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Biohydrometallurgy for Cobalt Recovery from Spent Li-ion Batteries using Acidophilic Bacteria Isolated from Acid Mine Drainage Asful Hariyadi; Umi Sholikah; Bangkit Gotama; Muhammad Abdul Ghony
CHEMICA: Jurnal Teknik Kimia Vol 9, No 2 (2022): August 2022
Publisher : Universitas Ahmad Dahlan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26555/chemica.v9i2.22328

Abstract

Nowadays, recycling Li-ion batteries is an important thing to do to minimize the risk of exposure to this hazardous solid waste. On the other hand, extracting these materials can optimize the economic potential of valuable minerals in the active cathode. Bioleaching was developed as an environmentally friendly method to extract cobalt from the cathode by utilizing the metabolic activity of A. ferrooxidants cells. Microorganisms were isolated from Acid Mine Drainage in a 9K liquid medium at pH=2.5 and used as an inoculum. The Bioleaching process was carried out with various cell concentrations of 5, 10, and 20 %v/v. A positive response was shown by monitoring the microorganism activity through changes in physical appearance, decreasing the pH value, and increasing the Fe3+ concentration. The structural analysis of cathode by XRD and SEM has shown the effect of Co dissolution before and after bioleaching. Optimum recovery of cobalt was achieved up to 57.81% after 14 days of incubation.
Pembuatan Larvasida Daun Jeruk Limau Dan Kelambu Air Untuk Pencegahan Kasus Demam Berdarah Karang Joang: Making Larvicides from Lime Leaves and Water Mosquito Nets to Prevent Cases of Dengue Fever in Karang Joang Lusi Ernawati; Dian Rahmawati; Asful Hariyadi; Riza Alviany
Berdikari: Jurnal Pengabdian Masyarakat Indonesia Vol. 5 No. 1 (2022): Berdikari: jurnal Pengabdian Masyarakat Indonesia
Publisher : Future Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.11594/bjpmi.05.01.02

Abstract

The health office in Balikpapan is still tracking the number of dengue cases, which has reached at least 90 cases, until the third week of March 2022. During this outbreak, almost everyone is focused on avoiding and treating Covid-19 infections. Dengue fever is an illness to which you should pay close attention. In particular, because dengue fever remains a dangerous sickness in Indonesia. A range of approaches, including the use of larvicides, have been used to prevent and control dengue hemorrhagic fever (DBD). It is only that the mosquito that spreads Dengue Hemorrhagic Fever (DBD) has become susceptible to chemical larvicides, which are widely used by the general public. The purpose of this community service project is to teach people how to produce environmentally friendly natural larvicides from lime leaves. Community socialization, training in how to create larvicide, and knowledge evaluation are all part of the implementation phase. The memorial service will be place in Karang Joang North Balikpapan. Through lectures question and answer sessions, the community gets involved in the implementation process. Training and the use of health protocols are used directly in the manufacturing of larvicides. Water nets were built in several water reservoirs owned by homeowners, as well as similar programs involving of the monitoring and evaluation to provide the instruction and training on natural larvicide technology.
Verifikasi Metode Analisis Kadar Total Fosfat dalam Air Limbah Laundry Merujuk pada SNI 06-6989.31-2005 Made Yuri Suryani; Asful Hariyadi; Adhe Paramita; Rika Awalin Safitri
Indonesian Journal of Laboratory Vol 6 No 1 Tahun 2023
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijl.v1i1.78083

