 mV/s for all variations of KOH. The highest specific capacitance value at scan rate 1 mV/s in the variation of KOH 1 M, 3 M, 5 M is at 16,36 F /gram, 68,27 F/gram and 63,24 F/gram. Additional testing was also performed using X-ray diffraction instrument and electron scanning microscope. Keywords : Cyclic Voltammetry, Supercapacitor, Carbon Electrode, Rubber Wood.
POTENSI DAUN JAHE MERAH SEBAGAI BAHAN DASAR PEMBUATAN ELEKTRODA SUPERKAPASITOR Erman Taer; Juwita Ade Putri; Novi Yanti; Apriwandi Apriwandi; Rika Taslim
Komunikasi Fisika Indonesia Vol 19, No 2 (2022)
Publisher : Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/jkfi.19.2.119-127

Abstract

Red ginger leaf waste (Zingiber Officinale Var Rubrum) has been successfully processed as an active carbon base material for supercapacitor electrodes. The process of making carbon electrodes starts from the preparation of the original material, drying, refining, chemical activation, integrated pyrolysis and neutralization. The focus of this research is on the chemical activator ZnCl2 which is used with different concentrations of (0.1 and 0.5) M. Activated carbon powder is printed using a press to produce carbon in the form of solid coins of uniform size. The optimization of the carbon element in the sample is carried out through a pyrolysis process at high temperature with a one-stage integrated technique. Where, carbonization in the N2 gas environment is carried out starting from room temperature 30°C up to 600°C followed by physical activation until the high temperature reaches 800°C in CO2 gas environment. Characterization of activated carbon samples from red ginger leaves begins with determining the amount of shrinkage that occurs in the pyrolysis process by measuring the mass, diameter and thickness of the carbon coins. Furthermore, the electrochemical properties were tested using two methods, namely cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) in a symmetrical two-electrode system. The electrochemical characterization was carried out under the influence of an aqueous electrolyte of 1M KOH and 1M Na2SO4 at a low potential window of 0-1 V. The optimum conditions of electrochemical properties were found in the red ginger leaf activated carbon sample with a ZnCl2 activator concentration of 0.5M for the electrolyte. KOH with a specific capacitance value of 115.9 F/g. while for electrolyte Na2SO4 found in ZnCl2 activator 0.1M with a value of 72 F/g. Through these results, red ginger leaves are known to have great potential as a base material for activated carbon electrodes to improve the performance of supercapacitors.
SINTESIS DAN KARAKTERISASI NANOPARTIKEL OKSIDA BESI MENGGUNAKAN METODE BALL MILLING DAN KOPRESIPITASI Riduan Alvinsen Sirait; Salomo Salomo; Juandi Muhammad; Erman Taer
Komunikasi Fisika Indonesia Vol 19, No 2 (2022)
Publisher : Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/jkfi.19.2.91-98

Abstract

This Research has carried out on natural sand originating from the Rokan river, Riau Province by converting it into magnetic iron oxide nanoparticles to determine changes in magnetic properties and particle size. Natural sand samples of the Rokan river were separated between magnetic and non-magnetic particles using an iron sand separator (ISS). ISS products are further synthesized using ball milling and coprecipitation methods. 70-hour ball milling products, coprecipitation without ball milling and coprecipitation with 70-hour ball milling are then given NdFeB (neodymium iron boron) magnets to clean impurities containing non-magnetic elements. The results of this study showed that the highest magnetic acceptability value was obtained in coprecipitation products with ball milling, which was 12.9 × 10-2. This is because coprecipitation products have an abundant content of chemicals in the form of magnetic elements. Based on the results of chemical composition testing using X-ray flourescence (XRF) it was found that in coprecipitation products with ball milling there was 64.504% iron (Fe) content, while 70-hour ball milling products and coprecipitation without ball milling the percentage of Fe protection was 15.023% and 54.152%, respectively. Based on the results of the identification of the chemical composition in the sample, coprecipitation products with 70-hour ball milling have high magnetic induction values and magnetic suseptibility caused by the magnetic content in products such as Fe which are very high and non-magnetic content is very low such as Si compared to 70-hour ball milling products and coprecipitation products without ball milling.
High-Performance Aqueous Electrolyte Symmetrical Supercapacitor using Porous Carbon Derived Cassava Peel Waste Erman Taer; Harahap Eva Wahyuni; Apriwandi Apriwandi; Taslim Rika
Journal of Applied Materials and Technology Vol. 4 No. 1 (2022): September 2022
Publisher : AMTS and Faculty of Engineering - Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/Jamt.4.1.1-10

