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All Journal Natural Science: Journal of Science and Technology KOVALEN: Jurnal Riset Kimia KAIBON ABHINAYA : JURNAL PENGABDIAN MASYARAKAT Jurnal ABDINUS : Jurnal Pengabdian Nusantara
Prismawiryanti Prismawiryanti
Jurusan Kimia FMIPA Universitas Tadulako
Humanities Chemical Engineering, Chemistry & Bioengineering Chemistry Computer Science & IT Economics, Econometrics & Finance Education Environmental Science Industrial & Manufacturing Engineering

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KAJIAN PENGGUNAAN BERBAGAI LEMPUNG TERAKTIVASI SEBAGAI ADSORBEN UNTUK MENURUNKAN KADAR AMONIA, NITRAT, DAN NITRIT DARI LIMBAH TAHU INDUSTRI Maradang, Aksan Y; Mirzan, Moh; Prismawiryanti, Prismawiryanti
Natural Science: Journal of Science and Technology Vol 3, No 1 (2014): Volume 3 Number 1 (March 2014)
Publisher : Univ. Tadulako

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Abstract

Tofu industry liquid waste, which is still contains high concentration of organic materials, is one of the causes of pollution in environment. On the other hand, clay can be used as adsorbent and easily to be obtained. The aim of this study was to reduce ammonia, nitrate, and nitrite concentration on liquid waste of tofu industry using colected clay from three different locations at laboratory scale. Clay was collected from Kalukubula, Beka and Sibowi villages at Sigi District Central Sulawesi Province. Each clay was activated by 0.1 M HCl, 0.1 M NH4Cl or 0.1 M NaOH. The result showed that clay from Beka village has highest capacity to reduce nitrate, nitrite and ammonia concentration on liquid waste of tofu industry. Clay from Kalukubula village was better as absorbent than clay from Sibowi village.  The strength of activator in increasing clay adsorptive was followed this order: NaOH < NH4Cl < HCl. Clay from Beka Village when activated by HCl 0.1 M, it could reduce 47.52%, 54.00% and 58.89% of amonia, nitrate and nitrite concentration, respectively.
APLIKASI FOTOKATALIS TIO2-ZEOLIT UNTUK MENURUNKAN INTENSITAS ZAT WARNA TARTRAZIN SECARA FOTOKATALITIK Firmansyah, Firmansyah; Mirzan, Moh.; Prismawiryanti, Prismawiryanti
Natural Science: Journal of Science and Technology Vol 4, No 1 (2015): Volume 4 Number 1 (March 2015)
Publisher : Univ. Tadulako

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Abstract

Telah dilakukan penelitian aplikasi fotokatalis TiO2-Zeolit untuk menurunkan intensitas zat warna Tartrazin secara fotokatalitik.Penelitian ini bertujuan untuk mencari kombinasi dosis fotokatalis dan waktu penyinaran terbaik untuk menrunkan intensitas zat warna Tartrazin.KonsentrasiTartrazin 20 ppm sebanyak 100 mL ditambahkan dengan 50; 75; 100; 125 dan 150 mg fotokatalis TiO2-Zeolit dengan penyinaran sinar-UVA (365 nm) selama 40; 80; 120; 160 dan 200 menit. Hasil penelitian menunjukkan penggunaan dosis fotokatalis TiO2-Zeolit sebanyak 100 mg dengan lama radiasi UV A 200 menit mampu mendegradasi Tartrazin sebesar 77,10 %.
DISTRIBUSI LOGAM MERKURI PADA SEDIMEN LAUT DI SEKITAR MUARA SUNGAI POBOYA Purnawan, Sandi; Sikanna, Rismawati; Prismawiryanti, Prismawiryanti
Natural Science: Journal of Science and Technology Vol 2, No 1 (2013): Volume 2 Number 1 (March 2013)
Publisher : Univ. Tadulako