Abstract

Peningkatan kegiatan Usaha Mikro Kecil dan Menengah (UMKM) di bidang jasa pencucian (laundry) Balikpapan semakin berkembang setiap tahunnya. Proses aktivitas laundry menghasillkan limbah cair yang mengandung polutan senyawa beracun dan berbahaya, salah satunya adalah senyawa fosfat, yang apabila memiliki kadar yang melebihi dari BMAL (Baku Mutu Air Limbah) yang sudah ditentukan yaitu maksimum 2 mg/L maka akan berbahaya bagi lingkungan dan dapat menyebabkan pencemaran air. Oleh sebab itu, dalam rangka mengendalikan pencemaran air seuai batas baku mutu air limbah maka diperlukan adanya analisis pengukuran kadar fosfat  sebelum di alirkan ke badan air. Adapun tujuan dari penelitian ini yaitu untuk mempelajari teknik karakterisasi parameter kadar fosfat yang terkandung dalam sampel uji dengan menggunakan instrumentasi Spektrofotometer UV-Vis berdasarkan SNI 06-6989.31-2005. Prosedur pengambilan contoh uji air limbah merujuk pada SNI 6989.59-2008 pada salah satu usaha laundry di Kota Balikpapan, Kalimantan Timur pada dua sumber saluran pembuangan sebelum masuk perairan penerima limbah. Analisis dilaksanakan pada Laboratorium Karakterisasi, Pusat Laboratorium Terpadu ITK dengan pengulangan sebanyak 7 (tujuh) kali pada masing-masing contoh uji. Data hasil analisis  pada parameter batas deteksi dan batas kuantitasi diperoleh sebesar 0,033 mg/L dan 0,083 mg/L. Nilai parameter presisi sampel uji air limbah laundry memperoleh nilai %RSD pada air limbah laundry A dan B sebesar 3,965% dan 3,809%. Nilai %recovery pada air limbah A dan B sebesar 98,211% dan 86,611%. Sehingga hasil analisa kadar fosfat dalam air limbah laundry A dan B diperoleh sebesar 0,290 mg/L dan 0,276 mg/L. Hasil tersebut menunjukkan bahwa kadar fosfat pada sampel air limbah laundry tidak melebihi batas ambang air limbah dan metode analisa uji dapat diterapkan pada Laboratorium Terpadu, Institut Teknologi Kalimantan.
Optimalisasi Unit Instalasi Pengolahan Air Limbah (IPAL) dengan Penambahan Proses Biofilter Anaerob Aerob pada PLTU Tanjung Enim 3 X 10 MW PT. BEST Muhammad Abdul Ghony; Ario Sandy; Putra Putra; Asful Hariyadi
Jurnal Ilmiah Teknik dan Sains Vol. 1 No. 2 (2023): Desember: Jurnal Ilmiah Teknik dan Sains (JITS)
Publisher : Lembaga Penelitian dan Pengabdian Masyarakat AKIPBA

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.62278/jits.v1i2.16

Abstract

Air merupakan salah satu bagian penting dalam proses penunjang dunia industri, salah satunya adalah industri pembangkit listrik dimana air digunakan dalam rumah tangga seperti mushola, toilet, dan lain-lain. PLTU mempunyai instalasi pengolahan air yang disebut Water Treatment Plant (WTP). Air yang dihasilkan dari WTP digunakan sebagai air proses, domestik dan hidrant dalam proses kerja PLTU. Limbah cair PLTU TE 3X10 MW (PT. BEST) operasional berasal dari proses blowdown boiler, seluruh peralatan WTP dan pencucian atau backwashing (dengan atau tanpa bahan kimia). Sedangkan limbah domestik berasal dari hasil aktivitas manusia contohnya adalah air tinja, air sabun, dan lain lain. Limbah PLTU dan air industri mengandung sejumlah padatan dan partikel, baik yang terlarut maupun yang mengendap. PLTU TE 3X10 MW, limbah industri dan domestik kini ditampung di Instalasi Pengolahan Air Limbah (IPAL). Hasil pengujian yang dilakukan di laboratorium WTP PLTU TE 3X10 MW menunjukkan bahwa limbah operasional dan domestik yang dihasilkan PLTU mengandung bahan pencemar yang melebihi baku mutu yaitu fosfat (PO4). Metode pada penelitian penurunan bahan pencemar ini adalah Biofilter Aerob dan anaerob. Hasil penelitian menunjukkan bahwa terjadi penurunan kadar pencemar keseluruhan dari indikator dengan efisiensi dampak paling jelas terlihat pada kadar fosfat sebesar 68%.
Study of Palm Oil Shell Utilization as Metallurgical Coke with Variation of Bondcrete Additive Asful Hariyadi; Dinda Khoirunnisa Hidayat; Moch. Purwanto
Jurnal Teknik Kimia dan Lingkungan Vol. 8 No. 1 (2024): April 2024
Publisher : Politeknik Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.33795/jtkl.v8i1.4811

Abstract

Coke, an essential ingredient in the steel and metallurgical industries, is typically derived from bituminous coal. However, in Indonesia, where bituminous coal is rare, coke production is dependent on coal imports due to the high moisture content of local coal. An alternative approach is to use biomass, such as palm oil processing waste, for "biomass coke" to produce a more environmentally friendly coke with lower greenhouse gas emissions. Palm kernel shell waste rich in lignocellulose proved suitable for this purpose due to its compressive strength and carbon content. Pyrolysis, a technique for creating porous micro-structured carbon from palm kernel shells, was used to produce this coke substitute, offering a more sustainable energy source with a lower carbon footprint than fossil fuels. Bio-coke exhibits low moisture content (5.84%) and ash content (13.20%) due to the moisture and ash reduction effects of bondcrete adhesive during combustion. It also demonstrates substantial compressive strength (14 mPa), a high calorific value (6795 cal/g), and a favorable pore structure with a large surface area, indicating a positive influence of bondcrete adhesive on coke properties without compromising energy potential.
Opportunity of durian seed flour as an alternative to commercial wheat flour Hidayat, Jefri Pandu; Robiandi, Fadli; Arisalwadi, Meidi; Hariyadi, Asful
Journal of Agritechnology and Food Processing Vol 2, No 2 (2022)
Publisher : UNIVERSITAS MUHAMMADIYAH MATARAM

