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All Journal Reaktor International Journal of Science and Engineering (IJSE) International Journal of Renewable Energy Development TEKNIK METANA Jurnal Ilmu Lingkungan JURNAL TEKNOLOGI KIMIA DAN INDUSTRI IPTEK The Journal for Technology and Science Prosiding Seminar Nasional Sains Dan Teknologi Fakultas Teknik Bulletin of Chemical Reaction Engineering & Catalysis Seminar Nasional Teknik Kimia Kejuangan Journal of Engineering and Technological Sciences Majalah Ilmiah MOMENTUM Science and Technology Indonesia Indonesia Journal of Halal Abdimas UNWAHAS : Jurnal Pengabdian Masyarakat UNWAHAS Jurnal Profesi Insinyur Indonesia Journal of Emerging Science and Engineering Bulletin of Chemical Reaction Engineering & Catalysis Advance Sustainable Science, Engineering and Technology (ASSET)
Luqman Buchori
Departemen Teknik Kimia, Fakultas Teknik, Universitas Diponegoro Jl Prof Sudharto, SH, Tembalang, Semarang, 50275, Telp/fax: (024)7460058
Religion Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Control & Systems Engineering Economics, Econometrics & Finance Education Electrical & Electronics Engineering Energy Engineering Environmental Science Industrial & Manufacturing Engineering Materials Science & Nanotechnology Medicine & Pharmacology Physics Social Sciences Transportation

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Effects of Ion Exchange Process on Catalyst Activity and Plasma-Assisted Reactor Toward Cracking of Palm Oil into Biofuels Istadi Istadi; Luqman Buchori; Didi Dwi Anggoro; Teguh Riyanto; Anindita Indriana; Chusnul Khotimah; Fachmy Adji Pangestu Setiawan
Bulletin of Chemical Reaction Engineering & Catalysis 2019: BCREC Volume 14 Issue 2 Year 2019 (August 2019)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (638.214 KB) | DOI: 10.9767/bcrec.14.2.4257.459-467

Abstract

Biofuels can be produced through a conventional catalytic cracking system and/or a hybrid catalytic-plasma cracking system. This paper was focused on studying effect of Na+ ion exchange to HY-Zeolite catalyst on catalyst performance to convert palm oil into biofuels over a conventional continuous fixed bed catalytic cracking reactor and comparing the catalytic cracking performance when carried out in a continuous hybrid catalytic-plasma reactor. The catalysts were characterized by X-ray Diffraction (XRD) and Bruneuer-Emmet-Teller (BET) surface area methods. The biofuels product were analyzed using Gas Chromatography-Mass Spectrometry (GC-MS) to determine the hydrocarbons composition of biofuels product. From the results, ion exchange process of Na+ into HY-Zeolite catalyst decreases the catalyst activity due to decreasing the number of active sites caused by blocking of Na+ ion. The selectivity to gasoline ranges achieved 34.25% with 99.11% total conversion when using HY catalyst over conventional continuous fixed bed reactor system. Unfortunately, the selectivity to gasoline ranges decreased to 13.96% and the total conversion decrease slightly to 98.06% when using NaY-Zeolite catalyst. As comparison when the cracking reaction was carried out in a hybrid catalytic-plasma reactor using a spent residual catalytic cracking (RCC) catalyst, the high energetics electron from plasma can improve the reactor performance, where the conversion and yield were increased and the selectivity to lower ranges of hydrocarbons was increased. However, the last results were potential to be intensively studied with respect to relation between reactor temperature and plasma-assisted catalytic reactor parameters. Copyright © 2019 BCREC Group. All rights reserved 
Advanced Chemical Reactor Technologies for Biodiesel Production from Vegetable Oils - A Review Luqman Buchori; Istadi Istadi; Purwanto Purwanto
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 3 Year 2016 (December 2016)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (475.793 KB) | DOI: 10.9767/bcrec.11.3.490.406-430