Abstract

Electrolytes have been generally recognized as one of the most important components in enhancing the electrochemical performance of supercapacitors. On the other hand, aqueous electrolytes are considered prime candidates for the development of the next generation of symmetric supercapacitors due to their low-cost, environmentally friendly, high ionic conductivity, fine ionic size, and high capacitance. Herein, the symmetrical supercapacitor of the sustainable porous carbon-based electrode material was confirmed through various aqueous electrolytes consisting of neutral, basic, and acidic Na2SO4, KOH, and H2SO4. Activated carbon is obtained from high potential biomass sources of cassava peel waste. Activated carbon synthesis was performed with a comprehensive approach in order to obtain abundant pore structure, high porosity, and improved wettability through a combination of high-temperature chemical and physical activation. in addition, the electrode material is designed to resemble a solid disc without the addition of a synthetic binder. The evaluation of the disc dimensions showed high porosity in the obtained activated carbon. Furthermore, the symmetrical supercapacitor of the optimized electrode material exhibit excellent specific capacitances of 112, 150, and 183 F g-1 at 1 mV s-1 in the electrolytes Na2SO4, KOH, and H2SO4, respectively. In addition, the highest rate capability of 70% was confirmed in the H2SO4 acid electrolyte. Moreover, their coulombic efficiency can be maintained around 89% with low equivalent series resistance 0.21-0.42 ?. Therefore, the activated carbon-based supercapacitor symmetric cell device from cassava peel shows high performance for developing high-performance supercapacitor applications with guaranteed stability in aqueous electrolytes.
SINTESIS KARBON BERPORI BERBASIS DAUN JERUK NIPIS (Citrus Aurentifolia S.) SEBAGAI MATERIAL ELEKTRODA UNTUK APLIKASI SUPERKAPASITOR Erman Taer; Melda Riyani Butet; Apriwandi Apriwandi; Rika Taslim
Komunikasi Fisika Indonesia Vol 20, No 1 (2023)
Publisher : Universitas Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31258/jkfi.20.1.9-18