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31764/jafp.v2i2.12236

Abstract

The  high carbohydrate content  in  durian seed flour  (DSF) has the potential to be a source of food energy that can replace wheat flour in the world. DSF processing has an impact on color changes that affect  the quality of the product.  Therefore, the purpose of this study is to modify durian seeds to obtain the best properties of durian seed flour through the soaking process. The modification was carried out  in a 0.6%  (w/v)  solution of sodium metabisulfite at a temperature of 30 ºC with a drying  temperature of 50 ºC for 17 hours before grinding and sifting in a size of 80 mesh.   Treatment of immersion time variables in minutes (40, 60, 80, 100, 120) using the Complete Randomized Design (RAL) method with three attempts.  The flour is then being analyzed its physical  and chemical properties.  The best treatment was obtained at soaking time during 120 minutes which had an impact on changes in chemical and physical properties.  The test  results showed that the longer soaking time reduced the moisture content and ash content of durian seed flour, but partially improved the  other parameters tested.  The amount of DSA, DSM  and fat is less affected by soaking time. In conclusion, DSF has the potential to be used as a base for pastries or biscuits due to its low water and protein content.  In addition, based on the residual content of sulfite, the durian seed flour obtained in this study is safe for consumption in accordance with GSFA standards.
Pengaruh Penggunaan Chemical Poly Alumunium Chloride (PAC) dan Polyacrylamide (PAM) terhadap Proses Penjernihan Air di Purifier PLTU Tanjung Enim PT. BEST 3 x 10 MW Abdul Ghony, Muhammad; Jessika; Hariyadi, Asful
Jurnal Ilmiah Teknik dan Sains Vol. 1 No. 3 (2024): April : Jurnal Ilmiah Teknik dan Sains (JITS)
Publisher : Lembaga Penelitian dan Pengabdian Masyarakat AKIPBA

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.62278/jits.v1i3.26

Abstract

Proses penjernihan air di Pembangkit Listrik Tenaga Uap (PLTU) adalah langkah kritis untuk memastikan operasi yang efisien dan ramah lingkungan. Proses ini dimulai di Water Treatment Plant (WTP) dengan tahap awal di purifier water tank. Pada tahap ini, bahan kimia seperti Poly Aluminium Chloride (PAC) dan Polyacrylamide (PAM) sering digunakan untuk mengatasi kekeruhan dan memurnikan air. Namun, penggunaan PAC dan PAM dalam penjernihan air di PLTU tidak selalu mengikuti standar tetap operasional. Operator di lapangan sering menginjeksikan larutan berdasarkan pengamatan visual terhadap kondisi air sungai saat itu. Penggunaan yang tidak optimal atau dosis yang tidak tepat dapat menimbulkan efek samping, seperti pH air yang menjadi asam akibat penggunaan PAC yang berlebihan. Oleh karena itu, metode koagulasi-flokulasi diterapkan untuk proses penjernihan, menggunakan alat hot plate magnetic stirrer. Penelitian menunjukkan pengaruh penggunaan PAC dan PAM terhadap nilai pH dan kekeruhan (turbidity) air di purifier water tank serta dampak dari dosis yang digunakan.
Studi Pengolahan Air Kolam Kampus ITK yang Tercemar Polutan Alga dengan Menggunakan Metode Lumpur Aktif Muhammad Yusuf; Asful Hariyadi; Ahmad Maulidi; Juwita Payungallo
Jurnal Ilmiah Teknik dan Sains Vol. 2 No. 1 (2024): Agustus: Jurnal Ilmiah Teknik dan Sains (JITS)
Publisher : Lembaga Penelitian dan Pengabdian Masyarakat AKIPBA

