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Determination and Characterization of Lycopene Compounds from N-Hexane Fraction of Tomato Fruit (Solanum Lycopersocum Grandyfolium) by using Fourier Transform Infrared and UV-Vis Spectrophotometry Arfiani Nur; Hajrah Hajrah; Asriani Ilyas; Aisyah Aisyah; Maria Cecilia Lezama Escalante
Walisongo Journal of Chemistry Vol 5, No 1 (2022): Walisongo Journal of Chemistry
Publisher : Department of Chemistry Faculty of Science and Technology Walisongo

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21580/wjc.v5i1.10885

Abstract

Determination and characterization of the lycopene content of the n-hexane fraction from potato-leaved tomato (Solanum lycopersicum grandyfolium) using Fourier transform infrared (FTIR) spectrophotometry and UV-Vis spectrophotometry. This study aims to determine the levels and characterization of lycopene compounds from potato-leaved tomato fruit using FTIR and UV-Vis spectrophotometers. The methods in this research include maceration, liquid-liquid extraction, crystallization with antisolvent, chromatography with three eluent systems, identification of lycopene compounds, and characterization of lycopene compounds using FTIR and UV-Vis. The results showed the presence of lycopene compounds based on the spectrum with absorption peaks at wave numbers 2924, 18 cm-1 and 2863, 66 cm-1 indicating C-H (stretching); 1637, 43 cm-1 indicating C=C alkene; and the wave numbers of 1461, 63 cm-1 and 1422, 46 cm-1 indicating the presence of a CH2 (bending) functional group. The results of UV-Vis spectrophotometric characterization showed the presence of lycopene compounds at three main wavelengths, namely at 445, 467, and 500 nm. The level of lycopene compounds produced from the n-hexane extract of potato-leaved tomato fruit was 7.25 mg/gram
Analisa Logam Berat Kadmium (Cd) dan Timbal (Pb) pada Kerang Hijau (Perna viridis) yang Beredar di Pelelangan Ikan Paotere Kota Makassar Titik Andriani; Fera Agustin; Sitti Chadijah; Syarifah Rabiatul Adawiah; Arfiani Nur
Chimica et Natura Acta Vol 10, No 3 (2022)
Publisher : Departemen Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24198/cna.v10.n3.42296

Abstract

Penelitian ini dilakukan untuk mengetahui kadar logam berat kadmium (Cd) dan timbal (Pb) pada kerang hijau (Perna viridis) yang beredar di pelelangan ikan paotere kota Makassar. Sampel daging kerang dipisahkan dari cangkangnya kemudian daging kerang dihaluskan, setelah itu didestruksi kering. Selanjutnya  dilakukan pengukuran kadar logam Pb dan Cd menggunakan Spektrofotometer Serapan Atom (SSA). Hasil dari penelitian ini diperoleh kandungan logam Pb yaitu 5,9 mg/kg, sedangkan kandungan logam Cd 0,7 mg/kg.  Hasil kandungan logam berat yang dianalisis ini melebihi ambang batas yang telah ditetapkan oleh Balai Pengawas Obat dan Makanan (BPOM).
Pemanfaatan Ekstrak Daun Miana (Coleus Scutellarioides (L) Benth) Menggunakan Metode Ultrasonic Asisted Extraction Untuk Identifikasi Formalin Pada Mie Basah Rismawaty Sikanna; Muliyani; Arfiani nur
Jurnal Kesehatan Panrita Husada Vol 8 No 2 (2023): Jurnal Kesehatan Panrita Husada
Publisher : Lembaga Penelitian dan Pengabdian Masyarakat (Stikes Panrita Husada Bulukumba)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37362/jkph.v8i2.1054