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Abstract

An investigation about Mercury metal content in marine sediment around Poboya stream has been done. The sediment samples were collected at 5 points of Poboya stream with 0; 15 and 30 days of time variations. The physical conditions of the water was analyzed i.e pH, temperature and salinity. The result showed that the lowest and the highest Mercury metal content (0,0103 and 0,185 mg/Kg) were found at point E and C respectively. It was found at the second and the first sampling accordingly. There was no significant increase of Mercury accumulation by time. In general, the Mercury metal content in the sediment around Poboya stream was still under government rule.
AKTIVITAS ANTIOKSIDAN EKSTRAK LIMBAH KULIT ARI BIJI KOPI (COFFEA SP) BERDASARKAN TINGKAT KEPOLARAN PELARUT Marcelinda, Agriyani; Ridhay, Ahmad; Prismawiryanti, Prismawiryanti
Natural Science: Journal of Science and Technology Vol 5, No 1 (2016): Volume 5 Number 1 (March 2016)
Publisher : Univ. Tadulako

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Abstract

"> Telah dilakukan penelitian tentang aktivitas antioksidan ekstrak kulit ari biji kopi (Coffea sp) berdasarkan tingkat kepolaran pelarut. Penelitian ini diawali dengan melakukan ekstraksi menggunakan pelarut metanol, selanjutnya dilakukan fraksinasi dengan pelarut nheksana, etil asetat dan n-butanol. Ekstrak hasil fraksinasi dengan n-heksana, etil asetat dann-butanol diuji aktivitas antioksidannya dengan metode DPPH. Hasil yang diperoleh untuk aktivitas antioksidan (IC50) pada ekstrak n-heksana, etil asetat, n-butanol dan vitamin C masing ? masing adalah 1182,2 ppm, 823,52 ppm, 556,67 ppm dan 101,85 ppm.
KAJIAN METODE GRAVIMETRI DALAM ANALISIS KADAR KARAGINAN RUMPUT LAUT Eucheuma cottonii Ernawati A. H. Bana; Mappiratu Mappiratu; Prismawiryanti Prismawiryanti
KOVALEN: Jurnal Riset Kimia Vol. 1 No. 1 (2015)
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

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Abstract

ABSTRAK Telah dilakukan penelitian tentang kajian metode gravimetri dalam analisis kadar karaginan rumput laut Eucheuma cottonii. Peneltian ini bertujuan untuk mendapatkan tingkat pemekatan dan rasio etanol/ekstrak pekat yang paling baik digunakan dalam penetapan kadar karaginan rumput laut Eucheuma cottonii. Penelitian dua faktor masing-masing faktor tingkat pemekatan dan faktor rasio etanol/ekstrak pekat, yaitu 30%, 40%, 50%, 60%, 70% dan 1,5 : 1; 2,0 : 1; 2,5 : 1; 3,0 : 1; dan 3,5 : 1. Kadar karaginan ditentukan menggunakan metode gravimetri, hasil yang diperoleh menunjukkan  tingkat pemekatan yang memberikan kadar karaginan tertinggi yaitu 50% dan rasio etanol/ekstrak pekat yaitu 3,5 : 1 yang menghasilkan kadar karaginan tinggi (51,752). Kata kunci: Eucheuma cottonii,Ekstraksi karaginan, Rasio etanol
KAJIAN SINTESIS GIPSUM DARI BATU GAMPING ASAL SULAWESI TENGAH Gloria Yoanita; Mappiratu Mappiratu; Prismawiryanti Prismawiryanti
KOVALEN: Jurnal Riset Kimia Vol. 2 No. 1 (2016)
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