Abstract

Biodiesel is an alternative biofuel that can replace diesel oil without requiring modifications to the engine and advantageously produces cleaner emissions. Biodiesel can be produced through transesterification process between oil or fat and alcohol to form esters and glycerol. The transesterification can be carried out with or without a catalyst. The catalyzed production of biodiesel can be performed by using homogeneous, heterogeneous and enzyme. Meanwhile, non-catalytic transesterification with supercritical alcohol provides a new way of producing biodiesel. Microwave and ultrasound assisted transesterification significantly can reduce reaction time as well as improve product yields. Another process, a plasma technology is promising for biodiesel synthesis from vegetable oils due to very short reaction time, no soap formation and no glycerol as a by-product. This paper reviews briefly the technologies on transesterification reaction for biodiesel production using homogeneous, heterogeneous, and enzyme catalysts, as well as advanced methods (supercritical, microwave, ultrasonic, and plasma technology). Advantages and disadvantages of each method were described comprehensively.
Preliminary Testing of Hybrid Catalytic-Plasma Reactor for Biodiesel Production Using Modified-Carbon Catalyst Luqman Buchori; Istadi Istadi; Purwanto Purwanto; Anggun Kurniawan; Teuku Irfan Maulana
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 1 Year 2016 (April 2016)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (381.707 KB) | DOI: 10.9767/bcrec.11.1.416.59-65

Abstract

Preliminary testing of hybrid catalytic-plasma reactor for biodiesel production through transesterification of soybean oil with methanol over modified-carbon catalyst was investigated. This research focused on synergetic roles of non-thermal plasma and catalysis in the transesterification process. The amount of modified-carbon catalyst with grain size of 1.75 mm was placed into fixed tubular reactor within discharge zone. The discharge zone of the hybrid catalytic-plasma reactor was defined in the volume area between high voltage and ground electrodes. Weight Hourly Space Velocity (WHSV) of 1.85 h-1 of reactant feed was studied at reaction temperature of 65 oC and at ambient pressure. The modified-carbon catalyst was prepared by impregnation of active carbon within H2SO4 solution followed by drying at 100 oC for overnight and calcining at 300 oC for 3 h. It was found that biodiesel yield obtained using the hybrid catalytic-plasma reactor was 92.39% and 73.91% when using active carbon and modified-carbon catalysts, respectively better than without plasma. Therefore, there were synergetic effects of non-thermal plasma and catalysis roles for driving the transesterification process. 
Mekanisasi Pengaduk Adonan Bahan Baku Wingko Babat Sebagai Upaya Peningkatan Produktivitas dan Kualitas Produk Luqman Buchori; Didi Dwi Anggoro; Dyah Hesti Wardhani
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2018: PROSIDING SNTKK 2018
Publisher : Seminar Nasional Teknik Kimia Kejuangan

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Abstract

Peningkatan Kualitas dan Kuantitas Produk Elektroplating Melalui Perbaikan Kualitas Larutan Kimia di Bak Elektroplating dengan Filter Elektroplating Luqman Buchori; Didi Dwi Anggoro; Dyah Hesti Wardhani
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2017: PROSIDING SNTKK
Publisher : Seminar Nasional Teknik Kimia Kejuangan

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Small electroplating industry is a small industry that is widely available in the city of Semarang. The mainprocesses in the electroplating industry are located in the coating process. This process occurs in theelectroplating bath. The quality of the metal coating is highly dependent on the quality of the chemicalsolution contained in the electroplating bath. If the chemical solution has good quality, such as the solutionwas clear, there are no impurities, the quality of the coating is also good. If the quality of the chemicalsolution is not good, then the results of the coating are also inferior such as there are bubbles in the layer, orthere is dirt on the die so that the coating process must be repeated. This will add to the cost of productionand a coating time so that increases operational costs. To solve this problem we need a system that canproduce a chemical solution that has good quality, clear, and there are no impurities. This system is calledthe filter electroplating. Results of electroplating filter application showed to increase the quantity andquality of production. The production capacity increased by 30% per day. The production turnover up 35%and profits increased by 45%. The chemical solution becomes clear and does not contain impurities so thatthe coating results becomes good.
Perkembangan Proses Produksi Biodiesel Sebagai Bahan Bakar Alternatif Luqman Buchori
Prosiding Seminar Nasional Teknik Kimia "Kejuangan" 2015: Prosiding SNTKK 2015
Publisher : Seminar Nasional Teknik Kimia Kejuangan

Show Abstract | Download Original | Original Source | Check in Google Scholar

Abstract

Biodiesel has become more attractive recently because of its environmental benefits and the fact that it is made from renewable resources. Biodiesel can replace diesel oil without requiring modifications to the engine and advantageously produces cleaner emissions. Productions of biodiesel by various process methods, i.e. homogeneous, heterogeneous, and enzyme catalysts, have advantages and disadvantages. Advanced methods, such as supercritical, microwave, and ultrasonic, still leave the problem despite the high yield of biodiesel produced. Utilizing of fixed bed catalytic reactor in a continuous process can produce biodiesel with a yield of higher than 90%. The newly developed plasma technology can produce biodiesel in a very short time (120 s) with mild operating conditions. This paper reviews briefly the literatures on transesterification reaction using homogeneous, heterogeneous, and enzyme catalysts as well as advanced methods (supercritical, microwave, ultrasonic, and plasma technology).
PENINGKATAN EFISIENSI PADA PRODUKSI SAMBAL MELALUI SCALE-UP ALAT PENGGILING BAHAN BAKU Dyah Hesti Wardhani; Nita Aryanti; Luqman Buchori; Heri Cahyono
ABDIMAS UNWAHAS Vol 2, No 2 (2017)
Publisher : Universitas Wahid Hasyim Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31942/abd.v2i2.2097