Abstract

Miana (Coleus scutellarioides (L) Benth.) leaves contain anthocyanin compounds that can be used to detect formalin in food, including wet noodles. The purpose of this study was to determine the highest levels of anthocyanin extract of miana leaves produced using the ultrasonic assisted extraction (UAE) method with variations in extration time and to determine the potential of miana leaf anthocyanin compounds in detecting formaldehyde content in wet noodles. The extraction method used is UAE with 5 variations of extraction time. Anthocyanin levels were measured using a UV-VIS Spectrophotometer at wavelengths of 510 and 700 nm using differential pH, namely pH 1 and pH 4.5. Formalin identification was carried out on wet noodles with the concentration of 0.25; 0.5; 1; and 2 ppm. The results obtained the highest level of anthocyanin in miana leaves, namely 196,66 mg/L wich was extracted for 10 minutes wich could be used for identification of formalin in wet noodles. Keywords: Miana leaf (Coleus scutellarioides (L) Benth.), Ultrasonic Assisted Extraction (UAE), Anthocyanin and Formaldehyde
Characterization of Hydroxyapatite of Chicken Eggshells Composite with Gelatin as Methylene Blue Absorbent Nurfadillah; Ramadani, Kurnia; Firnanelty; Chadijah, Sitti; Aisyah, Aisyah; Ilyas, Asriani; Nur, Arfiani; Adawiah, Syarifah Rabiatul; Andriani, Titik
Al-Kimia Vol 11 No 2 (2023): DESEMBER
Publisher : Study Program of Chemistry - Alauddin State Islamic University of Makassar

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24252/al-kimia.v11i2.40781

Abstract

Chicken egg shells contain an inorganic element (CaCO3) which has potency to be a source of calcium hydroxide (Ca(OH)2) which is then reacted with diammonium hydrogen phosphate ((NH4)2HPO4) as a phosphate precursor for hydroxyapatite synthesis. This study aims to determine the characterization of hydroxyapatite from eggshells and determine the absorbability of hydroxyapatite-gelatin composites against methylene blue. Synthesis of hydroxyapatite used precipitation method. The calcination results obtained calcium hydroxide (Ca(OH)2) content in the shell of 68.3%. Analysis of hydroxyapatite with Fourier Tranform Infra-Red (FT-IR) there was a wavenumber of 3434 cm-1 perform hydroxyl groups (-OH-), 1421 cm-1 carbonate groups (-CO3-2) and 1035 cm-1, 604 cm-1, 471 cm-1 phosphate groups (-PO4-2), and analysis by x-ray diffraction revealed that pure hydroxyapatite crystals had formed at an angle of 2Ɵ = 34,08 with crystallinity of 100%. The peaks that appear on the XRD diffractogram are adjusted to the Joint Committee on Power Diffraction Standards (JCPDS) No. 09-0432. The synthesis of HAp-gelatin composites obtained typical groups such as, amine groups from gelatin and phosphate groups and carbonates from Hap. The results of methylene blue absorption using hydroxyapatite-gelatin composites have obtained optimum conditions at a ratio of 2: 4 for 240 minutes with an efficiency of 63%. Based on these data, it reveals that the longer the time given, the greater the methylene blue absorbed
Pengujian Kualitas Air Minum Isi Ulang (Galon) Masyarakat Samata-Gowa Sulawesi Selatan Iin, Iin Novianty; Nur, Arfiani; Febryanti, Amalyah; Rasyid, Firnanelty
DHARMA BAKTI Dharma Bakti-Vol 5 No 2-Oktober 2022
Publisher : LPPM IST AKPRIND Yogyakarta

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.34151/dharma.v5i2.4020

Abstract

An assesment of the quality of refill drinking water (gallon water) has been carried out. The purpose of this study is to determine the quality of drinking water consumed by people in Samata-Gowa. There were five water samples taken from five residents' houses. The method used were testing physical and chemical parameters. These two methods consisted of temperature, color, odor, and taste tests; biological test with simple method; chemical test using tea water; pH meter test (acidity); conductivity test; and assay for Pb and Fe metal levels using AAS (Atomic Absorption Spectrophotometer). The results obtained included that the temperature of the five samples was in the range of 23.0 °C-27.0 °C, there were showing no turbidity/colorless, odorless, and bland taste; biological test of each sample showed no precipitate formed; chemical tests on the five samples indicated that there were no change in color; pH and conductivity values ranged from 7.5-8.79 and 65.2-109.3 S/cm, respectively; Fe and Pb levels in each sample were 0.0-0.1 mg/mL and 0.05-0.08 mg/L. Based on these data, the quality of refill drinking water for the people of Gowa-Samata is still suitable for consumption because some of these parameters qualified the standards.
Esterification Reaction of Glycerol to The Derivatives Catalyzed by Amberlyst 36 Aisyah, Aisyah; Rezeki, Rezeki; Firnanelty, Firnanelty; Abubakar, A. Nur Fitriani; Zahra, Ummi; Patunrengi, Iswadi Ibrahim; Nur, Arfiani
Jurnal Akta Kimia Indonesia (Indonesia Chimica Acta) Volume 14, No 1: June 2021
Publisher : Hasanuddin University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20956/ica.v14i1.12837