Abstract

In this study, the electrode material was successfully made from activated carbon based on lime leaf biomass with variations in physical activation temperature of 800 ˚C, 850 ˚C, and 900 ˚C for supercapacitor applications. Porous carbon was synthesized through pre-carbonization steps, chemical activation using ZnCl2 activator, carbonization using N2 gas at a temperature of 600 ˚C, and physical activation using CO2. Density analysis confirmed the potential for the DJN-850 sample to have a high shrinkage of 52.24%. X-ray diffraction shows an amorphous structure of carbon characterized by broading peaks at 2θ=22° and 24°. Scanning electron microscopy analysis performed that the optimized sample possessed rich meso-,macropores followed by a high carbon content of 90.25%. The Fourier spectroscopic transformation test results identified the presence of functional groups O-H, C-O, C-H, C=C, and C≡C in the sample. The precursor activated at 850 C possessed a specific surface area of 675.129 m2 g-1 with adjusting micro-mesopore. Furthermore, the electrochemical properties of the samples were measured using cyclic voltammetry and galvanostatic charge-discharge with specific capacitances of 144.14 F g-1 and 189 F g-1, respectively.. Keywords: biomass precursor; Citrus aurentifolia S., carbon porous, electrode material, supercapacitor
Co-Authors ', Rika ', Sugianto A. Ira Afdhal Rizki Afrinal, Afrinal Agustino Agustino Agustino Agustino Agustino Agustino Agustino Agustino Agustino Agustino Agustino, Agustino Ahmad Fudholi Akrajas Ali Umar Andika Afrianda Anisa Indriawati Anita, Sofia Antonius Surbakti Antonius Surbakti Antonius Surbakti Apriwandi Apriwandi . Apriyani, Irma Awaludin Martin Awitdrus Awitdrus, Awitdrus Azwat, Luqyana Adha Bidayatul Armynah Budi Astuti Chitraningrum, Nidya D.N. Sarah D.N. Sarah, D.N. Decha Apriliany Suwandi Delovita Ginting, Delovita Deniza, Rindhu Nabila Desmagrini Desmagrini Desmawati Desmawati Dewi Marina Dewi Ramayani Eko Nur Arif Erwin Amiruddin Erwin Erwin Eva Wahyuni Harahap Fachry Abda El Rahman Fairuzy, Zeeva Khalilah Fitria Puspita Sari Gina Sania H. Yusra Harahap Eva Wahyuni Hardanto, Lilik Tri Hasanah, Fainida Hefniati Hermansyah Aziz Husna, Ropiqotul Indah Tamara Sitorus Indriawati, Anisa Inrizky Domy Muchammadsam Iwantono Iwan Barnawi Jasril Jasril Juandi Juandi Julnaidi Julnaidi Julnaidi, Julnaidi Juwita Ade Putri Khairul Ihsan Khotimah, Nur Khumairah, Zahra Kresna, Pharada Kristin Natalia Kusmawati, Intan Lazuardi Umar Lilik Tri Hardanto Lutfi Rindang Lestari M. Paiszal Marina, Dewi Meisya, Meisya Melda Riyani Butet Melinda Vivi Miftah Ainul Mardiah Minarni Shiddiq Mohamad Deraman, Mohamad Mozaffari, Nastaran Mozaffari, Niloofar Muhammad Nasir Muhammad Nasir Mukhlis Mukhlis Mustika, Widya Sinta Nasruddin Nasruddin Novi Yanti Novi Yanti Novi Yanti Nur Akmal Nursyafni, Nursyafni Nursyaputri, Wan Mery Nurwijayanti Pandi Kurniawan Pharada Kresna Pratiwi, Lini Purba, Cenora Evelynza Putri, Hardini Chania Putri, Rahma Lia R. Farma R. Farma R. Farma, R. R. Syech R. Taslim R. Taslim R. Taslim R. Taslim R. Taslim R. Taslim R. Taslim R. Taslim R. Taslim, R. Rahmi Dewi Rahmondia N. Setiadi Rahmondia Nanda Setiadi Rakhmawati Farma Rati, Yolanda Retno Handayani Riad Syech Riduan Alvinsen Sirait Rika ' Rika Taslim Rika Taslim Rika Taslim Rika Utari Rikaryalita Novitra Rini, Ari Sulistyo Romi Fadli Syahputra S. Aiman S. D. Hartati S. Nurjanah Saktioto Saktioto Salomo Salomo Septa Herniyanti Sitorus, Afrida Helena Sri Yanti Sugianto ' Sugianto Sugianto Sugianto Sugianto Sugianto Sugianto Sugianto Sugianto Sugianto Sugianto Sugianto Sugianto Sugiyanto Sugiyanto Sukendi Sukendi Sulistyo Rini, Ari Supian, Faridah Lisa Syahrul Syahrul Syamsudhuha Syamsudhuha T. Oktaviani Taslim Rika Usman Malik W. S. Mustika W.S. Mustika Wetya Fatma Kumala Sari Widodo Budi Kurniawan Yan Soerbakti Yan Soerbakti Yana, Debi Yanuar Hamzah Yolanda Rati Zikri Alrifani Zulkarnain Usman Zulkifli ' Zulkifli Zulkifli Zulkifli Zulkifli Zurya Hanifa