Abstract

Di kota Semarang terdapat beberapa UKM penghasil sambal seafood, diantaranya UKM Winafood dan Sambal Sedep Oma yang merupakam UKM mitra bagi program pengabdian masyarakat IbPUD. Kedua UKM sudah mempunyai nomer PIRT dan sertifikasi halal sehingga mempunyai potensi untuk meningkatkan kapasitas dan memperluas daerah pemasaran. Namun potensi ini terbentur kendala dalam proses produksinya. Proses penggilingan merupakan tahapan yang penting dalam persiapan bahan baku pada produksi sambal. Kedua UKM masih menggunakan peralatan skala rumah tangga dalam persiapan bahan bakunya sehingga kapasitasnya sangat terbatas. Selama ini penggilingan bahan baku dilakukan menggunakan chopper rumah tangga yang berukuran kecil kapasitas 250 g. Sehingga jika membuat sambal dari 5-6 kg cabai dan bumbu-bumbu dengan rasio yang hampir sama dengan cabai, diperlukan preparasi yang lama. Untuk mengatasi masalah pada UKM mitra tersebut, maka tim pengusul merencanakan perbaikan baik pada proses produksi dalam bentuk mekanisasi alat penggiling bahan baku berbentuk screw yang digerakan dengan motor. Alat ini mempunyai 2 ukuran hasil luaran untuk menyesuaikan dengan spesifikasi kehalusan cabai maupun bumbu yang digiling. Alat ini mampu mereduksi waktu produksi dari 8-9 jam menjadi 6-7 jam. Meskipun meningkatkan efektifitas waktu produksinya, pada kapasitas produksi 5-6 kg cabai, alat ini belum memberi peningkatan keuntungan yang berarti.Kata kunci: penggiling cabai, sambal seafood, UKM Sambal sedep Oma, UKM Winafood
Preparation of MgO-CaO/SiO2 catalyst from dolomite and geothermal solid waste for biodiesel production Widayat Widayat; Nadia Taradissa Maheswari; Wahyu Fitriani; Luqman Buchori; Hantoro Satriadi; K Kusmiyati; Norzita Ngadi
International Journal of Renewable Energy Development Vol 12, No 3 (2023): May 2023
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2023.51573

Abstract

Energy demand will increase along with the increase in population. The current energy demand is dominated by non-renewable energy as it could reduce dependence on fossil energy sources; hence, it is imperative to be developed. Biodiesel with waste cooking oil as its raw material is one of the renewable energies currently being developed. Catalyst can be utilized to improve the quality of biodiesel product and process. The major content in solid waste of geothermal power plant is silica oxide, while dolomite contains magnesium oxide and calcium oxide. This study aims to test the MgO-CaO/SiO2 catalyst performance from geothermal waste and dolomite in biodiesel production. The results of catalyst characterization based on FTIR, SEM, and BET tests indicates a successful impregnation method in MgO-CaO/SiO2 catalyst production. The result shows that the best variable to produce biodiesel is at the ratio of MgO-CaO: SiO2 is 15:85. The conversion of biodiesel using this variable is 92.63%. The overall results of biodiesel obtained in this study have a good quality and is in accordance with SNI 7182-2015.
Advanced Chemical Reactor Technologies for Biodiesel Production from Vegetable Oils - A Review Luqman Buchori; Istadi Istadi; Purwanto Purwanto
Bulletin of Chemical Reaction Engineering & Catalysis 2016: BCREC Volume 11 Issue 3 Year 2016 (December 2016)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.11.3.490.406-430