Abstract

Several studies reported the use of acid catalysts of esterification of glycerol to acetin derivatives and amberlysts are no exception. However, among these strong sulfuric acid catalysts, amberlyst 36 is still rarely used and hence challenging to investigate. This study aimed to determine the yield and the selectivity of the esterification reaction of glycerol into acetine derivatives using a 5% of solid catalyst amberlyst 36 at a temperature of 90°C in a reflux system. The conversion value resulting from the reaction was 80.74%, with a selectivity value of 6.8% for triacetin. FTIR and GC-MS data support the monoacetin and triacetin structures. The findings indicate that the simple method and easily obtained catalyst can produce a high yield of acetin derivatives. This method is still possibly optimized to perform maximum yield with high selectivity.
Independensi Penuntutan Perkara Koneksitas Ditinjau dari Peraturan Presiden Nomor 15 Tahun 2021 Tentang Organisasi dan Tata Kerja Kejaksaan Nofia Sari, Okta; Arfiani, Nur; Mustofa, Mustofa
WELFARE STATE Jurnal Hukum Vol. 2 No. 2 (2023): Oktober
Publisher : Prodi Ilmu Hukum Fakultas Hukum Universitas Islam Jember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.56013/welfarestate.v2i2.2307

Abstract

In Article 89 paragraph 1 of the Criminal Procedure Code it is stated that "criminal acts committed jointly by those belonging to the general court environment and the military court environment, are examined and tried by courts within the general court environment unless according to the decision of the Minister of Defense and Security with the approval of the Minister of Justice, the case must be examined and tried by a court within the military court environment”. In this case, it is necessary to increase the effectiveness of the implementation of the duties and powers of the Attorney General's Office of the Republic of Indonesia in carrying out technical coordination of prosecutorial prosecution and handling of connected cases and the application of the principles of embodiment of bureaucratic reform and the acceleration of the provision of legal services to the public by appointing a Junior Attorney General for Military Crime in the structure the Attorney General's Office. the existence of Presidential Decree Number 15 of 2021 is intended to accelerate the handling of connectivity cases. However, competent human resources are needed to run this structure as well as budget allocations for military members who fill these positions.  
Keberlakuan Non-Refoulement Principle Dikaitkan Dengan Sovereignty Principle: Tinjauan Terhadap Pengungsi Rohingya di Indonesia Sumampouw, Wuri; Kurnia, Kana; Arfiani, Nur; Hadrian, Reza
JURNAL USM LAW REVIEW Vol 7, No 3 (2024): DECEMBER
Publisher : Universitas Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26623/julr.v7i3.9441

Abstract

This research aims to determine the determination of the status of the Rohingya ethnic group according to the Refugee Convention and the application of the principle of non-refoulement in handling Rohingya refugees in Indonesia in relation to the principle of sovereignty, and then whether the application of the principle of non-refoulement is absolute or not applied in Indonesia. Due to the large number of Rohingya ethnic groups entering Indonesian territory and causing social problems, security can even threaten sovereignty. The research method is normative legal research, relying on secondary data. The research results show that Indonesia is not a country that has ratified the 1951 convention, as a result, it is difficult for asylum seekers to obtain protection regarding their certainty, and considering the ongoing security situation in Myanmar, of course, the only hope for asylum seekers to achieve a long-term solution is through resettlement in third countries and even though Indonesia has not ratified the 1951 convention, Indonesia still needs to comply with the principle of non-refoulement even though there are no penalties imposed on Indonesia if Indonesia violates the 1951 convention and forces refugees to leave Indonesia considering that the convention does not explain in writing what The consequences that non-convention countries will face if they reject asylum seekers and refugees and force them to leave Indonesia. Penelitian ini bertujuan untuk mengetahui penentuan status etnis Rohingya Menurut Konvensi Pengungsi dan penerapan prinsip non refoulement dalam penanganan pengungsi Rohingya di Indonesia dikaitkan dengan prinsip sovereignty, dan kemudian apakah penerapan prinsip non refoulement ini mutlak atau tidak diterapkan di Indonesia. Di karenakan banyaknya etnis Rohingya yang masuk ke wilayah Indonesia dan menimbulkan masalah-masalah sosial, keamanan bahkan dapat mengancam kedaulatan. Metode penelitiannya adalah penelitian hukum normatif, bertumpu pada data sekunder. Hasil penelitian menunjukan bahwa Indonesia bukan merupakan negara yang meratifikasi konvensi 1951, akibatnya pencari suaka kesulitan untuk mendapatkan perlindungan terkait kepastian mereka dan mengingat situasi keamanan yang sedang berlangsung di Myanmar maka tentu saja, maka satu-satunya harapan para pencari suaka untuk mencapai solusi jangka panjang adalah melalui pemukiman kembali di negara ketiga dan walaupun Indonesia tidak meratifikasi konvensi 1951, Indonesia tetap perlu untuk mematuhi prinsip non refoulement sekalipun tidak ada hukuman yang dijatuhkan ke Indonesia apabila Indonesia melanggar konvensi 1951 dan memaksa pengungsi meninggalkan negara Indonesia mengingat di dalam konvensi tidak menjelaskan secara tertulis apa konsekuensi yang akan dihadapi negara-negara non konvensi jika mereka menolak pencari suaka dan pengungsi serta memaksa mereka meninggalkan negara Indonesia. 
Sintesis Kemosensor Anion Senyawa 4-(2,6-difenil-Piridin-4-Il)-2-Metoksi-Fenol Dari Vanilin Arfiani Nur; Bambang Purwono
Jurnal Rekayasa Kimia & Lingkungan Vol 12, No 1 (2017): Jurnal Rekayasa Kimia & Lingkungan
Publisher : Chemical Engineering Department, Syiah Kuala University, Banda Aceh, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.23955/rkl.v12i1.4957