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Abstract

ABSTRACT Research has been done for synthesis gypsum from limestone in Central Sulawesi. This Research aims are to know the best ratio of sulphuric acid of limestone that producer the highest CaSO4 and which areas in the Central Sulawesi as a producer of best limestone for the raw materials CaSO4. Variation ratio of sulphuric acid used is 70:25, 80:25, 90:25, 100:25, and 110:25. This Research using a group randomized design (GRD). The treatment was applied variations from limestone on the 3 areas, that is limestone from Bangkep (group 1), limestone from Buol (group 2) and limestone from Donggala (group 3). The purity of CaSO4 be analiyzed using AAS and uv-vis Spectrofotometri. The result showed that the best ratio of sulphuric acid is 110:25 and producer area of the best limestone for the raw materials of CaSO4 in the Bangkep. Keywords: Gypsum, Limestone, Sulfuric Acid, Yield, Purity
PRODUKSI GLUKOSA DARI JERAMI PADI (Oryza sativa) MENGGUNAKAN JAMUR Trichoderma sp. Yuli Rismawati; Syaiful Bahri; Prismawiryanti Prismawiryanti
KOVALEN: Jurnal Riset Kimia Vol. 2 No. 2 (2016)
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

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Abstract

Research glucose production from rice straw (Oryza sativa) using Trichoderma sp. has conducted. This study aime is to determine the effect konsentrasi Trichoderma sp. And a straw fermentation of rice (Oryza sativa) against production. Research glucose levels was done using a completely randomized design (CRD) with factorial pattern 4 variation of the concentration of Trichoderma sp. (0%, 24%, 36% and 48%) and fermentation time (3, 4, 5and6 weeks), glucose levels were analyzed using DNS with UV-Visible spectrophotometry. The measurement results showed that the highest glucose levels obtained at various concentration Trichoderma sp. 36% fermentation time during the five week sthat is equal to 14.525%. There is a positive interaction between the concentration of Trichoderma sp. and the fermentation time, the best combination of time and fungal concentration of 5 weeks and 36%, respectively.Keywords : Rice straw, Trichoderma sp., Fermentation, DNS, Spectrophotometer Uv-Visibel, Glucose.
HIDROLISIS SELULOSA DARI SEKAM PADI (Oryza sativa) MENJADI GLUKOSA DENGAN KATALIS ARANG TERSULFONASI Adeks Pramana; Abdul Rahman Razak; Prismawiryanti Prismawiryanti
KOVALEN: Jurnal Riset Kimia Vol. 2 No. 3 (2016)
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

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Abstract

Cellulose hydrolysis from rice husk (Oryza sativa) into glucose with sulfonated charcoal catalyst was conducted. The aim of this research was to determine sulfuric acid concentration and contact time on the sulfonation process of charcoal which would produce the highest glucose rendement from cellulose hydrolysis of rice husk. Sulfuric acid concentrations in this experiment were 8, 10, and 12 N with variation of contact time of 4, 6, 8, 10 and 12 hours respectively.  Rice husk was delignified with NaOH 10% to produce cellulose which was hydrolyzed by sulfonated charcoal catalyst. Hydrolysis reaction with the ratio cellulose/aquadest 1:25 (w/v) was conducted in autoclave with temperature 130 oC for 3 hours. The result showed that 8 N concentration of sulfuric acid and 12 hours of contact time produced the highest glucose rendement 17,9%. Keywords : rice husks, cellulose, glucose, sulfonated charcoal
SINTESIS KARBOKSIMETIL SELULOSA (CMC) DARI SELULOSA KULIT DURIAN (Durio zibethinus) Dini Safitri; Erwin Abdul Rahim; Prismawiryanti Prismawiryanti; Rismawati Sikanna
KOVALEN: Jurnal Riset Kimia Vol. 3 No. 1 (2017): Edisi April
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