Abstract

Biodiesel is an alternative biofuel that can replace diesel oil without requiring modifications to the engine and advantageously produces cleaner emissions. Biodiesel can be produced through transesterification process between oil or fat and alcohol to form esters and glycerol. The transesterification can be carried out with or without a catalyst. The catalyzed production of biodiesel can be performed by using homogeneous, heterogeneous and enzyme. Meanwhile, non-catalytic transesterification with supercritical alcohol provides a new way of producing biodiesel. Microwave and ultrasound assisted transesterification significantly can reduce reaction time as well as improve product yields. Another process, a plasma technology is promising for biodiesel synthesis from vegetable oils due to very short reaction time, no soap formation and no glycerol as a by-product. This paper reviews briefly the technologies on transesterification reaction for biodiesel production using homogeneous, heterogeneous, and enzyme catalysts, as well as advanced methods (supercritical, microwave, ultrasonic, and plasma technology). Advantages and disadvantages of each method were described comprehensively.
Optimization of Monoglycerides Production Using KF/CaO-MgO Heterogeneous Catalysis Luqman Buchori; Didi Dwi Anggoro; Indro Sumantri; Riko Rikardo Putra
Bulletin of Chemical Reaction Engineering & Catalysis 2019: BCREC Volume 14 Issue 3 Year 2019 (December 2019)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.14.3.4251.689-696

Abstract

The production of monoglyceride or monoacylglycerol (MAG) from triglycerides and glycerol has been studied. The purpose of this research was to study the effect of using KF/CaO-MgO catalyst on MAG production with batch reactor. The effect of reaction temperature, reaction time, and catalyst loading was investigated using Response Surface Methods (RSM). The reaction temperature, reaction time, and catalyst loading were varied at 200-220 ºC,  2-4 hours, and 0.1-0.3 % w/w, respectively. The maximum yield of monoglyceride 41.58% was achieved the optimum conditions of  catalyst loading of 0.19 % (w/w), reaction temperature of 208.4 ºC, and reaction time of 3.20 hours.  
Co-Authors . Widayat Amin Nugroho Anggun Kurniawan Anindita Indriana Aprilina Purbasari Ardian D. Yudhistira Aris Bagus Pradana, Aris Bagus Arman, Mhd. Adithia Perdana Arum Sakti Prasetyo Astrilia Damayanti B Budiyono Berkah Fajar Bintang Ayu Kalimantini Boby Gusman Irianto Samosir Budi Sasongko Setia Budiyono Budiyono Chusnul Khotimah Dewi Fatmawati Didi D. Anggoro Didi D. Anggoro Didi Dwi Anggoro Dinda Labibah Ubay Dyah Hesti Wardhani Dyah Hesti Wardhani Fachmy Adji Pangestu Setiawan Faleh Setia Budi Faleh Setia Budi Faleh Setia Budi Fegi Yuliandri Fradriyan Aulia Giveni Christina Silaen Hadiyanto Hantoro Satriadi Hargono Hargono Harum Nissaulfasha Herawati Oktavianty Heri Cahyono Heru Susanto I Nyoman Widiasa I. Istadi I.G.B Ngurah Makertihartha Indro Sumantri Inshani Utami Istadi Istikhoratun, Titik JD Ryan Christy S Khonsa Syahidah Kusmiyati Kusmiyati Laeli Kurniasari M. Dani Supardan M. Dani Supardan M. Djaeni Maria Augustine Graciafernandy Meitiandari Mutiara Mhd. Shaumi Al Anshar Muhamad, Theobroma Guntur Muhammad Ulil Absori Nadia Taradissa Maheswari Ndaru Okvitarini Ngadi, Norzita Nita Aryanti Norzita Ngadi Nur Hidayati Nurjati Solikhin Nurul Aishah Aishah Nurushofa, Faustina Alda Okryreza Abdurrachman P Purwanto Pakpahan, Agnes J. Pakpahan, Andre W. S. Pratama, Pambudi Pajar Pratama, Wahyu Diski Pratiwi, Wahyu Zuli Purwanto Purwanto Purwanto Purwanto Putri Diliyan Shakti Ratnawati Ratnawati Resti Nur Utami Riko Rikardo Putra Riyanto, Teguh Rizki Andre Handika Roikhatus Solikhah Salsabila, Unik Hanifah Saputra, Roni Ade Setia Budi Sasongko Setia Budi Sasongko Setiadi, Iqfan Dwi Silviana Silviana Siswo Sumardiono Suherman Suherman Suherman Suherman Sulardjaka Sulardjaka Sulardjaka, S Syarief, Elijah Teguh Riyanto Teuku Irfan Maulana Titik Istirokhatun Udin Mabruro Wahyu Fitriani Widayat Widayat Widayat Yayuk Astuti Yazid Bindar Yazid Bindar Yudha Duta Utama