Abstract

Telah dilakukan sintesis kemosensor anion senyawa 4-(2,6-difenil-piridin-4-il)-2-metoksi-fenol (DPMF). Sintesis senyawa target DPMF dilakukan melalui senyawa antara kalkon dengan rendemen reaksi 77%. Uji sebagai sensor anion dilakukan dalam pelarut DMSO-air terhadap anion F-, Cl-, Br-, CN- dan H2PO4-. Senyawa DPMF ini menghasilkan perubahan warna dari tidak berwarna menjadi kuning pada penambahan anion CN-. Analisis spektrofotometer UV-vis pada senyawa DPMF menghasilkan perubahan mak = 320 nm ke mak = 370 nm pada penambahan anion CN-. Limit deteksi terhadap anion CN- sebesar 4,11x10-6M. Senyawa ini juga dapat berperan sebagai kemosensor fluoresen dengan sistem ON-OFF.
Synthesis and Characterization of Nickel Nanoparticles: Biological and Photocatalytic Properties Fadliah, Fadliah; Raya, Indah; Ahmad, Ahyar; Taba, Paulina; Burhanuddinnur, Muhammad; Gaffar, Maming; Putri, Tri Widayati; Nur, Arfiani; Abubakar, Andi Nur Fitriani; Munadi, Rachmin; Majid, Ahmad Fudhail; Pratama, Irham; Yasser, M.; Jarre, Sulistiani; Karim, Harningsih
Indonesian Journal of Chemistry Vol 25, No 1 (2025)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ijc.90034

Abstract

The potential uses of ecologically benign nickel nanoparticle manufacturing in various sectors, such as biomedicine, energy storage, and catalysis, have garnered much interest. This paper covers green approaches to nickel nanoparticle manufacturing, which integrate natural substances as stabilizing and reducing agents with eco-friendly processes. Phytochemicals derived from bacteria, microorganisms, and plant leaf extracts can convert nickel ions (Ni2+) into nickel nanoparticles. Room temperature is used for the synthesis procedure, and neither dangerous compounds nor unusual reaction conditions are used. Using a variety of analytical methods, the resultant nickel nanoparticles were characterized. We also investigate the possibility of using the generated nickel nanoparticles as a cytotoxic, photocatalytic, antioxidant, and antibacterial agents. The antimicrobial activity of nickel nanoparticles demonstrates their potent antibacterial properties, while their antioxidant activity demonstrates their capacity to combat free radicals effectively. Furthermore, nickel nanoparticles' cytotoxic activity demonstrates their capacity to kill cancer cells, and their photocatalytic activity demonstrates their efficiency in breaking down organic contaminants. This review highlights the value of ecologically benign synthetic methods and creates new avenues for developing nickel nanoparticle applications in health and the environment.