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.62278/jits.v2i1.33

Abstract

Pengolahan air limbah dilakukan sebagai upaya pencegahan pencemaran air. Limbah suatu proses dikembalikan ke sungai hendaknya dalam keadaan sesuai nilai baku mutu. Salah satu metode yang digunakan pada industri untuk mengolah  limbah cair  adalah dengan penggunaan lumpur aktif.  Bakteri aerob pada lumpur aktif berperan sebagai pengurai bahan-bahan organik di dalam limbah cair. Pada penelitian ini, bioaktivator EM4 digunakan untuk menghilangkan bau pada air limbah dan memperpendek waktu aklimatisasi mikroorganisme. Penelitian ini bertujuan untuk menganalisis kadar COD, pengujian MLSS (Mixed Liquor Suspended Solid), dan NTU. Hasil penelitian menunjukkan bahwa kandungan air limbah masih melebihi nilai baku mutu yang telah ditetapkan sesuai Peraturan Pemerintah Nomor 22 Tahun 2021, dengan kadar COD sebesar 869.565 mg/L dan nilai MLSS sebesar 200 mg/L. Sehingga berdasarkan data tersebut air tersebut masih jauh dari kata layak untuk digunakan untuk keperluan rumah tangga. Hal ini disebabkan oleh banyak faktor diantaranya waktu pengendapan yang lama, kurangnya penambahan bakteri (EM4) dan volume tangki pada waktu retensi.
PELATIHAN MANAJEMEN CAFE DAN MEDIA SOSIAL DESA WISATA MERANTI, BALIKPAPAN Maryo Inri Pratama; Asful Hariyadi; Umar Mustofa; Ilham Faathir Putra; Nadia Puspita Ayu Ningtyas; Muhammad Daffa Rujid; Fachri Febrianto
J-ABDI: Jurnal Pengabdian kepada Masyarakat Vol. 4 No. 8: Januari 2025
Publisher : Bajang Institute

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Kawasan Wisata Hutan Meranti di Kota Balikpapan, yang terletak di KM 15 Kelurahan Karang Joang, Kecamatan Balikpapan Utara. Meskipun memiliki daya tarik alam yang melimpah, kawasan ini menghadapi kendala seperti keterbatasan fasilitas dan kurangnya pengalaman manajerial. Untuk mengatasi masalah ini, dilakukan program pengabdian masyarakat melalui dua pelatihan utama: manajemen kafe dan manajemen media sosial. Pelatihan manajemen kafe bertujuan untuk meningkatkan keterampilan operasional dan pengelolaan kafe, serta menjadikannya pusat kuliner. Sementara itu, pelatihan manajemen media sosial bertujuan untuk meningkatkan kemampuan pemasaran digital melalui pembuatan konten kreatif menggunakan teknologi seperti ChatGPT. Hasil pelatihan menunjukkan adanya peningkatan pemahaman peserta dalam kedua bidang tersebut. Program ini diharapkan dapat memperkuat keberlanjutan pengelolaan kawasan, mendorong peningkatan ekonomi lokal, dan menjadikan Hutan Meranti sebagai destinasi wisata yang unggul dan berdaya saing.
Degradation of Lignocellulose Biomass into Bio-oil and Biochar by Hydrothermal Liquefaction (HTL) Rizka Lestari; Lalak Tarbiyatun Nasyin Maleiva; Ahmad T. Yuliansyah; Asful Hariyadi; Fadhil Muhammad Tarmidzi
International Journal of Marine Engineering Innovation and Research Vol 10, No 1 (2025)
Publisher : Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.12962/j25481479.v10i1.22310

Abstract

Communities around the world are becoming more concerned about the environmental impact of using and heavily relying on fossil fuels, leading to a growing popularity of sustainable energy solutions. Biomass energy has become a popular topic of study around the world due to its sustainability. This study aims to investigate the feasibility of biomass waste valorization through its thermochemical or biochemical conversion into a sustainable, high-value energy commodity, thereby augmenting its economic and environmental value proposition. Hydrothermal liquefaction (HTL) was identified as the most effective method for treating biomass waste. Experiments were carried out by mixing water and biomass waste in a 500 mL autoclave batch reactor at temperatures ranging from 270 °C to 330 °C, with b/w ratios of 1:20, 2:20, and 3:20 and a retention time of 30 minutes. This study was additionally carried out under a starting pressure of 5 bar. Bio-oil had the highest product dispersion (84% at 330°C and a b/w ratio of 3:30). Meanwhile, the biochar yield was less than 10%. The solid product, on the other hand, had GCV values that were about the same as bituminous and sub-bituminous coals, at 6474 and 4888 cal/g, respectively. The carbon content of biochar at 270°C and 330°C is 50.86% and 66.77%, respectively, resulting from a variable b/w ratio of 2:20. GC-MS analyzed the highest-yielding product, bio-oil. The GC-MS study revealed a number of value-added chemicals resulting from the breakdown of hemicellulose, cellulose, and lignin compounds.