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Abstract

The investigation about of carboxymethyl cellulose (CMC) of Durian peel  (Durio zibethinus) cellulose has been done. The research aim is to determine the best ratio of sodium mono-chloroacetate toward cellulose and is to determine the reaction time in the synthesis of carboxymethyl cellulose of durian peel in order to obtain the highest substitution degree. The applied of ratio variations and reaction time were 5:5, 6:5, 7:5, 8:5, 9:5 grams and 1, 2, 3, 4, 5, respectively. The result showed that the best ratio of sodium mono-chloroacetate toward cellulose was 7:5 gram with yields and the substitution degree of 39.39% and 1.17, respectively. The best time reaction was found at 4 hours with yields and the substitution degree of 39.77 % and 1.2, respectively. Keywords: Durian peel, carboxymethyl cellulose, substitution degree.
APLIKASI SELULOSA BAKTERIAL-DIETILENTRIAMINA SEBAGAI LAPISAN PENGIKAT LOGAM Pb DAN Cd PADA METODE DIFFUSIVE GRADIENT IN THIN FILMS (DGT) Khairuddin Khairuddin; Prismawiryanti Prismawiryanti; Indriani Indriani
KOVALEN: Jurnal Riset Kimia Vol. 3 No. 1 (2017): Edisi April
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

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Abstract

This research aimed to synthesis and apply of bacterial cellulose-diethylenetriamine as a binding layer on the diffusive gradients in thin films method for preconcentration of labile metal Pb and Cd in aquatic systems and sediment of Palu Bay. The results are expected to be used for the analysis of environmental contaminants aquatic pollutant/sediment replace conventional methods. DGT method easily carried into the field and sensitive to identify certain metal ions. The results showed concentration of heavy metals dissolved in seawater for Pb between 0.024 to 0.048 mg / L, while for Cd between 0.006 to 0.015 mg / L. The concentration of Pb in sediments from 7.426 to 16.043 mg / L and Cd 0.387 to 0.950 mg / L. Partial regression analysis between Pb and Cd concentrations in water with a concentration of cadmium metals Pb and Cd in the sediments showed that the concentration of heavy metals in water has a positive correlation with the concentration of Pb and Cd in the sediment.Keyword: Pb, Cd, DGT, bacterial cellulose-diethylenetriamine, Palu Bay
Co-Authors Abd. Rahman Razak Abdul Rahman Razak Adeks Pramana Agriyani Marcelinda, Agriyani Ahmad Ridhay Aksan Y Maradang Andarwati, Sophia Andi Tenri Ajeng Angria Deswika Malambu Arianto Asniawati Asniawati Dini Safitri Dwi Juli Puspitasari Dwi Juli Pusptasari Eka Surya Wahyuningsih Enni Indriani Ernawati A. H. Bana Erwin Abdul Rahim Firmansyah Firmansyah Fitra Langgeng Mangesti Fitriah Fitriah Frischa Sari Kencana Gloria Yoanita Hajrah Hajrah Hardi Ys Hardi Ys. Heince Andre Pua Husain Sosidi Husain Sosidi Inda, Nov Irmawati Indriani Indriani Indriani Indriani Jaya Hardi Jusman, Jusman Khairuddin Khairuddin Krisma Meylin Lasampa Laksono Trisnantoro Lisma Habiba Mappiratu Mappiratu Mappiratu Mappiratu Marsela, Anggi Moh Iqbal Moh Mirzan Moh. Mirzan Moh. Mirzan Moh. Mirzan Muh.Ricky Arisandi M. Tahili Nanda Novita Nea, Sirah Diniati Ni Ketut Sumarni Nov Irmawati Inda Nov Irmawati Inda Novaldi Novaldi Nurhaeni Nurhaeni Nurhaeni Nurhaeni Nurhaeni Nurhalisa, Sitti Pasjan Satrimafitrah Patrisia Marcevin Rengku Pratiwi Dwiasmukti Putri Wahyuni Ramadanil Riski, Mutiara Zalfa Rismawati Sikanna Rismawati Sikanna Rudy, Sri Utami Ruslan Ruslan Ruslan Sandi Purnawan Sriwulan Indriani Pea Syaiful Bahri Syamsuddin Syamsuddin Syamsuddin Sylvia Florensy Bawias Umma Fahriah Soleh Wahyu Harso WILDA YANTI Yuli Rismawati